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Molecular structure of Pt(PF3)4 by gas-phase electron diffraction

dc.contributor.authorRitz, C. L.en_US
dc.contributor.authorBartell, Lawrence S.en_US
dc.date.accessioned2006-04-07T16:30:01Z
dc.date.available2006-04-07T16:30:01Z
dc.date.issued1976-03en_US
dc.identifier.citationRitz, C. L., Bartell, L. S. (1976/03)."Molecular structure of Pt(PF3)4 by gas-phase electron diffraction." Journal of Molecular Structure 31(1): 73-76. <http://hdl.handle.net/2027.42/21811>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGS-44BMV0V-7R/2/7a5f44e0c830cb14ef1a9517c9f24570en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/21811
dc.description.abstractThe structure of Pt(PF3)4 was reinvestigated making use of a new theory of intramolecular dynamic scattering. Derived molecular parameters were insensitive to the dynamic corrections. Refinements for this tetrahedral molecule yielded rg(Pt-P) = 2.229(5) A, rg(P-F) = 1.550(4) A, and [angle]PtPF = 118.9[deg](0.4), with the indicated uncertainties representing 2.5[sigma]. Amplitudes of vibration were also determined. Diffraction patterns were consistent with freely rotating PF3 groups.en_US
dc.format.extent284400 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleMolecular structure of Pt(PF3)4 by gas-phase electron diffractionen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/21811/1/0000211.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-2860(76)80121-4en_US
dc.identifier.sourceJournal of Molecular Structureen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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