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Hydroxylation and expoxidation reactions catalyzed by synthetic metalloporphyrinates. Models related to the active oxygen species of cytochrome P-450

dc.contributor.authorGroves, John T.en_US
dc.contributor.authorKruper, William J.en_US
dc.contributor.authorNemo, Thomas E.en_US
dc.contributor.authorMyers, Richard S.en_US
dc.date.accessioned2006-04-07T17:27:19Z
dc.date.available2006-04-07T17:27:19Z
dc.date.issued1980-02en_US
dc.identifier.citationGroves, John T., Kruper, William J., Nemo, Thomas E., Myers, Richard S. (1980/02)."Hydroxylation and expoxidation reactions catalyzed by synthetic metalloporphyrinates. Models related to the active oxygen species of cytochrome P-450." Journal of Molecular Catalysis 7(2): 169-177. <http://hdl.handle.net/2027.42/23326>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6W91-4406V6D-2N/2/f484a0cb212d5ebd46f7d6c1488e7d6den_US
dc.identifier.urihttps://hdl.handle.net/2027.42/23326
dc.description.abstractIodosylbenzene has been found to react with catalytic amounts of synthetic metalloporphyrinates to give epoxides and alcohols from olefins and alkanes. Tetraphenylporphinatoiron(III) chloride (TPPFeCl) catalyzed the epoxidation of cis-stilbene to cis-stilbene oxide whereas the trans isomer was unreactive. Dioctyl protoporphyrin IX reacted with iodosylbenzene to give significant oxidation of the side chain alkyl groups. The distribution of products is interpreted to be the result of an intramolecular oxygen transfer reaction.Treatment of tetra-ortho-tolylporphinatoiron(III) chloride (TTPFeCl) with iodosylbenzene afforded a reactive intermediate which degraded the porphyrin in the absence of a oxidizable substrate. Similar oxidation of tetraphenylporphinatochromium(III) chloride with iodosylbenzene gave a stable intermediate which has been characterized as an oxochromium(V) complex.en_US
dc.format.extent446774 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleHydroxylation and expoxidation reactions catalyzed by synthetic metalloporphyrinates. Models related to the active oxygen species of cytochrome P-450en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Mich. 48109 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Mich. 48109 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Mich. 48109 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Mich. 48109 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/23326/1/0000266.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0304-5102(80)85016-4en_US
dc.identifier.sourceJournal of Molecular Catalysisen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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