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Fluorescence yield near edge spectroscopy of [pi]-bonded CO on Fe(100)

dc.contributor.authorDwyer, D. J.en_US
dc.contributor.authorRausenberger, B.en_US
dc.contributor.authorLu, J. P.en_US
dc.contributor.authorBernasek, S. L.en_US
dc.contributor.authorFischer, Daniel A.en_US
dc.contributor.authorCameron, S. D.en_US
dc.contributor.authorParker, Deborah Holmesen_US
dc.contributor.authorGland, John L.en_US
dc.date.accessioned2006-04-07T20:37:25Z
dc.date.available2006-04-07T20:37:25Z
dc.date.issued1989-12-03en_US
dc.identifier.citationDwyer, D. J., Rausenberger, B., Lu, J. P., Bernasek, S. L., Fischer, D. A., Cameron, S. D., Parker, D. H., Gland, J. L. (1989/12/03)."Fluorescence yield near edge spectroscopy of [pi]-bonded CO on Fe(100)." Surface Science 224(1-3): 375-385. <http://hdl.handle.net/2027.42/27641>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TVX-46TY2X4-1B1/2/e97f2b9387a27de42864aa7d996dbcaaen_US
dc.identifier.urihttps://hdl.handle.net/2027.42/27641
dc.description.abstractNear edge X-ray absorption fine structure (NEXAFS) spectra of CO adsorbed on the Fe(100) surface are reported. Spectra, obtained by fluorescence yield (FYNES), are presented for each of the four individual CO adsorption configurations observed on this surface. The [pi]-bonded state exhibits an unusual FYNES spectrum and polarization dependence which indicates that the molecule is either extensively rehybridized or tilted with respect to the surface normal. The FYNES spectra of each of the adsorption states directly reflect the perturbation of the carbon-oxygen bond by the surface and track systematically with the heat of adsorption.en_US
dc.format.extent727191 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleFluorescence yield near edge spectroscopy of [pi]-bonded CO on Fe(100)en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109, USAen_US
dc.contributor.affiliationotherDepartment of Chemistry, Laboratory for Surface Science and Technology, University of Maine, Orono, ME 04469, USAen_US
dc.contributor.affiliationotherDepartment of Chemistry, Laboratory for Surface Science and Technology, University of Maine, Orono, ME 04469, USAen_US
dc.contributor.affiliationotherDepartment of Chemistry, Princeton University, Princeton, NJ 08544, USAen_US
dc.contributor.affiliationotherDepartment of Chemistry, Princeton University, Princeton, NJ 08544, USAen_US
dc.contributor.affiliationotherExxon PRT, Brookhaven National Laboratory, Building 510E, Upton, NY, USAen_US
dc.contributor.affiliationotherExxon Research and Engineering, Analytical Science Laboratory, Route 22 East, Annandale, NJ 08801, USAen_US
dc.contributor.affiliationotherDepartment of Chemistry, University of Colorado at Boulder, Boulder, CO 80309, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/27641/1/0000017.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0039-6028(89)90921-7en_US
dc.identifier.sourceSurface Scienceen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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