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Preparation and reactions of 1,1-zinc, boron and 1,1-copper, boron alkenyl bimetallics

dc.contributor.authorWaas, Jack R.en_US
dc.contributor.authorSidduri, Achyutha Raoen_US
dc.contributor.authorKnochel, Paulen_US
dc.date.accessioned2006-04-10T15:10:27Z
dc.date.available2006-04-10T15:10:27Z
dc.date.issued1992-06-23en_US
dc.identifier.citationWaas, Jack R., Sidduri, AchyuthaRao, Knochel, Paul (1992/06/23)."Preparation and reactions of 1,1-zinc, boron and 1,1-copper, boron alkenyl bimetallics." Tetrahedron Letters 33(26): 3717-3720. <http://hdl.handle.net/2027.42/29979>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6THS-49394S0-6/2/2db9963a5cf88841a9a9ef9eb6897db2en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/29979
dc.description.abstractPinacol [alpha]-iodoalkenylboronates 8, readily prepared by the hydroboration of 1-iodoalkynes, were converted to 1,1-bimetallics of boron and zinc or copper which react with a wide range of electrophiles affording polyfunctional boronic esters. After H2O2 oxidation (30% H2O2, sat.aq. NaOAc), polyfunctional ketones were produced in good to excellent yields.en_US
dc.format.extent347808 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titlePreparation and reactions of 1,1-zinc, boron and 1,1-copper, boron alkenyl bimetallicsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumWillard H. Dow Laboratories, Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USAen_US
dc.contributor.affiliationumWillard H. Dow Laboratories, Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USAen_US
dc.contributor.affiliationumWillard H. Dow Laboratories, Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/29979/1/0000343.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0040-4039(92)80007-7en_US
dc.identifier.sourceTetrahedron Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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