Vibrational spectroscopic studies of -alternating valine peptides
dc.contributor.author | Naik, Vaman M. | en_US |
dc.date.accessioned | 2006-04-10T15:15:29Z | |
dc.date.available | 2006-04-10T15:15:29Z | |
dc.date.issued | 1992-04-24 | en_US |
dc.identifier.citation | Naik, Vaman M. (1992/04/24)."Vibrational spectroscopic studies of -alternating valine peptides." Vibrational Spectroscopy 3(2): 105-113. <http://hdl.handle.net/2027.42/30098> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6THW-4490280-K/2/25c71da9e70232176ae833f69340a27c | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/30098 | |
dc.description.abstract | Raman and infrared spectra of Boc-(Val--Val)n-OMe [(-Val)n], with n = 4, 6 and 8, were obtained in crystalline and solution states. Based on predictions from normal-mode calculations of a number of relevant single- and double-stranded [beta]-helix conformations, structures were assigned for the three oligopeptides under the above-mentioned conditions. In the crystalline state, all three oligopeptides have a double-stranded [short up arrow][downwards arrow] [beta]5.6 structure. In cyclohexane and in chloroform, the [short up arrow][downwards arrow] [beta]5.6 structure predominates for (-Val)4. In chloroform the (-Val)6 has a [beta]4.4 structure. (-Val)8 in cyclohexane and in chloroform exists predominantly in a [short up arrow][downwards arrow] [beta]5.6 structure together with some [beta]4.4. | en_US |
dc.format.extent | 1201610 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Vibrational spectroscopic studies of -alternating valine peptides | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Natural Sciences, University of Michigan-Dearborn, Dearborn, MI 48128 USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/30098/1/0000470.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0924-2031(92)80003-K | en_US |
dc.identifier.source | Vibrational Spectroscopy | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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