The polarography of aqueous pertechnetate ion
dc.contributor.author | Rulfs, Charles L. | en_US |
dc.contributor.author | Pacer, Richard A. | en_US |
dc.contributor.author | Anderson, Alfred | en_US |
dc.date.accessioned | 2006-04-17T16:13:27Z | |
dc.date.available | 2006-04-17T16:13:27Z | |
dc.date.issued | 1967 | en_US |
dc.identifier.citation | Rulfs, Charles L., Pacer, Richard, Anderson, Alfred (1967)."The polarography of aqueous pertechnetate ion." Journal of Electroanalytical Chemistry 15(): 61-66. <http://hdl.handle.net/2027.42/33380> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TGB-44X74D5-R/2/2005c5e6c5e7c20ee36cf8faf90bba4e | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/33380 | |
dc.description.abstract | The polarographic reduction of pertechnetate in 4-0.01 M perchloric acid media takes place in two stages. The E of the more positive wave at +0.10 to -0.17 V S.C.E. is pH-dependent, E=0.06-0.106 pH. Coulometry indicates a four-electron process, TcO4-+8 H++4 e-=Tc3+. A second wave at -0.73 V appears to involve the three-electron step (III) --> (O).Technetium electrodeposits into mercury in a finely-divided form. Centrifugation of the product indicates particles of 10-5-10-6 cm diameter. A freshly-prepared technetium "amalgam" dropping-electrode showed no anodic polarographic activity in 0.1M HCl from -0.8 to +0.05 V S.C.E., indicating little solubility, or true amalgam character. | en_US |
dc.format.extent | 511865 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | The polarography of aqueous pertechnetate ion | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/33380/1/0000778.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0022-0728(67)85008-3 | en_US |
dc.identifier.source | Journal of Electroanalytical Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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