Organosilanetriols: model compounds and potential precursors for metal-containing silicate assemblies Dedicated to Professor Manfred Meisel on the occasion of his 60th birthday
dc.contributor.author | Murugavel, Ramaswamy | en_US |
dc.contributor.author | Bhattacharjee, Manish | en_US |
dc.contributor.author | Roesky, Herbert W. | en_US |
dc.date.accessioned | 2006-04-19T13:48:06Z | |
dc.date.available | 2006-04-19T13:48:06Z | |
dc.date.issued | 1999-04 | en_US |
dc.identifier.citation | Murugavel, Ramaswamy; Bhattacharjee, Manish; Roesky, Herbert W. (1999)."Organosilanetriols: model compounds and potential precursors for metal-containing silicate assemblies Dedicated to Professor Manfred Meisel on the occasion of his 60th birthday ." Applied Organometallic Chemistry 13(4): 227-243. <http://hdl.handle.net/2027.42/34738> | en_US |
dc.identifier.issn | 0268-2605 | en_US |
dc.identifier.issn | 1099-0739 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/34738 | |
dc.description.abstract | The chemistry of silanols and related amino-silanes is a topic of current interest in view of their possible applications as building blocks in materials science. In particular, discrete silanetriols and triaminosilanes are useful synthons for the generation of three-dimensional metallasiloxanes. Research work in our laboratory in this area is centered around the synthesis of stable silanetriols and studies of their reactivity toward various metal precursors. Starting from a series of stable N -bonded silanetriols and triaminosilanes, we have been able to synthesize a rangeof metallasiloxanes and iminosilicates showing novel structural features. Elements such as aluminum, gallium, indium, titanium, zirconium, tantalum, tin and rhenium have been incorporated in these heterosiloxane frameworks. Both the metallasiloxanes and iminosilicates have been extensively characterized by means of IR and NMR spectroscopy and by single-crystal X-ray diffraction studies in representative cases. A (cobalt carbonyl cluster)-anchored aluminosiloxane is an efficient catalyst for hydroformylation reactions of olefins. Many of these metallasiloxanes and iminosilicates contain hydrolyzable functionalities such as M–C, M–OR and Si–N bonds, providing a possibility of using these compounds as starting materials for the preparation of supramolecular cage structures and synthetic zeolites under mild conditions. Copyright © 1999 John Wiley & Sons, Ltd. | en_US |
dc.format.extent | 284406 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Ltd. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Industrial Chemistry and Chemical Engineering | en_US |
dc.title | Organosilanetriols: model compounds and potential precursors for metal-containing silicate assemblies Dedicated to Professor Manfred Meisel on the occasion of his 60th birthday | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationother | Department of Chemistry, Indian Institute of Technology, Powai, Bombay-400 076, India | en_US |
dc.contributor.affiliationother | Institut fÜr Anorganische Chemie der UniversitÄt GÖttingen, Tammannstrasse 4, D-37077 GÖttingen, Germany | en_US |
dc.contributor.affiliationother | Institut fÜr Anorganische Chemie der UniversitÄt GÖttingen, Tammannstrasse 4, D-37077 GÖttingen, Germany ; Institut fÜr Anorganische Chemie der UniversitÄt GÖttingen, Tammannstrasse 4, D-37077 GÖttingen, Germany | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/34738/1/842_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/(SICI)1099-0739(199904)13:4<227::AID-AOC842>3.0.CO;2-0 | en_US |
dc.identifier.source | Applied Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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