Functionalized polyhedral oligosilsesquioxane (POSS) macromers: new graftable POSS hydride, POSS α-olefin, POSS epoxy, and POSS chlorosilane macromers and POSS–siloxane triblocks
dc.contributor.author | Shockey, Edward G. | en_US |
dc.contributor.author | Bolf, Alan G. | en_US |
dc.contributor.author | Jones, Paul F. | en_US |
dc.contributor.author | Schwab, Joseph J. | en_US |
dc.contributor.author | Chaffee, Kevin P. | en_US |
dc.contributor.author | Haddad, Timothy S. | en_US |
dc.contributor.author | Lichtenhan, Joseph D. | en_US |
dc.date.accessioned | 2006-04-19T13:48:20Z | |
dc.date.available | 2006-04-19T13:48:20Z | |
dc.date.issued | 1999-04 | en_US |
dc.identifier.citation | Shockey, Edward G.; Bolf, Alan G.; Jones, Paul F.; Schwab, Joseph J.; Chaffee, Kevin P.; Haddad, Timothy S.; Lichtenhan, Joseph D. (1999)."Functionalized polyhedral oligosilsesquioxane (POSS) macromers: new graftable POSS hydride, POSS α-olefin, POSS epoxy, and POSS chlorosilane macromers and POSS–siloxane triblocks." Applied Organometallic Chemistry 13(4): 311-327. <http://hdl.handle.net/2027.42/34743> | en_US |
dc.identifier.issn | 0268-2605 | en_US |
dc.identifier.issn | 1099-0739 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/34743 | |
dc.description.abstract | A series of polyhedral oligomeric silsesquioxanes (POSS) monomers bearing silane or α-olefin substituents have been prepared and their chemistry explored. Both the POSS silanes and α-olefin monomers readily participate in hydrosilation chemistry and have been used as starting materials for the preparation of POSS sol–gel-type reagents. Similarly, POSS silanes and α-olefins are reactive towards silane- and olefin-functionalized polymers, which makes them useful as grafting reagents. The utility of these reagents as graftable monomers was demonstrated by synthesis of a series of POSS–siloxane–POSS triblock polymers. Thermaland X-ray diffraction (XRD) characterization of the triblock polymers was performed in order to examine how the length of the siloxane segment affects the properties of the polymer. The POSS α-olefin monomers were found tobe unreactive with respect to Ziegler–Natta polymerization. The reaction of POSS α-olefins with m -chloroperbenzoic acid (MCPBA) to give POSS epoxides was demonstrated and the thermal stability of the POSS epoxides determined. Copyright © 1999 John Wiley & Sons, Ltd. | en_US |
dc.format.extent | 189580 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Ltd. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Industrial Chemistry and Chemical Engineering | en_US |
dc.title | Functionalized polyhedral oligosilsesquioxane (POSS) macromers: new graftable POSS hydride, POSS α-olefin, POSS epoxy, and POSS chlorosilane macromers and POSS–siloxane triblocks | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationother | Hughes STX Corporation, Phillips Laboratory, Propulsion Directorate, Edwards AFB, CA 93524-7680, USA | en_US |
dc.contributor.affiliationother | Hughes STX Corporation, Phillips Laboratory, Propulsion Directorate, Edwards AFB, CA 93524-7680, USA | en_US |
dc.contributor.affiliationother | Phillips Laboratory, Propulsion Directorate, Edwards AFB, CA 93524-7680, USA | en_US |
dc.contributor.affiliationother | Hughes STX Corporation, Phillips Laboratory, Propulsion Directorate, Edwards AFB, CA 93524-7680, USA ; Hybrid Plastics, 18237 Mount Baldy Circle, Fountain Valley, CA 92708-6117, USA | en_US |
dc.contributor.affiliationother | Phillips Laboratory, Propulsion Directorate, Edwards AFB, CA 93524-7680, USA | en_US |
dc.contributor.affiliationother | Hughes STX Corporation, Phillips Laboratory, Propulsion Directorate, Edwards AFB, CA 93524-7680, USA | en_US |
dc.contributor.affiliationother | Hughes STX Corporation, Phillips Laboratory, Propulsion Directorate, Edwards AFB, CA 93524-7680, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/34743/1/847_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/(SICI)1099-0739(199904)13:4<311::AID-AOC847>3.0.CO;2-1 | en_US |
dc.identifier.source | Applied Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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