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Vibrational analysis of chain folding in polyethylene crystals

dc.contributor.authorTasumi, M.en_US
dc.contributor.authorKrimm, Samuelen_US
dc.date.accessioned2006-04-28T18:15:29Z
dc.date.available2006-04-28T18:15:29Z
dc.date.issued1968-05en_US
dc.identifier.citationTasumi, M.; Krimm, S. (1968)."Vibrational analysis of chain folding in polyethylene crystals." Journal of Polymer Science Part A-2: Polymer Physics 6(5): 995-1010. <http://hdl.handle.net/2027.42/38768>en_US
dc.identifier.issn0449-2978en_US
dc.identifier.issn1542-9377en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/38768
dc.description.abstractThe vibration frequencies of a polyethylene crystal lattice have been computed for various structures in which a fully deuterated chain is mixed with a normal chain. Intermolecular potential functions previously developed by the authors were used in the calculation. It is shown that such structures make it possible to distinguish experimentally between chain folding in the (110) plane and folding parallel to the (100) plane. Calculations have also been done for a regular polymer of (CH 2 CD 2 ). Such a structure would permit the determination of the parity of the number of methylene groups in the fold.en_US
dc.format.extent694753 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherJohn Wiley & Sons, Inc.en_US
dc.subject.otherPhysicsen_US
dc.subject.otherPolymer and Materials Scienceen_US
dc.titleVibrational analysis of chain folding in polyethylene crystalsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumHarrison M. Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan 48104en_US
dc.contributor.affiliationumHarrison M. Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan 48104en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/38768/1/160060518_ftp.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1002/pol.1968.160060518en_US
dc.identifier.sourceJournal of Polymer Science Part A-2: Polymer Physicsen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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