Nucleic acid base grafted polyethylenimine. Cytosyl pendant groups synthesis and characterization
dc.contributor.author | Chu, Vano P. | en_US |
dc.contributor.author | Overberger, Charles Gilbert | en_US |
dc.date.accessioned | 2006-04-28T18:17:33Z | |
dc.date.available | 2006-04-28T18:17:33Z | |
dc.date.issued | 1986-10 | en_US |
dc.identifier.citation | Chu, V. P.; Overberger, C. G. (1986)."Nucleic acid base grafted polyethylenimine. Cytosyl pendant groups synthesis and characterization." Journal of Polymer Science Part A: Polymer Chemistry 24(10): 2657-2693. <http://hdl.handle.net/2027.42/38809> | en_US |
dc.identifier.issn | 0887-624X | en_US |
dc.identifier.issn | 1099-0518 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38809 | |
dc.description.abstract | Poly(N-acyl ethylenimine) of various molecular weights was synthesized by the cationic ring-opening polymerization of 2-H-2-oxazoline and 2-methyl-2-oxazoline. Acid hydrolysis afforded the linear poly(ethylenimine) which was used in the following grafting reactions. Vapor pressure osmometry, gel permeation chromatography and viscosity measurements were used to characterize the polymers synthesized. Potassium 2-(cytos-1-yl)propanoate and potassium 3-(cytos-1-yl)butanoate were synthesized in good yield from the nucleic acid base. These cytosyl pendant groups were grafted onto the poly(ethylenimine) using 4-chloro-1-(4-chlorobenzenesulfonyl)benzotriazole, 93% graft, and norborn-5-ene-2,3-carboximido diphenyl phosphate, 70% graft. Grafting of the t -butoxycarbonyl and n -butoxycarbonyl protected cytosyl pendant groups resulted in a 47% and 40% graft, respectively. | en_US |
dc.format.extent | 2152510 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Inc. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Polymer and Materials Science | en_US |
dc.title | Nucleic acid base grafted polyethylenimine. Cytosyl pendant groups synthesis and characterization | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry and Macromolecular Research Center, The University of Michigan, Ann Arbor, MI 48109 | en_US |
dc.contributor.affiliationum | Department of Chemistry and Macromolecular Research Center, The University of Michigan, Ann Arbor, MI 48109 ; Department of Chemistry and Macromolecular Research Center, The University of Michigan, Ann Arbor, MI 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38809/1/080241022_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/pola.1986.080241022 | en_US |
dc.identifier.source | Journal of Polymer Science Part A: Polymer Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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