Cyclopolymerization of ( E,E ) - [6.2]paracyclophane-1,5-diene
dc.contributor.author | Longone, Daniel T. | en_US |
dc.contributor.author | Glatzhofer, Daniel T. | en_US |
dc.date.accessioned | 2006-04-28T18:18:14Z | |
dc.date.available | 2006-04-28T18:18:14Z | |
dc.date.issued | 1986-08 | en_US |
dc.identifier.citation | Longone, Daniel T.; Glatzhofer, Daniel T. (1986)."Cyclopolymerization of ( E,E ) - [6.2]paracyclophane-1,5-diene." Journal of Polymer Science Part A: Polymer Chemistry 24(8): 1725-1733. <http://hdl.handle.net/2027.42/38822> | en_US |
dc.identifier.issn | 0887-624X | en_US |
dc.identifier.issn | 1099-0518 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38822 | |
dc.description.abstract | Polymerization of ( E , E )-[6.2]paracyclophane-1,5-diene proceeds by an intra–intermolecular mechanism to give a polymer containing a [3.2]paracyclophane in the repeat unit. Polymerization occurs with either free radical or cationic initiation; anionic initiation was unsuccessful. Cationic polymerization is favored and appears to proceed through a stabilized carbonium ion intermediate. Spectroscopic and model compound studies are consistent with the proposed polymer structure. Thermal analyses of the polymer indicate a complex thermooxidative behavior in the presence of oxygen, while depolymerization occurs above about 400°C in an inert atmosphere. | en_US |
dc.format.extent | 497516 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Inc. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Polymer and Materials Science | en_US |
dc.title | Cyclopolymerization of ( E,E ) - [6.2]paracyclophane-1,5-diene | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38822/1/080240801_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/pola.1986.080240801 | en_US |
dc.identifier.source | Journal of Polymer Science Part A: Polymer Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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