Negative thermal expansion artificial material from iron-nickel alloys by oxide co-extrusion with reductive sintering

Abstract

Objects with a fine-scale design of bimetallic beams can display negative thermal expansion. Based on a unit cell design for a negative expansion, produced by Optimal Design methods, we fabricate a thermoelastic “artificial material” using coextrusion of iron and nickel oxides, followed by reductive sintering. A bulk sample with 162 unit cells from Fe-60Ni and Fe-36Ni alloys displayed a thermal expansion coefficient of −3.0 × 10 −6 /°C, in agreement with the optimal design prediction.