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Green Medium for the Hydrolysis of 5-Cyanovaleramide

dc.contributor.authorDuan, P. -G.en_US
dc.contributor.authorLi, Shuangen_US
dc.contributor.authorYang, Yanen_US
dc.contributor.authorWang, Zhi-Zhongen_US
dc.date.accessioned2009-05-04T18:26:50Z
dc.date.available2010-07-06T14:30:32Zen_US
dc.date.issued2009-05en_US
dc.identifier.citationDuan, P.-G.; Li, S.; Yang, Y.; Wang, Z.-Z. (2009). "Green Medium for the Hydrolysis of 5-Cyanovaleramide." Chemical Engineering & Technology - CET 32(5): 771-777. <http://hdl.handle.net/2027.42/62148>en_US
dc.identifier.issn0930-7516en_US
dc.identifier.issn1521-4125en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/62148
dc.description.abstractHydrolysis of 5-cyanovaleramide (5-CVAM) in near-critical water without the addition of any catalyst has been demonstrated. The results demonstrated that the cyano group at one end of the carbon of 5-CVAM is more reactive than the amide group at the other end, under the same experimental conditions. The relations between 5-CVAM concentration and residence time revealed that hydrolysis of 5-CVAM shows second-order reaction kinetics in the investigated temperature range. The rate constants, average apparent activation energy and pre-exponential factor were evaluated according to the Arrhenius equation. Based on the experimental results, a carbon balance was calculated, and a hydrolysis reaction scheme of 5-CVAM was proposed.en_US
dc.format.extent181556 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.publisherWILEY-VCH Verlagen_US
dc.subject.otherChemistryen_US
dc.subject.otherIndustrial Chemistry and Chemical Engineeringen_US
dc.titleGreen Medium for the Hydrolysis of 5-Cyanovaleramideen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumShanghai Key Laboratory of Green Chemistry and Green Process, Department of Chemistry, East China Normal University, Shanghai, P.R. China ; Department of Chemical Engineering, The University of Michigan, Ann Arbor, USAen_US
dc.contributor.affiliationotherShanghai Key Laboratory of Green Chemistry and Green Process, Department of Chemistry, East China Normal University, Shanghai, P.R. Chinaen_US
dc.contributor.affiliationotherShanghai Key Laboratory of Green Chemistry and Green Process, Department of Chemistry, East China Normal University, Shanghai, P.R. Chinaen_US
dc.contributor.affiliationotherShanghai Key Laboratory of Green Chemistry and Green Process, Department of Chemistry, East China Normal University, Shanghai, P.R. Chinaen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/62148/1/771_ftp.pdf
dc.identifier.doi10.1002/ceat.200800607en_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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