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Ketone Hydrosilylation with Sugar Silanes Followed by Intramolecular Aglycone Delivery: An Orthogonal Glycosylation Strategy

dc.contributor.authorBuchan, Zachary Allenen_US
dc.contributor.authorBader, Scott J.en_US
dc.contributor.authorMontgomery, Johnen_US
dc.date.accessioned2009-07-06T15:40:54Z
dc.date.available2010-08-02T17:56:56Zen_US
dc.date.issued2009-06-15en_US
dc.identifier.citationBuchan, Zachary 14A.; Bader, Scott 14J.; Montgomery, John (2009). "Ketone Hydrosilylation with Sugar Silanes Followed by Intramolecular Aglycone Delivery: An Orthogonal Glycosylation Strategy We acknowledge support from the National Institutes of Health (GM 57014) and from Thermo Fisher for a pilot project grant administered by the University of Michigan Life Sciences Institute. ." Angewandte Chemie International Edition 48(26): 4840-4844. <http://hdl.handle.net/2027.42/63086>en_US
dc.identifier.issn1433-7851en_US
dc.identifier.issn1521-3773en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/63086
dc.description.abstractGettin' a little sugar—no alcohol required : A procedure for the direct glycosylation of ketones without a hydroxy intermediate enables the site-selective glycosylation of hydroxyketones at the ketone or the alcohol functionality without the use of protecting groups on the aglycone (see scheme). Site selectivity is controlled by the catalyst structure in hydrosilylation and dehydrogenative silylation reactions with sugar silanes. Bn=benzyl.en_US
dc.format.extent2514303 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.publisherWILEY-VCH Verlagen_US
dc.subject.otherChemistryen_US
dc.subject.otherGeneral Chemistryen_US
dc.titleKetone Hydrosilylation with Sugar Silanes Followed by Intramolecular Aglycone Delivery: An Orthogonal Glycosylation Strategyen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (USA), Fax: (+1) 734-763-1106, http://www.umich.edu/∼jmgroupen_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (USA), Fax: (+1) 734-763-1106, http://www.umich.edu/∼jmgroupen_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (USA), Fax: (+1) 734-763-1106, http://www.umich.edu/∼jmgroup ;en_US
dc.identifier.pmid19492383en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/63086/1/anie_200901666_sm_miscellaneous_information.pdf
dc.identifier.doi10.1002/anie.200901666en_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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