Show simple item record

Kinetics and Mechanism of Hydroxyapatite Crystal Dissolution in Weak Acid Buffers Using the Rotating Disk Method

dc.contributor.authorWu, Maw-Shengen_US
dc.contributor.authorHiguchi, William I.en_US
dc.contributor.authorFox, Jeffrey L.en_US
dc.contributor.authorFriedman, Michaelen_US
dc.date.accessioned2010-04-13T19:12:00Z
dc.date.available2010-04-13T19:12:00Z
dc.date.issued1976en_US
dc.identifier.citationWu, Maw-Sheng; Higuchi, William; Fox, Jeffrey; Friedman, Michael (1976). "Kinetics and Mechanism of Hydroxyapatite Crystal Dissolution in Weak Acid Buffers Using the Rotating Disk Method." Journal of Dental Research 3(55): 496-505. <http://hdl.handle.net/2027.42/67157>en_US
dc.identifier.issn0022-0345en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/67157
dc.description.abstractThe dissolution rates of synthetic hydroxyapatite pellets under sink conditions were measured using the rotating disk method. The experimental data were analyzed by means of a physical model that yielded an ionic activity product of KHAP = a10Ca2+ a6 PO4 3- a2OH- = 1 × 10-124.5±1.0 that was found to govern the dissolution reaction. Also, a surface resistance factor of k' equal to about 174 sec/cm was deduced from the data.en_US
dc.format.extent3108 bytes
dc.format.extent586620 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherSAGE Publicationsen_US
dc.titleKinetics and Mechanism of Hydroxyapatite Crystal Dissolution in Weak Acid Buffers Using the Rotating Disk Methoden_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelDentistryen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumCollege of Pharmacy, The University of Michigan, Ann Arbor, Michigan 48109, USAen_US
dc.contributor.affiliationumCollege of Pharmacy, The University of Michigan, Ann Arbor, Michigan 48109, USAen_US
dc.contributor.affiliationumCollege of Pharmacy, The University of Michigan, Ann Arbor, Michigan 48109, USAen_US
dc.contributor.affiliationumCollege of Pharmacy, The University of Michigan, Ann Arbor, Michigan 48109, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/67157/2/10.1177_00220345760550033201.pdf
dc.identifier.doi10.1177/00220345760550033201en_US
dc.identifier.citedreferenceHiguchi, W.I. ; Gray, J.A.; Hefferren, J.J.; and Patel, P.R.: Mechanism of Enamel Dissolution in Acid Buffers, J Dent Res 44: 330-341, 1965.en_US
dc.identifier.citedreferenceHiguchi, W.I. ; Patel, P.R.; and Hefferren, J.J.: Quantitation of Enamel Demineralization Mechanisms: II, J Pharm Sci 54: 587-590, 1965.en_US
dc.identifier.citedreferenceHiguchi, W.I. ; Mir, N.A.; Patel, P.R.; Becker, J.W.; and Hefferren, J.J.: Quantitation of Enamel Demineralization Mechanisms : III. A Critical Examination of the Hydroxyapatite Model, J Dent Res 48: 396-409, 1969.en_US
dc.identifier.citedreferenceMir, N.A., and Higuchi, W.I.: The Mechanism Of Action of Solution Fluoride upon the Demineralization Rate of Human Enamel, Arch Oral Biol 14: 901-920, 1969.en_US
dc.identifier.citedreferenceAvnimelich, Y.; Moreno, E.C.; and Brown, W.E.: Solubility and Surface Properties of Finely Divided Hydroxyapatite, J Res Nat Bureau Standards 77A (suppl) : 149-155, 1972.en_US
dc.identifier.citedreferenceMoreno, E.C. ; Gregory, T.M.; and Brown, W.E.: Preparation and Solubility of Hydroxyapatite, J Res Nat Bureau Standards 72A (suppl) : 773-782, 1968.en_US
dc.identifier.citedreferenceNancollas, G.H.: Physicochemistry of Enamel Demineralization and Remineralization, J Dent Res 53: 297-302, 1974.en_US
dc.identifier.citedreferenceHicuchi, W.I.: Diffusion Model Useful in Biopharmaceutics, J Pharm Sci 56: 315-324, 1967.en_US
dc.identifier.citedreferenceFrank-Kamenetskii, D.A.: Diffusion and Heat Transfer in Chemical Kinetics, New York : Plenum Press, 1969, p 103.en_US
dc.identifier.citedreferenceLevich, V.G.: Physicochemical Hydrodynamics, New York: Prentice-Hall, Inc., 1962.en_US
dc.identifier.citedreferenceGee, A.; Domingues, L.P.; and Deitz, V.R.: Determination of Inorganic Constituents in Sugar, Anal Chem 26: 1487-1492, 1954.en_US
dc.identifier.citedreferenceWu, M.S., and Prakongpan, S.: Unpublished data, 1975.en_US
dc.identifier.citedreferenceJohnson, N.W. ; Poole, D.F.G.; and Tyler, J.Z.: Factors Affecting the Differential Dissolution of Human Enamel in Acid and EDTA: A Scanning Electron Microscope Study, Arch Oral Biol 16: 384-392, 1971.en_US
dc.identifier.citedreferenceNichol, T.; Judd, G.; and Ansell, G.S.: A Two-Stage Model for Human Enamel Demineralization as Determined by Scanning Electron Microscope Analysis, J Dent Res 52: 487-493, 1973.en_US
dc.identifier.citedreferenceJohnson, N.W. : Differences in the Shape of Human Enamel Crystallites after Partial Destruction by Caries, EDTA and Various Acids, Arch Oral Biol 11: 1421-1423, 1966.en_US
dc.identifier.citedreferenceGray, J.A.: Kinetics of the Dissolution of Human Dental Enamel in Acid, J Dent Res 41: 633-645, 1962.en_US
dc.identifier.citedreferenceDedhiya, M.G. ; Young, F.; Hefferren, J.J.; and Higuchi, W.I.: The Inhibition of Hydroxyapatite Dissolution by Sr2+ and Mg2+ under Partial Saturated Conditions in Solutions Containing F-, J Dent Res (Special Issue) : Abstract No. 204, 1974.en_US
dc.identifier.citedreferenceYoung, F.; Fawzi, M.; Dedhiya, M.G.; Wu, M.S.; and Higuchi, W.I.: Dual Mechanisms for Dental Enamel Dissolution in Acid Buffers, J Dent Res (Special Issue) : Abstract No. 576, 1974.en_US
dc.identifier.citedreferenceRobinson, R.A., and Stokes, R.H.: Electrolyte Solutions, London: Butterworth, 1959.en_US
dc.identifier.citedreferenceGregory, T.M. ; Moreno, E.C.; and Brown, W.E.: Solubility of Ca HPO4 2H2O in the System Ca (OH) 2-H3PO4-H2O at 5, 15, 25 and 37.5°C, J Res Nat Bureau Standards 74A: 461-475, 1970.en_US
dc.identifier.citedreferenceWu, M.S.: Kinetics of Hydroxyapatite Dissolution and Influence of Foreign Ions Under Sink Conditions, Ph D thesis, Ann Arbor, Michigan : University of Michigan, 1975.en_US
dc.identifier.citedreferenceBray, W.C., and Winninghoff, W.J. : The Effect of Salts on the Solubility of Other Salt: III. Solubility of Thallous Chloride in Solution of Potassium Nitrate, Potassium Sulfate and Thallous Sulfate at 25°C, J Am Chem Soc 33: 1663-1672, 1911.en_US
dc.identifier.citedreferenceDedhiya, M.G. ; Young, F.; and Higuchi, W.I.: Mechanism for the Retardation of the Acid Dissolution Rate of Hydroxyapatite by Strontium, J Dent Res 52: 1097-1109, 1973.en_US
dc.identifier.citedreferenceDedhiya, M.G. ; Young, F.; and Higuchi, W.I.: Mechanism of Hydroxyapatite Dissolution : The Synergistic Effects of Solution Fluoride, J Phys Chem 78: 1273-1279, 1974.en_US
dc.identifier.citedreferenceLiang, Z.S., and Higuchi, W.I.: Kinetics and Mechanism of the Reaction Between Hydroxyapatite and Fluoride in Aqueous Acid Media, J Phys Chem 77: 1704-1710, 1973.en_US
dc.identifier.citedreferenceHodes, B.: Dissolution Rate Studies of Some Calcium Phosphates Using the Rotating Disk Method, Ph D thesis, Ann Arbor, Michigan: University of Michigan, 1971.en_US
dc.identifier.citedreferenceHwu, R.C. : Kinetics and Mechanism of Dicalcium Phosphate Dihydrate to Fluoroapatite Conversion in Fluoride Solutions, Ph D thesis, Ann Arbor, Michigan: University of Michigan, 1974.en_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


Files in this item

Show simple item record

Remediation of Harmful Language

The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.

Accessibility

If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.