Quasielastic Scattering of Thermal Neutrons by CH3OH and CH3SH
dc.contributor.author | Sampson, Thomas E. | en_US |
dc.contributor.author | Carpenter, John M. | en_US |
dc.date.accessioned | 2010-05-06T22:03:12Z | |
dc.date.available | 2010-05-06T22:03:12Z | |
dc.date.issued | 1969-12-15 | en_US |
dc.identifier.citation | Sampson, Thomas E.; Carpenter, John M. (1969). "Quasielastic Scattering of Thermal Neutrons by CH3OH and CH3SH." The Journal of Chemical Physics 51(12): 5543-5546. <http://hdl.handle.net/2027.42/70369> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/70369 | |
dc.description.abstract | We report measurements of the line broadening of thermal neutrons quasielastically scattered from room temperature methyl alcohol and methyl mercaptan in the liquid phase. The linewidths for CH3SH are found to be approximately twice those of CH3OH. This is interpreted to be additional evidence of the relative freedom of molecular motions and lack of hydrogen bonding in CH3SH. The linewidth data are discussed in terms of the simple diffusion model, and for methanol, in terms of a globular diffusion model. For methanol a diffusion constant of 3.25 × 10−5 cm2sec−1 and a diffusing globule mass of ∼3.5 molecules are in agreement with the data. An upper limit of D = 6.5 × 10−5cm2sec−1D=6.5×10−5cm2sec−1 is found for the diffusion constant of CH3SH. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 327723 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Quasielastic Scattering of Thermal Neutrons by CH3OH and CH3SH | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Nuclear Engineering, The University of Michigan, Ann Arbor, Michigan | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/70369/2/JCPSA6-51-12-5543-1.pdf | |
dc.identifier.doi | 10.1063/1.1671981 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
dc.identifier.citedreference | K. E. Larsson, Thermal Neutron Scattering, P. A. Egelstaff, Ed. (Academic Press Inc., New York, 1965), pp. 347–413. | en_US |
dc.identifier.citedreference | K. Krynicki and J. G. Powles, Proc. Phys. Soc. (London) 83, 983 (1964). | en_US |
dc.identifier.citedreference | D. H. Saunderson and V. S. Rainey, Inelastic Scattering of Neutrons in Solids and Liquids (International Atomic Energy Agency, Vienna, 1963), Vol. 1, p. 413. | en_US |
dc.identifier.citedreference | B. K. Aldren, R. C. Eden, and J. W. White, Discussions Faraday Soc. 43, 169 (1967). | en_US |
dc.identifier.citedreference | T. E. Sampson and J. M. Carpenter, Neutron Inelastic Scattering (International Atomic Energy Agency, Vienna, 1968), Vol. 1, p. 491. | en_US |
dc.identifier.citedreference | Thomas E. Sampson, Ph.D. thesis, University of Michigan, 1969 (unpublished). | en_US |
dc.identifier.citedreference | George H. Vineyard, Phys. Rev. 110, 999 (1958). | en_US |
dc.identifier.citedreference | P. A. Egelstaff, S. J. Cocking, and T. K. Alexander, Inelastic Scattering of Neutrons in Solids and Liquids (International Atomic Energy Agency, Vienna, 1961), p. 165. | en_US |
dc.identifier.citedreference | R. M. Brugger, Thermal Neutron Scattering, P. A. Egelstaff, Ed. (Academic Press Inc., New York, 1965), pp. 76–80. | en_US |
dc.identifier.citedreference | P. F. Zweifel, “Neutron Cross Sections and Spectra Studies,” University of Michigan, Rept. 03712‐5‐P, 1964. | en_US |
dc.identifier.citedreference | E. A. Straker, J. Chem. Phys. 43, 4134 (1965). | en_US |
dc.identifier.citedreference | E. A. Straker, Ph.D. thesis, University of Michigan, 1965 (unpublished). | en_US |
dc.identifier.citedreference | T. E. Sampson and J. M. Carpenter, Nucl. Instr. Methods 50, 179 (1967). | en_US |
dc.identifier.citedreference | K. S. Singwi and A. Sjölander, Phys. Rev. 119, 863 (1960). | en_US |
dc.identifier.citedreference | K.‐E. Larsson and L. Bergstedt, Phys. Rev. 151, 117 (1966). | en_US |
dc.identifier.citedreference | U. Dahlborg, B. Friberg, K. E. Larsson, and E. Pirkmajer, Neutron Inelastic Scattering (International Atomic Energy Agency, Vienna, 1968), Vol. 1, p. 581. | en_US |
dc.identifier.citedreference | K. E. Larsson and U. Dahlborg, Physica 30, 156 (1964). | en_US |
dc.identifier.citedreference | E. L. Slaggie, Neutron Thermalization and Reactor Spectra (International Atomic Energy Agency, Vienna, 1968), Vol. 1, p. 311. | en_US |
dc.identifier.citedreference | E. L. Slaggie, Nucl. Sci. Eng. 30, 199 (1967). | en_US |
dc.identifier.citedreference | R. M. Brugger, Nucl. Sci. Eng. 33, 187 (1968). | en_US |
dc.identifier.citedreference | L. A. DeGraaf, thesis, Technische Hogeschool, Delft, The Netherlands, 1967 (unpublished). | en_US |
dc.identifier.citedreference | R. E. Rathbun and A. L. Babb, J. Phys. Chem. 65, 1072 (1961). | en_US |
dc.identifier.citedreference | P. A. Egelstaff, Advan. Phys. 11, 203 (1962). | en_US |
dc.identifier.citedreference | P. A. Egelstaff, An Introduction to the Liquid State (Academic Press Inc., New York, 1967), p. 127. | en_US |
dc.identifier.citedreference | B. Jacobson, Acta Chem. Scand. 9, 997 (1955). | en_US |
dc.identifier.citedreference | E. D. Becker, J. Chem. Phys. 31, 269 (1959). | en_US |
dc.identifier.citedreference | A. Ens and F. E. Murray, Can. J. Chem. 35, 170 (1957). | en_US |
dc.identifier.citedreference | K. E. Larsson, L. Q. do Amaral, N. Ivanchev, S. Ripeanu, L. Bergstedt, and U. Dahlborg, Phys. Rev. 151, 126 (1966). | en_US |
dc.identifier.citedreference | K. E. Larsson, Phys. Rev. 167, 171 (1968). | en_US |
dc.owningcollname | Physics, Department of |
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