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Reactions of High‐Energy, Excited I128 Ions with Gaseous Molecules

dc.contributor.authorRack, Edward P.en_US
dc.contributor.authorGordus, Adon A.en_US
dc.date.accessioned2010-05-06T22:18:22Z
dc.date.available2010-05-06T22:18:22Z
dc.date.issued1962-01-15en_US
dc.identifier.citationRack, Edward P.; Gordus, Adon A. (1962). "Reactions of High‐Energy, Excited I128 Ions with Gaseous Molecules." The Journal of Chemical Physics 36(2): 287-291. <http://hdl.handle.net/2027.42/70530>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70530
dc.description.abstractThe manner in which molecular additives inhibit the reaction of (n, γ) activated I128 with CH4 was determined in an effort to observe indirectly reactions of I128 with the additives. The data suggest that (1) O2, N2, and CF4 serve only to remove excess I128 kinetic energy; (2) the ionization potential of O2 is greater than 12.16 ev, the potential energy of I+(1D2); (3) the ionization potential of C2F6 is less than 12.16 ev; (4) CH3I, CF3I, n‐C3H7I, and C6H6 inhibit the reaction principally as a result of I++additive ion‐molecule reactions and/or physical quenching.en_US
dc.format.extent3102 bytes
dc.format.extent383643 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleReactions of High‐Energy, Excited I128 Ions with Gaseous Moleculesen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michiganen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70530/2/JCPSA6-36-2-287-1.pdf
dc.identifier.doi10.1063/1.1732497en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.identifier.citedreferenceA. A. Gordus (unpublished data).en_US
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dc.identifier.citedreferenceThe diameters for C2F6C2F6 and CH2F2CH2F2 were estimated as 6.8 and 4.9 A.en_US
dc.identifier.citedreferenceK. J. Laidler, The Chemical Kinetics of Excited States (Oxford University Press, Oxford, England, 1955), pp. 102–103.en_US
dc.identifier.citedreferenceThe ionization potential of CHF2CHF2 is 9.45 ev.16en_US
dc.identifier.citedreferenceF. P. Lossing, P. Kebarle, and J. B. DeSousa in Advances in Mass Spectroscopy, edited by J. D. Waldron (Pergamon Press, Ltd., London, 1959), pp. 431–441.en_US
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dc.identifier.citedreferenceS. C. Lind, Radiation Chemistry of Gases (Reinhold Publishing Company, New York, 1961), pp. 133, 203.en_US
dc.owningcollnamePhysics, Department of


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