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(N2O)2⋅SO2:(N2O)2⋅SO2: Rotational spectrum and structure of the first van der Waals trimer containing sulfur dioxide

dc.contributor.authorPeebles, Rebecca A.en_US
dc.contributor.authorKuczkowski, Robert L.en_US
dc.date.accessioned2010-05-06T22:55:41Z
dc.date.available2010-05-06T22:55:41Z
dc.date.issued2000-05-22en_US
dc.identifier.citationPeebles, Rebecca A.; Kuczkowski, Robert L. (2000). "(N2O)2⋅SO2:(N2O)2⋅SO2: Rotational spectrum and structure of the first van der Waals trimer containing sulfur dioxide." The Journal of Chemical Physics 112(20): 8839-8846. <http://hdl.handle.net/2027.42/70924>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70924
dc.description.abstractThe trimer (N2O)2⋅SO2(N2O)2⋅SO2 has been studied by Fourier transform microwave spectroscopy. The rotational constants for the normal species are A = 1369.1014(11) MHz,A=1369.1014(11)MHz, B = 1115.5816(11) MHz,B=1115.5816(11)MHz, and C = 730.5790(4) MHz.C=730.5790(4)MHz. Five isotopomers of the complex have been studied, allowing a determination of its structure. The configuration aligns the centers-of-mass of the three monomers in an approximate equilateral triangle. The monomers twist relative to this plane so that the two N2OsN2Os are intermediate between T-shaped and crossed rather than the usual slipped-parallel planar. The SO2SO2 is oriented so that its oxygens are straddling one N2ON2O (similar to the N2O⋅SO2N2O⋅SO2 dimer), while its sulfur is closest to the oxygen end of the other N2O.N2O. The dipole moment of (15N2O)2⋅SO2(15N2O)2⋅SO2 was measured, giving μa = 0.606(1) D,μa=0.606(1)D, μb = 1.256(2) D,μb=1.256(2)D, μc = 0.058(2) D,μc=0.058(2)D, and μtotal = 1.396(2) D.μtotal=1.396(2)D. A semiempirical model has been used to predict the trimer structure, and comparison is made with this model as well as with the dimer N2O⋅SO2.N2O⋅SO2. © 2000 American Institute of Physics.en_US
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dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.title(N2O)2⋅SO2:(N2O)2⋅SO2: Rotational spectrum and structure of the first van der Waals trimer containing sulfur dioxideen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70924/2/JCPSA6-112-20-8839-1.pdf
dc.identifier.doi10.1063/1.481498en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.owningcollnamePhysics, Department of


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