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Hyperfine Structure of Indium Fluoride

dc.contributor.authorHammerle, Robert H.en_US
dc.contributor.authorVan Ausdal, Rayen_US
dc.contributor.authorZorn, Jens C.en_US
dc.date.accessioned2010-05-06T23:00:07Z
dc.date.available2010-05-06T23:00:07Z
dc.date.issued1972-11-15en_US
dc.identifier.citationHammerle, Robert H.; Van Ausdal, Ray; Zorn, Jens C. (1972). "Hyperfine Structure of Indium Fluoride." The Journal of Chemical Physics 57(10): 4068-4070. <http://hdl.handle.net/2027.42/70971>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/70971
dc.description.abstractThe radiofrequency spectrum of the indium fluoride molecule, 115In19F, has been measured with a high resolution molecular beam electric resonance spectrometer. We determined the hyperfine structure in the J=1 and the J=2 rotational states of several vibrational levels under conditions of very weak external electric and magnetic fields. The ∼700 MHz electric quadrupole interaction constant of the indium nucleus changes by 0.010(1) MHz between adjacent rotational states. We looked for, but did not find, an electric hexadecapole interaction of the indium nucleus; the upper limit for the (hexadecapole) interaction constant is 2 kHz.en_US
dc.format.extent3102 bytes
dc.format.extent208176 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleHyperfine Structure of Indium Fluorideen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumRandall Laboratory of Physics, The University of Michigan, Ann Arbor, Michigan 48104en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/70971/2/JCPSA6-57-10-4068-1.pdf
dc.identifier.doi10.1063/1.1678025en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
dc.identifier.citedreferenceR. H. Hammerle, Ph.D. dissertation, The University of Michigan, University Microfilms, Ann Arbor, Michigan, 1971.en_US
dc.identifier.citedreferenceR. H. Hammerle and J. C. Zorn (unpublished).en_US
dc.identifier.citedreferenceJ. C. Zorn, T. C. English, J. T. Dickinson, and D. A. Stephenson, J. Chem. Phys. 45, 3731 (1966).en_US
dc.identifier.citedreferenceJ. T. Dickinson, D. A. Stephenson, and J. C. Zorn, J. Chem. Phys. 53, 1525 (1970).en_US
dc.identifier.citedreferenceT. C. English and J. C. Zorn, J. Chem. Phys. 47, 3896 (1967).en_US
dc.identifier.citedreferenceD. A. Stephenson, J. T. Dickinson, and J. C. Zorn, J. Chem. Phys. 53, 1529 (1970).en_US
dc.identifier.citedreferenceR. M. Sternheimer, private communication.en_US
dc.identifier.citedreferenceH. J. Zeiger and D. I. Bolef, Phys. Rev. 85, 788 (1952).en_US
dc.identifier.citedreferenceE. W. Kaiser, J. Chem. Phys. 53, 1686 (1970).en_US
dc.identifier.citedreferenceHere Q  =  0.834×10−24 cm2Q=0.834×10−24cm2 as reported by G. F. Koster [Phys. Rev. 86, 148 (1952)] was used. The rotational and vibrational constants are from R. F. Barrow, D. V. Glaser, and P. B. Zeeman, Proc. Phys. Soc. London 68A, 962 (1955).en_US
dc.identifier.citedreference(1−γ∞)  =  76.5(1−γ∞)=76.5 is calculated from the experimentally determined value of eqQ and H. W. de Wijn’s theory [J. Chem. Phys. 44, 810 (1966)] for the quadrupole interaction assuming that the ionic character of InF is one and using Q  =  0.834×10−24 cm2.Q=0.834×10−24cm2.en_US
dc.owningcollnamePhysics, Department of


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