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The Infrared Absorption Spectrum of Carbon Suboxide

dc.contributor.authorLord, R. C.en_US
dc.contributor.authorWright, Normanen_US
dc.date.accessioned2010-05-06T23:29:39Z
dc.date.available2010-05-06T23:29:39Z
dc.date.issued1937-08en_US
dc.identifier.citationLord, R. C.; Wright, Norman (1937). "The Infrared Absorption Spectrum of Carbon Suboxide." The Journal of Chemical Physics 5(8): 642-649. <http://hdl.handle.net/2027.42/71281>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/71281
dc.description.abstractThe infrared absorption spectrum of carbon suboxide vapor has been studied under low dispersion in the region from 2μ to 25μ. The vibrational bands observed may be satisfactorily accounted for on the basis of a linear symmetric structure for the carbon suboxide molecule, in agreement with evidence obtained from Raman spectra and from electron diffraction investigations.en_US
dc.format.extent3102 bytes
dc.format.extent568662 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleThe Infrared Absorption Spectrum of Carbon Suboxideen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartments of Chemistry and Physics, University of Michigan, Ann Arbor, Michiganen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/71281/2/JCPSA6-5-8-642-1.pdf
dc.identifier.doi10.1063/1.1750091en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
dc.identifier.citedreferenceBrockway and Pauling, Proc. Nat. Acad. Sci. 19, 860 (1933).en_US
dc.identifier.citedreferenceBoersch, Naturwiss. 22, 172 (1934); Wien Ber. 144 (IIb) 1 (1935).en_US
dc.identifier.citedreferenceBadger and Barton, Proc. Nat. Acad. Sci. 20, 166 (1934).en_US
dc.identifier.citedreferenceThompson and Healey, Proc. Roy. Soc. (London) A157, 331 (1936).en_US
dc.identifier.citedreferenceEngler and Kohlrausch, Zeits. f. Physik. Chemie B34, 214 (1936).en_US
dc.identifier.citedreferenceH. M. Randall and J. Strong, Rev. Sci. Inst. 2, 585 (1931).en_US
dc.identifier.citedreferenceF. A. Firestone, Rev. Sci. Inst. 3, 163 (1932).en_US
dc.identifier.citedreferenceHurd and Pilgrim, J. Am. Chem. Soc. 55, 757 (1933).en_US
dc.identifier.citedreferenceE.g., reference 4, p. 332.en_US
dc.identifier.citedreferenceCompare the acetylene vibrations ν4ν4 and ν5ν5 (Colby, Phys. Rev. 47, 388 (1935)) which are analogous to ν5,6ν5,6 and ν7ν7 in carbon suboxide. Difficulties with the calculation of the corresponding frequencies in benzene, ν11ν11 and ν10,ν10, have been pointed out by Kohlrausch, Zeits. f. Physik. Chemie B30, 313 (1935) and by Lord and Andrews, J. Phys. Chem. 41, 151 (1937).en_US
dc.identifier.citedreferenceSee Dennison, Rev. Mod. Phys. 3, 297 (1931).en_US
dc.identifier.citedreferenceBarker and Wu, Phys. Rev. 45, 1 (1934).en_US
dc.identifier.citedreferenceCf. Dennison, reference 11, p. 296.en_US
dc.identifier.citedreferenceCf. the relatively high intensity of the overtones at 3610 and 3717 cm−13717cm−1 in CO2.CO2. This pair of bands constitutes a resonance doublet.en_US
dc.owningcollnamePhysics, Department of


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