View Item 

Show simple item record

Intermolecular multiple scattering of electrons. II. Observed effects for SF6

dc.contributor.authorJin, Andingen_US
dc.contributor.authorBartell, Lawrence S.en_US
dc.date.accessioned2010-05-06T23:32:46Z
dc.date.available2010-05-06T23:32:46Z
dc.date.issued1983-06-15en_US
dc.identifier.citationJin, Anding; Bartell, Lawrence S. (1983). "Intermolecular multiple scattering of electrons. II. Observed effects for SF6." The Journal of Chemical Physics 78(12): 7165-7168. <http://hdl.handle.net/2027.42/71314>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/71314
dc.description.abstractA theory of intermolecular multiple scattering of electrons by vapor molecules is tested by comparing predicted effects with effects observed over a wide range of sample densities. It is found that the theory, which contains no adjustable constants and is based on small angle approximations, gives a good account of experimental observations. The degree to which experimental structure refinements are degraded by multiple scattering is also examined. It is found that derived internuclear distances are disturbed very little even when the mean number of scatterings per electron is as high as 2 and the interference features are washed out by a factor of 2. Apparent amplitudes of vibration are influenced more significantly but are still correctable with fair precision.en_US
dc.format.extent3102 bytes
dc.format.extent309532 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleIntermolecular multiple scattering of electrons. II. Observed effects for SF6en_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/71314/2/JCPSA6-78-12-7165-1.pdf
dc.identifier.doi10.1063/1.444757en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
dc.identifier.citedreferenceL. S. Bartell, M. A. Kacner, and S. R. Goates, J. Chem. Phys. 75, 2730, 2736 (1981).en_US
dc.identifier.citedreferenceS. R. Goates, Ph.D. thesis, University of Michigan, 1981.en_US
dc.identifier.citedreferenceM. A. Kacner, Ph.D. thesis, University of Michigan, 1983.en_US
dc.identifier.citedreferenceL. S. Bartell and A. Jin, J. Chem. Phys. 78, 7159 (1983).en_US
dc.identifier.citedreferenceSee AIP document No. PAPS JCPSA‐78‐7165‐9 for 9 pages of related materials including conditions under which the diffraction plates were taken, representative intensities and derived results. Order by PAPS number and journal reference from American Institute of Physics, Physics Auxiliary Publication Service, 335 E. 46 St., New York, NY 10017. The price is $1.50 for each microfiche (98 pages), or $5 for photocopies of up to 30 pages and $0.15 for each page over 30 pages. Airmail is additional. Make checks payable to American Institute of Physics.en_US
dc.identifier.citedreferenceK. Ashkenas and F. S. Sherman, Rarified Gas Dynamics, Fourth Symposium, edited by J. M. de Leeuw (Academic, New York, 1966), Vol. II, p. 84.en_US
dc.identifier.citedreferenceL. S. Bartell, in Physical Methods in Chemistry, 4th ed., edited by A. Weissberger and B. W. Rossiter (Interscience, New York, 1973).en_US
dc.identifier.citedreferenceL. S. Bartell, J. Mol. Struct. 84, 117 (1982).en_US
dc.identifier.citedreferenceK. L. Sellers, L. Schafer, and R. A. Bonham, J. Mol. Struct. 49, 125 (1978).en_US
dc.identifier.citedreferenceC. Tavard, D. Nicoles, and M. Rouault, J. Chim. Phys. (Paris) 64, 540 (1967).en_US
dc.identifier.citedreferenceSee, for example, B. R. Miller and L. S. Bartell, J. Chem. Phys. 72, 800 (1980).en_US
dc.identifier.citedreferenceL. S. Bartell, J. Appl. Phys. 31, 252 (1960).en_US
dc.identifier.citedreferenceH. R. Foster, J. Appl. Phys. 41, 5344 (1970); L. S. Bartell and L. O. Brockway, 24, 656 (1953).en_US
dc.identifier.citedreferenceP. Pulay, R. Mawhorter, D. A. Kohl, and M. Fink, J. Chem. Phys. (submitted); D. A. Kohl and L. S. Bartell, J. Chem. Phys. 51, 2891, 2896 (1969).en_US
dc.identifier.citedreferenceAt higher pressures systematic intensity residuals are observed that arise because the effects of multiple scattering in experimental data are not compensated for in the single scattering fitting theory. These residuals are significantly correlated in form and position with those caused by the redistribution of molecular electrons.en_US
dc.owningcollnamePhysics, Department of


Files in this item

Name:
JCPSA6-78-12-7165-1.pdf
Size:
302.2KB
Format:
PDF
View/Open

Show simple item record

Remediation of Harmful Language

The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.

Accessibility

If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.