Now showing items 1-3 of 3
Structure and vibrational assignments for PCl5 : An electron diffraction study
(Elsevier, 1971-04)
Gas-phase phosphorus pentachloride is a trigonal bipyramid with axial bonds 0.104+/-0.01 A (e.s.d.) longer than equatorial bonds. The mean bond lengths are 2.061+/-0.002 A. Amplitudes of vibration were determined, resolving ...
Electron diffraction study of gaseous tetrahydrofuran
(Elsevier, 1969)
The gas phase molecular structure of tetrahydrofuran has been reinvestigated. Experimental diffraction intensities are well accounted for by a freely pseudo-rotating molecule. The mean value of the pseudo-rotational puckering ...
Electron diffraction study of the structure and internal rotation of cyclobutanecarboxylic acid chloride
(Elsevier, 1971-04)
The conformational equilibrium of (CH23CH-COCl in the vapor phase was studied as part of a broader investigation of molecules in the series R-COX. It was found that the cyclobutyl derivative exists almost entirely as gauche ...