THE UNIVERSITY OF MICHIGAN INDUSTRY PROGRAM OF THE COLLEGE OF ENGINEERING THERMODYNAMIC PROPERTIES OF CARBON TETRAFLUORIDE Nallan C. S. Chari A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Science in The University of Michigan 1960 April, 1960 IP-430

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ACKNOWLEDGMENTS The author wishes to express his sincere appreciation and thanks to all those who aided in this investigation and especially to: Professor J. J. Martin, who supervised the work, for his time, valuable suggestions and his encouragement that led the author to continue his graduate studies. Professor K. H. Coats, who also supervised the work, for his interest and constructive criticisms. Professors D. W. McCready, D.V. Ragone, C. M. Thatcher, and G. J. Van Wylen for their interest in the investigations. Mr. R. K. Bhada for his great assistance in taking the data. Professor R. C. R. Bartels of the computing center for permitting the use of IBM 704 for preparing the tables of thermodynamic properties in this investigation. E. I. du Pont de Nemours and Company for their generous financial support in this investigation. ii

TABLE OF '' TENTS'' Page A CKNOWLEDGE MENTS............................................ LIST OF TABLES,..o........ o........ *....................... LIST OF FIGURES............................o............ NOMENCLATUE.................. a s........ a........... ii vi viii A.B $"ii;AC T...........................b.........................SSl IANFTR.O DUC TI 0 N.... I............................................ L IT!RATURE SURVEY............... *...................... x 1 2 Vapor Pressure.e............................... Critical Properties....................e.... Pre ssure -Volume -Temperat-ure Behavior.......,.... Liquid Density....9...................... e.. Normal Boiling Point........................... Melting Point................................ Heat of Vaporization........................ Specific Heat of Liquid and Solid.............. Specific Heat of Vapor........................ e e * e ee seoeeeeeese ~eeaseeee* e S 0. m,5.. 9 es< ".. e 1). * * e o e, *... II...m.. * a V e. e e e. * o aeeeeeeeee Jleee~*eeO eeleeeeeee. 0....... 0 s * * 0 8. * *. o. * 0.. 0 0... 2 5 6 1 12 12 1?. 20 2 - EXPERIMENTAL WORK...... o..................................... Vapor Pressure Measurements.................... Low-Pressure Vapor Pressure Equipment.................. High-Pressure Vapor Pressure Equipment................. Saturated Liquid Density Measurementts.....,.,......e o. Critical Temperature........ o............... o..;'i. —i'XLATION OF DATA.... e..,............. e ajpor Pressure Dat....................S e..... i qui d Density ata... ss.................... ~eat;:Capacity at Zero Pressure e. T. 19......e El e...s r s... 9 o dX i * 9 eO e 2'. 26 2:.^. i:. S L.. n.s a. 0 o v e I D r e,..* a.... e oa o Vapor Pressure.... o......... Liq uid Densi+y's..e.......,.... riti cal Constants.. e... s, o ~PVTT Behavior....o...,....... 7 e.. *. e 5 S) e e 11 e tp e S1 o s 11.. 0 e- @ a9 a 11 f. 0 e.. * * e...... oe~beeeeeeY~*ee DeFeeeeeeee~eee~ c ~ 1). 0 I. 1 s. Z,.. 19.. 0 s.0 1 a a 1. I. 0.... 1.: 2 -2 ^2. i. Heat Capacity at Zero Pressure,.......... iii

TABLE OF CONTENTS (CONT'D) DISCUSSION.............................................. Vapor Pressure......................................... Liquid Density......................................... Critical Constants........................... Heat Capacity at Zero Pressure.......................... CALCULATION PROCEDURE FOR EVALUATING THE THERMODYNAMIC PROPERTIES OF CARBON TATRAFLUORIDE........................... Saturated Vapor and Liquid....................... Enthalpy of Vapor.................................... Entropy of Vapor.................................. Saturation Temperature Table............................ Saturation Pressure Table................................ Superheated Vapor................................ APPENDIX A - TABLES OF THERMODYNAMIC PROPERTIES............. APPENDIX B - VAPOR PRESSURE................................. APPENDIX C - SATURATED LIQUID DENSITY....................... APPENDIX D - HEAT CAPACITY OF VAPOR AT ZERO PRESSURE......... APPENDIX E - EVALUATION OF THERMODYNAMIC PROPERTIES AT THE REFERENCE CONDITIONS............................ APPENDIX F - CALIBRATION OF THE PLATINUM RESISTANCE THERMOMETERS...........X....................... APPENDIX G - PROGRAMS FOR CALCULATING THE THERMODYNAMIC PROPERTIES ON IBM 704......................... APPENDIX H - SATURATED VAPOR DENSITIES OBTAIED BY EXTRAPOLATION OF P-V-T DATA BY BHADA TO THE VAPOR PRESSURE CURVE.....................*............ APPENDIX I - GENERALIZED DATA ON THE LIQUID DENSITIES OF SOME FLUOROCHLORO DERIVATIVES OF METHANE........ APPENDIX J - REDUCED VAPOR PRESSURE DATA FOR SOME CHLOROFLUORO DERIVATIVES OF METHANE............ APPENDIX K - DETAILS OF CALCULATION FOR THE ENTHALPY AND ENTROPY AT THE REFERENCE TEMPERATURE............. Page 35 35 35 37 39 45 45 46 49 51 52 52 106 110 112 118 121 149 151 155 160 iv

TABLE OF CONTENTS (CONTTD) Page APPENDIX L - DETAILS OF CALCULATIONS FOR THE DETERMINATION OF ENTROPY BY STATISTICAL METHODS AND THERMAL METHODS FOR THE IDEAL CASE..................... 167 APPENDIX M - TABLE OF CONSTANTS AND CONVERSION FACTORS........ 172 BIBLIOGRAPHY.........,................................ 175 v

LIST OF TABLES Table Page I Summary of Data on the Fundamental Frequencies of CF4.............................................. 10 II Comparison of Critical Constants..................... 39 III Comparison of Calculated and Experimental Heat Capacities of Liquid CF4........................... 44 IV Saturation Temperature Table........................ 55 V Saturation Pressure Table.............. 60 VI Thermodynamic Properties of Superheated Vapor...... 67 VII Comparison of Vapor Pressure Data with the Vapor Pressure Equation for Carbon Tetrafluoride........... 107 VIII Comparison of Liquid Density Data with the Liquid Density Equation.................. 111 IX Heat Capacities at Zero Pressure (CV) by Statistical Methods for CF4.......................... 113 X Comparison of Heat Capacities at Zero Pressure with the Heat Capacity Equation...................... 113 XI Entropy Determination by Thermal Methods at the Reference Temperature................................ 115 XII Enthalpy Determination by Thermal Methods at the Reference Temperature............................. 116 XIII Entropy at 300~K by Statistical Methods............. 117 vi

LIST OF FIGURES Figure Page 1 Schematic Diagram of the Low-pressure Vapor Pressure Equipment.................................. 14 2 Picture of the Low Pressure Vapor Pressure Equipment..................................... 15 3 Schematic Diagram of the Low-temperature Bath....... 17 4 Schematic Diagram of the High-pressure Vapor Pressure Equipment......................... 19 5 Picture of the Liquid Density Apparatus........... 22 6 Correlation of the Vapor Pressure Equation.......... 25 7 Temperature-Density Diagram for CF4................. 27 8 Reduced Vapor Pressure Plot for CC12F2, CC1 F3 and CF4........................................ 36 9 Generalized Liquid Density Data for CH2F2, CHF3, CC12F2, and CF4................................. 38 10 Diagram for the Consistency Test of the Heat Capacity Equation.............................. 40 11 Pressure-Enthalpy Diagram for Carbon Tetrafluoride.. 53 vii

NOMENC IATUL E A,B,C,D,E,F a.1, a2,a -,a 4 A.2,B&2, C2 A.,B2,,C A4,A5,B5, 5 b c Cp Cv d e fl,f2,f3,f4,f5 h H AH J K k M P R S S T Constants of vapor pressure elqua.tion constants of liquid density equation Constants in the equation state Characteristic constant of the equation of state Velocity of light Heat capacity at constant pressure Heat capacity at constant volume Saturated density Base of natural logarithm Temperature functions of the equation state Planck's constant Enthalpy Enthalpy change Conversion factor Boltzman' s constant Constant of equation of state Molecular weight Pressure Universal gas constant Entropy Entropy change Absolute temperature (~R + 459.69) viii

v v NOMENCLATURE (CONTID) Volume Constants of heat capacity equation Fundamental frequency Subscripts V P T C r Bar indicates extensive property per unit mass Constant volume Constant pressure Constant temperature The value at critical point Reduced property Superscripts g 1 Ix Property of gas, Eg. Vg Property of liquid, Eg. VI Vaporization property, Eg. &Hv Indicates zero pressure ix

ABSTRACT Experimental data on the vapor pressure, saturated liquid density, critical properties and calculated heat capacity at zero pressure have been determined for carbon tetrafluoride. The ranges of these determinations are as follows: 1. Vapor pressure was measured from 181~R to 408~R. The corresponding pressure range is from 0.125 psia to 531 psia. 2. The saturated liquid density measurements were made from 165~R to 409~R. The equivalent liquid density range is from 118 lb/cu.ft. to 46 lb/cu.ft. 3. The critical temperature was observed to be 409.50~R with the estimated critical pressure of 543.16 lb/sq.in. absolute and critical density of 39.06 lb/cu.ft. 4. The specific heat at zero pressure was determined from 180~R to 1170~R from the reported spectroscopic data on the fundamental frequencies in the literature. These data were correlated in the form of equations, which represent the data with satisfactory precision. These equations, along with the other equations available in the literature were then used in the formulas developed for calculating the thermodynamic properties of the saturated liquid and vapor and of the superheated vapor. The thermodynamic properties of the saturated vapor and liquid are presented in two sections. The first section, entitled the saturation temperature table presents the saturation pressure, specific volume x

of gas, specific volume of liquid, density of gas, density of liquid, enthalpy of liquid, latent heat of vaporization, enthalpy of gas, entropy of liquid and entropy of gas at saturation conditions corresponding to each temperature in the range of -270~F to-the critical temperature. The second section, entitled the saturation pressure table presents the same thermodynamic properties as listed above, but this time in the given range of pressures from 0.2 psia to the critical pressure. The saturation temperature is presented in this table in place of saturation pressure of the first section. The thermodynamic properties of the superheated vapor are reported as values of volume, enthalpy and entropy up to about 300~F superheat conditions at tabular pressures from 0.2 psia to the critical pressure. Above the critical pressure and up to a pressure of 5000 psia, these properties are presented up to 700~Fo These properties are assumed to cover the range of conditions, where carbon tetrafluoride is normally expected to be used as a refrigerant. xi

'' - y -)Di -' r-q I \1 Carb on t;etrafluoride, also known as:Freon-14.iC is a new refrigerant -wich, offers cbh. promise in the area of ultra loAwr temperaturess Because of its extremely low -oiln on-toxcing n or-noxi n-inframeri abl e and chemically iner.t nan ture, it is not mnlikely that caiior, tet raflu'oride w domrinate te area o f wt eriperee aturie refrigeration. in the nrear future So far, th.e reported data in thr e literature on certain physical proper.ties of car-on tetrafl.ord have 'teen inadequ'late to determinre the precise tiherm-odrynamiic7 properties o.f' the compoundo Ever- among certain available datai, there tias been a wide istrepan awong diffcrnr souirces e.Tt is, therefore, the purpose of this investiga.tion a a) to determi-ne the uecessa.r data exper metally,^ (b to correlate the da,ta,by means of sitabl-...e ecqeua..tons to represent the - da`a,;with a high, degree of precision, ec to develop equations for the tierzmod —nam prope.e.s sing the atove n ions and ot.her data, a ava iible from the litereature, and (d) to prepare tabl.es arnd ctlsr-s_ of Ite the, esrmodynamic- properties ~for -the con-venienr4t use in the desi gn, a.-d operat'on of re'frierating. units n using this compound. Trade.-n,:arked nram e o the E. I. duPo nt de Nlemours and Cormpar,Wilmingtnon, Delawa re, I

LI TERATURE SURVEY The following sections give a, summary of the various publications dealing with the physical properties of carbon tetrafluoride, necessary for the computations of the various thermodynamic properties of the compound. Vapor Pressure Experimental data on the vapor pressures of carbon tetrafluoride were first reported by Ruff and Keim(37) in the temperature range of 92~K to 143.5~K. The corresponding vapor pressures range from 2e5 mm Hg to 754 mm Hgo The data were correlated by the equation loglP = 7.3067 - 632 (1) where P is in mm Hg and T in ~Ko Menzel and Mohry(y-3 measured vapor pressures in the temperature range of -193.2~0 to -127o29~Co The corresponding vapor pressures are from Ool mm of Hg to 798.9 mm of Hg. They presented the correlating equation, -701.7 loglO mP - + 7 1o75 loglT - 0o0076715T + 5.044,20 (2) with the same nomenclature as for Equation (1). Booth and McNabney(7) measured vapor pressures at eight temperatures in the range of from -19840~F to 49.9~F. The corresponding vapor pressures are from 14.7 psia to 542.4 psia. The data were represented by the equation~ 2735 o415 log10P = 62.84:35 - 27 - - 22.8079 logT + 0.015017T (3) where P is in psia and T in ~R~ -2 -

7=< 'Piske - ar lnd P —nk{ 2'; reported va por pressu-res cac 1.la ted froom q/'ation (3.' Tb:,e t re sCt. howeveiF, a sl>it di sagreeme.t e e callat eda values:from oth, te soo;r~ces s-inc-;e Fr, Flank used a rou3de.doff conversion facator o T'he cri ical te:nperatre e ard cr.. pressure of F were de" 77 \ tersrmined ex:p pri-en+tail ly 'y, ooth an d cMcabney - to be 49.90 nd '2 p.S e -' e,~po MI't~lLVCL.,,+''e C^_''S NL, a-' 4- f4=.;Ltn,9. 9 at. and 54 2. 4 psi-:% respectivel" 'si.ng these valu-es, the critical dernsit.was estimira.ted to be 39 b/cu.. f.asei on a value of FR o T/Pc C F J 3C5, a val.ue t pical o compounds of this class.{7l On. t;.e asis of orrelations with ot'er fluorochloro derivatives, Seger' — es... iat.ed bte critical tier pera.uce to '-e -9,0~C. TIie critical densasiy: -s esrt:~ 1..l.e 0, oa s t ict593 U Co PressSu.e -~ 'Vol.'-Le - Temp..era..l.re Be:auvior Mac orc ack a,.d.d Src creide.- 2 + de + rm t A ned t". T e P-I- ehviorn a tempera ure _ran a of.. ".:"o v' " '; - c and a pressure range of 0 to 50 r atmos pheces.. ench of 'th;e ti.petueS, a"e dat.- 'were correl`ated 'a an ecua'tion of _the for.. P' - J....,,r' P2 ~+, -r. F (l ere A, P-, Cr e A -nd T t v al" coe fficiens at t uhpe teIeraure in u..es ion Thl.ese coeffi.i s e +;vta-lted a seven.temperatu..es in the a> ove 'ran'ge, Grahama" -' es t+i>-ted theF P-,.;etae'hai or from the cr.it'ical constan.ts of> ooth and Mcl':r:ne.- an d 'te genaera,7lized redu.ced properties of

other fluor-chlorderivatives of methane. A modified Beattie-Bridgeman equation of state 'was proposed as P = (0034506 - 45.729 x 10-6T)d- + (0o.0042460T 3- 328)d2 + 0.12194T d (5) where P is in psia, d is the density of vapor in lb/cu.ft., and T in ~R. Bhada(6) determined the P-V-T behavior of carbon tetrafluoride in his newly-developed variable-volume P-V-T bomb. He studied the P-V-T behavior in the temperature range of 360~R to 851.65~R for the specific volumes ranging from 0o30351 ft3/lb to 0.012716 ft3/lb. The corresponding pressure ranges were from about 135 psia to about 2000 psia. He correlated the data within an average deviation of + 0.2% for the most part, by means of the following form of the Martin-Hou equation of state. fl f2 f? f4 p nz1 + + 3 + + (6) V-b ) (i-b)2 (_-b ) (V-b)4 (I!b) 5 where, fl = RT kT f25 A2 + B2T + C5e f-: A3 + B3T + C3e f4 = A4 kT f5 -A5 + B5T + Cse ' Liquid Density Ruff and Keim(37) determined the liquid density of CF4 at -178~C and -1800~C experimentally and reported a constant value of 1.96 g/cc in this temperature range, The same investigators(38) later measured the liqiud densities at 140.70K and 143.40K and reported values of 1.629 and 1.619 g/cc respectively.

Klea-swm Vand Ir ekc- 2 neas-. ed W- i' i rd denv s> a-6. as 1.9.r. C, g/0 to sn-v e irvestizg.ators l 9" later -men tioned this value tio he riot as Cr<ile as repo-e:d -e ca se of te p sence 0o Itpur ties Using the ddat:.....ff and Kei. — m-..d. Klet:n and r 'enkel 2, 'raa's1:e ' es h -av-.srtde -;.fr tne r'ct'L. nea-,r dw.e er to:be te's _i. -en rep.reseed ds d1 - 2..; -: it t.nt d dd1-oer- 7d 7; h'rere dsv< is rte den. it,, of the Sa..9.-ahed vapor at t-.t -rper t.r e From a, correBation o- vai.Ou,;,s ~luorcnioro deriva tive-sS Se,^Ogera-n9 deri ved t-.f e Qli.Y...d densir of. C:. s,,;,cction of te Y-pavra,e a G'a.,he0~ ', ",~; e........er -er d, s t -- is ed ' the rt r:a t- eeperu.r.re ~y thod fplcain of d h eore of corresponding stares, \orr> 0 1 P a Ls'0Y:..... [:'70 l'1- _ 4.- c0 Td. m"; dest o s P at:s' ol: ''o., '.e izr t he. d cnsi Corcial roil-Olngng Poi Letea arid r g-ni g; 2 d mt- irned tie nora1 ',bo.linig p oint of Ct, as 42A 4.C.5e- Eoth r- Mc0he re * estalished the;:oiling point orrespond i g o ple ps a ai t2 e r vCpor press r. e e,, ton as r12.. Reff anrd Kent' e 7s of' tred da vau of L'-. ss for the 'oiling poLit d. sntst rttig a. vale of 7,0 mir in '-u: a.,on S 1. Mezel and Mohr. '::. rsimlarl reported a n.i.ai. point of 12 + 0l~0, >- sibostitu - ng in <ation (2>' Seger -- reported s value of 130 ~ for. the normal ~boiling point of C>y tbamed on conrrelations 'wtb other flrochiloro derivaive.i s ~ 1ed a va! u~ of -1 in ~C fr' g 't.' ~ ves ~,~~~~~~~~~~~~~~~~~~~~~~~~~~

-6 - Melting Point Lebeau and Damiens(25) determined the melting point experimentally to be -191 ~C. Ruff and Keimr f'7) found the melting point to be -186.3 + 1 C. Klemm and Henkel(23) measured the melting point as -186e8 + 0.5~C. Later, the same investigators used a much purer sample and found it had a higher melting point of -183.6 + 02~ Eucken and Schroder(13) also determined the melting point experimentally and reported it to be -183.69~C. Heat of Vaporization No experimental data have been found on the heat of vaporization of carbon tetrafluoride. Ruff and Keim(37) estimated the heat of vaporization at the boiling point by using Equation (1) and the Clapeyron equation and reported it to be 2.9 K cal/mole. Menzel and Mohry(3) calculated heat of vaporization by a similar method and represented them by the emuation, LAH (AH + 3.5T - 0.035081T2)) ( 9) where AH is the heat of vaporization at any -temperature T(~K), A4o is the latent heat of vaporization at absolute zero (given to be 3209 cal/mole), P is the vapor pressure at the given temperature and Pc the critical pressure. From a correlation of various fluorochloro derivatives, Seger(39) estimated the heat of vaporization. at its normal boiling point to be AH - 31 3 (10) M where TB is the normal boiling point in ~K, and M the molecular weight. The effect of temperature on the latent heat of vaporization for this

S; ~~~~-%"~ ~ ~~ I"," - - r o +; `J`~e~7er -,~e2,1,,,-~i r" LI -i..-, _,t 11).'A There A 1is a cosan oh ied sittion of var es from. Eqa'ti; L on {O I 0 "' I S'rcons and Sn n.t: d 'aLaed, the errop: of vaporizsation at the noramal oiin.g poair> ', a ssi i2deal gas teav:or anrd using a ud density of 1. 9 g fro rt. d.- o. Ri nd Ke1i 2. Th,.e val _e reported is 20.3 cal, ole K K ' Te ea:' of v apor iz-t on. a the:ormal boiling poJint mat hn"e otairTed _ ul>7g plo:nipi g ttisa. 'bT y. o.ortl oiling po1t of 145.2o "'-Ko ISpactfi^c Feat: of Li'-od ad Solid. ii..fro,.. 12K o. ie.ep. e.ltf o i.n. i. < e:re oespon din. h: a, i c apaci ties range from. 3'2 o I~7", c-al, oa:. 'role " Li-iK.d ea-: capc ities *were measured- fro td fo 9.. b~ tn to, ".o.nd fo.nd t f o ro Io - to 19.11 cafl,':16 mole g::..' Se> -- and Ashon YI:; e:etascr-ed the neae espe i: t,' of li.:m!ttd CF. freom 9' 759'K to l O7 ot< 0 'K:,:aii'g values from 18b 5.o 20.0 cal. 7g n.ole)'oKt These daa, ';were correla 'ed bc' t'e. e. uat,o 24.. + >'11:, + ~ n 0t 0 121 Sa.. 2 O O l. ( where T is i.n K Eased on. correlations,th var ious fluoroc loro derlvat ives Sen er9e 9 estim+ated t:at CF rao d ave an app roxima tel - constant specific

heat of C: 3.571 M-05704 (1) in the range of reduced temperatures of 0.5 - 0.75. In this equation, M represents the molecular weight. Specific Heat of Vapor The only available data on the specific heats of CF4 in the gaseous state by direct experimental measurement are by Eucken and Bertram(l2) who measured the heat capacities at the temperatures of 113, 173 and 199~K. The corresponding specific heats are 6.27, 7.63 and 8.39 + 0.5 cal/(mole)(~K) respectively. All other published data are based on. fundamental spectroscopic absorption frequencies using statistical methods. The Raman spectrum of liquid CFj4 was first obtained by Yost, Lassetre, and Gross (4:) The f-ndamental frequencies reported were ' 41 4 37, ~2 635 and s' 904 cm-l respectively. The first infrared spectraum for the gaseous state was reported by Eucken and Bertram(12), who reported only two absorption bands of v2 -653 and v4 - 1350 cm-1. Later Bailey, Hale and Thompson ( obtained 10 infrared bands in the region from 630 to 2550 cm'l and determined the fundamental frequencies to be v2 - 630 and 44 1252 cm1. The same investigators(3) later corrected the value of v4 to 1265 cm1. Plyler 33) measured the infrared spectra, of CF4 in the gas state and determined two of the fundamental frequencies of a12 and '4 to be 630 and 1277 cm1l respectively. Later Plyler and Benedict(34 ) remeasured the

spectr an.d reprs-L tne as i. oe two ared-tve eeces of p2 r 29 an d 12 and to $amzn-actve ft ee of 1. 37 cz cdt, 4.nY:. e:s e / r2 'e N;/VLT-: -~I~ _-I ' _ F s;e-:d v er> p,;e swples and ssore gas than in evi,: es taat: ons at d x::r ed:ce in frar-ed re- oeln:t.es of agre - 7,e:-t.. Ran. l one oc::,.c-easczed t'b.ost. e. a.. ' - Dec ke,.Me* ster a:nd Clevelavnd"1 n ' recomarended t-e use of - r c, 91 =fro. t.e data of ote. alt. and the use ~,,. u.,:,V ' O... of '2 7 and: = 12!? c.1 reported > Baile', Bale and.hops on. Cla. ssen 9',easuired te a.ma. spectra of CF nr a nev t,-p of tube a..d:.n Ir'l1di -t:on appa,ra. ~.,s spejai.l> desin. ed for ca.ses. The sample t usedw. v L:...;la{ted *t.o.;av'e a, "ighi p.r2e unaenal e frde:: encies 'were nreported 'o r e ri.- ",, r -t 9N"A 7 2 anld t. ~ 12/77 cr - respe.tivel::.; >os' re-,g'e- data or::. "fme fdacer'cl '.e fwruerties have teen N 1,, MO~ S d, i-;e ' -"s!,'.,l L1L 2r^'' ~ Y 1 ~r:I~hl.Cr~f C7 S'' vtolx.e 'y st It c e.t..:: hods fo t.e a ss ggnents i ofe:os.: ' r.d epresenred te y t.e.. 3. Ov 0. a0 21. x 10 2. S. e r:'*'e d e'd "~...1 6:;.'0 *where 0 is givenr in Bi ),.' 2 ' ce:-re c-,ased onr sa,ss....7ent s reco:m.ended -. Decker-, M.e ser and Cleveland{9)

TABLE I FUTDAMENTAL FREQUENCIES OF CF4 SU.MSARY OF DA1TA ON THE Frequency Source 2 l Q 4 Remarks _~~~~~~~~' = 2 ~.~ Yost et al (4) Eucken and Bertram(12) Bailey, Hale and Thompson (3) Bailey, Hale and Thompson(4) Plyler and Benedict(34) Woltz and Nielsen(42) Claassen(9) Goubeau et al. (16) 635 904 650 4.35 54.5 629 632 63o 628 1350 1252 1265 1277 1283 1277 1281 Raman spectrum in liquid Infrared spectrum for gas Infrared spectrum for gas (corrected the value of v4) (Remeasurement) Infrared with pure samples Raman spectrum in gas Raman spectrumn in gas with highly pure samples O 3 908.2 908

- 11 - a.-nd represen.ed e tem t..ato,' 0012 0 _t.120"f - C027':2 x: 1C 7436 x 1 7<. iT2 T =5) whiere the unrits are:he sa me as in. E:,.at:ion (4i:telles and Pi.zer 1-> cculated 't he: p'' va.les fromt the assignmert;s of PF'ler and Fe:ed.c '' - and 'tal.ated t:e in the range of from lC rK to I^OCO~K. Also.the values of S, S and I; )/T iwere ~etat;ab~lasj2Xt~ed IrSn T"lhi.s ra~roge o ~ tpearipra - res. the L sfre.u, wt...Cy and s. orption o3f spersonic waves i n.. CF. Da-ta, were taken rat uStwo, freq;o>enie Fs, of{g 290'7' K C- anrd t1c, K C ard a. presste -range of 1/' to<. ataosp:F res At ta tcreperat:ure of 22 ~ aend a pressure of 1 atmosphere, <t.,. s -pe '-: itc.3 i.;ea;.a 'WE.~ S d.m r 'ied no -a. e 1t - L, +:'...... s ~~~~L.UI ~ n

EXPERIMENTAL WORK The sample of carbon tetrafluoride used in the experimental investigations was supplied by the E.I. du Pont de N\emours and Company. According to their analysis by the vapor phase chromatograph, the sample contained 0004 wt% of CC1F? and 0.25 vol.% of air as impurities. Recautions were therefore taken r to remove the air completely before making the experimental runs. The experimental work in this study involved the measurements of vapor pressure, saturated liquid density and the critical temperature of carbon tetrafluoride. New equipment has been built based upon the previous investigations by Hou(7) on some of the physical properties of trifluorome thane o The vapor pressure measuremrents covered the temperature range from 181R to 408~R (equivalent to a pressure range of 0c125 psia to 531 psia). The saturated liquid density measurements were made from 1650F to 409~R. The corresponding liquid density range was from 118 lb/cu.fto to 46 lb/cuofto The critical temperature was determined to be 409O50~F. The following sect;ons present a brief description of the experimental techniques employed in these investigations. Vapor Pressure Measurements The vapor pressure measurements were made in two different sets of equipment, each designed for a different pressure range. The low pressure vapor pressure equiapment was designed for pressures from a few millimeters of mercury absolute to about atmospheric pressure, The high pressure -12 -

-13 -Vapor prFss.re e.upe;E it 'Was designed for pressures... fs roi atimospheric press..r;e to 'ubou *00 psia.o In I o?.: the cases, t he e vpo.r pressures were dete' mned - the static iethod. Lo~ Pre F ssur'e Vrapor Prs Pressure E tuipme nti Tce lIo'-pressre vapor p-ess're vpo p s e >ipmert.. wa s. l for the:rrost: pFanrs o 2f gl-ass, S.. f'Lo d~a -ggrla.m osf this s e;',:ipmen1t is shown in Figure 1. A piu,:.ctu:.re. of 'thi.s app-ras s presented in Figure 2, T1he Syst"enm w.aS,initially: eva.cu-.te.d I m.ean. s,o tie merc ry diffusn.on.i p.,. ump~ -. -.nd pth ue Bo' tovac puerssp { u don to a pressu.re of abort microns of,er.sr:.:', This pressure 'was messi..red ty.ee. of the McLeod gage (F} Ca.rYor., t e' traflF or:,or-de fron. t:.e;.r::l.:. nde:r,:- - was sl owly i.troduced into the sti:. n.-less st.:eel Iso'te:niscopEe ':' - is ners th e ioteniscope in a 'bath of. o.d Ie iso:rescop e was prpovided 'wit.n a fittingO for 1/4 -: irs es't-,e,':ee:li,:uir.g a::nd connIect'ed t0o -sta: sntee 'vave r.e, After tre ioe us lo.,t ina.f-fii.i determined y- t'ae technine of raisin.ng aond lo..er of the: a.: s des'r: ed y H the s ainless steel vasive:r: e I:-.s closed at.-:.da:ie isoer isuope ',as trar.sfered to a con.st.ant te, per- " -. -..i, er- repea'td fol.lhofs or'-e made to completely r-eove t._f.e eL? "l,: ',the ioo:.d, p- ess ins the isotenisT pope 'was tested '.elifore eah,-c'~ r 'n" ':,:,eans of t the- lo pressure Bo'u..rdo:rtuvbe gage (3' and i f L 'was less tshan 1I- 12 at ospheres p ress ure a. the temperat'c e of the bath:the system, "?as cinected to thte TU-tute manometer (E T'he mercizrv manometer legs of t.e U'-tult e m'riometer are rmadIe of 20 mm O.D. glass tubing and are a/bout 4./ inch- es lon..ri.e is.:enisope.ss ea s e a.,-aintaired at constant, temperat-ure for at leasst; i -t 20 zmin:rutes -:fore enac-h. run:: means of the conseta,,nt temperature

I I H E i ioride Cylinder E - Mercury U-Tube Manometer a High Pressure Bath F - McLeod Gage b Stainless Steel G - Mercury Diffusion Pump c Valves H - Vacuum Pump d,ef J - Barometric Leg gh i Stop-Cocks jk Figure 1. Schematic Diagram of the Low-Pressure Vapor Pressure Equipment.

-15 - Figure 2. Picture of the Low Pressure Vapor Pressure Equipment.

-16 - baths. Two different baths were used in position B, depending upon the required temperature range. A bath of isopentane was used for temperatures from -1270C to 1550C and below -155 ~C, liquefied propane was used as the bath fluid. Figure 3 shows the arrangement of the constant temperature bath system. The bath fluid was agitated vigorously by means of a stirrer. The bath was precooled to the required temperature by means of dry ice and liquid nitrogen. The temperature was maintained constant in the bath by controlling the rate of flow of cold air bubbling through the bath. In order to prevent clogging of the air lines before entering the bath, the condensibles in air were removed by passing through a condensibles trap as shown in Figure 3. The air, free from moisture and other condensibles was cooled by bubbling through liquid nitrogen contained in a. dewar flask, and passed into the constant temperature bath through a silvered, vacuum insulated Dewar tube. The temperature of the bath could be controlled accurately by a trial and error procedure of controlling the rate of flow of air bubbling through the liquid nitrogen container. The right leg of the mercury manometer was continuously evacuated by means of the Hyvac pump and the mercury diffusion pump to about 3 microns of mercury absolute pressure. The pressure exerted by the liquid in the isoteniscope was thus determined by measuring the difference in the mercury levels of the manometer by means of a cathetometer. The cathetometer used in these measurements could be read to 0.01 mm by means of the vernier-attachment. Readings of the cathetometer in these experiments were reproducible to 0.02 mm of mercury.

_ Pressure Gage Dewar Tube Compressed Air — ~L. LI Condensibles Dewar Constant Trap Flask Temperature Bath Figure 3. Schematic Diagram of the Low-Temperature Bath.

High-Pressure Vapor Pressure Equipment The schematic diagram of the high-pressure vapor pressure equipment is shown in Figure 4. Part of the low-pressure vapor pressure equipment was used for the purpose of evacuating the high pressure vapor pressure system. The stop-cocks d,e,f,h and j of the low-pressure vapor pressure equipment were opened and stop-cock k closed. The glass-tube fitting (I) was then connected to the high-pressure vapor pressure system. The system of evacuation and loading of the isoteniscope -were the same as described in. the section of the low-pressure vapor pressure ecuipment. The high-pressure vapor pressure eqluipment was constructed of stainless steel. All the lines were built of 1/4" st;ainless steel high pressure tubing connected with proper high pressure fittings. The U-leg, shown in Figure 4 was filled,with mercury tup to a level slightly above the valve (p). ThIe right leg was filled for the remaining part with oil including the Bourdon tube of the pressure gageo Two different baths were used in position B, depending upon the temperature ranges requiredo n-propanol cooled by means of dr\ ice was used. As the bath fluid for temperatures from about critical down to -78~C. Below -78 C, isopentane was used as the bath fluid down to about -125~C. The method of controlling the temperature down to -78~C was the same as that described by Hou(17), by the variation of the height of immersion of a tube containing a mixture of dry ice and n-propanol in the bath, until constant temperature had been maintained. A number of boil-offs were made during each run which not only served to remove the volatile impurities, but also gave the evidence of the presence of two phases, which is essential for these measurements.

To Low-Pressure /* ----- - _ Vapor Pressure Equipment K 1 Oil Mercury Level 7 nI A p Vent _ ~ ~~~, A - Carbon Tetrafluoride Cylinder B - Low Temperature Bath C - Isoteniscope D - Pressure Gage E - Carbon Tetrafluoride Bomb k,b,m,n,p - High Pressure Stainless Steel Valves / J Figure 4. Schematic Diagram of the High-Pressure Vapor Pressure Equipment.

-20 - Four pressure gages were used in position D of Figure 4 as follows A 0-1000 lb/sA,.in. As:hcroft test gage with 5 lb. subdivisions xwas used for pressures from 500 psia and up. A 0-500 lb/l's. in. Heise test gage withl 1/2 psia subdivisions was used for pressures ranging from 100 to 500 psia.. 0-100 lb /s.in. Heise test gage with 0.1 psia subdivisions was used for pressures ranging from 100 psia, down to about 20 psia. All the Heise test gages w:ere temperature compensated and provided wiIth external bleeder system so that it was possible to completely evacuate the bourdon tubes of' these gages before filling them with oil. The press:re gages were calibrated before and after the vapor pressure measurements by means of the Dead Weight Gage Tester in the Sohma Precision Laboratory. Saturated Liquid Density Measurements The methods used in tlhe measurements of the saturated liquid densities are essentially the sa-me as described by Hou. (17) A number of floats -were prepared in the required density range and calibrated precisely using the microbala,-ce of the Sobma Precision Laboratory. The densit-y "bulbs were then prepared, which. contained the calibrated floats in them, and each of the density bulbs were numberede The density bulbs were then evacuated by being connected to the low pressure vapor pressure equiprent, in the same mannr.,er as that described in the section of the high-pressure vapor pressure equipment. Each of the bulbs was immersed in a bath of liquid nitrogen and carbon tetrafluoride, whicb had been given a number of oil-offs to remove all impurities in a, collection bomhb, Swas loaded into the bulb until

-21 - approximately half the volume of the bulb was filled with the liquid. The liquid was frozen quite rapidly and the bulb was then sealed off, using a gas-oxygen torch. The sealed tip was annealed with a low temperature flame~ The liquid density bulb was then connected to a rubber tube for vertical suspension and immersed in the bath as shown in Figure 5. A transparent Dewar flask was used for containing the bath fluid. The liquid density apparatus Swas completely encased in a steel casing with its front-view section made up of two sheets of shatterproof glass sheets. This was necessary because there was a chance that certain glass bulbs could shatter, even though it was expected that they would withstand pressures up to as high as 1000 psia. Further protection from shattering of the density bulbs was achieved by means of another explosion shield in front of the glass-window. By means of a lamp behind the bath, the liquid and the float in the density bulb were very clearly visible as shown in Figure 5o The temperature was controlled by the regulation of the rate of flow of compressed air, by means of the air-regulator system situated outside the apparatus. For the measurements of the saturated liquid density, it was necessary to determine the saturation temperature at which the liquid had the same density as the calibrated density float. At this temperature, the float would have no tendency to either rise to the liquid surface, or sink to the bottom of the bulbo Since this was extremely hard to detect, sets of temperatures at which the float started to rise and the float started to sink were determined. By convergence of these temperatures after maintaining at each temperature for about 10-15 minutes constantly, it was possible to make fairly accurate measurements of the saturated

-22 - Figure 5. Picture of the Liquid Density Apparatus.

-23 - liquid densities by averaging the two temperatures at which the float started to sink and started to rise. The difference in these two temperatures was approximately 0.03~C, at the final convergence. The same baths, as described in the section on the vapor pressure measurements, were used for the liquid density measurements. Critical Temperature The critical temperature was determined by averaging the temperatures at which the liquid meniscus disappeared and reappeared. The same liquid density bulbs as described earlier were used for these deterrrminations. Since it was necessary that the liquid density bulb should contain just the right amount of liquid for observing the critical phenomena, a number of bulbs were made with different quantities of liquid in them, and the correct bulbs were selected among them by trial and error.

CORRELATION OF DATA Vapor Pressure Data Precise experimental data on the vapor pressures of some of the compounds were plotted on a ~nP vs 1/T graph. It was observed that a straight line did not result as predicted by the Clausius-Clapeyron eq:,uation, but a definite S-shaped curve was obtained as shown in an exaggerated manner in Figure 6a. The negative slope of this curve M,(46) which is equivalent to -d(enP)/d(l/T) is plotted as a function of T in Figure 6b. The first and second derivatives of M with respect to T, 2 namely the values of (dM) and (d-m) are plotted in Figures 6c and 6d d2M respectively, as a function of T. It was observed that d- was a horizontal line up to a temperature close to the critical and from there on it had a tendency of upward curvature. Thus, it was possible to represent the equation of the curve of Figure 6d, by the equation d2M y d M x Y (16) dT2 (F-T)2 Integrating successively, dM xT+ Y +I1 (17) dT F-T and 12 M X n - yn(F-T) + I1T + 12 (18) dT x yen(F-T) Ii 12 dinP) - M - I- - 2 T2 - + -- + ]dT (19) T 2 T T T or >-T yinT y(F-T) inP = - F FT n (F-T) + IlnT - I2/T + 13 (20)

-I I -'I. I-~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ I I, ~~~~~~~~~~~~~~~~~~~- I I I --,, i~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~al Critical, Point Critical Point jnP x 1/T (a) dM d2M dl? Triple Point T (c) tr I Critical Point Critical Point Triple Point T (b) T (d) Figure 6. Correlation of the Vapor Pressure Equation.

-26 - Grouping the constants, &nP = A + B/T + CenT + DT + E (F-T) ~n(F-T) (21) T It was found from an examination of the vapor pressure behavior of several compounds that the constant F was approximately 8~C above the critical temperature of the compound. The data on the vapor pressures of carbon tetrafluoride were fitted by means of Equation (21) by determining the constants, so that the data were represented with a high degree of precision throughout the entire range. On the basis of several trials, the value of F was determined to be 424~R, since it represented the data best of all other values of F used for testing the equation on carbon tetrafluoride. Other constants were similarly determined by testing the various combinations of the five-point fit in the entire range. Liquid Density Data The critical density was determined by the method of rectilinear diameter. The plot is shown in Figure 7. The values of saturated vapor densities were calculated from the simultaneous solution of the vapor pressure equation (Equation 21) and the Martin-Hou equation for the P-V-T behavior presented by Bhada.(6) Also the saturated vapor density values obtained by extrapolation of the experimental isometrices of Bhada to the saturation curve are shown in the figure. A smooth curve was drawn through the saturated liquid density data obtained in this investigation and the locus of the mid-points between the saturation densities of vapor and liquid was drawn. This locus, called the rectilinear diameter, was practically a straight line and by extrapolation of this line to the critical temperature, the critical density was determined to be 39.06 lb/cu.ft. Based on this value of the critical density, the saturated liquid and vapor

-27-..-O a gs o through values calculated from the simulIBhada.) 2 i. '3IMI~W~i3dV43J, LEGEND The saturated liquid density curve is drawn through values calculated from the liquid density equation. The saturated vapor density curve is drawn through values calculated from the simultaneous solution of the vapor pressure equation ar~ the P-V-T equation reported by Figure 7. Temperature-Density Diagram for CF4.

-28 - densities were recomputed and Figure 7 was prepared on this basis. The rectilinear diameter in this case was found to have a very slight curvature to the right at temperatures close to critical. However, the data in this range are not sufficiently accurate to warrant this slight curvature for this compound. Hou(17) proposed the following equation for the correlation of the saturated liquid density data: d = de + al(l - T)/3 + a2( - T)2/3 + a3(1 - T Tc Tc Tc + a4(l - T 3 (22) Tc where dc is the value of the critical density and Tc the critical temperature. This equation has been tested earlier to successfully represent the data on dichlorodifluoromethane and perfluorocyclobutane. (20,28) This equation was also found to represent the data of carbon tetrafluoride with excellent precision. Heat Capacity at Zero Pressure The heat capacity at zero pressure Cv* was computed from the data available in the literature on the fundamental frequencies of the compound, using the methods of statistical mechanics. The computations were based upon the assumption that the heat capacity consists of components due to translational, rotational and vibrational motions of the molecule. The anharmonic contributions were estimated from the correlation of data on other chlorofluoro compounds as described by Albright et al.(l) and McCullough and co-workers.(31) The details of the methods are outlined below. The translational and external rotational components for the heat capacity at zero pressure are independent of the nature and size

-29 - of the molecule and have each a value of 3/2 R. The total vibrational contributions were obtained as summations of the contributions of all individual degrees of freedom, each corresponding to the particular value of the fundamental frequency v, as follows: 4 x2 ei (C*) = R Z (23) v i=l (exi 1) where xi = 1.4388 vi/T (24) and T in degrees Kelvin. The most recent of all the data on the fundamental frequencies of carbon tetrafluoride are by Goubeau et al. (16) Because of their claim of the high purity of the sample used and high precision in measurements, these values have been used in the calculations of the vibrational contributions. The statistical weights of the energy levels are respectively 2, 3, 1 and 3 for the four fundamental frequencies v1, v2, V3 and V4 values. The anharmonic contributions were calculated from the semiempirical equations presented by McCullough and co-workers.(31) Based upon the experimental data of Masi (29), which he claims are to within 0.15% from -30~C to 90~C for the heat capacity of CC12F2 Albright and co-workers(l) determined the corrections for anharmonicity. They assumed that the difference in the values of the specific heats calculated using the rigid-rotator harmonic oscillator approximation and the experimental data was only due to the anharmonic contribution and correlated the data to obtain the constants in the equation presented by McCullough and coworkers. In their calculations for the harmonic oscillator case, they used the fundamental frequencies determined by Claassen(9) and products of the moments of inertia by Gelles and Pitzer.(15)

-30 - The data were correlated in the form of the following equation presented by McCullough and co-workers: C= 2 H* - Ho C<(anh) = Z( ){[3(C*/R)/U] - [1 + U][ T ]} (25) where U - (26) Albright and co-workers determined the constants in this equation for CC12F2 to be Z = 0.1573 and the frequency of the harmonic H* - H~ oscillator for (C*/R) and ( — -) values to be 300 cm-1. T As suggested by Albright et al., the calculations for evaluating the contributions for anharmonicity were made based on the following assumptions: (1) The value of Z is the same for CC12F2 and CF4 (2) The value of v is proportional to the sums of the fundamental frequencies. Using the values of fundamental frequencies for CC12F2 determined by Claassen and the latest values of fundamental frequencies of CF4 by Goubeau et al., the proportionality constant was calculated. The following equations were derived using the equations presented by Hougen and Watson(21) and the semi-empirical equations presented by McCullough and co-workers. Other constants were obtained from Rossini et al.(36) 547.00914 x = -eT (27) x2 ex a = (ex- 1)2 (28) b = (ex (29)

547 11" 7i 2 12 C \^(anh~) 5~- 015T3- {i- " (i + |)bst} (31) The values of C.C were computed at several temperatures as sumnma.tions of the tr.anslational, rotational, vibrational, a~nd anharmonic contributions. PT. results of these values 'were correlated 'by, means of an equation of the following formn C~ a + 3" + T2 ~. -3 (32) which, is the common form for representing the specific heat as a, function of tempera',ure in. 'the literature This eqiuation has been found to represent the values calculated from the statistical meth.ods, s uie satisfac, torilyo

RESULTS The data obtained in this investigation and other data used in the computation of the thermodynamic properties is correlated by the following equations ~ vapor Pressure pb6.7 505285 loglP - 20.715L4539 2 ---- --- 4.69017025 logl0T 0 7707077954 + 64-798076:- 10 4T + - (424 - T) ogo(424 - T) T (33) where P is in psia and T in ~Ro This e[ua tion represents the vapor pressure data with an aver= age of 0.124 percent deviationo Liquid De nsity d' - dc + 69. 5648907(1 - 0)1/ + 4.5866119(1 -)2/ I-c _c I CC Te + 36.17166615(1 -:-) - 8.05898583(1 T' T / (34) "c "c where d- is the liquid density in lb/cu.ft. and dc and Tc are respectively the critical density and the critical temperature. The ecuation represents the data within 0.14 percent deviation. Critical Consta nts The critical temperature was determined experimentally to be 409.50 ~R. The critical pressure was calculated by substituting the value -32 -

of the critical temperat:'re in the vapor pressure eq-uation, and found to be 54. ol6 psiae The, cril-ial density was determined to be 139 06 lb/cu.ft+ by the rectilinear dia.metere me t..od. PVT Behavior The following equaation, correlated by Bhads a) has been used in furtber computaJtjions of th.e thtermodyna.-mic properties of carbon tetrafluoride. RT P =,; - _ + (v-m) -kT/Tc -T/Tc A2 + B2T + C2e A; + B_'T + C-e!;;^T21 ~' ); C ~~i \(v*-b) -kT/Tc Ah4 k + B5T + Cre +,-+ I/ / __ ^ _I _ ( - b ) 4 ( [-b, ) 5 (35) R = 10715/ 0 oi,- Oo1219, K3362 (ft3)( {psia )/ (l' b) (~P.) A2 - -31K37886 ^2 -- 3o2480704 10! 3 02 - -21.911976 A -:.O=056,:30627 - G 56567'67 x 10-5 C 7n oC0052630252 A4 - 3o.l5173T x 10 AR L -l52l0W'6 10x B^5 - 6.6533757 x 10-9 c5 -3K. 5786565 x 10-6 b - 5.7104970 x 10 -k 5.0 and P is in psia and T in ~R0

Heat Capacity at Zero Pressure LL-O -~-u a~t emo Pr where C* is in This range of 180~R Cv - 3.00559282 x 10-2 + 2. 704352 x 10-4 T 2. 5660077 x 10o T2 2.953880 x o" 3 Btui/(1b)(OB and T in ~R. e,:uation represents the data. wit+hin 0.:3 percent in the to 1170 ~F.

DI SClSSI 01 T9s.por PreSs sre The consistency of trhe data. on the vapor pressures of carbon tetrafluoride obtained in this:nvestigation wes tested ty means of a reduced plot of log Pr vs. 1 /Tr as present;ed in Figure t. The values of Pr aend T7, are respectively the red-ced vapor pressuiare and reduced temperature of the compoundo Data on ot'er fluoro-chloro-d erivatives in this series -were also plotted o:n this graph. Data on the vapor pressures of dichlorodifluoromethene -were taken from Kelles et al. 2 d Grka andyka and co-workers. (l) Datta on the vapor pressuires of chlorotrifluoromethane were obtained from Albright. 2) Other availdale data on the vapor pressures of carbon. tetrafluoride were taken from Booth and McNabney 7, Menzel and Mohryi- - and Ruf.f ad Kei.i. and are -.lso sho'w'n in Figure The daea preser.ted in t t^lhis inve, sti gation ifollomw extremely consistently with the; generral trend for otherc compou.nds in this series. The data agree ywell vitr. te values repo) ted by Booth and McNLabnrey a-nd Menzel and Mo-ry, ',&r t it; s u.nite evident from the examinsaion of tbhe plot thae the dat a b f and and Keie,inconsfi stenr; ith t the general ti-rends expected for this coipound.o The reason co-l;d be due to imp:r"ities presernt in the compound. 0 Li:luid Density' The consistency of the liqauid density data on CF4 was tested on a reduced liuid densit;y plot of, 1/'.? ' 2/; d- c S z Tc ^, l)/ i -) Tvs. dc./ C Tc

a? o.. o J 0 g? I ID I O DATA 08TAED IN THIS INVESTIGATION ON CF O DATA BY MENZEL AND MOHRY ON C F (Ref. 30) O DATA BY BOOTH AND McNABNEY ON CF (Ref. 7) X DATA BY RUFF AND KEIM ON CF4 (Ref.37,38) A DATA BY ALBRIGHT ON C CI F, (Ref. 2) O DATA BY MICHEL ON C CIF2 (Ref.22) 7 DATA BY KINETIC CHEMICAL, GENERAL CHEMICAL AND MICHIGAN DATA ON C C12F2 (Ref. 5,18,22,28) 1.0 I.1 I.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 T,/T Figure 8. Reduced Vapor Pressure Plot for CCl2F2, CClF3 and CF4.

for a few ch.loro-fluoro derivatives of methane. These data are presented in Figure 9o The data on the saturated liquid densities of carbon tetraflluoride obtained in this investigation are plotted along 'with other data 'by Ruff and Keim( 37- 8) in this diagram. Data on dichlorodifluoromethane were taken from Gryka et al. (18) The liquid density data for CC1lF, were ob'tained from Alright. (2) Data. on CH2F2 were taken from Benning and and mm et al) (28) and McHarnessU5) and Mar-tin et al (2 Data on trifluoromethane were taken from Hou and Msrtin. o20) i t is ui'te evident from the examination of this plot that] there appears to be a general trend for all these compounds. Th.e data on th.e liqjuid densities obtained in this investigation follow' the generaal trends extremely well. The data points of Ruff and Keim, however, appear to be quite scattered, thereby proving to be inconsistent.'wi;th regalrd to the normal `trendso The errors in. their data could khave beenr caused either by inracxcuracr L:r, the temperature measiu.rements or 'the density mea-surem nts or 'roth. Critical Constants Three of the runs made on the critical temperature agree very well -Awithin +,00,3~F. Th e crittcal pressure was calculated by extrapolaAtion of the vapor pressure curve up tko the critical temperature. Taking into account the error introduced by the critical temperature and the percentage deviation of the neighboring points -with respect to the vapor pressure equation, the critical pressure is subject to an error of about 0.2 percento The critical density determined from the extrapolation of the rectilinear diameter to the critical temperature may have an error of

-38 - 2.75 2.65 2.55 9 A AI I izl-^ / P / 1 I2.25 - I,-I, p% K// / A~c V XX / 7< V /X/ 2.05 1.96 1.85 1.75 I M ~ d V- CH2F2 DATA o- CHFZ DATA A - CCI2F2 DATA 0 - CCI F DATA 0 - CF4 DATA In this iwntigation X - C F4 DATA BY RUFF 8 KEIM V I 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 2/3 (I - T/Tc) Figure 9. Generalized Liquid Density Data for CH2F2, CHF3, CC12F2, and CF4.

-39 - less than 1.0 percent, taking into account the maximum of 0.14 percent for the liquid density equation fit and 0.2 percent for the error in cri.tical temperature measurement and the remaining in reading from the graph. Table II presents a summary of the critical constants reported in this investigation along with other data from the literature. TABLE II COMPARISON OF CRITICAL CONSTANTS Literature Source Property This Investigation Booth & McNabney(7) Critical temperature 409.50 409.79 Critical pressure 543.16 540.81 Critical density 39.06 39.61 (estimated) Heat Capacity at Zero Pressure To test the consistency of the heat capacity equation which was obtained by statistical methods, the experimental data on the liquid heat capacity of carbon tetrafluoride were taken as the criterion. The proced;re consisted of calculating the saturated liquid heat capa3city from the vapor pressure equation (Equation 33), liquid density equation (Equation 34), P-V-T equation (Equation 35) and the heat capacity of the gos at zero pressure (Equation 36). The method used is illustrated in Fig.ure 10. The n:ihalpy changes are calculated along the five steps shown in the diagram.

p /Constant Temperature Constant Volume 1 H Diagram for Testing the Consistency of Gas Heat Capacity Equation. Figure 10. The following are the final forms of the equations derived from the vapor pressure equation (Equation 21), liquid density equation (Equation 22), P-V-T equation (Equation 35) and the equation for the heat capacity at zero pressure (Equation 32). Step 1-2: Step 2-3: Step 3-4~ Step 4-5: AH dH = (Av) dP = CvdT + V(P)VdT (37) (38) dH = T (P) dV + VdP dT V - = [T(p) + V(dV) ]dV dT V dVT - AH = (AV) T + dT dH = CY dT + V2(dP) dT - s - dT sat (39) ('0) Step 5-1: (41)

-41 - Summing up Equation ( 7) 'through. Equation (41) and solving for Cv -v - C s+ + (dI')t + V,~~~d-V-: sat da-T - I.dP,,. d " dTT' dP vdP `d'\ ~ ~T~/ RL d~f TV() d 1 et ~- - aP.,sa (42) 1(47.) Since d atH> dT -^I ) j,dP ( d2P; "I - -i 112'sat ~~' - v T ( s - V + T( ) d( )s dT sat dT sat dW at d 'satI +444) Also, or PdP dP d ~ -dP> TdIT sat a-T VP (dP~ (d2~, d-T' ' sa t., dT e+ - LT + (dv)Pd T sat i dPT dT' "; I in -I; ip I U 1F^ I,,, 47 d, '7' 'e L Substituting Equation 4.tK in TE;aation (42) C,Cs dP', I+ ( CV, -_ Cs + 'T' --- dT" sat d r L. sa+t-9 - )I fdP~ + T d2 d s. T d- sat dPl dv f-,dP TI —.).. V-) 'dT '' s dT d T + dP\,d dTP E, dT'sat - d -j d'd T d sl, at (48)

-42 - or = o5 + Tv~(dP) + (-V _ Vj)[E(dP) Td2P c- =s 2.V ' ( s'+ " -d~ v F - TrS2P~ I C- sa+ - - sat T(dT )sat (dP - dV \ dP dT' sat 'dT -dT sat,d^P,dP dV + T[ (^t) d s a, t dTV sat Simplifying and using the value of (Ts) ppl tion of proper onve on fa tors, application of proper conversion factors, (49) from Equation (47), with the r d~2 C,: c + 0.185053T {( - (- P,) C 'sat (dP) d(V dT sat dT sat TdPsat (dP,d T r C (dP] 12 1 dP 2 dl' v \ _- 1Y ) (50) where the value of Cv is obtained from the relation '\ ' p d2 v= C. + J T (T) dLT 00 (51) The following are the final forms of the equations derived from the vapor pressure equation (Equation 21), liquid density equation (Equation 22), P-V-T equation (EEquat.ion 35) and the equation for the heat capacity at zero pressure (Equation 32). 1.- _ (52) d (53) (d-) dT sat =P{ - + + D! ( 1 + F- (F-T)} Pi- ~, +T ' T where B - 2.302585093B and D: - 2.e02585093D.

C2k 32 - T-~ e kT %, C0k kT B3 - T7 e dP. (-d) dT V R t _f-b) (',bb )2 ('-b)3 C5k kT T kT (+ 5 - 5 (V-b)5 (54) 2 dT- V kT Ck 2 ' ' _ c) e.Vjr -b2 C k2 - Te (c, — t ) e + OriiL kT k 2 - Tc (- T) 5 ('V,-b) (55) dP dX T -=RT (V -b 2 4 A4. i. i-b) - kIr2 (A2 + B2T + C2e kT 5(A5 + B5~T + Ce Tc),( -b)6 T ~ kT _ 3 (A_ O7, I.. + BcT + C-ce (V-b)4 w.. (56) dVi1 dT 1 2 s Tj, d(dy) dT 1( ': o ( ) 2 'I -2/3 { a,,i - ) + 2a2(1 - 44(1 )} + 4a~4(~,1 T= T - I - 7 1/, - )!71 + 3aa I (57) Cv = a + pT + /T2 + 5T3 T 2(k — ) T e.LC. c kT 02 t 2 + {(v b) C7 I + 2 (V -b)2 05 4(v.b)I (58) The comparison of the liquid heat capacity obtained from using Equation (50) through (58) with the experimental liquid heat capcity by Selby and Aston (4) is presented in Table III.

~-44 TABLE I I I COMPARISON OF CALCULATED AND EXPERIMENTAL HEAT CAPACITIES OF LIQUID CF4 Li4uid heat capacity Btu/(lb)(~R) Temperature Percent Deviation Experimental Calculated 220 0O2081 0.2014 + 3 3 240 0.2104 0.2148 2.3 Because of the second derivatives involved, this presents an excellent check on the consistency of all the equations used, especially the equation on the gas heat capacity.

CALCULATION PROCEDURE FOR EVALUATING THE THERMODYNAMIC PROPERTIES OF CARBON TETRAFLUORIDE The datum plane for calculating the thermodynamic properties of carbon tetrafluoride was taken at absolute zero. Thus, at 0~ R, for solid, H = 0 and S = 0. The properties of saturated liquid at 180~R were then calculated from the thermal data on the compound down to 120K by Eucken and Schroder.(13) Below 12~K, the contributions for the thermodynamic properties were obtained by evaluating the Debye functions and the PlanckEinstein functions and integrating the specific heat values calculated thus in the range from 0 to 12~K. The entropy checks very well with the values obtained by the statistical methods. The details of these comparisons are shown in. the Appendix. The tables of the thermodynamic properties are divided into two sections. The first section represents the thermodynamic properties of saturated vapor and liquid. The second section contains the tab-es of thermodynamic properties of superheated vapor. Saturated Vapor and Liquid The thermodynamic properties of saturated vapor and liquid.i..e divided into two parts. Table IV represents the thermodynamic proper' —.es as functions of temperature, and is termed "saturation temperature ta-ee The properties evaluated are (1) saturation pressure (psia and Gage), (2) liquid specific volume, (3) gas specific volume, (4) liquid density, (5) gas density, (6) liquid enthalpy, (7) latent heat, (8) gas e:irilpy, (9) liquid entropy and (10) gas entropy. Table V represents the thermodynamic properties as functions of pressures and is termed "satu.ation -45 -

-46 - pressure table." The same properties as listed for Table IV are tabulated except that the saturation temperature is tabulated in place of saturation pressure listed in the previous table. A convenient interval of pressure has been chosen depending upon the pressure, so as to be most useful from the point of view of practical utility. The equations used for the calculation of the thermodynamic properties are developed as follows: Enthalpy of Vapor The following fundamental relation expresses the effect of temperature and pressure on enthalpy. dH = CpdTp + [V - T(dV/dT)p] dPT But VdPT - d (PV)T - PdT (60) and - (d/dT)p dPT (dP/dT)V dVT (61) Substituting Equation (60) and Equation (61) in Equation (59), dP dH - CpdTp + d(PV)T - Pd + T(dT)V dVT 62 With the initial datum conditions of T at zero pressure and aigiven r: and P or V, and evaluating the respective derivatives from;the P-V-T equatioon, the following equation is obtained.

kT - A2 V A2 + C^2e ( - -o To *.l V Cp dT + [(P'V)T 00 + k Tc.c + J [ V-co ('V-b)2 kT AQ + C-e Tc(i + kT-. -. iTc A4 =,4 (V- 0) (VJb) 3 ( \f b; A5 + C5e kT TI r l m + k L) ] 3 d'p (63) (V-h )5 where subscript 0 indicates da.t'+,m condition. By integrating Equation (63), H - Io = f T To kT *X- V A2 + C2e T(1 + Tc) Cp dT + [(PV' T]V=- + - ( — rp -~' 1 o (I- ) k + T A.,, + C-e c(1 ja.... kT, + T.c + + 2 (I' -b)2 kT Ac + c e (1 5~ + 3(V, -tb ) kT,y (64) From the relation - -2 -:1 H H ) - ( - H) and the relation Cp = C.- + R (65) (66)

We get,.i. A2 L - [I C~ dT + FV + - VJ kT + C2e l C1 + k A A-, + C -e C &1,;'' kT+, + -— C c / + AL + - (" —b ) -- 2 (<-b)2 kT A5 + 5e- Ti + (1 + }, 2! 12 kT - ZI Tr "tL! i.1 (6-) Using the reference propertie.s as P1, j, T1 and H1, E:lation (67) gives the values of -H - Href':Dropping the subscript 2 in order to generalize the properties for anyr temperathlre and pressure, kT A2 + C2e Tc(1 i'-', 1, ~T2 7'!.'I -T H - T. - + - + —. + P"' + (V-hb) kT A-, + C.-,e T0c1, 7 + k - ) r 4 - 2(~ - )2 A5 + 5 r 1 + 5 ) 4. ~_:, ' n + 4 4(7-' — A4.x (68) 1wh ere X = Href [OE Tref + 1 2 1 t 1 4 2 Tref + 7' T ref + 4. ef t 'P ef P ref. ref ref 4 - ref ref -ef kTref A2 + C2e T — (+ k., T ~,,-P Li. ( + iref - 'b).? - - L

kTref A3 + C3e Tc (1 + kTref Tc + + 2(Vef - b)2 kTref kTf A5 + C5e Tc (1 + Tre) 4( -b)4 4(Vref A4 3(Ver - b)3 (69 con-td) Entropy of Vapor The following fundamental relation expresses the effect of temperature and volume on entropy. dS = Cv T + (d Td - v T dT 'T Integrating the above equation between T and zero pressure a-nd any given T and P or V, T s -S = - Cx dT + V TT -o V V* R V-b kT k rT B2 - C2 - e Tc + TTc (V-b)2 kT k - TB3 - C3 Tc (V-b)3 kT k - T, 5 - C5 T e (V-b)5 ] dVT or T S - S J= f To * dT C -+ in (V-b) - B2 (V-b) B3 2 (-b)2 2 (V-b, ) 2 B5 4 4(v-b)4 +{ C2 + (V-b) C3 c3(V-b) 2 (V-b)2 4(v-b) 4 kT V -- e TC]Tc Vo (72)

-50 - From the relation that (73) T2 AS = f as- -- T1 Cv dT + [Rin(V-b) T -B B3 V-b 2(V-b)2 B5 4(V-b)4 kT k ~ T- C2 + _ e- Tc {2V-b Tc C3 2(V-b)2 C5 1,T2 + V-b4-1 T1 Similar to the case of enthalpy, by using the reference properties of P,, a, T1 and S and dropping the subscript 2 for generalizing the properties, S = a in T + P T + v T2 + 5 T3 + R en (V-b) 2 3 - B2 (V-b) _ B3 B5 2(V-b)2 4(V-b)4 kT -~ k - C- 2 C3 + e Tc [ - + + c (v-b) +2(V-b)2 Y = Sref - [a in Tref + P Tref + C5 5 4] + Y y 2 6 3 2 Tref + 3 Tref (75) where + F,n (lref - b) - B2 (Vref - b) B3 2(Vef - b)2 - B5 4('ef-b)4 kT + k Tc { C2 Tc -ref - + 3 + 2(V ref b)2 (76) -4 (-, )t — The method of calculation of these tables is summarized below.

-.51 - Saturation Temperature Table (i) Saturation pressure was obtained by substituting the value of temperature (~R) in the vapor pressure ejuation (Equation 33). (ii) The vol'ue of saturated vapor was obtained by substituting the values of pressure and temperature and solving the P-V-T ecuation. (Equaltion b5), by trial and error using Newton s iteration method. The density of the vapor is the reciprocal of the vapor density. (iii) The saturated liquid specific volume was computed from Equation (34) and Equation (52). The liquid density was obtained directly from Equation (34). (iv) The latent heat (Av) was calculated from Equation (43) and Equation (53). (v) The value of X from Equation (69) was computed from the known reference condition of the enthalpy at Tref - 180~R. The value of H for the saturated vapor was then computed from Equation (68). (vi) The liquid enthalpy was determined by subtracting the latent heat of vaporization from the vapor enthalpy(vii) The value of Y was calculated from Equation (76) from the known reference conditions and the entropy of vapor was then computed from Equation (T5). (viii) The entropy of liquid was determined by subtracting the entropy of vaporization, which has a value of kHIV/T, from the entropy of vapor.

i) Saturation Pressure Table Saturation te_-pecature \-s o tained by substituting t;n.e value of ess e a te vapor pressure ad sol th e.;a.tiorr (E quation 3 ) by trial arnd error using,e.ewtonrs iteration meth-od. The method of calcula ti ng thre remaining properties is t-,he same as ( 1ii to viii me nti oned a,,ove. Super.t ea ted.'apor Tee properties are prese:rnted in lTae;le \VI as funct ions of P and T for albout O00~F degree of sI. per?:ea at each of th'e pressures. The pressure intervals have been so chosen as to have mraximum utility for practical app1ica tions;. (1' The volu.me of the gas tas c'omputed b:- substit Luti ng the values of prtess-ore ar.nd temperat-....re and solving the F-v'-iT equation '[ E.i;ation ' 5 1by tria.l arnd error using Newtor:s iteration meth od. (ii., L. The value of enrth-. lp,es computed in the same manner as described for the satura.tion properties. (iii) Tle value- of entropr was s.iilaarl1 computed b;y- the same method a,s described for the satrationr properties. Figure 11 presents ti.e pressure-enrthalp diagram su ari.zing the results of tie tacEles presented for the saturation vapor and li.uid and for tne,, superheated vapor regionro Constant temperature, voli.ume and entropy lin~res are presented for +lthe conventp erce of desgn a.:nd opera.tion of refrigerating equippert t using thi.s compound.

UNITS TEMPERATURE ~F ENTROPY BTU/LB -~F VOLUME CU. FT/LB REFERENCE CONDITIONS H=O AND S=0O FOR SOLIDS AT 00 ~R C;ONSTANT I IVOLUME b6 b &A 19 I i u a rt 3000( $oo0~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~0 2OO0~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~1 700 5O~~~~~~~~~~~~~O 300 I I 0.50 4000 "'120 14I 60 1 ~~~80 UL I / LI I VIII I A I 104 50 - - - w oll~~~~~~~~~~~~~~~~~~ ~~~~~~~~~-0.8 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~0.75 ~~~~~~~~~10. lw.0-. 300 0.30 P 2~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~.0 ~~~o_ -160 ~ ~ ZiA _' Ld ~ ~ ~ ~ ~ ~ ~ ~~~~o o' o' o 7 I II I v I 1 9 6 -22 25.0 O0 650 24.,,v, 81 1 r ~..1...... -.. I c —r-nn I I i/i I I r v l riI i/i I I ri I /0 I " 015. 5' i ' I r r 1 1 I I I/I r II I I I I/ I I II o o I -f- R I I I /I Io L o 0.6 z~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~5. -260 +~~~~~~~~~~~~ aoc 9 0.2~~~, 0.7 L 2cu 0 0 20 3 0 0 6 7 0 90 10 10 10 3 0110 7 A 1A*A% 3A CO I SCALE CHANGE I-..j", IK)V Iru -II J/LB) L i z.lu - zzU Y30 24V 25u 260 270 280 ENTHALPY (BTU Figure 11. Pressure-Enthalpy Diagram for Carbon Tetrafluoride.

APPENDIX A TABLES OF THERMODYNAMIC PROPERTIES

-55 - TABLE IV SATURATION TEMPERATURE TABLE Units Gage Pressure Inches of mercury vacuum up to 14.696 psia and psig above that pressure Liquid Specific Volume Gas Specific Volume Cu. ft./lb. Liquid Density Gas Density Liquid Enthalpy Latent Heat Gas Enthalpy Liquid Entropy Gas Entropy lb./cu.ft. Btu/lb. Btu/(lb)(~F)

____ focT9*(J ^9 ^*0 U ''"*O1 ____ Q ^ c- * (i Q _____ +7 t. *' 7fr * i I t- /^Q1-7 * ^ 2 I 3 U 1_?* ^OC (J T _ +I7^O Q OO - 17ICT I7T*9T 9 1 9 +7. e 0.7 0'O 9 9 +7 c- / 9 '9 +7' T 7 C-+ 0 C7 I '9 Q +7.0'9 ' 0 79'/ QT T T- '9 91?q 9 - Q. 0 +;/ c 9+.+7 c + 0 T, */. e C, 9 4+, T/ - 0 0 9c- *be ' I C 70/ 79 c0 ', 0' I 0 +'0o6 / 6 9 T 0 - C 9 Q T 7 -/L [ P9 0 9C+, C0u /'f "c' (JOI O., T 9e /.9 707 0 T1,0'.0+ C )y 7 9 0+7 '9 eg[7.- I i T 9 9 k/Le90. +79/S e O 70)C, O[ '1e)9./ TF'71./0/'I O L;[ 9(,e I- I*o I. C. 9* '(').)e 9o 9T6 9 o e e 69[T7 -g,~ 'l q l u q9e, ) 0 /i A-h-[I I C. OT' _ 0~!: T 9 _ n (7[ TI e T 1 * C~. 0 T * <:9:fc 6 *: c t j' T __ c,- 7 c 7(ie ' - b - bx {o Q ()[ 9 7 eoi T. i" a7 T 9 A:: C 7.` 7+)k*9 [ 9 + c9-+-'(/ 910" 991619 9;00j. q0jg0 9/1090i 919, e c J01750060 t991,9T e 9i *qTe i77_ hI. 9 yi. Q t 0 0 1 9 C 'U [9 C ~ 7{ T 99 9 9 +7 T + " T -. I + 9 e T 0 9 h I C 7 0, C 9i 0 0 00?60 0 T o 7 C e +7 C I' 7e7 -c'(! 9,C0,0 I c 61 C. ' - 9 6 +7 /999Rc! C 0 40196C ) e j9 69 T ~& 9 e 711oT C ~ '*' e q u ' * c t "96 0 91 T9 0 ( J' 0 t'7 T c+( q 9 9 9 7C 0 0 I r 0 -e /T. + 47 e 9 77 - t,.. o ( ")C: 99' e T Q 0 / r T 9 T 9 /7 C P t7 /9/ 11 T 'I/F U 0T +,"C (0 7 Q 9 ( 4 - C 00 e 09 ' T 7( l 47 0 I, +" e 77.(94900 C/,9 4 O0'0 +(OT i /19-T6 9 -t 0 i 7 /407/ 9 T '999+79T -f<: 19179)0097 P 0 * +97 09l149 p77.. ' 917 9 ). 9 e6 7/ 9g eo0 0 9 0'+? * "-+()T T T r~ T'r 0 9 *i..~'9 +,0? ~? + [T C / (J T T o T o ] (c,-.?.7 O ~ 0-17 C o+. C7 9 ~ v- 7 / 7' + c 77-,(_. ('9 Io / cc l) Rc9'[ l _ t 2'r.:: q 7 _ [ i',+P. r' * 7 +7/ __ 6+,? " ~.p? e7 T Q _?!rI o I 7 t( 0 ' 76f9 I ft OC9b0: 9 * O0 ZOL?qe C9' c- dc'O ( r" o I /-'<-T 7/77Q Qc7679c' q! ~.'-T 7 T 9T 7 ) T T 'C UT qp'[co991 o o9 o o 7o-7O 77 09C 7 79TTe-& 'T?1 -,/ /f.9 e 9/1C,) * 79 Q,/g e T 7 9 1/Q 91 T / 016TT 9 I, -eT +.e,cC (C74000 " C 1T ''e7 OF9"/7, ' j T Q 9C6: 9 T (_ i () / l() 7J cI,([ C) I 7 6Q 7 A 01 C0 eOUT P/(.~ / - 0O 9~ 0 00.0/o e +7 7 TTI7t '9 7 -1y 9et /" 7.//4C0. / e0. 9 1o9 L7 " +7 o /9U 0 9 + O 9/ 970e 9?/9. e 9 9 *! ~O9O/7*? ^7 -9 90 8Ig9' L'9 A 0 U9/f 9 U 9qeF9 / 0 Q +, 0 o< 969 9 ' P 9!CI0 7 11', -, / - /;e t.L - ' 0 96'F9 Zt ~-' it o b ^ 9 +;, I u ' 0I i0 UTT 9i 9L'6FQ 3i- 0( j00 0/.60 '. " 6~J9 9 0. 99 e c 9 -. ~ 09 7 I -/ Q T o /.c{, m 6 9' '_- + 7 QC& +' I T O c-c T0 / /0 0/ -:' g. 9 'e 0+' 9171~'9 '9 7Zt7t-,9; C. t6,)9. O 'CT C TI C9 f: Q ~ t l- e) I e jT "*", 7 T C'Tb 9.,/ 0/-) C e 99 I0 '[ "C79 7 9' ''7 1 '197 -07 Tr 9 * 0 6 / 7~ * 0 if + * 9 c Q ~ * ( 9. u 0 *. T T " A U h 9 T T I 0 * T40 7 9 r T 0 ~ TI - 8/9-97n. 05, +, - I O * o- c. ec Lj c)+0 C ~ A 1. /'-" 1O6 'k /-, - co';7 o ( 7T/0e o c} Cc9/9T 7 ~? 9e 7+./ 9 ' // e1.0 T 9,c1 e '~,c7 I 0 0 T-1(.; O(, T - c T 6T/ 7 T00 0 T 0.! 9 9o - T 67.+.i? a ~ 4 r, +7 7CI I? 9 7 9 9 I Q P A +t7 i P 9 e I C I I I o. 0:, 0.. T, C 0 l' I,~ T 7 C- 6999'0 1c9+sd7 09OII i7 1*T909090 C)1T0-/7+919O9T I09 * T T IC O O.7.I0*^'7 QP T 0 0997. 97+79 *;0C9+7 0 0 9 9 9 0 9T C T 9 Q0T 9 c 0 '0 +7 9 I U </ T / 7 T T T J 9 9) / 0 7 90 * /97 7 0 7 c9990 +7 90+7 910'99 '0 96 0 ( r -i * C? c9 6 A /7A QO I i; 7 -, * T 77 7 T 0 7 C9 7 + >6P 1'9'U /9116./i 0 6I P:[ c' 69c9 /.;. r- ~ C (CCc IL CQ+cCuTr C To ~T > I T70, 100 e C C - I0 7 9 T? CF 0 1 e97 -/tt0[790 7.6 9 U c94116/) 9C; 0. 6/<9, C90 _, + o Qo+' / g e,..t 7 0 0* 0 ' e 27 0[ 0 9 * 9 1P)) C( ) 9 - /7.7416 T '7.90/ 71/i)U '0' " Q-9 ___ 47/ 1 P. I 91/97 9/9 ) 97111097 9979999 7?707C*,.? - i c T _ iQ TlCQ OL00 C). r T: -; Tc./7OT.. Lg~7H~~9tlY'O~~~~~~ CeLLJ L)i4$C:? t C 0 0 ) 0C Q/(16 C7 9/7 077... 9999 O0 907 t ZU; QT C,FT -b 0 )C)( O ($ ' I /, 9. Z '; 'e IT / U. - A e 7 0~ /g I 9 9 17.. R /9'9T1 +:, 1 ' * I 111: ~ o T..I I.. 9 9 7. 67 9 9 0 ()/ 09: 9 - -., ~ + Q ' c 9 T c Q ' 9 T T 1 -/ / 49. p T/9 0977 7/9 70Q 'C 7 -f49T I eU / eo i-T 1- T [u! T TL ce/ 4. iUI. e,QOAT7^; U('1' 7 [ T;T e 0j7i ~ (;I o Oe ~)i +.e To~.T ) e * C * 7 — - 7k >J- C.if^7 )%''9 +9 I C QC 9 p U 7 i u t C T T 4c Co Li C I; Q O 4 QP( I~, 7 0 i 4-bc I j *09C; 0( 7 0 ' *,:.; I / ' ('~ c'. 7 c A [ UT '7, 0e Tc +7 9',,- e T C I *-I: TI ' 9.. 1: / F o0 I0 T Zo c C T O t 7e C~[ 999 i ij i 7 -; 7 T i 7. i- T c.T - c T 97 /g ge:. *: 0"eIC 9 Q ij (0 [ f T i C T0 C- 1b C T T C T r I, l T o ) * c i) C C 7b {7 Po.~C Q 7.777r7 l * /994/ 0(9; 4/9 1ii I O 7 ~l I I,i ' I' I 99 90.9 7 0 9: I 7.. C. ce '6TTI997 T T'/. /:' I [ U 9 0e97... 9 0; 9 C, e /09..C0( or)0 Q T 6 Q Q C 7 T + q. 0 T I e (797. /T4 /I.-) T+Ct/.,T T 1,- 9,...(:/) T,9 761 /99 70 0997.U [~9199) 79719 o0[9CTe (C) T. i7/49069 / 91/0996- f?,,,099,, /10Q4G C /6,b44 P T u J C I T/ C I~q 'Po / C, + 9097 977770-9 6 I f7. I Ad9OLN AdO1,Na AdI1VHiLNa iTvaH xd9I1VHML ALIS/ma XLISNCI 0A dO s 70A dS aOV VISd d OIa SvO aInbIn sv1 ILVI iI flbI sVo aInbI Svr M17I a U n Is s a d d AI 71gVl

TABLE IV (CONT'D) TEMP PRESSURE - DEG F PSIA -2 1. 7.9;;,) GAGE.i1 nI. LIQUID GAS LIQUID GAS SP VOL SP VOL DENSITY DENSITY n yin 1n >.w4 14 I n., / O.t; 4 /; LIQUID LATENT GAS LIQUID ENTHALPY HEAT ENTHALPY ENTROPY 4 ).i;l)~i t,? hI *44 1 ) - (.-); 6 i m 0J.,66 aB. ENTROPY r )., 1 7 4 -214 7.5744 14.49366 0000933 3~o 3/7 10n ~r04 a)2437 2 40336. -373 10't361 0 0. 0'0 0(.6147 -213. 799239 13.7869 0a0039541,, 3.7 1811 1%4. 12( ".*2683~ 43.'4 uD, 5 48 6 0 a 2 5 10 5, 8 3 3 4 0.3689 O_6 _ 0.6141 -212 8.2662 13.0492 0 009;36o 3.56763 104.536 0~2o030 457 (877 60.i43 105.930 0.3707.65.39 -211. 8.6616 i12.52 0 0.00 3663 3.*42423 1 ( +*33 0.29204 4 6.O O"0 60 26 106.02/ 0.316 (.6123 _ -210. 9.0503 11 4935 0.009600 328773 104.166 0.30416 46.21I2 a5991)0 i06.23 0.1/'24 0~612 -20 3. 9.4 52 6 ~0.6o7 12 0.00 61 7 3.1 7o __ i j ^ 0~ l 6 __ 4 0+1 0.3 ___ - * ^_106~30( 3 10. 211 0.*,313 0 *8318 __ -2068. 9 o662,.b262 0.60 1634 3.0 13.4 ("I79 0 3~ Do 46.64.;0 5 et)7 -? 106,317 0 (1.9141 0.6117 -207. 10.300 9 4 i 00 6 2 I0 3 2 6 o 0 20 3 4 46 40 90 '? ^>. 10604140 * 5.61,7 -206. 10.,46 o.042 0.001669 2.o04'9 103.420 0.336-62 1+70( 61 D390434 106.510 ~ 0.(1 (.6101 -20. 5 11.206 I' _ 7 * 1.1 4 O 0 009 6 o i 2 2.9 a b5 ____6o9 3 a bv> ___OI 0( 1 43 3o 6~ 3 9 t ___ i ~ 6 O 9 600. _ -204. i 1.682 6.136 0.00970? 2.59496 103.044 0 346 36 47.512 9 6 1 2 o2 l9o70 19 0. 91O '*6o"7 ~-20 3 ~ ___ i e. 1 i.7 4 _____ _j, p13. 0.003o~oo9722~ __ 2.* 4 0 a 0 O/ ____14 2 ~ rt56 *('4003 4 5 9.06 106.7973 - -202. 12.662 4 099 0.00974)0 ~40460 102.666 *41338 47.9 16 9o.o941 106.o % O 7Y '; I)O' 'n -201. 1 3 2 207 3 0 0 92 7 0 ( 6 3 1 D( (7 4 1.2>476(6 0.491 l6 4.8 & 1 9 2 5 5 h 8 16 IO.10 6. 9. 818 O k). __ f 0 /4 -200. 13.748 i 930 0.009 /i 77 0 202 —0 906 l7~/ 2 b6 ' ^ 4 9.~3943 9*0601 10f' 09 1..100" (. O6769 -199. 14.306 0.I0 793 0.0097933 2.al1 '0 n 6 79! 0.4031 48. 167 0361 "i o 1 i ' 76o 0 a. o ". 0 _ r 6064 -19. 8 14.662 0 166 0.O00-ol3 0 '2 62 i O03 0'+4 13 - +4b o4C;3 30.31 107.~1 2() 0 1010 0.0033 -197. 1 1.476 Of 60 0000 103~b 2 1 39983-1 in 1 7'1 ~l 0 4 43.71) 643i ____ 99 1:-3( 1 0. o6 6~ /1. 93. -03 (I 4 -196 16.086 1.:392 0 0098 30 1.92 7 11} j 3 19 ((*l 7 49.29n3 9 61 6o i 10/'.460( 0.904' 0'. i4' -195. 16.719 2.__ 023 0.0198693 2 373 (.1377 7 __24 9 1 b 1 o u 6 10 7.3 33 (. a 3lo: 2 0 4 t -194. 17.170 2.6 '4 0 00O 9 Ja1 04 1 131. ('. 33I 71 43. i4-.) O I / 10 -) *646o) a7 100) '.'( 6(''40( -193. 18.039 3 ~ 3 4.3 3 0. 0 4. 0 7 1 I I 3 3 100 ' a ' 10 ' 401 i) ( 00 '6.8)( -192. 18.726 4.*03202 0. 099266 1.6 *(i(-4z '*1373 00*1G'A f )0. 310 ) -191a 19a438 4._74742 0.00 946 1.* 6 10611 _ 100*146 7.61o6 9). 4 2 4(oi 3) 10.' 213 (1 f 9 0 -190. 20.1 68 59472 0 009 - l*t 1.3 3'i ao4'z3b I)* 36a (39.017 0 *'0n5* 0. 4 '.' 021 -"189. 20.* 9198 ____ 6.223 0.00?9o ~ i~ 031_ 0 j- ' 6 __ ''. 08 9 'g o _ ~ 17 l')9133 0 ^0^r a 7771 -188. 21.692 6.996 0.01000a.~4I2 04,, 4 2~ 3 s3l~121 8 37.lt07 l0~.00oj (1f 6o)12 -1. -l 22.4o6 7' a, 7 1 ' 00 < 10 4 0 1 ' '4 1 r; 8 __ I 17 6 / o 7 3____ 1._~_1313J? _____?. 9 ( 06. 72919 0 ( n A, 0 08 __ - 1o66. 23.303 ~~0 71 0 ( i0~4 l0o4 / 9'^o ~'.126 31.303~^ 306 0)99 1398.3831 0 *9 3"0 7.610'4 - 1ld3 o 24,142 ___ 4 t> 0 Q O n i 2 o ___ )j > / 3o 9 0.___ * 31.01o 3 0 0 1 (.__ 3 ~ "i __ '0 9.4 730 (0 1"') (__ ).19 S93 __ - 1 64. 25.004 10 ~ 33 0.Ot~ u''o ' 1~ 77 (3 / /.9)lo7o2 3 1*. 0 31? / 96.t 300) 100.9617 ))e01 0.1-99 9 - 18 3 2 3.-) 9 l03 11011~ O0. )I~0l08 107 0 0 3 ( 0 3 7.2 9 3- 2 6.39)). 3 I(D.3 4 1' 39 491 -182. 26.19 6 1 2 i0~ 10 0.0 i1 1 6 i l 47 (31 7 'p 1 *32.932 3 0. 1 606.143 4017.130' 0.3 6 987 -168 4 * 257.1732 1 0.36 _ 0 b0 1.1 3 3159.9 4 5 '. 624 5 2.1 17 3 2 60 (.332 I10 a 2 I) 0 - 9 8 -160. ~o.630 13g114 0."''~lo~ o ~*12-;)24 3o~ 352 "*' 90301 *033 074 9 0 0 * i 1 2.iOof 1 936 u939C/i 0 5929 - 17. 2 3.632 1 * 6 0.0)0~33 i 1.011400 0.100 9 0. 9 l ) 9l3 3 a lo Oa 0.) 1 0 0082 0 9 0 ) a -17 68 30.6 (2 15.166 0.*010 210) 1.034 44 37 93+44 0 03407 53.4 o<64 93g403~6i'9 (09 09 533 (",i0 '<1~<i3f02 )).19/C) -177. 31.716 6 17.020 0.010231 1.0~236(9 1 " 3 3 ( 0 9 ~ 8 1 31 i/(3 - * 9 7 (04_06 31.4110n 0.23 1 -176 32. 177 18.081 0.010253 0.9911l 97.533 1 0(090 53.9692 530100 ("'0/01) 00'~c] ')~.i9(-l6 -17. a 3.36864 19. 16 0.0~027- 0,6 10 7 t__ 7 327 1.0440 )' 34. 2 1l)' ) 1 0 3 (1.9o 0 31 ( _ 939 _ -174. 34. 17- 20.263 0 *010297 0.93.3: 3 97 12(l.07z/ 34+,4-37,)0! 3j0n 1i0) lO.47)3(70 Q+03934 0 9 -"173. 36.121 __ 21.425 0 3 010319 0490438 ____ 9 9 1 1 1-+.4 71'.0?' 2 _z i 0(. 04 _0 63'9~i2.la1 1 1 9 41 __4 112. 37.290 22 594 0 010 341 0.877( 8 96.7')3 i 1^^5 34~. 448 31.660 ]0'.6125 0.4047 0.6947 171. 38.489 23.193 0.010363 0 o8!51 1 96.4 31 1 (1741 33.13 3413(13 0.o? 1 0.4656 0.1944 -170. 39.71.6 295 020 0~01 3866 0 82767o ib~2183 i*1(a 3 03a43'48 3>4.341 109.100 (J0.4j(4,)~394t -1 6 4 0. 9 7 2 26*276 ~ 0 i 04 0 10 ) - o6. 0 7 4 3 1 * 6 6 5 94 1 0 41 (7O o173 (1.99 6 - 166. 4 7 1.l2u 0. 1320 4 0 & 0 6,~ 3 10113-i7 31 001 0 0." 'o i i)). 931 -16 7. 4 3.5 74 27 8 8 78 0.0 1 0U 43 ~ 0 ) a 7 t v_ a64 o 1.371)3 0 1106 1) " I (' 1)0+ ~'~0n ' 7 ^97 4 _ 166. 44.921 30.722 5 0.u 0476 0.13 66 9j*434 1.3 3 )0*43'9 5316/0 ) 0.4013 t '.3976 -165 ~ 46.6 29 I8IaO (1 0 2 0 i 0 10 0 0 i 4o 0*9 ) J,Z 21. 3 1:1 0 41 1o _,972 - 1 6 4. 4 o 40_. o. 0 ) 4 1 i ' 0 i1 ) 6 l 7)g11 13 ___ ')L 0'g o l i _ - 16. 4 a * 6 a 4 3 2 40 4 91 0. 0~0 0 04 'L., /4 O V L i"))4 U a ' l - 1 6 2 3 0 * 6 1 J Z~ ~ 0 * 0 ~ ~ 3 k. ~2 ) 9 4 1 3 ~ 1 1 1 6 3 1 3 (i * 41) ( i. 1 I16 1 1 ~.12 6 6 ~ 0 ' 71.0 9 0 2 1 ~ 0 9 )' 1 0, 1 1 1 '' 0.1 3)7 3 - 1i 6 0 * 93.'~665 33 ~1 oO* 9 6~7 0 '0 10 62 0 *b. ' o7 9 * 1 i -.) 1.0 6 100 6 ))7 * '-s*) -: I * m11 0 1 i'3 I. (-)I * 4(a~. 3 U9-( -1 *9 3 2 3, 7 _ 4 0 a 4 1 0 * ) -10 64^ o 0~603o6 __ 9o 13 1*6'60 __ *-n* 2 1,l 1 ___ a^ 4, *i / __ I.l0 o io I '+ 1 O f ___ *"S1J2 -196. 36s843 4 2 * 1 4 0 * 0 ~10 I4 6 O J 4 0 6 )).L.*498 -157 38.4864 43 7 0 1 69 0.3 7 6 7 3 7 I 7 4 0 3 0 2') 10 0.* 1 4 '14 0. 89 -1 3 6. 6 0. 16 0 4 3 464 0 1046 ( (0 ' 3 1 0 ) ) 41 1) 7)00100 1 o '. a 6 8 a 2

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TABLE IV (CONT D) TEMP PRESSURE DEG F PSIA GAGE LIQUID GAS LIQUID SP VOL SP VOL DENSITY GAS LIQUID LATENT DENSITY BNTHALPY HEAT GAS LIQUID GAS ENTHALPY ENTROPY ENTROPY -91. 246.*67 2 2r 1o9 o7 5 i i6 1 22 5 9 1O7 /62 3 3r 1 1/i37 ll. 54a 0.9 4 6-0 7.6 7 11 4-94 2 -9l~r4 2 7 o / -oo 2 7 6 l 1 i 0 Ls 3/ *lid 1 i -) 9l ( 0 ( 7 570 -9 3 2oa628 _ 241-90j0013j 1 124n37 6 2 3 5 8. 0 5 9 3 76 (68860(1 36 6 9 4 1 3 a8 0()2 0a 47 C)4 ( 57(14 -9 261 9 2 4- 0 * 0! i ) i 4 1 7 ~2 2 8 8 6 8 * 2 42 7 7 7 7 O 201 3 6 36 7 11s 6 0 471i 7 U I - 1 4 i - 3 2 4 3 / 7.* 1 6 * 0 4 * la4 i3 7 6 9 I7 - 0. 0 * <L / i i l i J O 6 * > 0 * 'J i 9 9 ( - ~ i ioo3 -) i / - * i 7 4 8 * 6 2 2/ ' ( i o s 6Y 9 3> * o 0 0 11 3 * " 37 j 7 i 2 o 0 4 8 a 6 4 6 9 4 -o 7 2 * O 3 3 lz 6 1 6 4 0 1') i 3 i i 1 4 I 2 8 2 1 7 8 1 6! 3 I o 3 3 74 1 1 1 3 0 4 i 39 * 69 1 -688 281~si Loo.j 001 9343 0a110~1 /7 *444 9*0C)43 /.d4ti44 5a 0t/ 1li34931/ 0 *47493 1)5687 / L d O * ( 7 2 7 I. ( 0 * i 9 (.) 0 0 8 i 4 i 7 1 9 9 3 O o 9/ O aD 10 -1 a 46 3o 0 a 1 7 3i 40. 4 6 8 3d6 oo 2 4O. 1 / 1/!i 3 a I 446' +1 314.13 I.l 4 3+.296 1. 4!436' (!h 810 _-h 2 D 4 < Y * > o2 0 0 0 j 6 I1 010j4 * I 466 6 i 6. 4 6 9 3 6 li i 4 0 4 7 7 010 6 6 -4;oo~3*'- 0401 7+i3) ~ 1 822 a9. /6 3 336 3 ll a f602 n 04 1 0 ih67? _-1 8 (3 Y i ^ j '1. ( ) 0 ( i 9 3 / o ( ~ 0 9 ) '7 f _____ i 2. (1e01 20 111) 4 10 1 2 4 1 0 318 3 * 1 8 9 6 _ 1 113 1 * 1 7 n 1 ) * 41/8 1 /n 6 h6 8 _ -3 4 6 I ~:- 0 0 boo 0* J6 ) ( 1) l 361 6 8 0464 8 i 810 1 I3 73 (05 C 4 17i 79 (6 h 64 _- l 0 2lg j i 1 v l9 0',i9426 7 i i () ) 6 1 4? 46 1 / 2 * 2 i 3 0 6 48 \ 4. I 661) -e00 3 0 0.! 1 4 O 0 h (! 4) 1 4 /i a6 1. I 0 1 o4 4 1 1 h 363 0 40 1 1 3.1 66 6 -/I "437i>9 2 11.001'11016//3 4 39 8 47 19 11.03478 0.48312 0.657 - 1 7 3 l Ut v a C)* ) 0 13.1300Sll()o 1.8t47 3.13C L l a IuIl 0.4611 73.5644 0 a 44o22 0 6 1_ * /.* _: -. 7 C11 1.7 4 1Oa8 2 1 I 8 8 0 t-t1 2 6 7 0 a 4 1 3 1i7) * 643 _ (,) ~ * D -j > j 8i ^ 4 L; 6 09 * *C) 14- 4 7 4iO _ O J 3 6 _ o6 ', 0; i 1 1 7 a o 9 i 8 9 /* i o t f 1 1 - j 6 7 6 ( _445_ 0) * ' 6 4 - 3 o 3 4 7 * 8 0*04 ) 0.0 11 1 9. 5 6.4 11 7 2 ) 4 4 i 4 876 0 63 9 ___ - 1 '.-> * 3 D d *, o "i ____ j j '-.. 0 0 () 14 4 ls 6 7 ^> 0 * 0( 7 / -J 7 ___ 6 o ~ 1 4 1 1 2 ~ 8 9 1 6 __ 8 3 6 i 0 2I 6 * 9 a o 1 2 b 62 1 1 0 > 4 7, 6 3 24 - /^~ / ~g^ 1;:)F0~'r6 0 t)~*f~ j4 J.-+/ 3' o0af)i'-o ( 6) 53 21 1/2 4/01 01it 24 228-4 1.?a ] l4/ 7 r 4ia 66 6 0.a662 I 36d. o- 0 a (.) i 46 7-, o.! 7 6, 1 4 1 1 2.o 9 1 69 2.6? 7 & 11 02 2 1. 4o 1 6 (1.W6 2 Il 0.'! J o 1 )01 /() 4.0 33 1 0313 (14 i 0) 64, O1 2 44 8 S 4,i; 0 ' 4 068 6 71) -7i - 3 81 *7 ___;*u 0 * 0 8 0, 0.60~ 4-_ 8 4 /1 a 0311 2 44 44 *1 a 94 I 1. 44(6 01 480 4 1.36114 -I 3. 0 - 6O n2 i3 2- o i O 4 C.! a 021 71 0 t a 4 I9 14 l* - 60 9 __-601._ L. 0* ) 9?4t b 09 *', 1! r, i,'S0 1 03.113_66~09/ 14. 300/62 3 J 1 94762 /69 963 1 / 1 3 7 6 49 ] 0 6 0C3 _ -DO 40000 i0'L;! / n 7 4 47 )16 8 nO l o 1 S iOl 1n 0a 1 11/03(.. 8 __-67. 4()o * >,'_4 ' 4 0 *,' 1 1 1 b l(.3 t6 s I 0 8 C_, 1 1 6 I 8 6 4 a 0 0*4933I0' S 1 61 5 92 -6o. ~ 6u6 401..3 00i-C)l ')0o4i3 64,3d8 1-. I 448, 86.4327 2.271 112.7038 0.494 141554 __-6) o. i wj~ C4 2 3 a4662 6 4 1 a 13 9 4 9 86.ob 24.,74 (. 324l a44 9-) 49 -6140X 430 4;^ 4 - -1.,*7,.-:0,t01^6(.3o 0 ) ~0Df)oo9 6 ' 14 ' 6 4 7 2 8 7 3046 403 l 1 i 406 0 * 4Y 64 0 5 72 -6 a ~ 4 -,I I 4 ' 24 3~13') i OO*0~ il o o o O _____ 6 2 & 4 o 1 6 a 9 8 s i7 ____ 87 j 7 W 5 2 j a s I t 1; 1 i 1 9 ]. '- 6 0 0 49 i ^ ____ > ft5_a__ 5 -60 4453. 0 'F06 S? i 0O0161o 0 10) a2 6. I 72 / 617 9 8 1 7 5 2 2 S 8 2 2 R 2 0 6 8 s 1.1 000 * 1 4S 87 Y'55 / -6 1. 4 0 4 2 6 1 a 7 2 I I 0 82 2].12 4 12 2i6 1 100666 o 6 464 9 4 49 -6 0 4 6 0 *61 4 4 - 1 0 168 2 r 0 a 3 4 0 3 2 6 6 0.09.2163 2i- 110i 3 i30 0 1i 40 -. -59 468 44 4 7'4 0 016 09 0 0 3 1 D 4 9 4.1 "-1 3 9 4 8 91o 6 212 3{0 1 0 a 0 R 8 6 a 0723 C)?. 1 -do 4 76 39 4l66 -7 0017 0c 00+970 -Co06^3 2Ci127 90 1 1ft13285 1 9444 'i1030 / 7 2 0 011 31 0. 4521 a 3 7 4 8 4 * 4 4 4 v 9 T 7 0 6 ( i 9 6 a 04 / t j j 6 g 3 t; J 4 _ 1 8 4 6 9 i t - 3 t 9 9 0 ( ) *! 11 -536.* 4 ' 2. / 4 71O3 7 0., 00 3 u66 2181 1 *6 5 1 4 i 4 6. 8o 30 I0 66 ~ 549 8 30 5 0 1 0 1 8 6 3 2 0 0 1 00 3 74 76 o.' 14 228ol D - l 92l27 / 6 16 10/ i2 1- 8 349(I C)*a5 3 (1.n484 (-3 a )09 9 a 9 Oa700i44 L^ 0 a v) 4 i v4 a1 64i) ' 4 a 4 l6 2 4.0 Do ) 93*0a644 14.a42 12079 0&9166 0 1i2 i )5468 )a-, 1 1 0 3 4 2v0 a C0, I 0 2 2639 3 34 39, 1 3. 2 44 '10 7 2 0 2 3 0.3i2 0.5449 j3 2 D 2 6 312 13 O019 1 7 C 3 0 3 6 5 4 a *- / 36 3 3. 4 1 R ll 2 3 106o2804 J0 31 4 3 I 4 2 4 - 019 543.16 6).408 0 0 0 602 0 i2o.04 3 1011()4 '3 aC 610 100",s6363 *000 100.63-63 (IS5284 0. 5284 I \n l

-6o TABLE V SATURATION PRESSURE TABLE Units Gage Pressure Inches of mercury vacuum up to 14.696 psia and psig above that pressure Liquid Specific Volume Gas Specific Volume Liquid Density Gas Density Liquid Enthalpy Latent Heat Gas Enthalpy Liquid Entropy Gas Entropy cu.ft./lb. lb./cu.ft. Btu/lb. Btu/(lb')(~F)

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-66 - C, Ca - zj-t' _llC i:,- IC C \O f - 4444 r- C C-4 -C4 rCC-I I -- C C 0jLlC 'C\ I C - i' I 4I44 ( CC CC-c -~C CCC CC'C.C CCC- -( C C C4CCC C CCC C-CC (C CCCIC C CC- C CC CC 444.4~~~~~~~~~~~~~~~rcc C — -C Cr44- 4-C C-.-Z cF-4 4.-o- -44 —CCoo -40C 00C\ C C C ~ c <T!CI C,-C ~ )0 C \, <,i'' CC- C C CC CCC CC CC -— I CC.C>3 CC C C C c c C C C C CCC44 C CCCCC C C7C04C4Cc 7CcCCCC4. CC4 C C C C — CC-C CC CC-C C —CC ~~~~~~~~~~~~~~~~~~~C - C C C)f i'(C CC - _ & C C C C ' -:I CC (I 0: f-C -_C 4C\ - (I (D aL C1 C CC CC CCCC CCC 40C-4Ci C C — LC,, -4 C4-CLC'LS - r- O C f`L 4r C C 4 I (4.44C-4447 ~~ %. 44. —c-4C-4 44041>44.- 0'44-,C. —CCC-r\CT, aU r-~c - f' C —4 r 4\ 'I44 CCC4C400 Cr C-44'C~~~~~~~~~~~~~~~~~~~~~~~~~~ ~~~~~~~~c\ C,-.\C\04(rC\, O — C\ 0 4~1-C 0 00 C C\ C c444 44. 444444o —L 414-C -o 40 C CC: (IC- (I 04 rI'0 _ CC C r-Li' d(, C ~C - r f< 4444404444044C, 444la,-4C,4444 C, rr '',; ~ 0 -C CC < ~C 4 C-4\4(rCC C' ir -: 404>444 41CCC4 C-14.C0C4.-CCC4C4-CC,014444C41~~~~~~~q:'y 7,1C\.4:~ 0-.C\ C44cCCO r I I-a'c cCx 0~u ~X 444 a OCO o(4 a: -4a.c —:441 —a oc c:x ca i - a 'C 0C7c-CO ID CCC C ) F-L- -C C - 4 C r-OC " _ - ILCL z.C - 0 f f \L, ' Xc C, C, 4 C,', < & 4 (I4, C - C l2-\ ',0 C!c -, c ', c!r L c c ( I 0 ( l Cc ~__j C r z,c \ C I C DOO I \ C Cr-W 'C "T r-C 1r- L- ~ o -r-r-a -— CCCC-444444C&> 444 C — — C a4a4IOC 444 44 040 I OC44%000~~~~~~~~~~~~aC r c rO~2, ~ CC CC-Or — 444-4 -44 400C-C044 —'CKC 444 444-C-'C4 C7 C-74 4C - a a C o O- -I4.C,(a c c- 44 7 ~;C, 1 40-4 4-J OC% 4 f-4C-0CCL-\1.,r- — T-C- 1C, u -C, --- j!C CCC C\0 C CC C- C\C C - C 0104 04 4-O4 -4 4 4-CC,. -EC- 44404 \ -— CICC C01C- CCCCC~~~~~~~~~~~~~~~~ Co-~!C C C r' C C c c "C\1 f, Cf, inL- f T:,L ~ CCC CC- C C CC \C CC"CCIC C 0,, C O01CC),Ll(IC CC C C CC7C CC ~ - C C- 2222222 ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ -0C-IC-CC-CCC-( CC-C- C C ~~~ CiCCCCCC~~~~~~~~~~~C- CC C CC C C CCCCC C C C C C JC 1 C: c~ccCC ckC C CC Lr-c c c) r ( CCC CLr Iif r-, \" C\C ccr C (x C) C (C C CD C c DI c, C-Cc C C, C C. C C C1 Cl C IC, C C CIC a, C\ IC C\ C C C C C C CCIC(O - ~ f, c cLl (I C r IC \(j c, r- C C-i~ C Co i I 0 (4 4 —4Q~0C2O4>4C-4C4.~oC-4'0~CD.C'bo>C-IC — CC'CC-CCCC CC 44C-,C' -CC' C4C-CC 4 C0-(44 C-. 4cC- c C 0C4 C-, CC, — C)44-44 C-.- CC44 -'0..4- 4414-IC, I CCCC 4. 44 C4 Z~-o -4 C, CC- C0 C.-cC;C'C0CC CCD 404 C).C, 4C) C-)C-C-C-C-C-C-C,-CCC) C-C CC- (04 OC C C C00 4 4 44 4 44 4 (44 c0 n O CO(\00000000- 010 'rC OOC0llt-~ C, o OO OCII CCCCCt-0 0 I C,(, i iCOCOOOOn 'tC —CCC(IC\CC, CC I t CX 010014O 4 1-2 r-44C) 4C4C\ r, - x c 4.4C.4(I 4..L 441,414114441.4C cC14 r4 cD4444CC4- m44 444144.44\,C-c C C.I~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~o 0 Da o o t. ~ a o0 e o 1> - -! 74C-4.4 T7 0 740 7 a0 4 L) L. In -- -441C4040 4 CL,- t r~ — )c 7 oc 0rCC0.4O400401CC4CCCC. cC.4Co.41o o> C m'c-C- oc,- cc, oor — r -r-r C-C-4r400040- CC 44'C --,D T -.C lC.C4444,C.o u " ioC-C-'a C cOO.( L,)-o-CC r)Ini 4(4(C-4(40C-J4(4(4(C-C-4 4444444(4.44.4444444.444444444444444444444 4 4~~~~~~~~~~~~~~~~~~I II II I I II II I I II II4 CC C )0 ICC0 D0 O C 0C C ) 00 l(C )~ ) COC l 0I 14 00000Cbo0Co000000o0C0000 -0(I-)0M00 -0 (0000000000C,0OOOOOcbO C<, ( -11 C',( In4 4 nmI n m m (mC-m ' mC 4 40'M O(004(4 Lf)040 40 04`0 0.04L DL)()INC)LI~N0 40.4 )I,U- ).0i~ n nC Il04 0 0L")04o 0oo O.4Oo0 4I C 040 0I 0- -4j U4- r 4000 4- r 4(4- 0co0.4-o4(4C-I -I PQ IN 0'0C-r ---40u 400 -r- 00O 0\C C-,(4 -, 44IN -o-0C-C-40404CT- 4- O00 —o(I C- I l N 4j C\, ~-c\Jrf-(N N 4( \ \ \ \ \Mc 1M C) MmMC~(, mcIMM (,( ocoe -ot 44444 444 444 444.4.4 4if)44 4444 444 444 4 '

-67 -TABLE VI THERMODYNAMIC PROPERTIES OF SUPERHEATED VAPOR Units V cu.ft./lb. H Btu/lb. S p Gage Btu/(lb) (~F) Psia Inches mercury vacuum up to 14.696 psia and psig above that pressure Saturation Temperature

-68 - TABLE VI PRESSURE= GAGE= SAT TEMP = 0*2 29*5128 -272.82 PRESSURE= GAGE= SAT TEMP = 0O3 29.3092 -267.83 T F V H S T F V H -270.00 115.5343 100.2634 0.6709 -260.00 81,0579 101.2339 0,6668 -260.00 121.6393 101.2388 0.6759 -250.00 85.1297 102.2318 0.6716 -250*00 127.7435 102.2363 0.6808 -240.00 89.2008 103.2517 0,6764 -240.00 133.8468 103.2559 0.6856 -230.00 93,2712 104.2935 0,6810 -230&00 139.9495 104.2975 0.6902 -220.00 97.3411 105,3571 0.6856 -220.00 146.0516 105.3609 0.6947 -210*00 101.4105 106.4425 0.6900 -210*00 152.1533 106.4461 0.6992 -200.00 105.4795 107.5496 0.6943 -200.00 158.2544 107.5530 0.7035 -190.00 109.5481 108.6783 0.6986 -190.00 164,3553 108.6814 0.7078 -180*00 113.6164 109.8284 0.7028 -180.00 170.4557 109.8314 0&7120 -170.00 117.6843 110.9999 0.7069 -170.00 176.5559 111.0028 0,7161 -160.00 121.7520 112 1927 0.7110 -160.00 182.6559 112.1954 0.7201 -150.00 125.8195 113.4066 0.7149 -150.00 188.7556 113.4092 0.7241 -140*00 129.8868 114.6416 0.7189 -140.00 194.8550 114.6441 0.7280 -130*00 133.9538 115.8975 0,7227 -130.00 200.9543 115.9000 0.7319 -120.00 138.0207 117 1743 0,7266 -120.00 207.0535 117.1766 0.7357 -110.00 142.0875 118.4718 0,7303 -110.00 213,1524 118.4741 0,7395 -loooo 1i46.1541.1.19.7899 0e7340 -100.00 219.2513 119.7921 0e7432 -90*00 150,2206 121.1285 0,7377 -90.00 225,3500 121.1306 0*7469 -80*00 154.2870 122.4875 0*7413 -80*00 231,4486 122.4895 0.7505 -70,00 158.3532 123,8667 0.7449 -70.00 237.5471 123.8686 0.7541 -60*00 162.4194 125.2660 0,7485 -60.00 243.6455 125.2679 0.7576 -50*00 166.4855 126.6853 0,7520 -50O00 249,7438 126.6871 0,7611 -4000.170-5515 1281i245 ~ 7554 -40*00 255.8420 128.1263 0.7646 -30.00 174.6174 129,5835 0&7589 -30.00 261.9402 129.5851 0.7680 -20.00 178.6833 131 0620 0.7623 -20.00 268.0383 131.0636 0.7714 -10.00 182.7491 132.5600 0.7656 -10.00 274.1363 132.5615 0.7748 0. 186.8148 134.0773 0.7690 0. 280.2342 134,0788 0,7781 10.00 190.8805 135 6138 0.7723 10.00 286.3321 135.6153 0,7814 20,00 194.9461 137,1694 0,7756 20.00 292.4300 137.1709 0,7847 30.00 199,0117 138.7440 0.7788 30.00 298.5278 138.7453 0*7880 40,00 203.0772 140.3372 0,7820 PRESSURE= 0.a4 PRESSURE= 0,5 GAGE= 29.1056 GAGE= 28#902 SA TEMP = -26412 SAT TEMP = -264612 T F V H S T F V H S H S -260,00 60,7670 101.2291 0,6603 -260*00 48,5925 101,2242 0.6552 -250,00 63,8228 102,2273 0,6651 -250,00 51,0387 102,2227 0O6601 -240,00 66,8778 103,2474 0,6699 -240,00 53,4840 103,2431 0,6648 -230,00 69,9322 104,2895 0,6745 -230,00 55.9287 1042855 0,6695 -220,00 72,9859 105.3533 0,6791 -220*00 58,3728 105,3496 0,6740 -210,00 76,0392 106.4390 0,6835 -210*00 60,8163 106,4354 0,6785 -200*00 79,0920 107.5462 0,6879 -200,00 63,2595 107*5428 096828 -190.00 82*1445 108.6750 0,6921 -190.00 65,7023 108.6718 0,6871 -180,00 85.1967 109.8253 0,6963 -180,00 68,1448 109.8223 0,6913 -170,00 88,2485 110.9970 0,7004 -170,00 70,5870 110.9941 0,6954 -160,00 91,3001 112&1899 0,7045 -160.00 73,028?9 1121871 069947 -150.00 94,3515 113.4040 0&7085 -150.00 75,4706 113.4013 0,7034 -140o00 97,4026 114.6391 0.7124 -140.00 77&9121 114.6366 0,7073 -130,00 100,4536 115.8951 0,7162 -130,00 80,3534 1158927 0,7112 -120.00 103.5044 117.1720 0.7201 -120.00 82,7945 117.1697 0,7150 -110.00 106,5550 _118.4696 0*7238 -110.00 85.2355 118,4674 0,7188 -100,00 109,6055 119.7878 0,7275 -10000 87,6764 1197857 0722 -90400 112,6559 121.1265 0,7312 -9000 90,1171 121.1244 0.7262 -80*00 115,7062 122.4855 0,7348 -80.00 925577 122,4835 07298 -70,00 118.7563 123.8648 0.7384 -70,00 94,9981 123,8629 0,733 -60,00 121.8064 125,2642 0,7420 -60.00 97.4385 125.2623 0.7369 -50.00 124,8563 126.6836 0,7455 -50,00 99.8788 136,6818 0,7404 -40*00 127.9062 128.1228 0,7489 -40,00 102,3191 128.1211 0,7439 -30.00 130,9560 129.5818 0,7524 -30,00 104.7592 129.5801 0,7473 -20,00 134.0058 131*0604 0,7558 -20,00 107.1993 131.0588 0,7507 -10,00 137.0555 132.5584 0.7592 -10,00 109&6393 132.5569 0,7541 0. 140.1051 134.0758 0.7625 0. 112.0792 1340743 0.7575 10.00 143,1546 135.6124 0&7658 10,00 114,5191 135*6109 0,7608 20*00 146,2041 137,1680 0,7691 20*00 116,9590 137.1666 0.7640 30,00 149,2536 138.7426 0,7723 30,00 119,3988 138.7412 0,7673 40O00 152,3030 140.3359 0,7755 40.00 121,8385 140.3346 0,7705

-69 - TABLE VI (CONT'D) PRESSURE= GAGE= 0.6 28.6984 PRESSURE= GAGE= C07 28a4948 SAT TEMP = -258,59 SAT TEMP = -256,40 T F V H S T F~ V H S -250.00 42.5159 102.2182 0.6560 -250.00 36.4279 102.2136 0.6525 -240.00 44.5548 103.2389 0.6607 -240&00 38.1765 103.2346 0.6572 -230.00 46.5930 104.2814 0O6654 -230*00 39.9247 104.2774 0.6619 -220.00 48.6307 105.3458 0.6699 -220.00 41.6720 105.3420 0.6664 -210.00 50.6679 106.4318 0.6743 -210*00 43.4189 106.4283 0.6708 -200.00 52.7045 107.5395 0.6787 -200.00 45.1653 107.5361 0.6752 -190.00 54.7409 108.6686 0.683C -190.00 46.9113 108.6654 0O6795 -180*00 56.7769 109.8192 0.6871 -180.00 48.6570 109.8162 086837 -170.00 58.8127 110.9912 0.6913 -170.00 50.4024 110.9883 0'6878 -160.00 60.8482 112.1844 0.6953 -160.00 52.1476 112.1816 0,6918 -150.00 62.8834 113.3987 0.6993 -150.00 53.8925 113.3960 0.6958._-140.00 64.9185 114.6340 0,7032 -140.00 55.6373 114.6315 0,6997 -130600 66.9533 115.8903 0.7071 -130.00 57.3818 115.8879 0.7036 -120.00 68.9880 117&1674 0.7109 -120,00 59.1262 117.1651 0&7074 -110.00 71.0225 118.4652 0.7147 -110.00 60.8704 118.4629 0.7112 -100.00 73.0569 119.7835 0.7184 -100.00 62.6145 119.7814 0.7149 -90.00 75&0912 121.1224 0.7221 -90.00 64,3584 121.1203 0.7186 -80,00 77,1253 122.4816 0,7257 -80*00 66,1022 122.4796 0,7222 -70&00 79.1594 123,8610 0,7293 -70.00 67.8460 123.8591 0.7258 -60,00 81.1933 125.2605 0,7328 -60.00 69.5896 125,2587 0,7293 -50,00 83.2272 126.6800 0,7363 -50,00 71.3331 126,6782 0.7328 -40.00 85.2610 128.1194 0.7398 -40,00 73.0766 128.1177 0.7363 -30,00 87.2947 129.5785 0.7432 -30.00 74.8200 129,5768 0.7397 -20,00 89.3283 131.0572 0.7466 -20.00 76.5633 131.0556 0.7432 -10.00 91,3618 132.5553 0.7500 -10.00 78,3065 132,5538 0,7465 0. 93.3953 134.0728 0,7533 0. 80.0497 134.0713 0,7499 10.00 95.4288 135,6095 0,7566 10.00 81,7928 135.6080 0,7532 20.00 97,4622 137,1652 0,7599 20,00 83,5359 137,1638 0,7564 30.00 99.4955 138,7398 0,7632 30,00 85,2789 138,7385 0,7597 40,00 101,5288 140,3332 0,7664 40,00 87,0219 140,3319 0,7629 50.00 103,5621 141.9453 0,7696 50.00 88,7649 141.9440 0,7661 PRESSURE= 0s - ---- PRESSURE-=,9 GAGE= 28.2912 GAGE= 28.0876 SAT TEMP = -254.46 SAT TEMP = -252,71 T F V H S __ T F V H -250000 31.8624 -102.2091 0.6494 -250.00 28,3112 102.2045 0,6468 -240*00 _33.3932 103,2304 _ 0.6542 -_ 240,00 29.6727 103.2261 0&6515 -230,00 34&9234 104,2734 0.6588 -230,00 31,0336 104,2694 06562 --220,00 36,4530 105,3382 0o6634 -220,00 32,3938 105,3345 0,6607 -210.00 37.9822 106.4247 0,6678 -210,00 33,7536 106.4211 0,6652 -200,00 39,5109 107.5327 0,6722 -200,00 35.1129 107,5293 0^6695 -190,00 41,0392 108.6622 0,6764 -190.00 36,4719 108.O6590 06738 — 180,00 4205671 109,8132 0,6806_ -180.00 37,8305 109.8101 0.6780 -170.00 44,0948 110.9854 0,6848 -170,00 391888 110985 0,6821 -160*00 45.6222 112.1788 0&6888 -160,00 40,5469 112.1761 0,6861 -150,00 47,1494 113*3934 0,6928 -150.00 4109047 113,3908 0,6901 - -140,00 _ 48,6764 114.6290 _06967 -14000 43,2623 114*6264 0o6941 -130.00 50,2032 115.8855 0,7006 -130.00 44*6198 115.8830 0,6979-._-120*00_ 51,7298 117.1627 0,7044 -120,00 45,9771 117.1604 0.7017 -110,00 53,2563 1184607 07082 - -11000 47,3342 118.4585 0,7055 -100.00 54,7826 11907792 0*7119 -100.00 48,6912 119,7771 0O7092 -90,00 56,3088 121.1182 0O7156 -90,00 50O0480 121.1162 0,7129.._ -80.00 57,8349 122.4776 007192 -80*00 51.4048 122.4756 0,7165 -70,00 5903609 123.8572 0,7228 -70.00 52,7614 123.8552 0.7201 -60&00 60,8868 125.2568 0,7263 -60,00 54,1179 125 2550 0,7237 -50.00 62,4126 126,6765 0.7298 -50,00 55.4744 126.6747 0,7272 -40,00 63,9383 128,1159 0,7333 -40&00 56.8308 128,1142 0o7306 -30.00 A654640 1 750812.1172 0-07307 6 A o,I -20,00 66,9895 131,0540 -10.00 68,5150 132&5522 _ 0. 70,0405 134,0698 10.00 71,5659 135,6066 20,00 73,0912 137,1624 0,7401 0,7435 0,7468 0750341 0, 534 -uvuus 58.1871 129.5735 0o7341 -20&00 59,5433 131.0523 0.7375 -10,00 608994 132,5507 0,7408 0. 62,2555 134.0683 0,7442 10,00 63,6116 13566051 0.7475 -20,00 64,9675 137*1610 0,7508 30e00 66.3235 138.7357 0,7540 40.00 67.6794 140,3293 0*7572 50.00 690352 141.9414 - 07604 -- 30,00 74,6165 138,7371 0&7567 _40.00 _._ 76,1417 _ 1-0.3306 0,7599 50.00 77,6669 141,9427 0.7631 -

-70 - TABLE VI (CONT'D) PRESSURE= GAGE= SAT TEMP = 1I 27.884 -251 11 PRESSURE= GAGE= SAT TEMP = 1.1 27.6804 -249,65 T F -250.00 -240.00 -230,00 -220#00 -210.00 -200.00 -190 00 -180.00 -170.00 -160.00 V H 25*4702 102.1999 26.6963 103.2218 27.9216 104.2654.29l1464 _1C 053307 30.3707 106.4176 31.5946 107.5260 32.8181 108.6558 34,0412 109.8071 35.2640 110.9796 36.4866 11241733 s 0,6444 0,6491 0O6538 0 6583 T F~ -240.00 -230.00 -220.00 -210.00 V H s U.6628 0.6671 0.6714 0.6756 0.6797 0.6838 -200.00 -190.00 -180 00 -170.00 -160.00 -150.00 -150 00 -140,00 -130.00 -120.00 -110 00 -100 00 -90 00 -80,00 -70 00 -60 00 -50.00.__ -40.00 -30 00 -20.00 -10.00 0O 10 00? A, fl4 37,7090 113.3881 38.9311 114,6239 40.1531 115.8806 41.3749 117.1581 42.5965 118,4562 43,8180 119.7750 45.0394 121.1141 46.2607 122*4736 47.4818 123.8533 48.7029 125.2531 49.9238 126.6729 51.1447 128.1125 0.6877 0.6917 0.6955 0.6994 0,7031 0.7068 -140.00 -130.00 -120.00 -110.00 -100.00 -90.00 24,2610 103.2175 0.6470 25.3755 104.2614 0.6516 26.4895 105.3269 0.6562 27.6029 1 06,4140 0.6606 28 7160 107.5226 086650 29.8286 108.6526 0.6692 30 9409 109.8040 0,6734 32,0529 110.9767 0.6775 33.1645 112.1705 0.6816 34,2761 113.3855 0,6856 35,3874 11',6214 0,&6895 36,4985 115.8782 0,6934 37,6094 117.1558 0&6972 38,7202 118,4540 0O7010 39,8309 119.7728 0,7047 40.9414 121.1121 007084 42.0518 122.4716 0.7120 43.1621 123.8514 0O7156 44 2724 125.2513 0,7191 45.3825 126.6711 0.7226 46,4925 128.1108 0,7261 47,6025 129.5702 0.7295 0,7105 0,7141 0.7177 0.7213 0.7248 0.7283 -B0 U U -70.00 -60.00 -50.00 -40.00 -30.00 - 52 3655 53*5863 54,8069 56 0276 57,2481 5R.A4A 129.5718 131.0507 132.5491 134.0668 135.6036 0,7317 0.7351 0.7385 0.7418 0.7451 o0 *744 -20.00 -10.00 0. 10.00 20.00 0.00 48,7124 49,8222 50,9320 52.0417 53,1513 54.2609 131 0491 132.5475 134,0653 135 6022 137. 1581 138.7330 U. 7329 0,7363 0,7397 0,7430 0.7462 0.7495 cr- v a vv.1 3 -...... I........ 30.00 59.6891 138.7344 0.7516 40.00 55.3705 140.3266 0,7527 40,00 60,9095 140.3279 0.7549 50,00 56,4800 141.9388 0.7559 50.00 62,1298 141.9401 07581 60.00 57.5895 143.5695 0.7591 PRFSSURE= 1,2 PRESSURE= 1 4 GAGE= 27.4768 GAGE= 27.0696 SAT TEMP = -248,299 SAT TEMP = -245*83 T F~ V H S T F~ V H S -240,00 22,2316 103.2133 0,6450 -240,00 19,0426 103,2047 0,6415 -230&00 23,2538 104.2574 0,6497 -230*00 19,9196 104.2493 0,6462 -220.00 24,2754 105.3231 0,6542 -220,00 20,7960 105.3155 0,6507 -210,00 25,2964 106.4104 0,6586 -210,00 21,6719 106.4032 0.6551 -200,00 26.3171 107.5192 0,6630 -200.00 22,5474 107.5124 0,6595 -190,00 27.3373 108,6494 0*6673 -190.00 23.4225 108.6430 006638 -180,00 28.3573 109*8010 0.6715 -180,00 24.2973 109.7949 0.6680 -170,00 29.3769 110.9738 0,6756 -170.00 25.1718 110.9680 0,6721 -160000 3003963 112.1678 06796 -160,00 26,0460 112.1622 0,6761 -150.00 31*4153 113,3828 0,6836 -150.00 26.9200 113*3775 0.6801 -140.00 32.4343 114.6189 0,6875 -14000 27.7936 114.6138 0,6841 -13000 33.4530 115&8758 0,6914 -130&00 28,6672 115*8709 0O6879 -120&00 34.4716 117.1534 0.6952 -120.00 29.5407 117.1488 0,6917 -110,00 35,4900 118*4518 0,6990 -110.00 30,4139 118.4473 0,6955 -100,00 36.5083 119.7707 0,7027 -100.00 31*2871 119.7664 0,6992 -90000 37*5264 121.1100 0.7064 -90.00 32.1601 121.1059 0,7029 -80*00 38*5445 122&4697 0.7100 -80.00 33,0329 122.4657 0*7065 -70.00 39.5624 123.8495 0,7136 -70.00 33.9057 123.8457 0,7101 -60,00 40.5803 125.2494 0,7172 -60,00 34,7784 125.2458 0*7137 -50.00 41,5980 126*6693 0.7207 -50.00 35.6510 126.6658 0,7172 -40.00 42*6157 128.1091 0,7241 -40,00 36.5235 128*1056 0.7207 -30O00 43,6333 129.5685 0,7276 -30.00 37*3959 129,5652 0e7241 -20,00 44*6508 131.0475 0,7310 -20,00 38,2683 131,0443 0,7275 -10,00 45,6682 132.5460 0.7343 -10,00 39.1406 132.5429 _ 0,7309 0. 46,6856 134.0638 0*,7377 0. 40.0128 134*0607 0,7342 10.00 47.7029 135,6007 0,7410 10,00 40,8850 135*5978 0*7375 20.00 48,7202 137,1567 007443 20,00 41.7571 137.1539 eY+74T08 30.00 49,7375 138.7316 0,7475 30,00 42,6292 138,7289 0,7440 7. n =.r.C, A E - A It......,, ( --, ^ 4I.,........',.. '.',L.n - n 7., -, +*U.Ou 5U, f+b 140lU.3,255 50.00 51,7718 141.9375 60.00 52,7889 143,5683 0.7539 0,7571 - 4U0Uu 4-3*,U12 140*322 50.00 44,3732 141*9349 60.00 45,2451 143.5658 - Us 747s 0,7505 _ 0,7536 __

-71 - PRESSURE= GAGE= SAT TEMP = 1.6 26,6624 -243065 TABLE VI (CONT'D) PRESSURE= GAGE= SAT TEMP = 1.8 26 2552 -241.69 T F~ V H s T F~ v H S -240.00 16.6508 103.1961 0,6385 -240.00 14.7904 103.1875 06358 -230.00 17.4189 104.2413 0.6431 -230.00 15.4739 10462332 0o6404 -220.00 18.1865 105.3079 0.6477 -220.00 16.1568 105.3004 0,6450 -210.00 18.9535 106.3961 0.6521 -210000 16.8392 106.3889 0.6494 -200.00 19,7202 107.5057 0.6565 -200.00 17.5212 107.4989 0.6538 -190.00 20.4864 108.6366 0,6607 -190.00 18 2028 108.6301 0.6581 -180.00 2102523 109.7888 0.6649 -180,00 18.8840 109.7827 0,6623 -170.00 22.0179 110.9622 0,6691 -170.00 19.5649 110.9564 0,6664 -160.00 22.7833 112.1567 0,6731 -160,00 20.2456 112,1512 0.6704 -150.00 23.5484 113,3723 0,6771 -150,00 20.9260 113.3670 0,6744 -140.00 24,3133 114.6088 006810 -140.00 21,6063 114.6037 0,6784 -130.00 25.0779 115.8661 0.6849 -130.00 22.2862 115.8612 0,6822 -120.00 25.8425 117.1441 0.6887 -120.00 2209661 117.1395 0.6861 -110.00 26.6069 118.4429 0,6925 -110.00 2306458 118.4384 0,6898 -100.00 27,3711 119,7621 0,6962 -100.00 24.3254 119.7578 0,6935 -90000 28,1353 121.1018 0,6999 -90.00 25.0048 121.0976 0,6972 -80,00 28.8993 122.4617 0,7035 -80O00 25.6842 122.4577 0,7009 -70.00 29.6632 123,8419 0,7071 -70.00 26,3634 123,8380 0,7044 -60c00 30.4270 125.2421 0.7107 -60,00 27e0426 12562384 0,7080 -50.00 31,1907 12606622 0,7142 -50,00 27,7216 126.6586 0,7115 -40,00 31,9543 128.1022 0.7176 -40.00 28,4006 128.0987 0,7150 -30,00 32,7179 129,5619 0,7211 -30,00 29,0794 129.5585 0.7184 -20,00 33,4814 131,0411 0,7245 -20.00 29,7583 131.0379 0,7218 -10.00 34,2448 132.5398 0,7278 -10.00 30,4370 132.5366 0,7252 0. 35,0082 134.0577 0,7312 0O 31,1157 134*0547 0.7285 10.00 35.7715 135e5949 0,7345 10,00 31.7943 13565920 0.7318 20,00 36,5347 137.1511 0.7378 20.00 32,4729 137*1482 0.7351 30.00 37e2979 138.7261 0,7410 30.00 3361514 138.7234 007384 40.00 38,0611 140.3199 0,7442 40,00 33.8299 140.3173 0,7416 50.00 38,8242 141.9324 0,7474 50.00 34,5084 141,9298 0,7448 60.00 39,5873 143.5633 0,7506 60.00 35,1867 143.5607 0,7479 PRESSURE= 2,.. PRESSURE= 2 5 GAGE= 25,848 GAGE= 24,83 SAT TEMP = -239.90 SAT TEMP = -235,99 TF~ V H s T F~ V H S -230,00 13.9179 104,2251 0,6380 -230.00 1,117i 104.2049. 0,6330 -220600 14,5331 105.2928 0,6426 -220,00 11,6104 105.2737 0,6375 -21000 15,1478 106,3817 0,6470 -210.00 12.1031 106.3638 0,6420 -200,00 15e7620 107,4921 0,6514 -200.00 1205954 107.4751 0,6463 -190,00 16,3758 108,6237 0,6557 -190,00 13,0873 108*6076 0,6506 -180.00 16,9893 109.7765 0,6599 -180,00 13,5789 109.7612 0,6548 -170.00 17,6025 110.9505 0,6640 -170,00 140702 110.9360 0.6589 -160,00 18,2155 112.1456 0,6681 -160,00 14e5612 112.1317 0,6630 -15000 18,8282 113.3617 0,6720 -150,00 15.0520 113.3484 0,6670 ___-140,00 19,4406 114,5986 0,6760 -140,00 15.5425 114.5860 0,6709 -130,00 20.0529 115 8564 0.6799 -130.00 16.0329 115,8443 0,6748 -120,00 20.6650 117.1348 0,6837 -120.00 16,5231 117.1232 0,6786 -110.00 21.2770 118.4339 0.6874 -110.00 17.0131 118.4228 006824 -100.00 21.8888 119.7535 0,6912 -100,00 17.5029 119.7428 0,6861 -90,00 22.5005 121.0935 0,6948 -90,00 17,9927 121*0832 0,6898 -80,00 23.1121 _122,4538 0.6985 -8000_ 18.4824 122.4438 0,O6934 -70,00 23,7236 123.8342 0.7021 -70.00 18-9720 123.8246 0.6970 --60,00 24.3350 125,2347 0,7056 -60,00 19,4614 125.2254 0,7006 -50.00 24.9463 126.6551 0.7091 -50.00 19,9508 12666462 0,7041 -40.00 25,5575 128,0953 0,7126 -40,00 20,4401 128.0867 0,7075 -30600 26.1687 129,5552 0,7160 -30,00 20,9293 129.5469 0,7110 -20 00 i26.7798 1310347 0.7194 -20000 21,4184 131,0266 0,7144 -10'00 27.3908 132.5335 0,7228 -10.00- 21,90785 132.525 7 0 --- — 7178 0, 28,0017 134.0517 0,7261 0 O 22.3965 134,0442 0,7211 10.00 28.6126 135.5890 0,7294 10.00 22.8855 135.5817 0.7244 20.00 29.2234 137,1454 0,7327 20,00 23.3744 137*1383 0,7277 30,00 29,8342 138.7206 0,7360 30,00 23,8633 138.7138 0,7309 40.00 30.4450 140,3146 0,7392 40.00 24,3521 140*3079 0,7342 A C C -7 11 A rt 1) -7 7 1. n 1.u '+ 540 1 1e9fU,7 7 5UOUUO 31,U5 141.9 72 U.74Z4 60.00 31,6663 143.5582 0.7456 70.00 32.2769 145.2076 047487 Vutuu e4 o8408 1419207 0.,7374 60.00 25,3295 143.5520 0,7405 70,00 25,8182 145,2015 0*7437

-72 - TABLE VI (CONT'D) PRESSURE= 3. GAGE= 23,812 -_____ SAT TEMP = -232.68 PRESSURE= GAGE= SAT TEMP = 3*5 221794 -229,80 T F V H -230.00 9.2499 104.1846 0,6288 -220.00 9.6619 105.2546 0&6333 -210*00 10.0733 106.3458 0.6378 -200,00 10,4844 107.4581 0.6422 -190,00 10.8950 108.5915 0.6465 -180.00 11,3053 109.7459 0.6507 -170.00 11.7153 110.9214 0.6548 -160.00 12.1250 112.1178 0,6589 -150.00 12.5345 113.3351 0&6628 -140000 12,9438 114.5733 0.6668 -130.00 13,3528 115.8321 06707 -120.00 13.7618 117.1116 0,6745 -110.00 14,1705 118.4116 0&6783 -100600 14.5791 119.7321 0*6820 -90000 14.9875 121.0728 0O6857 -80*00 15,3959 122.4339 0&6893 -70,00 15,8042 123.8150 06929 --60600 16,2124 125*2162 0.6964 -50.00 16.6205 126.6372 0*6999 -40,00 17.0285 128.0781 0,7034 -30,00 17.4364 129.5386 0,7069 -20^00 17.8442 131.0186 0.7103 -10,00 18,2520 132.5180 0.7136 0. 18.6598 134.0366 0.7170 10,00 19.0674 135.5744 0,7203 20.00 19,4750 137.1312 0O7236 30.00 19.8826 138.7069 0.7268 40.00 20.2901 140.3013 _ 07300 50.00 20.6976 141.9143 0.7332 60.00 21.1050 143.5457 0.7364 70.00 21,5124 145.1954 0.7395 T F~ V H S -220.00 8.2700 105.2355 0.6298 -210.00 8.6235 106.3277 0.6343 -200.00 8.9764 107.4410 0.6387 -190.00 9,3290 108.5753 0.6429 -180.00 9.6813 109.7306 0.6471 -170.00 10,0332 110.9068 0,6513 -160.00 10.3849 112.1039 0,6553 -150.00 10.7363 113.3219 0,6593 -140.00 11.0875 114.5606 0,6633 -130,00 11.4385 115.8200 0,6672 -120,00 11.7894 117.0999 0.6710 -110.00 12.1401 118.4004 0,6748 -100.00 12.4906 119.7213 0.6785 -90.00 12.8411 121.0626 0,6822 -80,00 13.1913 122.4239 0.6858 -70,00 13.5415 123.8054 0*6894 -50,00 13,8916 -- 125.2069. 0.6929 -50.00 14.2416 126.6283 0,6964 -40.00 14.5916 128.0695 0.6999 -30*00 14.9414 129.5302 0*7034 -20.00 15.2912 131.0105 0.7068 -10.00 15.6410 132.5102 0,7101 0. 15.9906 134&0291 07135 10.00 16.3402 135.5671 0,7168 20.00 16.6898 137.1241 0.7201 30.00 17.0393 138.7000 0,7233 40,00 17.3887 140.2946 0,7265 50.00__ 17.7382 141.9078 0*7297 60,00 18,0875 143,5394 0.7329 70,00 18&4369 145.1893 0.7361 80.00 18.7862 146.8573 0,7392 PRESSURE= 4,5 GAGE= 20&758 SAT TEMP -224,91 PRESSURE= GAGE= SAT TEMP = 4. 21.776 -227.23 T F~ V H S -220*00 7*2261 105*2163 0,6268 -210,00 7*5360 106.3096 0,6312 -200,00 7,8455 107,4239 0*6356 -190,00 8,1545 108 5591 0,6399 -180,00 8,4632 109.7152 0,6441 -170,00 8,7716 110.8922 0,6482 -160,00 9,0797 112.0900 0,6523 -150,00 9.3876 113,3086 0&6563 -140.00 9.6953 114,5479 0&6602 -130*00 10,0028 115*8078 0,6641 -120,00 10,3101 117,0883 0,6679 -110,00 10,6172 118.3892 0.6717 -100,00 10,9242 119,7106 0,6754 -90,00 11.2311 121.0522 0.6791 -30.00 11,5379 122.4140 0,6828 -70,00 11,8446 123.7959 0,6864 -60,00 12.1510 125.1977 0.6899 -50.00 12,4575 126,6194 0,6934 -40,00 12,7639 128.0608 0,6969 -30,00 13.0702 129.5219 0,7003 -20,00 13,3765 131.0024 0.7037 -10,.00 13. 6826 132.5024 0,7071 0. 13,9888 134.0215 - 0.71-05 — 10,00 14,2948 135.5598 0,7138 20,00 14,6008 137.1171 0,7170 30.00 14,9068 138,6932 0,7203 40.00 15,2127 140.2880 0,7235 50.00_ 15,5186 141.9013 __ 0,7267 60.00 15,8244 143.5331 0-7299 70.00 16,1302 145.1832 0,7330 80.00 16.4359 146.8514 0,7362 T F~ -220,00 6,4 -210.00 6,6 -200,00 6,c -190,00 7,2.-1 S', 00 7, -170,00 7,7 -160,00 8,C -150,00 9.3 -140,00 8.6 -130.00 8,8 -120 00 9,1 -110.00 9.4 -100 00 9,7 -90.00 9C9 -80,00 10.2 -70,00 10,5 -60.00 10,7 -50,00 11.l -40.00 11. 3 -30,00 11.6 -20,00 11.8 -10.00 12,1 10.00 12.7 20.00 129c 30,00 13.2 40.00 13,5 50.00 13,7 60.00 l4.0 70,00 14.3 80 00 14,6 V H S %142 105,1971 0,6241 5902 106,2915 0,6285?658 10764068 0,6329 7410 108,5428 0,6372 158 8 109,6998 0,6414 7904 110.8775 0,6455 )646 112,0760 0,6496 3387 11.2952 0,6536 i125 114.5351 0.6576 3861 115.7956 0&6614 L595 117.0766 06653 +328 118,3780 0,6690 7059 119.6998 0,6728?790 121.0419 0,6764 '519 122.4041 0,6801 >246 123,7863 0.6837 7972 125.1884 0,6872 )698 126.6104 0,6907 3424 128*0522 0,6942 5148 129.5135 0&6977 3872 130.9944 0,7011 L595 132.4946 0,7044 ~318 134.0140 0.7078 7040 135,5525 0.7111 )761 137.1100 0,7144 '482 138.6863 0.7176 5202 140,2813 0,7209 r922 14168949 0,7240 Y642-14.'5-268 8 727 -- 3361 145.1771 0,7304 080 146.8455 0*7335

-73 - TABLE VI (CONT'D) PRESSURE= GAGE= SAT TFMP = 5, 19.74 -92 &7Q9 PRESSURE= GAGE= SAT TEMP = 515 18.722 -220.84 T F V H S T F V H S -220.00 5.7646 105.1778 0.6216 -220.00 5.2331 105.1584 0-6194 -210.00 6.0136 106.2733 0.6261 -210.00 5.4599 106.2551 0.6239 -200.00 6.2621 107.3896 0.6305 -200.00 5.6863 107.3724 06283 -190.00 6.5102 108.5266 0.6348 -190.00 5,9122 108.5103 0,6326 -180.00 657579 109.6843 0.6390 -180.00 6,1378 109.6689 0.6368 -170.00 7.0054 110.8628 0.6431 -170.00 6,3631 110.8481 0.6410 -160.00 7.2525 112&0620 0,6472 -160.00 6.5881 112.0480 0.6450 -150,00 7.4995 113.2819 0.6512 -150.00 6.8129 113.2685 0.6490 -140,00 7.7462 114.5224 0.6552 -140.00 7.0374 114.5096 0.6530 -130.00 7.9927 115.7834 0.6590 -130600 7.2618 115.7712 0.6569 -120 00 8.2391 117.0649 0.6629 -120.00 74860 117.0532 0.6607 -110.00 8.4853 118.3668 0.6666 _ -110.00 7.7100 118.3556 0.6645 -100.00 8,7313 119.6891 0.6704 -100.00 7.9339 119.6783 0.6682 -90,00 8.9772 121.0315 06741 -90.00 8.1576 121.0212 0.6719 -80800 9.2230 122.3941 0.6777 -80,00 8,3812 122.3841 0.6755 -70*00 9.4687 123.7767 0.6813 -70.00 8.6048 123.7671 0.6791 -60.00 9.7143 125.1792 0*6848 -60.00 8.8282 125.1700 0.6827 -50.00 9.9597 126.6015 0.6884 -50,00 9.0515 126.5926 0.6862 -40*00 10.2052 128.0436 0.6918 -40.00 9.2747 128.0349 0.6897 -30.00 10.4505 129.5052 0,6953 -30.00 9.4979 129.4968 0.6931 -20.00 10.6958 130.9863 0.6987 -20&00 9.7210 130.9782 0.6965 -10.00 10.9410 132.4867 0.7021 -10,00 9.9440 132.4789 0.6999 0. 11,1862 134.0064 0,7054 0. 10.1670 133.9988 0,7032 10.00 11.4313 135&5452 0,7087 10.00 10.3900 135.5378 0.7065 20*00 11.6763 137.1029 0.7120 20.00 10.6128 137.0958 0,7098 30,00 11.9213 138.6794 0,7152 30.00 10.8357 138.6725 017131 40.00 12.1662 140.2746 0.7185 40.00 11,0584 140.2679 0.7163 50.00 12.4111 141.8884 0.7217 50,00 11.2812 141.8819 0&7195 60.00 12.6560 143.5206 0,7248 60.00 11.5039 143.5143 0.7227 70.00 12,9008 145.1710 0.7280 70.00 11.7265 145.1649 0.7258 80.00 13.1456 146,8396 0.7311 80.00 11.9491 146.8336 0.7289 PRESSURE= 6& PRESSURE= 6^5 GAGE= 17.704 GAGE 16686 _____ SAT TEMP = -219,02 SAT TEMP = -217.32 TF~ V H S T F V H S -210.00 4.9986 106.2368 0.6219 -210.00 4.6081 106.2185 0,6200 -200.00 5,2064 107.3551 0.6263 -200.00 4,8004 107.3378 0,6244 -190.00 5.4139 108.4940 0.6306 -190.00 4.9923 108.4776 0.6288 -180.00 5.6210 109.6534 0,6348 -180.00 5.1838 109.6379 0.6330 -170.00 5,8279 110.8334 0.6390 -170.00 5.3750 110.8187 0,6371 -160.00 6,0344 112.0340 0.6430 -160.00 5.5659 112,0200 0.6412 -150.00 6.2407 113.2552 0.6470 -150.00 5,7565 113.2418 0,6452 -140.00 6,4468 114*4969 0.6510 -140.00 5,9470 114,4841 0.6492 -130.00 6.6527 115.7590 0.6549 -130.00 6.1372 115.7467 0.6530 -120.00 6,8584 117.0415 0,6587 -120.00 6.3273 117.0298 0.6569 -110.00 7,0639 118.3444 0,6625 -110.00 6.5172 118,3331 0.6607 -100.00 7,2693 119.6675 0.6662 -100.00 6.7070 119.6567 0,6644 -90.00 7,4746 121.0108 0.6699 -90,00 6.8967 121.0004 0.6681 -80.00 7.6798 122.3741 0.6735 -80.00 7,0862 122.3642 0,6717 -70.00 7,8848 123.7575 0.6771 -70.00 7,2756 123.7479 0&6753 -60.00 8,0898 125.1607 0,6807 -60.00 7,4650 125.1514 0,6789 -50.00 8,2946 126.5837 0,6842 -50.00 7.6542 126.5748 0.6824 -40,00 8,4994 128.0264 0*6877 -40,00 7.8433 128,0177 0,6859 -30,00 8,7040 129.4885 0.6911 -30.00 8.0323 129.4801 0.6893 -20.00 8,9087 130.9701 0.6945 -20.00 8.2213 130.9621 0.6927 -10.00 9.1132 132.4711 0.6979 -10.00 8,4103 132.4633 0,6961 00 9.3178 133.9913 0.7013 0. 8,5991 133.9837 0.6994 10.00 9,5222 135.5305 0,7046 10.00 8,7880 135.5232 0*7028 20,00 9.7266 137,0887 0,7079 20.00 8,9767 137.0816 0.7060 30,00 9,9310 138.6656 0,7111 30.00 9.1654 138.6588 0.7093 40,00 10,1353 140.2613 0,7143 40,00 9,3541 140.2546 0.7125 50,00 10.3395 141.8754 0,7175 50.00 9.5427 141.8690 0.7157 60,00 10,5437 143.5080 0.7207 60.00 9.7313 143.5017 0.7189....................... 70.00 10.7479 145.1588 07238 80.00 10,9521 146.8277 0,7270 90,00 11,1562 148.5146 0,7301 70 00 9,9199 14b51LDZ / UZ /Z 80.00 10.1084 146,8218 0,7252 90.00 10.2969 148.5088 0.7283

-74 - TABLE VI (CONT'D) PRESSURE= GAGE= SAT TEMP = 7. 15.668 -215.73 _____..., 6 6.._8_... PRESSURE= GAGE= SAT TEMP = 715 14,65 -214.22 _I____ T F~ V -210.00 -200,00 -190 00 -180.00 -170.00 -160 00 -150.00 -140.00 -130.00 -120.00 -1 1000 4.2735 4.4524 4.6308 4.8089 4,. 9867 5.1643 5.3415 5.5186 5.6955 5.8721 H 106.2002 107.3205 108.4612 109.6223 s 0.6183 0.6227 0.6270 0.6313 110.8039 112.0059 113.2284 114.4713 115.7345 0.6354 0,6395 0,6435 0,6475 0.6514 6.0487 -100.00 6,2251 -90,00 6,4013 -80,00 6.5774 -70*00 6.7535 -60*00 6,9294 -50.00 7.1052 -40.00 7,2810 -30.00 7.4566 -20.00 7*6321 -10.00 7.8077 0. 7.9832 10.00 8,1586 20,00 8,3340 30,00 8,5093 40,00 8.6846 50.00 8,8598 60.00 9.0350 117.0181 0,6552 11863219 0,6590 119.6459 0,6627 120.9900 0,6664 122.3542 0.6700 123.7382 0.6736 125.1422 0.6772 126.5658 0 6 8 07 128.0091 0,6842 129.4719 0,6876 130.9540 0,6910 132.4555 0*6944 133.9761 0.6978 T F -210.00 3 -200,00 4 -190,00 4 -180.00 4 -170.00 4 -160.00 4 -150.00 4 -140.00 5 -130.00 5 -120.00 5 -110,00 5 -100.00 5 -90.00 5 -80.00 6 -70.00 6 -60.00 6 -50 00 6 -40,00 6 -30*00 6 -20.00 7 -10.00 7 0. 7.6503 110.7891 0.6338.8162 111.9918 0,6379.9819 113,2150 0,6419,1473 114.4584 0.6459.3126 115.7222 0,6498.4777 117.0063 0,6536.6426 118,3106 0.6574.8073 119.6351 0,6611,9720 120.9796 0,6648.1365 122,3442 0.6685.3009 123.7286 0,6721.4652 125.1329 0,6756.6295.7936.9577,1216.2855.4493 126,5569 128,0005 129.4635 130,9460 132.4476 133,9686 Uo6791 0.6826 0,6861 0, 6895 0 6928 0,6962 135 5158 137.0745 138.6519 140a2479 141,8625 143.4954 0.7011 0.7044 0.7076 0.7108 0. 7140 0.7172 10.00 20,00 30.00 40.00 50.00 A t. n 7,6132 7 7769 7,9406 8, 1043 8,2679 f.6. ql 135.5085 137,0674 138.6450 140.2412 141,8560 143.4891 0,6995 0.7028 0.7060 0,7093 0,7125 0 & 7156 70.00 9.2101 145.1466 0.7204 70;00 8.5950 145.1405 0,7188 80 00 93852 146.8158 07235 80.00 8 7 5 8 5 146.8099 0.7219 90.00 9.5603 148.5030 0.7266 90.00 8.9220 148,4973 0.7250 PRESSURE= 84 PRESSURE= 885 GAGE= 13,632 GAGE= 12.614 SAT TEMP = -212.79 SAT TEMP = -211,43 T F V H S T F V H S -210.00 3.7296 106.1633 0.6152 -210,00 3,5057 106.1448 0,6138 -200,00 3,8868 107.2858 0.6196 -200,00 3 6539 107,2683 0,6182 -190,00 4*0435 108,4283 0*6240 -190.00 3,8016 108.4119 0.6225 -180,00 4.1999 109.5912 0,6282 -180.00 3.9490 109*5755 0,6268 -170,00 4.3559 110.7743 0*6323 -170.00 4,0961 110.7595 0,6309 -160,00 4.5117 111.9777 0,6364 -160*00 4*2429 111*9636 0*6350 -150*00 4*6672 113.2015 0,6404 -150.00 4,3895 113*1881 0.6390 -140.00 4*8225 114.4456 0,6444 -140.00 4*5358 114,4328 0,6430 -130.00 4.9776 115.7100 0,6483 -130.00 4*6819 115*6977 0.6469 -120*00 5*1325 116.9946 0.6521 -120.00 4,8279 116.9828 0,6507 -110.00 5.2872 118.2994 0 6559 -110.00 4,9737 118.2881 0,6545 -100,00 5,4418 119.6243 0 6596 -100.00 5,1193 119.6134 0,6583 -90.00 5.5963 120.9692 0.6633 -90,00 5,2649 120,9588 0,6620 -80,00 5*7507 122.3342 0,6670 -80,00 5*4103 122,3242 0.6656 -70.00 5,9049 123.7190 0.6706 -70*00 5 5555 123*7093 0,6692 - _ 60.00 6.0591 125.1236 0 6741 -60.00 5,7007 125*1143 0,6728 -50.00 6.2132 126.5479 0,6777 -50.00 5,8458 126.5389 0,6763 -40,00 6,3671 127.9918 0,6811 -40,00 5.9908 127*9831 0,6798 -30,00 6.5210 129*4552 0.6846 -30,00 6,1358 129.4468 0,6832 -20,00 6,6749 130,9379 0,6880 -20,00 6*2806 130,9299 0,6866 -10,00 6*8285 132*4398 0,6914 -10.00 6o4253 132,4320 0,6900 0. 6.9822 133*9610 0,6947 0, 6*5701 133,9534 0,6933 10.00 7.1359 135.5Y-12 -— 6980 10,00 6*7148 135*4938 0&6967 20,00 7,2895 137*0602 0,7013 20,00 6,8594 137*0531 0,6999 30,00 7*4430 138.6381 0,7046 30,00 7,0040 138.6312 0,7032 40.00 7.5965 140.2345 0,7078 40,00 7*1485 140,2279 0.7064 50*00 7.7500 141*8495 0.7110 50.00 7,2930 141.8430 047096 60,00 7*9034 143.4828 0,7142 60,00 7,4375 143,4765 0,7128 Iu uu bsO.U 00 14.e1344 U. 173 80,00 8,2101 146.8040 0.7204 90.00 8,3634 148.4915 0,7235 70o00 /,&81 14e512U2 U,/1i5 80.00 7,7262 146,7980 0,7191 90,00 7,8706 148,4857 0,7222

-75 - TABLE VI (CONT'D) PRESSURE= 9, GAGE= 11596 PRESSURE= GAGE= 9,5 10,578 SAT TEMP = -210,13 SAT TEMP = -208688 T F~ V H S T F~ V H S -210.00 3.3066 106,1263 0.6125 -200,00 3,2616 107.2333 0.6156 -200.00 3,4468 107,2508 0,6169 -190,00 3,3943 108.3788 0,6200 -190,00 3,5866 108.3953 0.6212 -180,00 3,5266 109.5442 0,6242 -180,00 3.7261 109,5599 0.6255 -170.00 3,6586 110.7297 016284 -170e00 3,8652 110.7446 0a6296 -160.00 3.7903 111.9353 0,6325 -160.00 4.0040 111,9495 0,6337 -150.00 3.9218 113.1611 0,6365 -150.00 4,1426 113.1746 0.6377 -140.00 4,0530 114.4070 0,6404 -140.00 4.2810 114.4199 0,6417 -130.00 4,1841 115.6731 0,6443 -130.00 4.4192 115.6854 0,6456 -120,00 4,3149 116.9592 0.6482 -120.00 4,5572 116.9710 0.6494 -110.00 4.4456 118.2655 0,6520 -110,00 4.6950 118.2768 0.6532 -100.00 4.5762 119.5918 0,6557 -100000 48327 6026 06570-90.00 47066 1209380 0,6594 -90.00 4,9702 120.9484 0.6606 -80.00 4,8369 122.3041 0,6630 -80,00 5.1076 122.3141 0,6643 -70.00 4 9671 123.6900 0,6667 -70*00 5.2450 123.6997 0.6679 -60,00 5,0972 125.0957 0,6702 -60.00 5,3822 125.1050 0,6714 -50.00 5,2272 126.5210 0,6737 -50*00 5,5193 126,5300 0,6750 -40.00 5,3571 127.9658 0,6772 -40,00 5.6564 127,9745 0,6785 -30,00 5,4869 129.4301 0,6807 -30,00 5.7933 12964385 0,6819 -20.00 5,6167 130.9137 0,6841 -20,00 5.9302 130.9218 0,6853 -10.00 5,7464 132.4165 0,6875 -10.00 6.0671 132.4243 0.6887 0. 5.8759 133.9382 0.6908 0. 6.2037 133 9458 0,6920 10,00 6,0055 135.4791 0,6941 10.00 6,3404 135,4865 0,6954 20,00 6,1351 137.0389 0,6974 20.00 6.4771 137,0460 0,6986 30*00 6,2645 138,6174 0.7007 30.00 6.6137 138.6243 0.7019 40,00 6,3940 140,2145 0.7039 40.00 6.7503 140.2212 0.7051 50,00 65234 141.8300 0.7071 50.00 6,8868 141 8365 0.7083 60,00 6,6527 143.4639 0,7103 60.00 _ 7,0233 143.4702 0.7115 70,00 6 7820 145.1160 0,7134 70,00 7,1597 145,1221 0,7146 80,00 6,9113 146.7861 0,7165 80,00 7,2961 146,7921 0,7178 90.00 7,0405 148.4742 0,7196 90,00 7.4325 148,4800 0,7209 100.00 7,1697 150.1800 0,7227 PRESSURE= 10. PRESSURE= 11. GAGE= 9156 GAGE= 7,524 SAT TEMP = -207,69 SAT TEMP = -205,44 TF~ V H S T F V H S -200,00 3,0949 107.2158 0*6144 -200,00 2.8068 107.1805 0.6122 -190,00 3.2211 108.3622 0.6188 -190.00 2.9221 108.3289 0.6165 -180,00 3.3471 109,5285 0,6230 -180,00 3.0369 109,4970 0,6208 -170,00 3,4726 110.7148 0,6272 -170,00 3.1514 110.6849 0.6250 -160,00 3,5979 111.9211 0,6313 -160,00 3.2657 111.8927 0.6291 -150,00 3,7230 113.1476 0,6353 -150*00 3.3796 113.1205 0,6331 -140,00 3.8478 114.3941 0,6393 -140,00 3.4934 114.3683 0,6371 -130.00 3,9725 115.6607 0.6432 -130.00 3.6069 115.6360 0,6410 -120.00 4.0969 116.9474 0,6470 -120,00 3,7203 116.9238 0.6448 -110.00 4,2212 118,2542 0,6508 -110.00 3.8335 118.2315 0,6486 -100,00 4.3453 119.5809 0,6545 -100,00 3.9466 119.5592 0,6523 -90,00 4e4693 120.9276 0,6582 -90a00 4,0595 120,9067 0,6560 -80,00 4,5932 122,2941 0.6619 -80,00 4,1723 122.2740 0,6597 -70,00 4,7170 123,6804 0,6655 -70,00 4.2850 123,6610 0*6633 -60,00 4,8407 125*0864 0,6690 -60,00 4,3976 125,0678 0,6669 -50,00 4,9643 126,5120 0,6726 -50.00 4.5101 126,4941 0,6704 -40,00 5,0877 127.9572 0,6760 -40,00 4,6225 127,9398 0,6739 -30,00 5,2112 129.4217 0,6795 -30,00 4.7349 129.4050 0,6773 -20,00 5.3345 130.9056 0,6829 -20,00 4,8471 130,8894 0,6807 -10,00 5,4578 132.4087 0,6863 -10.00 4.9593 132.3930 0,6841 0. 5,5810 133.9308 0,6896 0. 5,0715 133.9157 0,6875 10e00 5,7041 135,4718 0,6930 10.00 5,1835 135.4573 0,6908 20,00 5.8272 137.0318 0,6962 20,00 5.2955 137.0175 0,6941 30.00 5,9503 138,6105 0,6995 30,00 5,4074 138.5967 0,6973 40,00 6,0733 140,2078 0,7027 40,00 5.5194 140.1944 0,7006 50,00 6,1963 141.8235 0,7059 50 00 5,6313 141.8106 0.7038 60,00 6,3192 143,4576 0,7091 60,00 5,7431 143.4450 0,7069 70.00 6,4421 14561099 0,7123 70,00 5,8549 145.0977 0.7101 80,00 6.5649 146,7802 0,7154 80,00 519667 146e7683 0U7132 90.00 6,6878 148.4684 0.7185 100.00 6.8105 150.1744 0 7 2 16 90100 6,0784 148.4569 0,7163 - 100.00 -6.-190 I- 150. 1632 - O.7 -1 94

TABLE VI (CONT'D) PRESSURE= 12, GAGE= 5,488 SAT TEMP = -203.35 PRESSURE= 13 GAGE= 3.452 SAT TEMP = -20139 _ ____ T F~ V H S -200.00 2.5668 107.1452 0,6101 -190000 2.6728 108.2955 0.6145 -180000 2.7784 109.4654 0,6188 -170.00 2.8837 110.6549 0,6229 -160000 2.9888 111.8642 0,6270 -150.00 3.0935 113.0934 0o6311 -140.00 3.1980 114.3424 0.6350 -130.00 3.3024 115.6113 0.6389 -120.00 3.4065 116.9001 0,6428 -110.00 3.5105 118.2088 0.6466 -100.00 3,6143 119*5374 0*6503 -90.00 3.7180 120.8858 0.6540 -80.00 3.8216 122.2530 0.6577 -70.00 3,9250 123.6417 0.6613 -60.00,.0284 125.0491 0.6649 -50,00___ 4,1316 126.4761 0_6684 -40.00 4.2348 127&9225 0.6719 -30.00 4,3379 129.3882 0,6753 -20O00 4.4410 130.8732 0,6787 -10.00 4,5439 132.3773 0.6821 0O 4.6468 133.9005 0.6855 10.00 47497 135.4426 0,6888 20.00 4,8523 137.0033 0.6921 30.00 4,9551 138.5829 0.6953 40&00 5,0578 140*1810 0.6986 50.00 5,1604 141&7976 0,7018 60.00 5.2631 143.4324 0.7050 70*00 5.3656 145.0854 0,7081 ___ 80000 5.4682 146.7564 0,7112 90.00 5.5707 148.4453 0.7143 100.00 5,6731 150.1519 0,7174 PRESSURE= 14* GAGE= 1,416 SAT TEMP = -199&54 T F~ -200,00 -190 00 -180,00 -170,00 V H 2,3637 107,1096 2,4619 108,2620 2,5597 109.4337 2.6572 110.6248 S 0,6083 0,6126 0.6169 0,6211 -160,00 2.7544 111.8356 -150.00 2,8514 113.0661 -140,00 2,9481 114*3164 -130,00 3.0446 115.5865 -120.00 3,1409 116.8764 -110,00 _ __32371 118.1861 -100,00 3,3331 119*5156 -90,00 3.4290 120.8648 -80,00?,5248 122.2337 -70,00 3.6204 123.6223 -60,00 3.7160 125*0304 -50*00 3,8114 126.4581 -40 00 3,9068 127. 9051 -30*00 A.0021 129.3714 -20.00 4.0973 130.8570 -10,00 4,1924 132.3617 0O 4,2875 133.8853 10.00 *,3825 135.4279 20,00 4.4775 136&9892 30,00 ae5723 138.5690 40*00 4,6672 140,1676 50,00 a.7620 141.7846 60&00 4.8568 143.4198 70.00 _ 49516 145*0732 80-,0. 50463 - 46-7445 90*00 5,1410 148*4338 100,00 5,2357 150.1407 PRESSURE= 14.696 GAGE= 0. SAT TEMP = -198,32 0.6252 0,6292 0.6332 0,6371 0*6409 0.6447 0,6485 006522 006558 0,6595 0,6630 0*6666 0 6700 0,6735 0,6769 0,6803 0,6836 0.6870 0,6903 0,6935 0,6967 0,7000 0,7031 0.7063 0,7094 0,7125 0,7156 T F~ -190,00 -180,00 -170&00 -160,00 -150,00 -140,00 -130,00 -120,00 -110, 00 -100.00 V H 2,2811 108,2283 2,3722 109,4018 2,4631 110*5947 2,5536 111,8070 S 0,6109 0,6151 0,6193 0,6234 T F~ v H 2.6438 113,0388 2,7339 114.2904 2,8237 115,5616 2.9133 116.8526 3,0028 118.1633 3.0921 119.4937 U* 627 0,6315 0*6354 0,6392 0,6430 0,6468 -190,00 2,1697 108&2048 -180,00 2,2568 109.3796 -170.00 2 3435 110.5736 -160.00 2,4299 111,7869 -150,00 2,5160 113.0198 -140,00 2,6020 114,2722 -130,00 2,6877 115.5443 -120,00 2,7732 116,8360 -110,00 2*8585 118,1474 -100.00 2.9437 119.4785 S 0,6097 0,6140 0,6182 0,6223 0,6263 0,6303 0.6342 0,6381 0,6419 0,6457 -90,00 3,1813 120.8438 0,6505 -90,00 30288 120,8292 0,6494 -80,00 3,2704 122,2136 0,6541 -80.00 3,1137 122.1995 0.6530 -70,00 3.3593 123.6029 0,6578 -70,00 3*1986 123.5894 0,6566 -60.00 3.4482 125.0117 0,6613 -60,00 3,2833 124.9987 0,6602 -50,00 3,5369 126.4400 0,6649 -5000 3,03679 126.4275 0,6637 -40,00 3,6256 127.8877 0,6683 -40,00 3,4525 127,8756 0,6672 -30*00 3.7142 129.3546 0,6718 -30*00 3,5369 129.3429 0,6707 -20.00 3,8027 130.8408 0,6752 -20,00 3,6213 130,8294 06741 00 9 13-10*00 8911 323460 6786-1000 7056 132,3350 0,6775 0. 3*9795 1338701 0,6820 0 3.7899 133.8596 0.6808 10000 4.0678 135.4132 0,6853 1000 3*8741 135,4030 0,6842 20,00 4,1561 136.9750 0,6836 20*00 3,9583 136.9651 0*6875 30,00 4,2442 138.5552 0,6918 30,00 4,0423 13815458 0,6907 40,00 4,3324 140.1542 0,6951 40,00 4,1263 140,1448 0,6939 50.00 4*4206 141.7715 0&6983 50,00 4,2103 141e7625 0&6972 60,00 4,5087 143.4072 0*7014 60,00 4.2943 143.3984 0,7003 70,00 4,5967 145*0609 0,7046 70.00 4,3782 145.0524 0.7035 80,00 4,6847 146.7326 007077 80,00 4,4621 146*7243 0&7066 90O00 4.7727 148.4222 100,00 4,8607 150.1295 110.00 49486 151.8543 U07108 0,7139 0*7170 90,00 4.5460 148.4142 100*00 4,6298 150.1217 110,00 4,7136 151.8467 0*7097 0*7128 0.7158

-77 - TABLE VI CON- 'D ) PRESSURE 15. GAGE= 0.304 SAT __TEMP = -197.80................ PRESSURE= 16, GAGE= 1,304 SAT TEMP = -196,14 T F V H T F V H -190.00 2.1244 108.1945 0.6092 -190.00 1 9872 108.1605 0.6077 -180.00 2.2097 109.3699 0.6135 -180.00 2.0675 109.3378 0.6120 -170.00 2.2948 110.5644 0.6177 -170.00 2 1475 110.5340 0.6162 -160.00 2.3795 111.7782 06218 -160.00 2 2271 11._ 7493 0.6203 -150.00 2.4639 113.0115 0.6259 -150.00 23065 112.9840 0624 -140,00 2,5482 114.2643 0.6298 -140.00 2.3857 114 2381 0,6283 -130.00 2.6322 115.5367 0,6333 -130,00 2,4647 115 5118 0s6323 -120.00 2.7160 116.8288 0.6376 -120.00 2.5434 116.8049 0.6361 -110.00 2.7997 118.1405 0,6414 -110.00 2,6220 118 1176 0.6399 -100,00 2.8832 119.4718 0,6452 -100.00 2,7005 119,4499 0.6437 -90,00 2,9666 120.8228 0.6489 -90,00 2,7788 120.8018 0&6474 -80,00 3.0499 122.1934 0,6525 -80,00 2,8569 122 1731 0,6511 -70&00 3,1330 123,5835 0e6562 -70.00 2 9350 123.5640 0,6547 -60,00 3,2161 124,9930 0,6597 -60.00 3,0130 124.9743 0,6582 -50.00 3.2990 126,4220 0,6633 -50.00 3 0909 126,4039 06618 -40.00 3,3819 127.8703 0,6668 -40,00 3 1686 127.8529 0,6653 -30,00 3,4647 129,3378. 0,6702 -30,00 3.2463 129.3210 0,6687 -20,00 3.5474 130.8245 0,6736 -20,00 3,3240 130.8082 0.6722 -10.00 3,6300 132,3302 0,6770 -10.00 3,4015 132 3145 0.6755 0. 3,7126 133,8549 0,6804 0. 3,4790 133,8397 0,6789 10.00 3,7951 13563985 0,6837 10.00 3,5565 135 3838 0,6822 20,00 3,8776 136,9608 0,6870 20,00 3,6339 136.9465 0,6855 30,00 3,9600 138.5416 0,6902 30.00 3.7112 1385278.06888 40,00 4,0423 140.1407 0,6935 40*00 3,7885 140 1276 0,6920 50,00 4,1246 141.7585 0,6967 50.00 3,8657 141 7455 0,6952 60,00 4,2069 143,3945 0.6999 60,00 3,9429 143.3819 0,6984 70.00 4,2892 145.0486 0,7030 70,00 4,0200 1450364 0,7015 80.00 4,3714 146,7207 0,7061 80,00 4,0972 146.7088 0,7047 90,600 4,4536 148,4106 0 7 092- 90,00 4,1743 148.3991 0,7078 100,00 4,5357 150.1182 0,7123 100,00 4,2513 150,1070 0,7109 110.00 4,6178 151.8434 0,7154 110,00 4,3284 151,8325 0,7139 PRESSURE= 17o GAGE= 2,304 SAT TEMP = -194,56 PRESSURE 18, GAGE= 3,304 SAT TEMP = -193,06 T F -190,00 -180,00 -170,00 _ -160,00 -150 00 -140,00 -130,00 -120,00 -110.00 -100 00 V H 1,8662 108.1264 1,9420 109.3056 2,0175 110,5035 2.0927 111.7204 S 0,6062 0,6105 0,6147 0,6189 T F~ -190,00 -180.00 -170.00 -160*00 V H 1,7586 108,0922 1,8305 109&2732 1,9020 110.4729 1.9732 111,6914 S 0,6049 0.6092 0,6134 0,6175 2,1676 112.9565 2,2423 114,2119 2,3168 115,4867 2,3911 116&7810 2,4652 118,0947 2,5392 119.4280 0.6229 0,6269 0.6308 0,6347 0,6385 0.6427 -150,00 -140,00 -130,00 -120,00 -110.00 -100.00 2.0442 112.9289 2,1149 114,1856 2,1854 115,4617 2,2557 116*7570 2,3258 118,0718 2.3958 119,4060 0,6216 0,6256 0.6295 0.6334 0,6372 0.6410 -90,00 2,6130 120,7807 0 6460 -90,00 2,4657 120,7596 0,6447 -80,00 2,6867 122.1529 0,6497 -80,00 2,5354 122,1326 0.6483 -70,00 2,7603 123.5445 0.6533 -70,00 2,6050 123,5250 0,6519 -60.00 2,8338 124.9555 0,6568 -60,00 2,6745 124,9367 0,6555 -50.00 2,9072 126,3858 0,6604 -50,00 2,7439 126.3677 0,6591 -40,00 2,9805 127.8354 0,6639 -40,00 2,8132 127.8179 0,6626 -30,00 3,0537 129,3041 0 6673 -30,00 2,8825 129,2873 0,6660 -20,00 3,1269 130,7920 0,6708 -20,00 2,9517 130,7757 0,6694 -10,00 3,1999 132,2988 0,6741 -10.00 3,0207 132,2831 0,6728 0O 3,2730 133.8245 0,6775 0, 3,0898 133,8093 0,6762 10.00 3,3459 135,3690 0,6808 10,00 3,1588 135.3543 0,6795 20,00 3,4188 136.9322 0,6841 20,00 3,2277 136.9180 0,6828 30,00 3.4917 138.5140 0,6874 30.00 3,2966 138,5002 0,6861 40&00 3,5645 140,1142 0,6906 40,00 3,3654 140,1008 0,6893 50.00 3,6372 141,7325 0,6938 50.00 3,4341 141,7194 0,69?5 60,00 3,7099 143,3692 0,6970 60.00 3,5028 143,3566 0,6957 70,00 3,7826 145,0241 0,7002 70,00 3,5715 145,0118 0,-6989 80,00 3,8552 146,6969 0,7033 80.00 3,6402 146.6850 0,7020......................... 7U6 90 0 5e0~^4.B~ U( 90,00 3,9279 14803875 100.00 4,0004 150.0957 110,00 4,0730 151,8215 0,7064 0.7095 0,7125 90,00 30088 148.3759 0/' uU1 100,00 3.7774 150,0845 0,7082 110.00 3,8460 151,8106 0,7112

-78 - TABLE VI (CONT'D) PRESSURE= 1ie GAGE= 4&304 SAT TEMP = -191,61 PRESSURE 20, GAGE= 5 304 SAT TEMP = -19.0. 23 _ T F V H s T F V H -190.00 1.6623 108.0578 0.6036 -190.00 1.5756 108.0232 0.6023 -180.00 1.7306 109.2408 0.6079 -180.00 1.6408 109.2082 0.6066 -170.00 1,7986 110.4422 0.6121 -170.00 1.7056 110.4114 0,6109 -160.00 1.8663 1'1.6623 0.6162 _ -160.00 1.7700 11..6331 _._O6150__ -150.00 1,9337 112.9013 0.6203 -150.00 1.8343 12.8735 0.6191 -140.00 2.0009 114.1593 0.6243 -140.00 1.8982 114.1329 0.6231 -130.00 2.0678 115.4365 0.6282 -130.00 1.9620 115.4113 0,6270 -120&00 2.1345 116.7330 0.6321 -120.00 2.0255 116.7089 0.6309 -110.00 2.2011 118.0488 0.6359 -110600 2.0889 118.0258 0.6347 -100.00 2.2676 119.3839 0.6397 -100,00 2__.1521 119.3619 066385 -90.00 2,3338 120.7384 (0.6434 -90,00 2.2152 120.7173 06422 -80.00 2.4000 122.1123 0,6471 -80,00 2.2781 122.0920 0.6459 -70.00 2.4660 123.5055 0.6507 -70.00 2.3410 1234859 0.6495 -60.00 2.5320 124.9179 0,6543 -60.00 2.4037 124.8991 0,6531 -50.00 2.5978 126.3496 0.6578 -50.00 2.4664 126.3315 0,6566 -40.00 2.6636 127.8005 0.6613 -40.00 2.5289 12.7830 0.6601 -30*00 2.7293 129.2704 0,6648 -30,00 2.5914 129.2535 0,6636 -20&00 2.7949 130,7594 0.6682 -20,00 2.6538 130.7431 0.6670 -10,00 2.8604 132.2673 0.6716 -10.00 2.7161 132.2515 0,6704 0. 2.9259 1'3.7941 0,6749 0, 2.7784 13.7788 06738 10.00 2.9913 135.3395 0.6783 10,00 2.8406 135.3248 0,6771 20,00 3.0567 136.9037 0,6816 20,00 2.9027 136.8894 O06804 30,00 3,1220 138.4863 0,648 30,00 2,9648 138.4725 0,6837 40.00 3,1872 1l0,0874 0,6881 40,00 3,0269 1400740 0,6869 50.00 3,2524 1Z1.7067 0,6913 50.00 3.0889 1^1.6937 0,6901 60.00 3,3175 1A3.3439 0.6945 60*00 3.1507 143.3313 0,6933 70.00 3,3827 1Z-4.9995 0.6976 70,00 3.2127 114,9872 0,6964 80.00 3,4478 146.6730 0.7007 80.00 3,2746 146.6611 0.6996 90.00 3.5128 128.3643 0,7038 90.00 3,3364 148.3527.7027 100.00 3.5779 150,0732 0.7069 100,00 3,3983 150.0620 0,7058 110.00 3,6429 151,7997 0.7100 110.00 3,4601 151.7887 0,7088 PRESSURE= 21, P GAGE= 6.304 SAT TEMP = -188.89 SAT T F V H S T F -180,00 1.5595 109.1755 0,6055 -180,00 -170,00 1,6214 110.3805 0,6097 -170.00 -160.00 1.6830 111.6038 0.6139 -160.00 -150.00 1.7443 112,8457 0.6179 -150.00 -140.00 1,8053 114.1064 0,6219 -140400 -130.00 1,8662 115.3861 0,6259 -130*00 -120.00 1.9268 116.6848 0,6298 -120.00 -110400 1.9873 118.0027 0,6336 -110.00 -100.00 2.0477 119.3398 0,6374 -100.00 -90.00 2,1078 120.6961 0,6411 -90.00 -80.00 2,1679 122.0716 906447 -80.00 -70.00 2,2278 123.4663 0,6484 -70&00 -60.00 2,2877 124.8802 0,6520 -60*00 -50.00 2,3474 126.3133 0.6555 -50.00 -40&00 2 4071 127.7655 0.6590 -40&00 -30.00 2_,4666 129.2366 0.6625 -30,00 -20,00 2,5261 130.7268 0.6659 -20,00 -10.00 2,5856 132.2358 0&6693 -10,00 0. 2,6449 133.7635 0.6726 0O 10.00 2,7042 135.3100 0,6760 10.00 20*00 2,7635 136.8751 0.6793 20.00 30.00 2,8227 138,4586 0&6825 30.00 40,00 2.8818 140,0605 0,6858 40*00 50.00 2,9409 141.6807 0,6890 50.00 60*00 3,0000 143.3190 0*6922 60*00 70*00 3,0589 144,9749 0*6953 70.00 80.00 3,1179 146.6492 0,6985 80,00 90,00 3,1769 148.3411 0*7016 90.00 100.00 3,2358 150&0507 0,7046 100400 110.00 3,2947 151.7778 0,7077 110.00 120*00 3,3535 t53.5222 0,7107 120.00 RESSURE= 22. GAGE= 7,304 TEMP = -187.61 V H 1,4855 109.1427 1,5448 110.3495 1.6038 111.5744 ____1.6625 112.8178 1,7209 114.0799 1.7791 115.3608 1,8371 116,6606 1.8950 117.9796 1.9527 119.3176 2.0102 120.6748 2.0677 122 6.0512 2.1250 123.4467 2,1822 124.8614 2.2393 126.2951 2,2963 127.7479 2,3532 129.2197 2,4101 130.7104 2,4669 132.2200 2,5236 133*7483 2,5802 135.2952 2,6369 136.8608 2,6934 138,4448 2,7499 140.0471 2,8064 141.6677 2,8628 143.3064 2,9191 144.9626 2,9755 146.6372 3,0318 148.3295 3.0881 150.0395 3.1443 151,7668 3,2005 153.5115 S 0,6043 0.6086 0.6127 0.6168 0,6208 0,6248 0, 6287 0, 6325 0,6363 0,6400 0,6437 0,6473 0.6509 0,6544 0,6579 0,6614 0.6648 0,6682 0,6716 0*6749 0,6782 0,6815 0.6847 0,6879 0, 6911 0,6943 0.6974 0,7005 0,7036 0,7066 0,7097

-79 - TABLE VI (CONT'D) PRESSURF= 23. GAGE= 8.304 SAT TEMP = -186*37 PRESSURE= 24. GAGE= 9&304 SAT TEMP = -185.17 T F -180.00 -170.00 -160.00 -150.00 -140.00 -130.00 -120.00 -110 00 -100.00 -90.00 V 1.4180 1.4749 1.5315 1.5878 H 109.1097 110.3183 11 5449 112.7898 S T F~ V H 1.6438 114.0532 1.6996 115.3354 1.7553 116.6364 1.8107 117.9564 1.8660 119.2954 1.9211 120.6536 -80.00 -70.00 -60.00 -50.00 -40.00 -30.00 1.9761 122.0308 2,0310 123.4271 2.0858 124.8425 2.1405 126.2769 2.1951 127.7304 2.2497 129.2028 0,6033 -180,00 1,3561 109.0766 0,6022 0,6075 -170,00 1,4108 110 2871 0,6065 0,6117 -160.00 1.4652 111.5154 0,6107 0,6158 -150*00 1.5193 112 7618 0,6147 0,6198 -140.00 1.5731 114.0266 0,6188 0.6237 -130*00 1.6268 115.3100 0,6227 0,6276 -120,00 1.6802 115 6122 0.6266 0.6314 -110.00 1.7334 117.9332 0.6304 0,6352 -100.00 1*7865 119.2732 0.6342 0O6389 -90.00 1._8394 120.6323 0.6379 _ 0.6426 -80.00 1.8922 122.0103 0,6416 0.6462 -70i00 1*9449 123.4074 0,6453 0.6498 -60.00 1.9975 12 -.8236 0,6488 0,6534 -50.00 2,0500 126.2587 0,6524 0,6569 -40O00 2,1024 127 7128 0,6559 0,6604 -30*00 2,1547 129.1858 0,6594 0-663-8 - -20.00 2,2070- 130.6777.',- 6628 0,6672 -10.00 2,2591 132.1884 0.6662 0.6705 0. 2,3113 133.7177 0.6696 0,6739 10.00 2.3633 135.2657 0.6729 0.6772 20.00 2*4153 136 8321 0.6762 0,6804 30.00 2.4672 135.4170 0.6795 0.6837 40*00 2.5191 140.0202 0e6827 0,6869 50.00 2.5710 141 6416 0,6859 0.6901 60.00 2.6228 143 2811 0.6891 0.6932 70.00 2*6745 14'69385 0*6923 0,6964 80.00 2.7262 146.6133 0,6954 0,6995 90.00 2.7779 148.3063 0*6985 07026 100.00 2.8295 150 6.0169 0.7016 0,7056 110.00 208812 151.7449 0,7046 0,7087 120.00 2.9328 153,4902 0,7077 -20.00 2.3041 130.6941 -10.00 2.3585 132.2042 0. 2,4128 133*7330 10.00 2,4671 135.2805 20.00 2,5213 136.8465 30*00 2,5754 _ 138.4309 40800 2,6295 140.0337 50*00 2,6836 141*6546 60*00 2,7376 143,2937 70*00 2,7914 144*9503 80,00 2,8454 146.6253 90000 2,8993 148.3179 100.00 2,9532 150.0282 110,00 3,0070 151.7559 120,00 300608 153,5009 PRESSURE= 25 GAGE= 10,304 SAT TEMP = -184&00 PRESSURE= 26 GAGE= 110304 SAT TEMP = -182.88 ___ __ - T F~ -180*00 -170*00 -160*00 -150.00 V H 1,2991 109.0434 1*3518 110*2558 1.4042 111.4857 1.4563 11267336 S 0,6012 0,6055 0,6097 0.6138 T F~ -180,00 -170,00 -160.00 -150.00 V H 1,2466 109.0101 1,2974 110,2243 1,3479 111.4559 1.3981 112.7054 S 0,6003 0.6045 0.6087 0.6128 -140*00 1.5081 113.9998 0,6178 -140,00 1,4481 113*9730 0.6168 -130.00 1,5597 115.2845 0,6217 -130.00 1 4978 115.2589 0,6208 -120,00 1,6111 1166.5878 0,6256 -120,00 1 5473 116.5635 0,6247 -110.00 1,6623 117,9100 0,6295 -110,00 1 5967 117.8867 0,6285 -100.00 1,7134 119,2510 0.6333 -100.00 1,6459 119.2287 0,6323 -90400 1*7643 120.6109 0,6370 -9 0,00 1,6949 12005895 0,6361 -80.00 1,8151 121.9898 0,6407 -80,00 1*7438 121.9693 0.6397 -70*00 1,8657 123.3877 0*6443 -70*00 1*7926 123,3680 0.6434 -60,00 1.9163 124.8046 0,6479 -60,00 1,8413 124,7857 0,6470 -50,00 1,9667 126,2405 0,6514 -50,00 1,8899 126.2222 0,6505 -40,00 2,0171 127.6952 06549 -40,00 1,9384 127.6776 0,6540 -30.00 2.0674 129.1689 0,6584 -30.00 1.9868 129.1519 0 6575 -20*00 2,1176 130.6613 - 0.6618 -20*00 2*0351 130.6449 0.6609 -10.00 2*1678 132*1725 0,6652 -10,00 2*0834 132.1567 0,6643 0. 2*2178 133,7024 0,6686 0. 2,1316 133.56871 0,6677 10.00 2,2678 135o2509 0,6719 10,00 2,1797 135.2360 0,6710 20,00 2,3178 136,58178 0,6752 20,00 2*2278 136.8035 0.6743 30,00 2*3677 138.4031 0*6785 30.00 2 2758 138.3892 0,6776 40,00 2 4176 140*0068 - 0,6818 40 00 203238 Jl39*9933.6-809 50.00 2*4674 141.6285 0,6850 50*00 2*3718 141.6155 0,6841 60,00 205172 143&2684 0&6882 60,00 2&4197 143*2557 0,6873 70*00 2*5669 144*9262 0O6913 70*00 2*4675 144*9139 0,6904 80*00 2*6165 146.6014 0,6945 80,00 2,5152 146*5894 0,6935 90.00 2*6662 148.2947 0*6976 90*00 2*5630 148*2831 0*6967... ^.. I I.... e n. 11 ^ _ ^^ -) 1.... U.. F. - I I1u00o 2 7158 15uuu5b 110O00 2*7654 151,7340 120*00 2*8150 153,4796 uo/uu6 0,7037 0,7067 1UUu0 Z*biU0 149YY944+ 110,00 2,6585 151.7230 120*00 2*7062 153.4689 0,7028 0,7058

V-7 - I 7(ORT0 'D) PRESSURE= GAGE= SAT TEMP = 27. 12.304 -181.78 PRESSURE= GAGE= SAT TEMP = T F V H -180.00 1.1979 108.9766 0.5993 -170.00 1.2470 110.1927 0.6036 -160.00 1.2958 111.4261 0.6078 -150.00 3__ 443 112.6771 0.6119 -140.00 1.3925 113.9461 0.6159 -130.00 1.4405 115.2333 0.6199 -120.00 1.4883 116.5390 0O6238 -110.00 1.5359 117.83633 0,6277 -100.00 1.5834 119.2063 0&6314 -90*00 1.6307 120.5681 0.6352 -80*00 1,6778 121.948-8- 0.6389 -70&00 1.7249 123.3483 0.6425 -60,00 1.7718 124.7667 0.6461 -50.00 1.8187 126.2039 0,6496 -40.00 1.8655 127.6600 0.6532 -30.00 1.9121 129.1349 0.6566 -20.00 1.9587 130.6285 0.6601 -10.00 2.0053 132.1408 0.6635 0. 2.0517 133.6718 0,6668 10.00 2.0981 135.2212 0.6702 20,00 2,1445 136.7891 0.6735 _ -_ 30..00 2.1908 138.3753 0.6767 40,00 2.2370 139.9798 0,6800 50.00 2.2832 141.6024 0,6832 60.00 2,3294 143.2431 0&6864 70.00 2.3755 144.9016 0.6895 80.00 2.4216 146.5780 0.6927 90.00 2.4676 148.2715 0.6958 100,00 2,5136 149.9831 0.6989 110.00 2.5596 151.7120 0.7019 120.00 2,6055 153.4583 0.7050 T F~ -180.00 -170 00 -160.00 -150.00 -140,00 -130.00 -120.00 -110.00 -100.00 -9 0,00 -80.00 -70,00 -60.00 -50.00 -40.00 -30,00 -20.00 -10.00 0. 1 0 00 20,00 30.00 40.00 50.00 60.00 70.00 80,00 90,00 100*00 110.00 120.00 v 1,1526 1,2002 1.2474 1.2942 1,3409 1,3873 1,4335 1.4795 1.5253 1.5710 1.6166 1.6620 1,7074 1.7526 1.7978 1.8428 1,8878 1,9327 1.9776 2,0224 2.0671 2,1118 2.1564 2.2010 2.2456 2.2901 2,3346 2.3789 2,4233 2.4677 2,5120 28. 13,304 180.72 H 108.9429 110. 1610 111.3961 112.6487 113.9191 115.2C77 116.5146 117.8399 119,1840 120.5467 121.9282 123.3285 124.7477 126.1856 127.6424 129.1179 130.6121 132.1250 133.6564 135.2064 136.7747 138.3614 139.9663 141.5894 143.2304 144.8893 146.5660 148.2599 149.9718 151.7011 153.4476 s 0.5984 0,6027 0.6C69 0.6110 0,6151. 0.6190 0.6229 0,6268 0.6306 0.6343 0.6380 0,6416 0,.6452 0.6488 0.6523 0.6558 0.6592 0.6626 0.6660 0.6693 0.6726 0.6759 0.6791 0,6824 0,6855 0.6887 0,6918 0.6950 0.6980.. 0,7011 0*7041 PRESSURE= 29 GAGE= 14,304 SAT TEMP = -179&68 PRESSURE= GAGE= SAT TEMP = 30& 15.304 -178,67 T F V -170,00 1,1566 110.1292 0,6019 -160,00 1,2023 111*3661 0.6061 -150.00 1,2477 112,6203 0,6102 _-140O0 1,2928 113,8921 0,6142 -130.00 1.3377 115.1820 0,6182 -120,00 1,3824 116.4900 0.6221 -110.00 1,4269 117,8165 0,6260 -100,00 1.4713 11961616 0.6297 -90,00 1.5155 120.5252 0,6335 -8000 1.5595 121,9076 0,6372 -70.00 1.6035 123.3087 0*6408 -60.00 1.6473 124.7286 0.6444 -50*00 1,6911 126.1673 0.6480 -40.00 1.7347 127,6247 0.6515 -30.00 1,7783 129,1009 0*6550 -20.00_ 1,8218 13065957 0,6584 -10,00 1,8652 132.1091 0,6618 0O 1,9086 133.6411 0*6652 10.00 1.9518 135.1915 0,6685 20,00 1.9951 136,7604 0,6718 30.00 2.0383 138.3475 0.6751 40.00 2,0814 139,9529 0,6783 o0.00 2.1245 141*5763 0.6815 60.00 2.1675 143.2177 0.6847 7000 2,2105 144.8770 0.6879 80.00 2,2535 146.5541 0.6910 90.00 2,2964 148.2482 0.6941 100.00 2.3393 149.9605 0.6972 110,00 2.3821 151.6901 0.7003 120*00 2,4250 153.4369 0,7033 130,00 2.4678 155.2009 0.7064 T F c -170.00 -160*00 -150.00 -140 00 -130.00 -120*00 -110.00 -100.00 -90,00 -80.00. -0 (OOO -70,00 -60.00 -50,00 -40 00 -30.00 -20.00 -10.00 0. 10.00 20.00 30.00 40,00 50,00 60.00 70.00 80,00 90,00 100.00 120.00 130*00 V H 1.1159 110.0973 0.6010 1,1602 111l3359 0.6052 1.2042 112,5917 0.6094 l,2479 11368650 06134 1,2914 115.1562 0.6174 1.3347 116.4655 0.6213 1.3779 117,7930 0.6251 1.4208 119.1391 0,6289 1,4636 120.5037 0,6327 1.5063 121.8870 0,6364,5489 123.2889 9 06400 1,5913 124.7096 0,6436 1.6336 126.1490 0,6472 1,6759 127.6071 0,6507 1.7181 129.0838 0.6542 1.7601 130 5792 0,6576 1,8022 132.0932 0.6610 1.8441 133,6257 0.6644 1.8860 135.1767 0.6677 1.9278 136.7460 0,6710 1.9696 138.3336 0.6743 2.0114 139.9394 0,6775 2.0531 141.56323 Z 04808 --- 2.0947 143,2051 0,6840 2.1363 144.8647 0.6871 2.1779 146*5421 0,6903 2,2193 148.2366 0,6934 2.2608 149.9492 0,6965 2,3023 — 151 S.-6 79 -- 06995 2,3437 153.4263 0,7026 2,3852 155.1905 0,7056

-81 - TABLE VI (CONT'D) PRESSURE= GAGE= SAT TFMP = 31. 16.304 -177.69 PRESSURE= GAGE= SAT TEMP = 32, 17 304 -176,73 TF V H S TF V H S -170.00 1.0778 110.0653 0,6002 -170.00 1.0421 110.0331 0.5994 -160.00 1.1208 111.3057 0,6044 -160.00 1.0839 111.2753 0.6036 -150.00 1,1635 112 5631 0.6086 -150.00 1.1254 112.5344 0.6078 -140.00 1.2060 113.8378 0,6126 -140,00 1.1666 113.8106 0,6118 -13 000 1.2482 115 1303 0,6166 -130.00 1,2076 115.1044 0.6158 -120,00 1.2902 116,4408 0,6205 -120,00 1.2484 116.4161 0,6197 -110.00 1.3320 117.7695 0,6244 -110.00 1.2890 117.7460 0.6236 -100.00 1,3736 119.1166 0.6282 -100.00 1,3294 119.0941 0.6274 -90.00 1.4151 120.4822 0.6319 -90,00 1,3697 120.4606 0,6311 -30.00 1.4565 121.8663 0,6356 -80,00 1,4098 121.8456 0.6348 -70.00 1,4977 123,2691 0,6392 -70,00 1.4498 123,2492 0,6385 -60.00 1.5389 124.6905 0,6428 -60.00 1,4897 124,6714 0,6421 -50.00 1.5799 126.1306 0,6464 -50.00 1.5295 126.1122 0,6457 -40.00 1.6209 127.5894 0.6499 -40.00 1,5693 127.5717 0,6492 -3000 1.6617 1290668 0.6534 -30.00 16089 16089 290497 06527 -20.00 157025 130.5628 0,6568 -20.00 1.6484 130.5463 0,6561 -10000 17432 11320773 06602 -10.00 106879 132.0614 0,6595 0. 188 17838 33.6104 0,6636 0. 17273 133,5950 0,6629 10.00 1,8244 135.1618 0.6670 10 00 1,7667 135.1470 0,6662 20.00 1,8650 136.7316 0,6703 20,00 1,8060 136,7172 0,6695 30,00 1,9054 138,3197 0,6735 30.00 1,8452 138,3057 0,6728 40,00 1,9458 139,9259 0,6768 40,00 1,8844 139,9124 0,6761 50.00 1,9862 141,5502 0,6800 50.00 1,9236 141,5371 0,6793 60,00 2,0266 143,1924 006832 60,00 1.9627 143,1797 006825 70,00 2.0669 144,8524 0,6864 70.00 2.0017 144.8401 006856 80.00 2,1071 146.5302 0,6895 80.00 2,0408 146.5182 0,6888 90,00 2,1473 148,2256 0,6926 90.00 2,0798 148.2140 0,6919 100,00 2,1874 149.9379 0,6957 100.00 2,1186 149.9266 0,6950 110.00 2,2276 151 6682 0,6988 110.00 2,1576 151,6572 0.6980 120.00 2.2677 153,4156 0,7018 120.00 2.1965 153.4049 0,7011 130,00 2,3079 155,1801 0,7048 130.00 2,2354 155.1698 0,7041 PRESSURE= 33, PRESSURE= 34i_ GAGE= 18.304 GAGE= 19,304 SAT TEMP = -175,79 SAT TEMP = -174*88 TF~ V H S T F V H S -170,00 1,0085 110.0008 0,5987 -170,00 0,9769 109,9684 0,5979 -160.00 1,0492 111,2449 0.6029 -160,00 1,0165 111.2143 0,6021 -150.00 1,0895 112,5055 0,6070 -150.00 1,0558 112,4767 0,6063 -140,00 1,1296 113,7833 0,6111 -140,00 1,0948 113,7559 0,6104 -130.00 1,1695 115,0785 0,6151 -130,00 1,1336 115,0524 0,6143 -120,00 1,2091 116.3914 0,6190 -120,00 1.11721 11663666 0,6183 -110.00 1,2485 117.7224 0,6229 -110.00 1,2105 117,6987 0,6221 -100,00 1,2878 119.0715 0,6267 -100,00 1,2487 119,0489 0,6259 -90.00 1,3269 120,4390 0,6304 -90,00 1,.2867 120 4173 0,6297 -80,00 1.3659 121.8249 0.6341 -80.00 1,3247 121,8041 0.6334 -70,00 1,4048 123,2293 0,6378 -70,00 1,3624 12362094 0,6371 -60.00 1,4436 124,6523 0,6414 -60.00 1.4001 124.6331 0,6407 -50.00 1.4822 126,0938 0.6449 -50.00 1,4377 126,0754 0.6442 -__-40.00 1,5208 '127,5539 0,6485 -40,00 1.4752 12765362 0,6477 -30,00 1,5593 129.0326 0,6519 -30,00 1,5125 129,0155 0,6512 -20,00 1,5977 130.5298 0,6554 -20.00 1,5499 130,5133 0,6547 -10,00 1,6360 132,0455 0,6588 -10.00 1,5871 132,0296 0,6581 0. 1,6742 133.5796 0,6622 0. 1,6243 133,5642 0,6615 10,00 1,7124 135,1321 0,6655 10.00 1,6614 135,1172 0,6648 20.00 1,7506 136,7028 0,6688 20,00 1,6985 136,6884 0,6681 30,00 1,7887 138,2918 0,6721 30,00 1,7355 138,2779 0,6714 40,00 1,8267 139.8989 0,6753 40,00 1,7724 139,8854 0,6746 50.00 1,8647 141,5240 0,6786 50.00 1,8093 141,5109 0,6779 _ 60.00 1,9027 143,1670 0.6817 60,00 1,8462 143,1543 0,6811 70,00 1,9406 144,8278 0,6849 70,00 1,8830 144,8155 — 06842 80000 1,9785 146,5063 0,6881_ 80,00 109198 146,4943 0,6874 _ 90,00 2,0163 148,2024 0,6912 90,00 1,9566 148,1908 0,6905 100,00 2,0540 149,53_ 0,6943 100000 1,9932 149,9040 0,6936 110&/tl?>&091a lrt-,A462. &.o971a110600 2&0* rtrt ----- "> -n'>oQ -— 111 -A4R9 —.........- - 120,00 130&00 2,1295 153.3943 0,7004 _ 2,1673 155.1594 0,7034 120. 00 13 0 -00 2,0665 153,3836 2.10-32 15 5. 149 --- 0,6997 -0 6,70O2-TV- -

-82 - TABLE VI (CONT'D) PRESSURE= GAGE= SAT TEMP = 35. 20.304 -1 77 3 a9 PRESSURE= GAGE= cSAT TPMD - 36. 21.304 2 1 A 3 4 4 -r 71A. 1 (.........~- -ml -~l' - - t - -l IVt T F V H S T F V H S -170.00 0.9471 109.9359 0,5972 -17000 0.9190 109.9032 0.5965 -160.00 009857 111*1837 0.6014 -160.00 0.9566 111.1529 0.6007 -150.00 1,0240 112.4477 06056 -150.00 0.9940 112.4186 0.6049 -140,00 __ 0._620 113.7284 0.6096 -140&00 1.0310 113.7009 0.6090 -130.00 1.0998 115.0263 0.6136 -130*00 1.0678 115.0002 0,6130 -120.00 1.1373 116.3418 0,6176 -120.00 1.1044 116.3169 0.6169 -110.00 1.1746 117.6750 06214 -110.00 1.1408 117.6512 0.6208 -100.00 12118 1190262 0,625353 -.00 1.1770 119.0035 0.6246 -90.00 1.2488 120.3957 0,6290 -90,00 1.2130 120.3739 0.6283 — 8000 1-2857 121.7834 0.6327 -80 00 1.2490 121.7625 0.6320 -70.00 1.3225 123.1895 0.6364 -70*00 1,2848 123.1695 0.6357 -60.00 1.3591 124.6140 0.6400 -60.00 1.3204 124.5948 06393 -50.00 1.3957 126.0570 0,6435 -50.00 1.3560 126.0385 0.6429 -40.00 1.4321 127.5184 0*6471 -40.00 1.3915 127.5007 0.6464 -30.00 1.4685 128.9984 0,6505 -30.00 1.4269 128.9813 0&6499 -20.00 1.5048 130.4968_ 0O6540 -20.00 1.4622 130.4803 0.6533 -10.00 1.5410 132*0136 0.6574 -10.00 1,4975 131.9977 0,6567 0. 1.5772 133.5488 0,6608 0. 1.5327 133.5334 0.6601 10.00 16641 100 15678 135.0874 0.6635 20.00 1.6493 136.6740 0.6674 20.00 1.6029 136.6596 0.6668 30.00 1.6853 138.2639 0,6707 30.00 1.6379 138.2499 0.6701 40.00 1,___ 7212 139.8719 0,6740 40,00 1.6729 139.8583 0,6733 50.00 1,7571 141.4978 0,6772 - - s5000 1.7078 141.4847 0.6765 60.00 1.7929 143.1416 0.6804 60.00 1.7426 143.1289 0,6797 70.00 1,8287 144.8032 0,6836 70,00 1,7775 144.7908 0,6829 80.00 1,8645 146.4824 0,6867 8000 1.8123 146.4704 0,6860 90.00 1,9002 148.1791 0,6898 90,00 1,8470 148.1675 0.6892 _100.OO 1,. 9358 149.8927 0*6929 100.00 1.8818 149.8820 0,6922 110.00 1.9715 151.6242 0.6960 1To.oo 1.9164 151.6132 0,6953 120.00 2,0071 153.3729 0,6990 12000 1.9510 153.3622 0.6984 130.00 2,0428 155.1386 0.7020 130&00 1.9857 155.1283 0,7014 PRESSURE= 37. PRESSURE= 38. GAGE= 22*304 GAGE= 23,304 SAT TEMP = -172.25 SAT TEMP = -171*40 T F V H S T F V H S -170.00 0.8924 109.8704 0.5958 -170.00 0.8671 109.8375 0,5951 -160.00 0.9291 111*1220 0.6000 -160.00 0,9030 111.0911 0,5994 -150.00 0.9655 112.3894 0,6042 -150*00 0,9386 112,3602 0,6035 -140,00 1,0017 113.6732 0,6083 -140.00 0.9739 113.6456 0,6076 -130.00 1.0376 114.9739 0*6123 -130.00 1,0089 114.9476 0.6116 -120*00 1,0732 116.2919 0,6162 _ -120.00 1.0437 116.2669 0.6156 -110.00 1.1087 117,6274 0,6201 -110.00 1,0783 117.6036 0,6195 -100,00 1,1440 118.9808 0.6239 -100.00 1.1128 118.9580 0,6233 -90e00 1,1792 120.3522 0&6277 -90,00 1.1471 120.3304 0.6270 -80.00 1*2142 121.7417 0*6314 -80.00 1.1812 121 7208 0,6307 -70*00 1,2491 123.1495 0*6350 -70,00 1,2152 123*1294 0.6344 -60.00 1.2838 124.5756 0,6387 __ -60.00 1,2492 124.5563 0,6380 -50.00 1,3185 126.0200 0,6422 -50.00 1.2830 126 0015 0.6416 -40.00 1,3531 127.4829 0.6458 -40.00 1.3167 127.4651 0&6451 -30.00 1,3876 128,9641 0.6492 -30*00 1.3503 128*9470 0,6486 -20.00 1,4220 130.4637 0,6527 -20.00 1,3838 130*4472 0,6521 -10.00 1,4563 131*9817 0.6561 -10.00 1.4173 131,9657 0,6555 0, 1,4906 133,5180 0.6595 0. 1,4507 133.5025 0,6589 10.00 1.5248 135,0725 0,6628 10.00 1.4841 135.0575 0.6622 20*00 1.5590 136,6452 0.6661 20.00 1*5174 136.6307 0.6655 30,00 1.5931 138.2360 0,6694 30*00 1,5506 138.2220 0,6688 40,00 1,6271 139*8448 0o6727 40.00 1,5838 139.8313 0,6721 50.00 1,6611 141.4716 0&6759 50&00 1.6169 141.4584 0.6753 60*00 1*6951 143.1162 0,6791 60.00 1l6500 143.1034 0,6785 70*00 1.7290 144,7785 0.6823 -70&00 1*6831 144*7662 0,6816 80,00 1.7629 146.4584 0,6854 80*00 1*7161 146.4465 0,6848 90,00 1,7967 148&1559 0,6885 90,00 1,7490 148,1443 0,6879 100.00 108305 149.8708 0,6916 100.00 1.7820 149.8595 0,6910 110*00 1.8642 1 5DlbUZ 120.00 1.8980 153.3516 130000 1,9317 155,1179 0,6977_ 120,00 1,8477 153.3409 0,6971 047007 130.00 1.8806 155.1075 0.7001

-83 - TABLE VI (CONT'D) PRESSURE= GAGE= SAT TEMP = 39. 24 304 -170.58 PRESSURE= GAGE= SAT TEMP = 40. 25.304 -169.77 T F V H S T F V H S -170o00 0.8432 109.8044 0,5945 -160.00 0.8548 111.0288 0.5981 -160.00 0.8783 111.0600 0*5987 -150.00 0.8888 112.3014 0.6023 -150,00 0.9130 112.3309 006029 -140.00 0.9225 113.5899 0.6063 -140.00 0.9475 113.6178 006070 -130.00 0.9559 114.8949 0,6104 -130.00 0.9817 114.9213 0.6110 -120.00 0.9891 116.2167 0.6143 -120*00 1.0157 116.2418 0e6149 -110.00 1.0222 117.5558 0.6182 -110.00 1.0495 117.5797 0.6188 -100.00 1.0550 118.9124 0.6220 -100.00 1.0832 118.9352 0,6226 -90.00 1.0877 120.2867 0.6258 -90.00 1.1166 120.3086 0.6264 -80.00 1.1203 121*6790 0.6295 -80,00 1.1500 121.6999 0*6301 -70 00 1.1527 123.0893 0.6332 -70.00 1,1832 123.1094 0,6338 -60.00 1.1850 124.5178 0,6368 -60.00 1.2163 124.5371 0,6374 -50.00 1.2172 125*9645 0.6404 -50.00 1.2492 125.9830 0.6410 -40.00 12493 127.4294 0.6439 -40.00 1.2821 127.4472 0.6445 -30.00 1.2813 128.9126 0.6474 -30.00 1.3149 128.9298 0,6480 -20&00 1.3133 130.4140 0,6509 -20,00 1.3477 130.4306 0.6514 -10.00 1.3452 131.9337 0,6543 -10.00 1.3803 131*9497 0.654 00 1.3770 133.4716 0,6577 0* 1.4129 133.4871 0.6582 10.00 1.4087 135.0277 046610 10*00 1.4454 135.0426 0,6616 20.00 1.4404 136.6018 0,6643 20.00 1.4779 136.6163 0,6649 30000 1.4720 138.1940 0,6676 30.00 1.5103 138.2080 0.6682 40.00 1.5036 139.8042 0,6709 40.00 1.5427 139,8177 0,6714 50.00 1.5351 141.4322 006741 50.00 1.5750 141.4453 0.6747 60,00 1.5666 143.0780 0,6773 60.00 1.6072 143.0907 0*6779 70.00 1.5981 144.7415 0,6805 70.00 1.6395 144.7538 0,6810 80.00 1.6295 146.4225 0.6836 80.00 1.6717 146.4345 0.6842 90.00 1.6609 148.1210 0.6867 90.00 1.7038 148.1327 0,6873 100.00 1.6922 149.8369 0,6898 100.00 1,7359 149.8482 0,6904 110.00 1.7234 151.5692 0.6929 110000 1.7679 151.5802 0.6935 120.00 1.7547 153.3195 0,6959 120.00 1.8000 153.3302 0.6965 130.00 1.7860 155.0867 0.6989 130.00 1.8321 155.0971 0,6995 140.00 1.8172 156.8708 0,7019.__ PRESSURE= 42. PRESSURE= 44, GAGE= 270304 GAGE= 29.304 SAT TEMP = -168.20 SAT TEMP = -166.68 T F V H S T F V H S -160.00 0,8111 110.9660 0.5968 -160.00 0,7713 110.9029 0.5957 -150.00 0,8437 112.2423 0.6010 -150.00 0.8026 112.1828 0.5999 -140 00 0.8759 113.5340 0.6051 -140.00 0.8336 113.4778 0,6040 -130.00 0,9079 114.8418 0.6092 -130000 008643 114,7885 0.6080 -120.00 0*9397 116.1663 0.6131 -120.00 0.8948 116.1156 0,6120 -110.00 0.9713 117.5077 0.6170. -110O00 0,9251 117.4595 0.6159 -100.00 1,0027 118.8665 0.6208 -100.00 0,9552 118.8205 0.6197 -90,00 __ 1,0340 120.2429 0,6246 ___ -90,00 _ 0.9851 120.1989 0.6235 -80.00 1,0651 121&6370 0,6283 -80*00 1.0149 121.5949 0,6272 -70,00 1,0961 123.0491 0,6320 -70,00 1&0446 123.0087 0.6309 -60*00 1.1269 124.4791 0.6356 -60.00 1,0742 124.4404 0,6345 -50,00 1l1577 125,9273 0.6392_ _ -50.00 1,1036 125.8901 0,6381 -40*00 1,1884 127.3936 0.6427 -40.00 1.1330 127.3578 0,6416 _-30eOQ __ 1.2189 128.8781 0.6462 _ _ _ -30,00 1.1622 128.8436 0.6451 -20.00 1,2494 130.3808 0.6497 -20.00 1.1914 130.3475 0.5486 -10.00 1,2799 1319017 0,56531 -10.00 1,2205 131.8696 0,6520 0. 1,3102 133.4407 0,6565 0. 1.2495 133.4097 0,6554 10_00_ 1 _. 1!3405 134.9977 0.6599 10000 1.2785 134.9678 0,6588 20*00 1,3707 136.5729 0,6632 20,00 1,3074 136.5439 0,6621 __30,00_ _1~4009 138.1660 0,6665 _ 30*00_ 1,3363 138.1380 0.6654 40.00 1.4311 139.7771 0.6697 40.00 1.3651 139.7499 0,6686 50,00 1.4611 141.4059 0.6729 50.00 1.3939 141.3796 0,6719 60.00 1,4912 143.0525 0*6761 60.00 1.4226 143.0270 0,6751 70.00 __ 15212 144.7168 0.6793 7000 __1,4513 144&6920 0,6782 80 00 1 l5511 146,3986 0,6825 80.00 1,4799 146.3746 0,6814 90.00 1.5811 148.0978 0.6856 90.00 1,5085 148.0745 0.6845 100.00 1.6110 149.8143 0.6887 100-00 1.5371 149.7917 0.6876 110 00o 16408 151.5480 0,6917 110000 1.5656 151*5261 0,6907 120&00 1*6705 153*2981 0,6948 120.00 1,5940 153.2767 0,6937 130*00 1a7004 155.0659 0&6978 130,00 1,6225 155*0451 0,6967 140.00 1,7301 156.8506 0,7008 -- 140,00 1.6510 156.8303 06997

TABLE VI (CONT'D) PRESSURE= GAGE= SAT TEMP = 46. 31.304 -165.21 PRESSURE= GAGE= SAT TEMP = 48. 33,304 -163.79 T F V H -160,00 -150.00 -140.00 -130.00 -120.00 -110 00 -100.00 -90 00 -80.00 -70.00 -60 00 -50.00 -40.00 -30.00 -20.00 -10.00 0.7350 110.8392 0.7652 112.1229 0.7950 113.4212 0.8245 114.73'9 0.8538 1 3.16.0647 0,8829 117.4111 0.9118 118.7743 0.9405 120.1548 0.9691 121.5527 0.9976 122.9682 s 0.5945 0.5987 0.6028 0.6069 T F-160.00 -150.00 -140600 -130.00 -120.00 -110.00 -100.00 -90.00 -80.00 -70.00 V 0.7017 0,7308 0.7595 0.780 o H 110.7751 112.0625 113.3643 114.6811 0,5934 0.5976 0.6018 0.6058 0a6109 0.6148 0.6186 0.6224 0.6261 046298 0.8162 0.8442 0.8720 0.8997 0,9272 0.9545 116.0136 117.3625 118 7280 120.1105 121.5104 122.9277 0,6098 0e6137 0,6176 0 6214 0,6251 0.6288 1.0260 1.0542 1.0824 1.1104 1.1384 1.1663 124.4016 125.8528 127.3219 128 8091 130.3142 131.8374 133.3786 134.9378 136.5149 138.1099 139.7227 141.3533 0. 6334 0.6370 086406 0.6441 0*6475 0.6510 -60.00 -50.00 -40.00 -30.00 -20.00 -10.00 0.9818 1.0089 1,0360 1.0629 1.0898 1,1166 0O 10 00 20 00 30 00 40*00 50*00 1 1941 1,2219 1,2496 1.2773 1,3049 1*3325 0.6544 0.6577 0.6610 0.6643 0.6676 0.6708 O. 10,00 20*00 30 00 40.00 50.00 1.1434 1,1700 1,1966 1.2232 1.2497 1.2762 1 3026 124.3626 0.5324 125&8154 0.6360 127.2859 0,6396 128.7744 0O6431 130.2808 0.6465 131.8052 0.6500 133.3475 046533 134.9078 05,567 136.4859 0.6600 138.0818 0.6633 139.6955 0.6666 141.3270 0.6698 i42. 9760- 076730 144.6426 0.6762 146.3266 0.6793 148.0279 0.6825 149.7465 0s6856 151.4821 0.5686 60.00 70.00 80.00 90 00 100 00 110.00 1.3600 1.3875 1.4149 1l4423 1.4697 1.4970 143.0015 144.6673 146.3506 148.0512 149.7691 151. 5041 0,6740 0,6772 0,6803 0,6835 0.6866 0.6896 60.00 70.00 80.00 90 00 100 00 110.*0 1.3289 1.3553 1.3816 1.4078 1.4341 120*00 1.5242 153.2553 0,6927 120.00 1.4603 153.234O 0.6917 130.00 1.5515 155.0243 0.6957 130.00 1.4864 155.0035 0.6947 140.00 1.5787 156.8101 0.6987 140.00 1.5125 156.7899 0.6977 _ PRESSURE= 5 PRESSURE= 5 2 GAGE= 35.304 GAGE= 37.304 SAT TEMP = -162.42 SAT TEMP = -161*08 T F~ V H S T F V H S -160*00 0.6711 110&7105 0.5923 -160.00 0.6428 110.6453 0.5913 -150.00 0.6992 112,0018 0,5966 -150.00 0.6699 111.9407 0.5956 -140.00 0*7269 113.3070 0.6007 -140*00 0.6968 113.2494 0.5997 -130.00 0.7544 114.6269 0.6048 -130.00 0.7233 114.5725 0.6038 -120.00 0.7816 115.9623 0,6088 -120*00 0.7496 115.9107 0.6078 -110.00 0.8086 117.3136 0O6127 -110 00 0.7757 117.2646 0,6117 -100.00 0,8354 118.6815 0,6166 -100.00 0.8016 118.6347 0,6156 -90.00 0.8620 120.0661 0.6204 -90.00 0.8273 120.0215 0.6194 -80*00 0.8885 121.4679 0.6241 -80400 0.8529 121 4253 0.6231 -70.00 0,9149 122.8870 0.6278 -70.00 0.8783 122,8462 0.6268 -60*00 0.9411 124.3236 0.6314 -6000 0.9036 124.2845 0.6305 ___ -50.00 09673 125,7779 0.6350..._ -50 00 0.9288 125.7403 0.6341 -40.00 0.9933 127.2499 0.6386 -40,00 0.9539 127.2138 0,6376 -30,00 1.0193 128.7397 0.6421 -30&00 0.9789 128&7050 0,6411 -20.00 1,0451 130.2474 0,6456 -20.00 1.0039 130 2139 0.6446 -10.00 1.0709 131.7730 0a.6490 -10.00 1.0287 131.7407 0.6480 0. 1.0966 133.3164 0,6524 0. 1.0535 133&2852 0.6514._ 10.00 1,1223 134.8777 0.6557 10.00 1.0782 134.8476 0.6548 20.00 1 1479 136.4568 0*6591 20.00 1.1029 136.4277 0.6581.... 30.00 1.1734 138.0537 0.6624 30,00 1.1275 138.0255 0,6614 40.00 1.1989 139.6683 0&6656 40,00 1.1520 139.6411 0,6647 50.00 1.2244 141.3006 0,6689 50*00 1,1766 141,2742 0.6679 60.00 1l2498 142.9504 0.6721 60,00 1.2010 142.9249 0.6711.. 70.00,_ 1.2751 144.6178 0.6752 70.00 1.2254 144.5930 0.6743 80.00 1,3004 146.3025 0.6784 80*00 1,2498 146,2785 0,6775 __ 90*00_ _1.3257 148.0046 _ _ 0.6815 __ 90800 1,2742 147.9812 0.6806 100.00 1,3510 149.7238 0,6846 100.00 1,2985 149,7012 0.6837 110,00 1*3762 151*4601 0.6877 110.00 1.3227 151.4381 0.6868 120*00 1.4014 153.2134 0*6907 120*00 1.3470 153.1921 0.6898 _ 130.00 1.4264 154.9827 0.6938_ 140,00 1,4516 156.7697 0.6968. 130,00 1,3711 154.9618 0.6929 - 140.00 1,3953 156.7494 0.6959

-85 - TABLE VI (CONT'ID) PRESSURE= 56. - GAGE= 41,304 SAT TEMP = -158,52 PRESSURE= GAGE= SAT TEMP = 54. 39,304 -159.78 T F V H -150.00 0.6429 -140,00 0.6689 -130.00 0.69/i6 -120.00 0Q t7200 -110.00 0.7452 -100.00 0.7703 -90.00 0.7951 -80.00 0.8198 -70.00 0.8444 -60.00 _ 0.8689 -50.00 0.8932 -40.00 0.9175 -30.00 0.9416 -20.00 0.9657 -10.00 0.9897 0. 1.0136 10.00 1.0374 20.00 1.0612 30.00 1.0850 40.00 1.1086 50.00 1.1323 60.00 1.1559 70.00 1.1794 80.00 1.2029 90.00 1.2264 100.00 1.2499 110.00 1.2733 120.00 1.2967 130.00 1.3199 140.00 1.3432 150.00 1.3665 111.879 113.191 114.511 115 858 117.215 118 587 119.976 121.382 122 805 124.245 125.702 127 177 128 67C 130 18C 131 703 133 25L 134.817 136 396 137 997 139.61! 141 24i 142 89S 144.56E 146 * 25 147.95] 149.67S 151.413 153 17C 2 0.5946.5 0.5988 8 0.6028 T F -150.00 -140.00 -130.00 — 1?, t' n v 076177 0.6429 0.6679.AQ?92 H B 111.8172 0,5936 113.1332 0,5978 114.4628 0.6019 11O8067 0.6059 30 U t)UO0. -_ vE v au —,. 54 0.6108 -110.00 0.7170 117.1659 0.6099 79 0.6147 -100.00 0.7412 118 5408 0.6137 8 0.6185 -90.00 s0.7653 119.9319 0.6176 >5 0.6222 -80.00 __0_7892 121 3396 0.623 __13 3 0.6259 -70.00 0.8130 122.7642 0,6250 52 0,6296 -60.00 0.8366 124.2059 0,6287?6 o0.6332 -50.00 0.8601 125.6649 0.6323 76 0.6357 -40.00 0.8836 127. 1413 0.6358 __ 31 0.6402 -30.00 0.9069 128.6352 0.6394 )4 0.6437 -2000 0. 9302 130.1468 0,6428 53 0.6'71 -10.00 0.9534 131.6759 0.6463 60 0,6505 0 0O. 0.9765 133.2227 06497 74 0.6539 10.00 0.9995 134.7872 0.6530 36 0.6572 20.00 1.0225 136.3694 0~6564 74 0.6605 30.00 1.0455 137.9692 0.6597 38 0,6638 40.00 1.0683 139.5865 0*6629 78 0,6670 50.00 1.0912 141.2214 0,6662 93 0,6703 60.00 1.1140 142.8737 0,6694 32 0.6734 44 0.6766 79 0.6797 35 0.6828 61 0.6859 037 0.6889 70.00 1.1367 80.00 1.1594 90,00 1,1821 100.00 1.2047 110.00 1.2273 120.00 1.2499 144.5434 U.b626 146,2304 0.6757 147.9345 0.6789 149.6558 0,6820 151.3941 0.6850 153.1493 0.6881 154.9410 156. 7292 158.5338 0.6920 0, 6950 0,6980..... 130.00 1,2724 140.00 --— 1.2949 150.00 1.3174 154e9Z31 Ueb911 156.7089 0.6941 _ 158.5141 0.6971 PRESSURE= GAGE= SAT TEMP = 58. 43.304 -157.29 ___ — _ __PRESSURE 60.. GAGE= 45.304 SAT TEMP = -156.09 o T F -150.00 -140.00 -130.00 -120,00 -110.00 -100.00 -90.00 _ -80.00 -70.00 v H 0.5943 111.7548 0.6188 113.0746 0.6430 114,4074 0.6669 115.7544 06906 117,1162 0.7141 118.4936 0.7374 119,8869 0.7606 121.2966 0.7837 122,7231 S 0. 5927 0.5969 0.6010 0.6050 T F~_ V -150.00 0.5724 -140.00 0.5962 -130,00 0.6198 -120,00 0.6430 H 111.6918 0.5918 113*0154 0.5960 _ 114,3521 0.6001 115.7020 0.6042 0. 6090 0.6129 0.6167 0.6204 0.6242 -110.00 -100.00 -90.00 -80.00 -70.00 0.6660 117.0665 0.6081 0.6889 118*4462 0.6120 0.7115 119.8418 0.6158 0.7340 121.2535 0.6196 0.7563 122.6818 0.6233 -60,00 0,8066 124,1665 0.6278 -60.00 0,7785 124.1270 0.6270 -50.00 0,8294 125.6271 0.6314 -50.00 0,8006 125.5892 0,6306 _-.0..400 0,8520 127,1049 0,6350 -..40,00 _ __08226 127,0685 0,6342 -30,00 0,8746 128,6003 0,6385 -30 00 0,8445 128.5652 0,6377 -20,00 0.8972 130.1131 0,6420 -20'00 0,8663 130.0794 0.6412 -10.00 0.9196 131.6435 0.6454 -10.00 0.8881 131.6110 0,6446 _0.a 0,9420 133.1914 0,6438 __20.I 0,9097 133.1601 0e6480 10.00 0,9643 134.7570 0,6522 - 1000 0,9313 134,7268 0,6514 20.00 0.9865 136.3402 0.6555 20O00 0,9529 136,3109 0,6547 30.00 1,0087 137.9409 0 6588 30,00 0,9744 137,9126 0,6580 40,00 1,0308 139.5592 0.6621 40,00 0,9958 139,5318 0,6613 50.00 1,0529 141,1949 0,6654 50 00 1,0172 141.1684 0,6646 60.00 1, 0749 142.8480 0.6686 60.00 1,0385 142.8224 0.6678 70.00 1.0969 144.5185 0.6718 70,00 1.0598 144.4937 06710 80.00 1.1189 146.2063 0.6749 80,00 1.0811 146.1822 0,6741 90.00 1.1408 147.9112 0,6780 90,00 1.1023 147.8878 0.6772 100.00 1.1627 149.6332 0,6811 100.00 1.1235 149.6105 0a6803 110.00 1.1846 151.3721 0.6842 110.00 1.1446 151.3501 - 0.6834 120.00 1.2064 153.1279 0.6873 120.00 1.1658 153.1065 0.6865.1 - - - I - - - I I - n -, - I -,' 1 0 0 0 0 0 1,I. fb 3 - 1." - I(-#( U Ib b ' - 130.00 1.2282 154.9U05 0.6903 140.00 1.2498 156.6886 0.6933 150.00 1,2716 158.4944 0.6963 140,00 1,2079 156,6694 0,6925 150.00 1.2290 158.4757 0.6955

TABLE VI (CONT'D) PRESSUR= 62. PRESSURE= 64 -- GAGE= 47.304 GAGE= 49304 SAT TEMP = -154.92 SAT TEMP -153.78 T F~ V H S T ~ H s -150.00 0 5519 111.6285..0,5909 - -150.00 0.5327 111.5647 0.5901 -140000 0 5751 112,9560 005951 -140.00 005553 112.8962 0.5943 -130*00 0.5981 114.2962 0.5993 -130.00 0.5777 114.2399 0.5984 -120.00 _ 0.6207 115.6491 0.6033 -120.00 05997 115.5960 0.6025 -110000 0.6430 117.0164 0.6073 -110.00 0,6215 116.9661 0.6065 -100.00 006652 118.3986 0,6112 -100.00 0.6430 118.3508 06104 _ -90.00 0 6872 119.7964 0.6150 -90.00 0,6644 119.7509 0.6142 -80.00 0.7090 121.2102 0.6188 - -80.00 0.6856 121.1668 0.6180 _ -7000 07307 1226405 06225 7000 7067307 122.5990 0.6217 -60.00 087523 124,0873 0.6262 -60,00 0.7277 124.0476 0,6254 -50.00 0.7737 125.5511 0.6298 -50.00 0,7485 125.5131 0.6290 -40.000 07951 127.320 0.6334 -4000 7951127.0320 0.7693 1269955 06326 -30,00 0.8163 128.5301 0.6369 -30,00 0.7899 128,4950 0,6361 -20.00 0.8375 130.0456 0.6404 -20,00 0.8104 130.0117 0.6396 -10,00 0.8586 131.5784 0,6433 -10.00 0.8309 131.5458 0,6431 __ 0. 0.8796 133.1287 0,6472 0. 0,8513 133.0973 0.6465 10.00 0,900 134,6964 0.6506 10.00 019005 134346616964 016666498 20,00 0,9214 136,2817 0,6539 20,00 0,8919 136.2524 0,6532 30.00 0.9423 137.8843 0,6573 30,00 0,9122 137.8560 0,6565 40.00 009630 139,5044 06605 40.00 0.9323 139,4770 0.6598 50.00 009838 141.1419 0,6638 50.00 0,9524 141,1154 0.6630 60000 1.0044 142,7967 0,6670 60.00 0,9725 142.7710 0,6662 70 00 1.0251 144.4688 0,6702 7000 00.9925 144.4439 0.6694 80,00 1,0457 146.1580 0,6733 80.00 1.0125 146.1339 0,6726 90.00 1,0663 147.8644 0.6765 90,00 1a0325 147,8410 0.6757 100.00 1.0868 149.5878 0,6796 100.00 1.0524 149,5650 0,6788 110.00 1.1073 151.3280 0e6827 110.00 1,0723 151,3060 0,6819 120,00 1.1278 153.0851 0.6857 120,00 1.0921 153,0637 0.6850 130,00 1,1482 154.8589 0.6887 130,00 1,1120 154,8381 U.6880 140,00 1,1686 156.6492 0,6918 140,00 1,1318 156,6290 0,6910 150.00 1.1890 158.4560 0,6947. 150,00 1,1515 158.4364 0,6940... PRESSURE _ 66. _ ________ _ PRESSURE 6 GAGE= 51,304 GAGE= 53,304 ___ SAT TEMP = -152,67__ -_______SAT TEMP = -151,58 TF v H S TF~ V H s -150.00 0,5147 1115004. 0..5892 -150.00 0,.4976 111.4356 — 05884 -140.00 0e5367 112.8361 0s5935 -140,00 0.5192 112,7755 0,5927 -130,00 0.5585 114.1834 0,5976 -13000 0. 5405 114 1265 0.5968 -120o00 - 0,5800 115.5426 0,6017 -120.00 0,5614 115.4890 0,6009 -110.00 0.6012 116.9155 0,6057 -110,00 0,5821 116,8648 0,6049 -100.00 0*6222 11803028 0.6096 -100,00 0.6026 118,2547 0.6088 -90,00 0,6430 119,7052 0.6134 -90.00 0,6229 119,6594 0.6127. -80,00 s..0.6636 121.1221 0,6172 -80, 00 0,6429 121.0787 0,6165 _ -70,00 0.6842 122,5573 0,6210 -70,00 0.6630 122,5156 0,6202 -60,00 0,7046 124,0078 0,6246 -60,00 0.6828 123,9678 0,6239 -50.00 007248 125,4749 0,6283 -50.00 0.7024 125,4353 0,6275 -40.00.. 0.7450. 126,9588. 0,6318 -40,00 0.7222 126.9221 0.6311 -30,00 0,7651 128 4597 0,6354 -30.00 0.7417 128.4244 0.,6346.. -20.00 0.7850 129.9778 0,6389 ___-20.,0s 0.7611 129,9439 06381. -10.00 0,8049 131,5132 0.6423 -10.00 0.7805 131.4805 0,6416 0. 0,8248 133,0658 0.6457 0. 0.7998 133.0342 0.6450 10.00 0,8445 134,6357 0,6491 10.00 0,8190 134,6053 0.6484 20.00 0.8642 136,2230 0,6524 _ 20.00__ 08382 136.1936 0.6517 30,00 0,8839 137e8276 0,6558 30,00 0.8573 13777992 0.6550 40400 0.9035 139.4496 0,6590_ 40,00 0,8763 139,4221 0,6583 50.00 0,9230 141,0888 0,6623 50.00 0.8953 141,0623.0.6616 - 60,00 0,9425 142,7453 0,6655 60.00 0.9143 142.7196 0.6648 70.00 0,9620 144.4190 0.6687 70o00 0,9332 144,3941 0,6680 80,00 0.9814 146 1098 0.6719 ______ 8000 0.9520 146,0856 0.6711__ 90i00.10007 147 8176 0.6750 90600 0.o9709 147,7941 0O6743 100.00 _ 10201 149 5423 0.6781 100.00 0.9897 149.5196 0,6774 110.00 1.0394 151.2839 0,6812 110.00 1.0084 151.2619 0.6805 120,00 l10587 153,0423 0,6842 120.00 1,0272 153.0209 0,6835 130.00 1.0779 154,8173 0,6873 130,00 1.0459 154.7965 0,6866 140.00 l___10971 156.6088 0.6903 140,00 1,0645 156.5886 0,6896 150.00 1.1163 158.4167 0.6933 150,00 1,0832 158.3971 0,6926

-87 - TABLE VI (CONT'D) PRESSURE= 70 PRESSURE= 72, GAGE= 55 304 GAGE= 57304 SAT TEMP = -150*51 SAT TEMP = -149.46 TF~ V H S TF V H S -15T000 04816 111.3703 0,5876 -140*00 0.4870 112.6530 0.5911 -140*00 0.5027 112.7145 045919 -130.00 0.5073 114.0112 0,5953 -130.00 0,5234 114.0682 0*5961 -120*00 0,5274 115.3809 0*5994 -120.00 0.5439 115.4351 016002 -110.00 0.5471 116.7625 0.6034 -110.00 0O5641 11668138 0,6042 -100,00 0,5666 118*1577 0.6074 -100.00 0,5841 118.2063 0,6081 _ -90600 0.5858 119*5662 0.6112 -90.00 0,6039 119&6134 0,6119 -80.00 0.6050 120.9914 0.6150 -80.00 0 6234 121 0352 0.6157 _ -70*00 0.6240 122.4307 0.6188 -70.00 0,6430 122*4737 0.6195 -60.00 0,6429 123.8867 0.6225 -60.00 0.6622 123.9265 0.6232 -50.00 0&6616 125.3590 0,6261 -50,00 0,6814 125.3972 0.6268 -40&00 0,6803 126,8484 0.6297 -40,00 0,7006 126*8852 0.6304 -30.00 0.6988 128.3536 0.6332 -30&00 0.7197 128o3891 0.6339 -20.00 0.7173 129,8758 0.6367 -20.00 __07386 129,9099 0,6374 -10.00 0.7357 131.4149 0.6402 -10,00 0,7574 131.4477 0.6409 0O 0.7540 132,9710 0,6436 0. 0,7762 133.0027 0.6443 10.00 0,7722 13465443 0.6470 10.00 0.7949 134.5748 0.6477 20.00 0.7904 136.1348 0,6504 20.00 0.8136 136*1642 ___ 0.6510 _ 30,00 0*8085 137.7424 0.6537 30,00 0,8322 137,7708 0.6543 40.00 0.8265 139.3671 0*6570 40,00 0,8507 139.3947 0.6576 50,00 0,8445 141*0091 0.6602 50.00 0,8692 141.0357 0.6609 60.00 0*8625 142&6681 0.6634 60*00 0,8876 142.6938 0.6641 70.00 0,8804 144.3441 0.6666 70.00 0,9060 144.3691 0.6673 80,00 0.8983 146.0372 0.6698 80,00 0.9244 146 0614 0.6705 90.00 0.9161 147*7472 0.6729 90.00 0,9427 147.7707 0.6736 100.00 0.9339 149.4741 0.6760 100.00 0.9610 149.4968 0.6767 110.00 0.9517 151*2177 0,6791 110.00 0.9792 151.2398 0.6798 120&00 0.9694 152.9780 0.6822 120.00 0.9975 152.9994 0*6829 130*00 0,9871 15467548 0.6852 130*00 1,0157 154,7756 0,6859 140,00 1.0048 156,5481 0*6882 140,00 1.0338 156,5683 0,6889 150,00 1.0225 158.3577 0,6912 150,00 1,0520 158,3774 -0*6919 160.00 1.0401 160.1836 0.6942 __.. PRESSURE= 74 _ ___ ____ __ PRESSURE=__ 76. GAGE= 59.304 GAGE= 61&304 SAT TEMP = -148.44 SAT TEMP = -147*44 T F~ V H S T F ~ V H S -140*00 0,4722 112,5912 0,5904 -140O00 0,4582 112.5289 0,5897 -13000 0___4921 113&9537 0e5946 -130,00 0,4777 113*8957 0*5939 -120.00 0*5117 115,3264 0,5987 -120.00 0,4968 115,2704 0,5980 -110,00 0,5309 116*7099 0,6027 -110*00 0,5157 116,6586 0*6020 -100.00 0,5501 118.1090 0,6066 -100.00 0.5344 118,0600 0,6060 -90,00 0*5689 119.5202 0,6105 -90,00 0,5528 119.4739 _ 0.6098 -80,00 0*5876 120.9475 0,6143 -80.00 0,5711 120,9033 0.6136 -70,00 0.6061 122 3889 0^6181 -70,00 0*5892 122^3469 0,6174 -60*00 0.6245 123*8467 0*6218 -60O00 0,6072 123.8065 0,6211 -50*00 0,6428 125.3207 0O6254 -50.00 0*6251 125.2822 0O6247 -40,00 0.6610 126.8101 0&6290 -40.00 0.6428 126*7733 0*6283 -30.00 0,6792 128*3181 0&6326 -30*00 0.6605 128.2826 0.6319 -20,00 0.6972 129,8416 0,6361 -20,00 0*6781 129.8074 -0*6354 -10.00 0,7151 131.3820 0e6395 _ -10.00 0,6956 131.3491 0.6389 O0 0*7329 132.9394 0,6429 0. 07130 132*9077 0,6423 10,00 0o7507 134.5138 0,6463 10,00 0O7303 134&4832 0,6457 20,00 0,7684 136&1053 0*6497 20*00 0.7476 136.0758 0.6490 30,00 0*7860 137.7139 0,6530 30.00 0O7648 137.6854 0,6524 40*00 0,8036 139.3396 0,6563 40&00 0,7820 139.3120 0.6557 50.00 0,8212 140*9824 0,6595 50,00 0,7991 140.9557 0*6589 60,00 0*8387 142.6423 0.6628 60*00 0,8162 142,6165 0*6621 70*00 0*8561 144*3192 0,6660 70,00 0,8331 144.2928 0,6653 80,00 0,8736 146.0130 0,6691 80*00 0,8502 145.9888 0,6685 90000 0*8909 147,7238 0&6723 90,00 0,8671 147.7003 0O6716 100.00 0,9083 149.4513 0&6754 100*00 0.8840 149.4285 0,6748 110.00 0,9256 151*1956 0.6785 110,00 0,9009 151*1735 0*6779 120*00 0*9429 152,9565 0&6815 120,00 079177 152.9351 - 0,6809 130,00 0.9601 154.7340 0.6846 130*00 0,9346 154.7131 0,6840 140,00 0,9774 156.5279 0,6876 140*00 0*9514 156*5076 0.6870 150.00 0*9946 158o3381 0O6906 150.00 0.9681 158*3184 0,6900 160,00 1,0117 160.1644 0&6936 160*00 0.9849 160.1453 - a06929

-88 - TABLE VI (COONT'D) PRESSURE=~ 7-. 78.......PRESSURE= GAGE= 63,304 GAGE= SAT TEMP = -146A45 SAT TEMP = 80, 65&304 -145.48 (7 T F V H S T F V H S -140,00 0,4449 112.4662 0,5889 -140,00 0,4322 112.4030 0.5882 -130,00 0.4640 113.8372 0,5932 -130,00 0.4510 113.7782 0,5925 -120,00 0.4827 115.2159 0,5973 -120&00 0.4694 115.1609 0,5966 -110,00 0 5012 116.6070 0,6013 -110.00 0.4875 116.5550 0,6006 -100.00 0,5195 118.0108 0.6053 -100,00 0.5053 117.9601 0,6046 -90.00 0.5375 119.4275 0,6092 __ -90,00 0,5230 119.3808 0,6085 -80600 0.5554 120.8589 0.6130 -80000 0,5405 120.8144 0,6123 -70*00_ _0e5731 122,3047 0,6167_ _ -70.00 0,5579 122,2624 0.6161 -60&00 0,5907 123.7663 0,6204 -60.00 0,5751 123.7258 0,6198 -50.00 0,6082 125,2436 0,6241 -50o00 0.5922 125 2049 0,6235 -40,00 0,6255 126*7364 _-3Q0. 0_6427 12 8 2454 -20.00 0,6600 129,7732 -,-_00 0.6770 131.3161 0 0.6940 132.8759 10,00 0.7110 134.4526 20,00 0.7278 136.0462 30,00 0.7446 137,6568 40,00 0,7614 139,2845 50.00 0,7781_ 1409291 60,00 0,7948 142,5906 70O00 0.8113 144.2679 80.00 0.8280 145.9646._ 90,00 0,8445 147.6768 100.00 0,8610 149,4057 110,00 _0,8775 151,1514 120.00 0,8939 152,9136 130,00 0,9103 154,6923 140,00 0,9267 156.4874 150,00 0,9430 158,2987 160,00..0.9594 160.1262 0.6277 -40.00 0.6312._ _-30.00 0,6348 -20,00 0,6382 _ -10 00 0.6417 0. 0.6451 10.00 0,6484 20,00 0.6517 30 00 0.6550 40o00 0,6583 50 00 0,6615 60600 0.6647 70.00 0,6679 80*00 0,6710 90,00 0,6741 10000 0,6772 110,00 0,6803 120O00 0,6833 130.00 0,6864 140.00 0,6894 150,00 0. 6923 - 160.00 0.6091 0,6259 0.6428 0,6594 0.6761 0.6926 0.7091 0,7255 0,7419 0,7582 0O7745 0,7906 0. 8068 0,8230 0,8391 0.8552 0.8712 0,8873 0,9033 0.9192 0,9352 126.6994 128.2099 129.7388 131.2831 132.8441 134.4219 136.0166 137.6283 139.2568 140.9024 142,5648 144,2430 145.9388 147&6533 149.3829 151.1292 152.8921 15466714 156.46771 158.2790 160.1070 0,6271 0,6306 0,6341 0.6376 0.6410 0,6444 0 6 47T8 0,6511 0.6544 0.6577 0, 6609 0,6641 0,6673 0,6704 0, 6735 0,6766 0O6797 0O6827 0.6858 0,6888 0.6917 _ PRESSURE= _ 82, _ _ -__ ____ ___ PRESSURE= — 84, GAGE= 67.304 GAGE= 69*304 SAT TEMP = -144,54 SAT TEMP = -143,60 T F~ V H s T F~ V H S -140.00 0,4202 112.3393 0,5875 -140.00 0,4088 112.2771 0,5869 -130,00 0.4386 113.7187 0,5918 -130,00 0*4268 113.6587 0.5911..-120,00.0,-4567 115,1054 0,5959 -120,00 0,4445 115.0496 0,5953 -110.00 0,4744 116,5027 0,6000 -110.00 0,4619 116.4497 0,5993 -100.00 0,4919 117.9109 0,6040 -100.00 0.4791 117.8615 0.6033 -90,00 0,5092 119,3338 0,6079 -90.00 _ 04961 __1192866 0,6072 -80,00 0,5264 120 7696 O0,6117 -80,00 0*5129 120,7246 0*6111 _ -70.00 0*5433 122*2199 0.6155 _-70,00 0,5295_ 122.1772 0,6148 -60.00 0,5602 123.6852 0,6192 -60.00 0,5460 123.6445 06186 -50.00 0,5769 125,1660 0,6228 -50.00 0.5624 125,1270 0,6222 -40.00 0,5935 126.6623 0,6264 -40.00 0,5786 126,6251 0,6258 -30.00 0,6099 128.1744 0.6300 -30.00 0,5947 128.1388 0,6294 -20.00 0,6264 129.7045 0,6335 -20.00 0,6107 129.6684 0,6329 -10,00 0,6427 131*2500 0,6370 -10.00 0.6268 131,2169 0&6364 O. 0,6590 132.8122 0,6404 0..0.6427 132.7803 0,6398 10,00 0,6751 134*3912 0,6438 10.00 0,6585 134.3605 0,6432 20.00 0.6912 135.9870 0,6472 20.00 0,6743 135.9573 0.6466 30,00 0,7073 137.5996 0*6505 ___ 30,00 0.6899 137&5710 0,6499 40,00 0,7233 139.2292.0,653-8 40.00 0,7056 139.2015 06532 50.00 0,7392 140.8756 0,6571 __ 50,00 0,7212 140.8489 0.6565 60.00 0.7551 -142.5389- - 0,6603 60&00 0.7367 142,5130 0,6597 70.00 0,7709 144.2181 0&6635 70.00 0,7522 144,1931 0,6629 80*00 0,7867 145.9146 0*6667 8000 0,7676 1458905 0,6661 90,00 0,8026 147,6297 0,6698 90,00 0,7831 147,6062 0,6693 100.00 0,8183 149.3601 0.6730 100,00 0.7985 149*3373 0,6724 110.00 0.8340 151.1071 0e6760 110.00 0.8139 151.0850 0,6755 120,00 0.8497 152 8706 0.6791 -12-0.00 0,8292 152,8491 0,6785 130,00 0,8653 154.6506 0*6822 130,00 0,8445 154*6297 0,6816 140.00 0,8810 156.4468 0,6852 140.00 0,8597 156&4266 O06846 150*00 0,8966 158.2593 0,6882 _15000 0,8750 158,2396 0,6876 160.00 0e9121 160.0879 0.6912 160.00 0.8902 160.0688 0,6906

-89 -TABLE VI (CONTD) PRESSURF= 86. PRFSSURE= R8. GAGE= 71304 SAT TEMP = -142s69 GAGE= 73*304 SAT TEMP = -141*79 __T F~ V H ___S T F~ V H S -140.00 0.3978 112.2127 0,5862 - 140.00 0.3874 112 1478 0.5855 -130.00 0.64155 113.5981 ___0.5905 -130.00 004047 113.5371 0.5898 -120.00 0.4329 114.9933 075946 -120.00 0.4219 114.9366 0,5940 -11000j 0 * 0.4500 116.3971 0.5987 -110000 004387 1163437 0.5981 -100600 0.4669 117.8117 0.6027 -100.00 0.4552 117.7617 0.6021 -90.00 0.4835 119.2392 0.6066 -90.00 0.4716 119.1915 006060 -80000 005000 120.6794 0.6105 -80000 0.4877 120.6340 006099 -70.00__ 0.5163 122.1343 0.6142 -70.00 0.5037 122.0913 0,6136 -60.00 0.5325 123.6036 0.6180 -60 00 0.5195 123.5625 0.6174 -50.00 0.5485 125.0879 0.6216 -50.00 0.5353 125.0487 0.6210 -40.00 0.5644 126.5877 0.6252 -40.00 0,5509 126.5502 0,6247 -30.00 0.5802 128.1030 0.6288 -30.00 0.5663 128.0672 0.6282 -20.00 0.5959 129.6342 0.6323 -20.00 0.5817 129.5999 0.6318 -10.00 0.6116 131.1837 0.6358 -10.00 0.5971 13161505 0.6352 0. 0.6270 132.7467 0.6393 0. 00.6122 132.7150 06387 10.00 0.6426 134.3297 0.6427 10000 0.6275 134.2989 0.6421 20.00 0.6580 135.9276 0.6460 20.00 0.6426 135.8979 0*6455 30.00 0.6734 137.5423 0.6494 30.00 0.6576 137.5136 0.6488 40,00 0.6887 139.1738 0.6527 40.00 0o6725 139.1445 0.6521 __ 50.00 0.7040 140.8221 0__ 6559 50.00 0*6875 140.7953 0o6554 60,00 0.7192 142.4871 0.6592 60.00 0.7024 142.4612 0*6586 70.00 0.7343 144.1681 0.6624 70*00 0.7172 144.1431 0.6618 80.00 0.7494 145.8663 0.6655 80.00 0.77320 145.8421 0.6650..__ 90.00 0.7645 147.5810 0.6687 90.00 0.7468 147.5576 0066.81 100.00 0.7796 149.3145 0.6718 100.00 0.7616 149.2916 0.6713 110.00 0.7946 151.0628 0.6749 110,00 0,7763 151.0406 0.6744 120.00 0.8096 152.8276 0.6780 120.00 0.7909 152.8061 0.6774 130.00 0.8246 154,6088 0.6810 130.00 0.8055 154.5863 0.6805 140.00 0.8395 156*4063 0.6840 140.00 0.8202 156.3860 0o6835 __ 150.00 0.8544 158.2199 0.6870 150000 0.8347 158.2002 0.6865 160.00 0.8693 160.0496 0.6900 160.00 0.8493 160.0305 0.6895 _______PRESSURE=_ 90. __ ____ ___ URE _2#___ ______AGP R E S S U R -- 5_=_ -9-.... --- PRES SU____-_ _ GAGE= 750304 GAGE= 77.304 SAT TEMP = -140090 SAT TEMP = -140.03 T F~ V H S T F V H s -140.00 0.3774 112.0824 0 5849 -140.00 0.3678 112.0165 0.5843 -130,00 0.3945 113.4779 0.5892 -130,00 0.3847 11364167 0.5886 -120.00 0.4113 114.8795 005934 -120.00 0.4012 114.8219 0.5928 -110.00 0.4278 116.2900 0.5975 -110000 0.4174 116.2358 0,5969 -100.00 0.4441 117.7113 0.6015 -100.00 0,4334 117.6606 0.6009 -90,00 0.4601 119.1435 0.6054 -90.00 0.4491 119.0953 0,6048 -80.00 0.4759 120.5883 0.6093 -80.00 0.4647 120.5425 0,6087 _-70.00 0.4917 122.0480 0,6131 -70.00 0.4801 122,0046 0,6125 -60.00 0.5072 123.5213 0,6168 -60.00 0,4954 123.4799 0.6162 -50,00 0,5226 12560093 0.6205 -50.00 0.5105 124.9697 0.6199 -40.00 0.5379 126.5126 0.6241 -40.00 0.5255 126.4749 0.6235 -30.00 0.5531 128.0313 0,6277 -30.00 0.5404 127.9952 0,6271 -20.00 0.5682 129.5654 0.6312 -20.00 0.5552 129.5309 0.6306 -10.00 0.5831 131.1155 0.6347 -10.00 0o5699 131.0824 0.6341 0. 0.5981 132.6831 0.6381 0. 0.5845 132.6512 0,6376 10.00 0.6130 134.2680 0,6415 10.00 0.5991 134.2353 0,6410 20.00 0.6278 135.8681 0.6449 20.00 0.6137 135.8383 0,6444 30.,00 0.6425 _1374 *849 0 6482 2 30.00 0,6281 137.4562 0e6477 40.00 0.6571 139.1169 0.6515 4000 0,6424 139.0893 0.6510 50.00 0.6718 140.7684 0.6548 50.00 0,6568 140,7416 0,6543 60.00 0.6864 142.4352 0.6581 60.00 0e6711 142.4093 0.6575 70.00 0.7009 144.1181 0.6613 70,00 0.6853 144.0931 0,6607 80.00 0.7154 145.8179 0,6644 80.00 0,6995 145.7936 0,6639 -90,00 0.7298 147.5341 0,6676 90.00 0.7137 147.5107 0,6671 100.00 0.7443 149.2687 0.6707 100.00 0.7278 149.2442 0.6702 110,00 0.7587 151.0185 0.6738 110.00 0,7419 150.9963 0,6733 120.00 0.7731 152.7846 0,6769 120,00 0.7560 152.7631 06764 130.00 0.7873 154.5655 0.6799 130.00 0.7700 154.5447 0,6794 140.00 0.8017 156.3657 0.6830 140.00 0.7840 15603454..06824 150.00 0.8160 158.1805 0.6860 150.00 0,7980 158.1608 0.6854 160.0 O 08302 160.0113 0*6889 160000 0,8120 159,9921 0. 6884

-90 - TABLE VI (CONT' D) PR )SSUR1F= PRESSURE= 94. 9OA GAGE= SAT TEMP = 79,304 -139.17 GAGE= SAT TFMP = 81.304 -138A33 T F ~ V H S T F~ V H S -130. 00 0.3752 113.3550 0,5880 -130.00 0.3662 113.2929 0.5874 -12000._0.3914 114.7638 0.5922_ -12000 _ 0.3821 114.7053 0.5916 -110.00 0.4074 116.1813 0*5963 -110.00 0.3978 116.1265 0,5957 -100.00 0.4232 117.6096 0.6003 -100.00 0.4134 117.5583 0.5997 -90,00 0.4386 119.0468 0*6042 -90.00 0.4285 118.9981 0.6037 -80.00 0_,4539 120,4964 0__ 6081 -8000 0<14437 120.4523 0,6076 -70.00 0.4691 121.9610 0,6119 -70.00 0.4585 121.9172 0,6114 -60.00 0.4841 123.4383 0.6157 -60.00 0.4732 123.3966 0.6151 -50.00 0.4989 124.9301 0,6194 -50.00 0.4878 124,8903 0.6188 -40.00 0.5137 126.4371 0.6230 -40.00 0.5023 126.3992 0,6224 -30.00 0.5283 127.9591 0.6266 -30.00 0.5166 127.9228 0.6260 -20.00 0.5428 129a4963 0,6301 -20.00 0.5309 129.4617 0.6296 -10.00 0,5572 131.0492 0,6336 -10.00 0,5450 131.0160 06331 ___. ____0,5716 132.6193 0,6371 0o 0,5591 132.5873 0,6365 10.00 0 5858 134,2045 0.6405 10.00 0,5731 134.1738 0.6399 20.00 0,6001 135.8085 0,6438 20,00 0.5872 135.7786 0.6433 30.00 0,6143 137.4274 0.6472 30,00 0.6011 137.3985 0.6467 _40,00 0,6283 139.0617 0,6505 _____ 40,00 __ 0.6148 139.0340 0.6500 50.00 0.6424 140,7130 0,6538 50,00.0,6286 140.6863 - 0-6532 60,00__ 0,6565 142.3833 0,6570 60,00 0,6424 142.3573 0,6565 70.00 0,6704 144,0680 0.6602 70.00 0,6561 144.0429 -- 0,6597 80.00 0,6843 145,7694 0,6634 80.00 0.6697 145.7451 0.6629 90.00 0,6982 147.4872 0,6666 90.00 0,6833 147a4637 0,6660 100,00 0.7120 149,2214 0,6697 100.00 0,6969 149,1986 0,6692 110.00 0.7259 150.9741 0,6728 110.-00 0.7105 150.9519 0,6723 120.00 0_7397 152.7415 0,6759 120,00 _07240 152,7200 0,6754 130,00 0.7533 154.5238 0,6789 130.00 0.7374 154.5030 0,6784 140,00 0.7670 156,3233 0,6819 140.00 0,7508 156,3031 0,6814 150.00 0.7808 158.1411 0.6849 150,00 0,7643 158,1213 0,6844 _ 160,00 0_7945 159,9730 0,6879 160,00 0.7777 159.9538 0,6874 170.00 0,8081 16168208 0,6909 170,00 0,7911 161.8021 0,6904 ____PRESSURE= 98, PRESSURE 10 _________ GAGE= 83,304 GAGE= 85.304 SAT TEMP = -137,50 SAT TEMP = -136.68 T_ F _o _V H s T F~ V Hs_ -130.00 0,3575 113.2304 0,5868 -130,00 0,3491 113e1675 0,5862 -120e00 0.3733 114.6489 0,5910 -120,00 0.3647 114,5902 0,5904 -110.00 0,3888 116.0737 0.5951 -110.00 0,3800 116,0189 0,5946 -100.00 0,4040 117,5067 0,5992 -100,00 0.3949 117,4547 0,5986 -90,00 0.4189 118.9490 0.6031 -90.00 0.4097 118,9023 0,6026 -80.00 0,4338 120.4063 0,6070 -80,00 0,4243 120,3602 0.6065 -70.00 0,4483 121.8732 0e6108 -70,00 0,4386 121,8290 0,6103 -60.00 0.4628 123.3548 0.6146 -60,00 0.4528 123.3127 0,6141 -50.00 0.4771 124.8503 0.6183 -50.00 0.4669 124,8102 0.6178 -40.00 0,4914 126,3611 0.6219 -40,00 0.4809 126.3229 0.6214 -30,00 0.5055 127,8865 0,6255 -30,00 0,4948 127.8500 0,6250 -20,00 0.5195 129.4269 0,'6291 -20,00 0.5085 129.3920 0,6285 -10.00 0.5334 130.9827 0,6326 -10.00 0,5222 130.9493 0.6320 _O Oe 5472 132.5552 0,6360 O. 0,5358 132.5231 0,6355 10.00 0.5610 134,1429 0,6394 10.00 0.5493 134.1120 0,6389 20.00 0,5746 135,7467 0,6428 20.00 0,5627 135.7170 0,6423 30.00 0.5884 137.3697 0,6462 30,00 0,5762 137.3408 0,6457 40.00 0,6019 139.0062 0,6495 40.00 _ 0.5895 138.9785 0,6490 50.00 0.6154 140.6595 0,6527 50.00 0,6027 140.6327 0,6522.60,00_ 0.6289 142.3312 0,6560 60.00 0.6159 142.3033 0,6555 70,00 0,6424 144.0178 0,6592 70.00 0.6292 143.9926 0,6587 80,00 0.6557 145.7208 0,6624 80,00 0.6423 145.6964 0,6619 90.00 0.6691 147.4401 0,6655 90.00 0.6554 147.4166 0.6651 100.00 0,6824 149.1759 0.6687 100.00 0,6684 149.1530 0,6682 110,00 0,6956 150.9279 0,6718 110,00 0,6815 150,9058 0,6713 120e00 0,7090 152.6984 0,6749 120,00 0,6945 152,6769 0,6744 130.00 0,7221 154.4822 0,6779 130.00 0.7075 154.4613 0,6774 140.00 0,7353 156.2829 016809 140,00 0*7204 156,2627 0,6805 150.00 0.7485 158.1016 0,6839 150.00 0,7333 158.0800o 06835 160,00 0,7617 159.9347 0,6869 160,00 0.7463 159,9155 0*6864 170,00 0,7748 161,7835 0,6899 170.00 0.7591 1i61.7649 — 689 -

-91 - TABLE VI (CONT'D) PRFSSURE= 1A05 GAGE= 90&304 SAT TEMP = -134.68 GAGE= 95*304 SAT TEMP = -132*75 T F V H S T F V H S -130600 0.3296 113.0081 0.5847 -130.00 0.3118 112.8458 0.5833 -120.00 0.3447 114.4421 0.5890 -120.00 0.3264 114.2917 0.5877 -110.00 0.3594 115.8804 0.5932 -110.00 0.3407 115.7400 0.5919 -100.00 0.3738 117.3234 0.5973 -100.00 0,3547 117.1939 0.5960 -90,00 0,3881 118.7796 0.6013 -90.00 0.3684 118.6556 0.6000 -80.00 0.4021 120.2441 0.6052 -80.00 0.3819 120.1269 0.6039 -70.00 0.4159 121.7203 0*6090 -70.00 0.3952 121.6092 0.6078 -60*00 0.4295 123.2069 0.6128 -60.00 0,4084 123.1035 0.6115 -50.00 0.4430 124.7094 0.6165 -50.00 0.4214 124.6108 0.6153 -40.00 0.4564 126.2269 0.6201 -40,00 0.4342 126.1302 0,6189 -30,00 0.4698 127.7585 0.6237 -30.00 0.4470 127.6662 046225 -20000 0,4830 129.3045 0.6273 -20,00 0.4597 129 2164 0,6261 -10.00 0.4960 130.8655 0.6308 -10.00 0.4723 130.7811 0.6296 O, 0,5091 132*4424 0,6343 0O 0.4848 132.3613 0_6331 10,00 0.5220 134.0346 0.6377 10.00 0.4972 133.9567 0.6365 20*00 0.5348 135*6425 0.6411 20.00 0.5095 135.5677 0.6399 30.00 0.5476 137.2663 0.6444 30.00 0.5218 137,1943 0*6433 40,00 0.5604 138.9089 0.6478 40.00 0.5341 138.8391 0.6466 50.00 0,5731 140.5656 0.6510 50*00 0,5462 140.4983 0O6499 60*00 0.5858 142.2385 0.6543 60.00 0,5583 142.1735 0.6532 70.00 0,5984 143.9296 0.6575 70.00 0.5705 143*8665 0.6564 80.00 0.6110 145.6355 0.6607 80.00 0,5825 145.5745 0O6596 90.00 0*6235 147.3576 0.6639 90,00 0,5945 147.2986 0.6627 100.00 0.6360 149.0960 06670 100400 0.6064 149.0388 06659 110.00 0,6484 150.8504 0.6701 110.00 0.6183 150.7950 0.6690 120.00 0.6608 152.6210 0.6732 120.00 0__ 6302 152.5673 0.6721 130.00 0.6732 154.4092 0.6763 130.00 0.6421 154.3570 0.6751 140.00 0.6856 156.2121 0,6793 140.00 0.6539 156.1614 0.6782 150.00 0.6979 158.0308 0*6823 150.00 06657 157.9816 0.6812 160.00 0.7103 159.8675 0.6853 160*00 0.6775 159.8176 0.6842 170.00 0.7226 161*7183 0&6882 170.00 0.6893 161.6717 0*6871 PRESSURE= 115 _ SSURE-S__ 120__AL --- GAGE= 100*304 GAGE= 105*304 SAT TEMP = -130*88 SAT TEMP = -129*07 T FH~ V H S T F~ V H -130,00 0,2955 112.6804 0,5820 -12000 0.2944 113.9833 0.5851 -120.00 0.3097 114.1387 0.5863 -110.00 0.3078 115,4533 0,5893 -110,00 0.3236 115.5977 0.5906 -100.00 0.3210 116.9258 0.5935 -100.00 0.3371 117.0607 0,5947 -90.00 0.3339 118.4037 0g5975 -90.00 0.3504 118.5304 0.5987 -80.00 0.3464 119.8876 0.6015 -80.00 0.3634 120.0087 0.6027 -70.00 0.3590 121.3843 0.6054 -70.00 0,3763 121l4972 0.6065 -60.00 0.3711 122.8879 0.6092 -60*00 0.3890 122*9971 0*6103 -50.00 0.3833 124.4072 0.6129 -50.00 0.4015 124.5085 0.6141 -40.00 0.3953 125.9362 0.6166 -40*00 0.4140 126.0350 0,6178 -30.00 0.4072 127.4808 0*6203 -30.00 0O4262 127&5731 0.6214 -20*00 0.4189 129.0372 0.6239 -20.00 0.4385 129.1279 0.6250 -10,00 Q04306 130,6104 0,6274 -10.00 0.4505 130*6952 0,6285 0. 0,4422 132.1974 0.6309 01 0.4625 132,2788 0,6320 10*00 0*4537 133.7986 0.6343 10.00 0.4745 133.8767 0.6354 20.00 0.4652 135.4171 06377 20o00 0.4864 135,4925 0*6388 30.00 0.4765 137.0494 0.6411 30.00 0,4982 137,1220 0.6422 40.00 0.4878 138.6973 0.6444 40.00 0.5099 138,7672 0.6455 50.00 0.4991 140.3622 0,6477 50*00 0.5216 140,4298 0*6488 60t00 0.5103 142.0418 0.6510 60,00 0.5332 142*1070 0.6521 70*00 0.5215 143.7387 0.6542 70.00 0.5449 143.8018 076553 80.00 0.5326 145,4503 0.6574 80.00 0,5564 145.5113 0.6585 90.00 0.5437 147,1801 0.6606 90.00 0.5680 147.2394 0*6617 100.00 0,5547 148.9241 0.6638 100.00 0.5795 148,9815 0.6648 110.00 0.5657 150.6840 0.6669 110.00 0.5909 150.7395 0.6679 120.00 0.5767 152.4597 0.6700 120,00 0.6023 152,5135 0.6710 130.00 0.5876 154,2512 0.6730 130*00 0,6137 154.3034 0.6741 140.00 0.5985 15670585 0.6761 140.00 0.6251 156.1116 0,6771 150.00 0.6095 157.8843 0o6791 150*00 0.6364 157.9337 0,6801 160.00 0.6203 159.7236 0a6821 160.00 0.6477 159,7716 0.6831 170.00 0.6312 161.5784 0.6850 170.00 0.6590 161&6250 0.6861 180.00 0.6420 163,4478 0*6880

-92 - TABLE VI (CONT'D) PRESSURE= 125 _______________ _PRESSURE =_-_ 1-O _ -...... GAGE= 110304 GAGE= 115304 SAT TEMP = -127.32 SAT TEMP = -125.61 T ~ __ VH T v H S_ -120.00 0.2802 113 825-0 — 0,5838 -120.00 0.2670 113.6607 0,5826 -110.00 0.2933 115.3068 0,5881 -110600 0.2799 115.1562 0.5869 -100.00 0.3061 116.7892 0.5923 -100600 0.2924 1166508 0.5911 -90.00 0.3186 118.2757 0.5964 -90.00 0.3046 118.1462 0.5952 -80.00 0,3309 119.7680 0.6004 -80.00 0,3165 119.6469 0.5992 -70.00 _ 0.3430 121.2704 0.6043 -70.00 0.3282 121.1537 0.6032 -60.00 0.3548 122.7809 0,6081 -60.00 0,3398 122*6728 0.6070 -50.00 0015666 124.3048 _06119 -5000 0*3512 124.2015 06108_ -40.00 0.3782 1258391 0,6156 -40.00 0.3782 12525839141 06156 -40,00 036241257412 -30.00 0.3897 127.3878 0.6192 -30.00 0,3735 127.2941 0*6182 -20,00 0.4010 12869485 0,6228 -20,00 0.3845 128.8593 0621 -10.00 0.4123 130.5252 0,6263 ___ -10.00 0.3954 130.4394 0.6253 0. 0.4235 132.1156 0.6298 0. 0.4062 132.0333 0.6288 10.00 0.4346 133.7201 0.6333 _____ 10.00 0.4170 133.6413 0,6323 20*00 0.4457 135.3413 0.6367 20.00 0,4277 135.2651 0.635 30.00 00.4566 136.9766 0.6401 30.00 0,4383 136.9034 0.6391 40.00 0.4675 138.6272 0.6434 40.00 0.4488 138.5568 0.6424 __ 50,00 0.4784 140.2945 0.6467 __ 50,00 0.4593 140.2265 0,6457 60.00 0.4892 141.9764 0.6500 60,00 0.4697 141.9109 0.6490 70.00 0.5000 143.6754 0.6532 ____ 70.00 0.4801 143.6120 06522 _ 80.00 0.5107 145.3892 0.6564 80.00 0.4904 145.3279 06555 90.00 0,5214 147.1207 0,6596 90.00 0.5008 147,0612 s06586 100.00 0.5320 148.8666 0,6628 100.00 0.5110 148.8091 0,6618 __ 110.00 0.5426 150.6283 0,6659 110.00 0.5212 150.5726 0a6649 120,00 0,5531 152.4058 0.6690 120.00 0,5314 152,3518 0.6680 130.00 0,5637 154.1989 ~06720 __ __130.00 0.5416 154,1466 0,6711 140,00 0.5742 156.0078 0.6751 140.00 0.5517 155,9571 0,6741 150,00 0,5847 157.8349 0,6781 150 00 0.5618 157,7831 006771 160,00 0.5952 159.6755 0,6811 160,00 0,5719 159.6275 0,6801 170.00 0,6056 161,5317 0,6841 170,00 0,5820 0 161.4850 0,6831___3 180,00 0,6160 163.4025 0,6870 180,00 0,5920 163.3573 0,6861 P_____ _ RESSURE= 135. -— ______PRESSURE= __140# -... GAGE= 120,304 GAGE= 125.304 SAT TEMP = -123,96 SAT TEMP = -122.34 T F V H S _______T F~ V H S __ -120,00 0,2549 113.4987 0.5814 -120.00 0.2436 113.3325 0*5 8 0 2 -110,00 0,2675 115,0064 0,5858 -11000 0,2558 114,8506 0,5846 -100,00 0.2797 116.5106 0,5900 -100,00 0,2678 116,3661 0,5889 -90,00 0,2915 118,0135 0,5941 -90,00 0,2794 117,8821 0,5931 -80.00 0,3032 119.5241 0.5982 -80.00 0.2908 119 3995 0,5971 -70,00 0.3145 121.0388 0,6021 -70,00 0,a3019 120,9224 0, 6011 -60,00 0,3258 122.5635 0,6060 -60,00 0,3128 122,4530 0,6050 -50,00 0 3368 124,0973 0,6098 -50.00 0,3235 123.9920 0.6088 -40,00 0,3477 125.6425 06135 -40,00 0,3341 125.5430 0,6125 -30,00 0,3585 127.1997 0,6172 -30,00 0,3446 127.1046 0e6162 -20,00 0,3692 128.7695 0,6208 -20,00 0,3550 128.6791 0,6198 -10.00 0,3798 130 *.3532 06243 -10O0 00,3652 130.2664 0,6234 0, 0,3903 131.9517 0,6278 0. 0,3754 131,8674 0,6269 10,00 0,4006 133.5621 0,6313 10,00 0,3855 133.4825 0.6304 20,00 0,4110 135,1887 0,6347 20,00 003955 135,1119 0,6338 30,00 0,4212 136,8300S 0,6381 30,00 0,4054 136,7563 0,6372 40,00 0.4314 138,4862 0.6415 40,00 0,4153 138e4154 0,6405 50.00 0,4416 140a1583 0,6448 50_00 0,4251 140,0899 0,.6439__ 60,00 0,4516 141.8452 0.6481 60,00 0.4349 141,7793 0,6471 70,00 0,4617 143,5485 0,065133 70e00 0,4446 143,4847 0,6504 80,00 0,4717 145.2665 0,6545 80,00 0,4543 145,2050 0,6536 90,00 0,4816 146,9998 0,6577 90,00 0,4639 146,9418 0,6568. 100,00 0,4916 148.7514 0,6609 100,00 0,4735 148.6936 0,6600 110,00 005014 150.5168 0,6640 110 00 0,4831 150.4609 0,6631 120,00 0,5113 152.2977 0,6671 120O00 0,4926 152 2436 0,6662 130,00 0,5211 154.0942 0,6702 130.00_ 0.5021 154.0418 0,6693 140,00 0,5308 155.9063 0,6732 140.00 0,5115 155,8554 0,6723 150.00 0,5406 15707338 0,6762 150.00 0,5209 157,6845 0,6753 160.00 0,5503 159.5767 0,6792 160,00 0,5303 159,5289 0,6783 170,00 0,5601 161.4383 0,6822 170,00 0,5398 161.3916 0,6813 180.00 0,5698 163,3120 0,6852 180 00 0,5491 163,2667 0,6843

-93 - TABLE VI (CONT'D) _._ PRESSURE= 145. GAGE= 130.304 SAT TEMP = -120*77 PRESSURE= 150, GAGE= 135.304 SAT TEMP = -119*23 T FV H -120.00 0.2330 113.1617 -110.00 0.2451 114.6967 -100.00 0.2568 116.2234 -90.00 0,2681 117.7485 -80*00 0,2792 119.2732 -70.00 0.2900 120.8041 -60O00 0.3007 122.3413 -50.00 0.3111 123.8857 -40*00 0.3214 125.4426 -30.00 0.3316 1?27.A008 S 0.5791 0, 5835 0O5878 0.5920 T F ~ -110.00 -100.00 -90.00 -80.00 V H 0.2349 114.5365 0.2464 116.0778 0.2576 117.6126 0.2683 119.1449 S 0.5824 0.5868 0,5910 0.5951 0.5961 0,6001 0.6040 0.6078 0,6115 O...1 2 -70.00 -60.00 -50.00 -40&00 -30.00 -7 A n -20&00 0.3417 128.5880 0o6189 -10.00 -10-00 0.3517 130.1790 0.6224 0. 0. 0.3615 131.7837 0.5260 10.00 -- 10.00 0.3713 133.4006 0.6294 20.00 20.00 0.3810 135.0348 0.6329 30*00 30000 0.3907 136*6823 0,6363 40.00.1. r, _ % 0% } _ ^ - -I I 1 -.1 / 1. - A, - _, - A 0.2790 120,6853 0.5991 0,2893 122.2284 0,6030 0.2995 123.7783 0.6068 0.3096 125.3413 0.6106 0.3195 126.9122 0.6143 0.3293 128.4963 0.6179 0.3390 130 0912 0,5215 0.3486 131.6996 0.6251 0.3581 133.3221 0.6286 0.3676 134.9579 0,6320 0.3769 136.6080 0,6354 0.3863 138.2729 0.6388 0.3955 -39.9525 0.6421 0.4047 141.6470 0.6454 0.4138 143.3568 0&6487 0.4229 145*0816 0.6519 0.4320 146.8220 0.6551 0.4410 148.5778 0.6582 40*00 0*4003 13.83443 50.00 0.4098 140.0213 60s00 0.4193 141.7132 70.00 0,4287 143.4208 80,00 0.4381 145.1434 90.00 0,4474 146,8819 0,5396 0.6430 0&6463 0. 6495 0.6527 0.6559 50.00 60,00 70*00 80 00 90o00 100 00 10000 0,4567 148,6357 0.6591 11000 0.4500 150.3488 0.6614 110,00 0,4660 150*4049 0.6622 120*00 0,4589 152*1351 0,6645 120,00 0,4752 152,1894 0.6653 130.00 0e4678 153.9367 0.6676 130,00 0,4844 153,9893 0,6684 140.00 0,4767 155*7536 0.6706 140,00 0*4935 155&8045 0,6715 150.00 0.4856 157.5857 0,6737 150,00 0O5026 157,6351 0,6745 16000 0e4944 159.4330 0.6767 160,00 0,5117 159,4810 0,6775 170,00 0,5032 161.2955 0o6796 170,00 0.5208 161&3420 0,6805 180.00 0.5120 163.1761 0,6826 180,00 0,5299 163a2214 0,6834 190.00 0,5208 165.0692 0,6855 PRESSURE= 155. PRESSURE= 160. GAGE= 140.304 GAGE= 145.304 SAT TEMP = -117.74 SAT TEMP = -116,27 _ F V H S T F V H S -110.00 0.2255 114.3766 0,5814 -110.00 0,2165 114.2118 0,5803 -100,00 _0,2367 115.9292 0,5858 -100.00 0,2276 115.7776 0,5847 -90,00 0,2476 117,4744 0,5900 -90.00 0,2383 117.3337 0,5890 -80.00 0.2583 119.0192 0.5941 -80O00 0.2487 118.8895 0.5932 -70.00 0.2686 120.5644 0,5981 -70&00 0,2588 120.4419 0,5972 -60.00 0,2787 122.1141 0,6021 -60*00 0.2687 121.9985 0,6011 -50,00 0,2887 123.6739 0,6059 -50.00 0,2786 123.5661 0.6050 -40.00 0,2985 125.2391 0.6097 -40,00 0,2881 125.1359 0,6088 -30,00 0,3081 126.8149 0,6134 -30.00 0,2975 126.7167 0,6125 -20,00 0,3177 128.4040 0,6171 -20,00 0,3069 128,3110 0.6162 -10.00 0.3272 130.0027 0,6206 -10.00 0.3160 __. 0,3365 131.6151 0&6242 O 0 0.3251 10,00 0,3458 133,2413 0&6277 10.00 0,3342 20.00 0,3549 134.8795 0.6311 20,00 0.3431 30,00 0,3641 136.5335 0,6346 30O00 0,3520 40,00 0.3731 138.2013 0,6379 40.00 0,3608 129.9138 0,6198 131,5300 0,6233 __ L33.1601 0,6268 L34.8014 0,6303 136.4586 0.6337 138.1295 0,6371 50.00 0.3821 139.8835 0,6413 50,00 0.3696 139*8142 0,6404 60,00 0.3911 141.5805 0,6446 _ 60,00 03782 141.5121 0,6437 70,00 0.4000 143*2950 0,6478 70.00 0.3869 143.2282 0&6470 80,00 0,4088 145,0196 0,6511 80,00 0.3955 144.9576 0,6502 90,00 0,4176 146.7619 06542. 90,00 0,4041 146,7016 0,6534 100,00 0.4263 148.5197 0,6574 100.00 0.4126 148.4615 0,6566 110.00 0,4351 150,2927 0O6606 110.00 0,4211 150.2387 0,6598 120,00 0.4437 152.0808 0e6637 120,00 0,4295 152,0264 0,6629 130400 0,4524 153*8841 0e6668 130,00 0,4379 153.8314 0,6660 __ 140*00 -_ 04610 155,7026_ 0.6698 140,00 0,4463 155.6516 0,6690 150.00 0.4696 157.5363 0,6728 150,00 0,4546 157*4868 0,6721 - 160,00 0,4781 159.3851 0,6759 160100 0.4629 159.3371 0.6751 170.00 0.4867 161.2490 0.6788 180,00 0,4953 163.1308 0.6818 190,00 0*5037 165*0251 0,6847 170.00 0,4712 161.2024 180O00 0,4795 163.0854 -190o00 0.4878 164.9811.e6781 D)6810 D.6840 —

TABLE VI (CONT'D) PRESSURE 165 GAGE= 150*304 SAT TEMP = -114.84 PRESSURE= 170 GAGE= 1550304 SAT TEMP = -113.44 TF~ V H S T F V H S -110.00 0.2081 114.0439 0.5793 -110.00 0.2001 113*8725 0,5782 -100,00 0.2190 115.6226 0&5837 -100.00 0.2109 115.4695 0,5827 -90.00 0.2295 117.1905 0,5880 -90,00 0.2213 117.0514 0*5871 -80.00 0.2398 118.7584 0.5922 -80,00 0,2313 118*6215 005913 -70600 0.2497 120.3178 0.5963 -70.00 0.2411 120.1975 0.5954 -60.00 0.2595 121.8868 0.6002 -60.00 0.2507 121.7706 0C5994 -50.00 0.2690 123.4575 0.6041 -50.00 0,2600 123.3469 0.6033 -40.00 0.2783 125.0319 0.6079 -40.00 0.2692 124.9319 0o6071 -30.00 0.2876 126.6222 0.6117 -30.00 0.2782 126.5233 0.6108 -20.00 0,2966 128.2173 0.6153 -20.00 0.2870 128.1228 0.6145 -10*00 0.3056 129.8242 0.6189 -10.00 0.2958 129.7361 0.6181 0 0.03145 131.4445 0X6225 0. 0 03045 131.3609 0.6217 10.00 0.3233 133.0785 0.6260 10.00 0.3130 132.9953 0.6252 20,00 0.3320 134.7228 0o6295 20*00 0.3216 134.6457 0.6287 30*00 0.3407 136.3834 0.6329 30&00 0.3300 136.3065 0.6321 40.00 0*3493 138.0573 0.6363 40&00 0.3384 137.9850 0&6355 50.00 0.3578 139.7447 0&6396 50.00 0.3467 139&6747 0.6389 60.00 0.3663 141.4471 0.6430 60.00 0.3549 141.3781 0.6422 70.00 0.3747 143.1637 0.6462 70.00 0.3632 143.0992 0.6455 80.00 0.3831 144.8954 0.6495 80.00 0.3713 144.8330 0.6487 90.00 0.3914 146.6413 0.6527 90.00 0.3794 146&5817 0&6519 100.00 0,3997 148.4033 0,6558 100.00 003875 148.3452 0e6551 110.00 0,4079 150.1801 0,6590 110.00 003955 150*1238 0,6582 120,00 0O4161 151.9719 0.6621 120.00 0.4035 151.9174 0.6614 130,00 0.4243 153.7787 0.6652 130,00 0.4115 153.7260 --- 06645 140.00 0.4324 155,6005 0,6683 140.00 0.4194 155.5498 0,6675 150,00 0,4405 157,4373 0,6713 150.00 0.4273 157.3885 0.6706 160.00 0.4486 159.2891 0.6743 160.00 0,4352 159.2423 0,6736 170.00 0.4567 161.1558 0.6773 170.00 0.4430 161.1111 0O6766 180,00 004648 163.0400 0,6803 180,00 0,4509 162,9947 0,6795 190.00 0.4728 164.9370 0,6832 - 190.00 0,4587 164.8932 0,6825 PRESSURE 175, GAGE= 160.304 SAT TEMP = -112.07 PRESSURE= 180. GAGE= 165.304 SAT TEMP = -110073 T F V H S T Fo V H S -110.00 0.1925 113,6934 - 05772 -110.00 0O1854 1135172 0.5762 -100.00 0.2033 115.3111 0,5818 -100.00 0.1960 115 1500 0,5808 -90.00 0o2135 116.9063 0,5862 -90,00 0.2061 116s7590 0.5852 -80.00 0.2234 118,4891 0.5904 -80,00 0*2158 118.3545 0.5895 -70*00 0.2330 120.0724 0&5945 -70,00 0.2253 119*9460 0,5936 -60,00 0,2423 121.6508 0,5985 -60,00 0,2345 121 5338 0,5976 -50,00 0.2515 123,2373 0,6024 -50.00 0.2435 123,1265 0,6016 -40.00 0,2604 124.8248 0,6062 -40.00 _ 0.2522 124.7210 0*6054 -30000 0.2693 126.4250 0.6100 -30.00 0,2609 126,3258 0.6092 -20.00 0O2780 128.0298 006137 -20.00 0.2694 127.9362 0,6129 -10000 0.2866 129.6473 0,6173 -10,00 0,2778 129.5579 0,6166 00. 0.2951 131&2758 0.6209 0_ 0.2861 13101903 0,6201 10.00 0.3034 132.9142 0,6244 10.00 0,2943 132,8328 0,6237 20,00 0,3117 134.5678 0,6279 20.00 0.3024 134,4895 006272 30.00 0.3199 136.2319 0,6314 30,00 0,3105 136,1570 0,6306 40.00 0,3281 137*9124 0,6348 40.00 003184 137,8395 0,6340 rn A n - A^ A 12f- I a - 4 onrl r n. 12 ao I _ tA n.11 1.1.. I I - c It:n n I I- 'U.Uu U356O 1.01-o U?4 Ubo.0 51uuO 60O00 0.3443 141,3115 0,6414 _ 60,00 _ 70.00 0.3523 143.0345 0,6447 7000 80.00 0.3603 144*7706 0.6480 80.00 _ 90.00 0,3682 146,5213 0,6512 90.00 10000 0.3760 148,2869 0&6544 100.00 U,3264 139o5359 0U6374 0,3342 141.2447 0O6407 0.3420 142,9698 0,6440 0.3498 14407081 0,6472 0.3575 146*4609 0,6505 0,3652 148.2285 0,6536 110.00 0.3838 150*0674 0,6575 110,00 0.3728 150.0109 0.6568 120.00 0,3916 151&8628 0,6606 _ __ 12000 0.3804 151&8081 0&6599 130.00 003994 153*6731 0,6637 130.00 0*3880 153.620:2 06630 140*00 0.4071 155,4985 0,6668 140.00 0.3955 155.4472 0,6661 150O00 0*4148 157*3388 0,6698 150.00 0.4030 157.2891 0.6691 160.00 0*4225 159.1941 0.6729 160.00 0.4105 159.1458 0.6722 __. __,,_A____.,_........................ 170U00 0.4301 161.0643 180.00 0,4378 162.9493 ub/9 10/.o00 0o4160 161Ol /0 4 0,6752 0.6788 180.00 0.4254 162*9038 0.6781 0,6818 190.00 0.4328 164.8049 0,6811 190.00 0.4454 164&8491

-95 - TABLE VI (CONT'D) PRESSURE= 185 GAGE= 170.304 SAT TEMP = -109.42 PRESSURE= 190. GAGE= 175*304 SAT TEMP = -108.13 T F~ V H S T F V H S -100.00 0.1891 114.9858 0.5799 -100.00 0.1825 114.8140 0.5789 -90.00 0.1990 116.6063 0.5843 -90.00 0.1924 116.4563 0,5834 -80.00 0.2087 118.2177 0,5886 -80.00 0.2019 118.0785 0,5877 -70.00 0.2179 119*8143 0,5928 -70400 0.2111 119.6869 0.5919 -60.00 0.2270 121.4154 0.5968 -60*00 0.2200 121.2954 0.5960 -50.00 0.2359 123.0146 0.6008 -50,00 0.2287 122.9013 0.6000 -40*00 0.2445 124.6162 0.6046 -40.00 0.2371 124.5104 046038 -300O0 0,2530 126.2258 0.6084 -30,00 0.2455 126.1250 0O6076 -20.00 0.2613 127.8418 0,6121 -20.00 0.2536 127.7468 0.6114 -10400 0.2696 129.4679 0,6158 -10.00 0.2617 129.3774 0.6150 0, 0.2777 131 1043 0.6194 0. 0.2697 131.0177 0.6187 10.00 0.2857 132.7509 0.6229 10*00 0.2775 132.6685 0.6222 20.00 0.2936 134*4108 0,6264 20.00 0.2853 134*3318 0.6257 30*00 0.3015 136.0818 0.6299 30*00 0.2930 136.0063 0.6292 40O00 0.3093 137.7663 06333 40.00 0.3006 13746929 0.6326 50,00 0.3170 139.4661 0.6367 50.00 0,3082 139.3962 0,6360 60s00 0.3247 141.1777 0,6400 60.00 0.3157 141.1105 0,6393 70.00 0,3323 142.9048 0,6433 70.00 0.3232 142.8398 0,6426 80,00 0.3399 1'4.6454 0,6465 800O0 0,3306 144*5827 0*6458 90,00 0,3475 146.4005 0,6498 90,00 0,3379 146.3399 0,6491 100.00 0,3549 1!-8.1701 0,6529 100,00 0,3452 148.1115 0,6523 110.00 0,3624 149,9544 0,6561 110.00 0,3525 149.8978 0,6554 120,00 0,3698 151.7534 06 592 120.00 0.3598 151.6986 0,6586 130.00 0,3772 153.5672 0,6623 130,00 0,3670 153.5142 0,6617 140,00 0.3845 155 3959 0,6654 140.00 0,3742 155,3445 0,6647 150.00 0,3919 157.2393 0,6685 150.00 0.3813 157.1895 0&6678 160,00 0,3992 159,0976 0,6715 160O00 0,3884 159.0493 0,6708 170,00 0,4064 160.9706 0,6745 170.00 0,3955 160.9237 0,6738 180,00 0,4137 162.8584 0.6775 180.00 0,4026 162.8129 0.6768 190,00 0,4209 154.7608 0,6804 190,00 0,4096 164.7166 0,6797 200*00 0.4281 166.6778 0,6833 200,00 0,4167 166,6349 0,6827 PRESSURE= 195, PRESSURE= 200 GAGE= 180.304 GAGE= 185,304 SAT TEMP = -106,86 SAT TEMP = -105,62 T F~ V H S T F~ V H S -100.00 0.1763 114.6461 0.5780 -100,00 0,1703 114.4736 0,5771 -90,00 _0,1861 116.3032 0.5825 -90,00 0,1801 116.1468 0,5816 -80,00 0,1955 117.9368 0&5869 -80,00 0,1893 117.7925 0,5860 -70,00 0,2045 119,5576 0,5911 -70,00 0,1983 119.4264 0&5903 -60*00 0,2133 121.1739 0*5952 -60&00 0,2069 121,0509 0,5944 -50.00 0,2218 122.7869 0O5992 __-50.00 0,2153 122.6711 0,5984 -40,00 0,2302 124.4036 0&6031 -40,00 0,2235 124,2958 0.6023 -30,00 0,2383 126,0233 0,6069 -30*00_ 0,2315 1259207 0,6061 -20,00 0,2464 127.6510 0,6106 -20.00 0,2394 127.5546 0.6099 -10.00 0.2543 129.2862 0,6143 -10,00 0.2472 129.1944 0,6136 0. 0,2621 130*9307 0,6179 0, 0,2548 130.8432 0,6172 _ 10.00 02698 132.5858 0,6215 10.00 0,2624 132.5026 0.6208 20,00 0*2775 134*2554 0.6250 20.00 0*2699 134,1726 0,6243 30.00 0*2849 135*9305 0,6285_ __ 30,00 0*2772 135,8543 0,6278 40,00 0.2923 137.6192 0,6319 40,00 0,2845 137*5452 0,6312 50.00 0,2998 139,3260 0,6353 50.00 0,2918 139,2555 0,6346 60,00 0,3071 141,0431 0,6386 60,00 0*2990 140.9755 0&6379 70,00 0,3144 142.7747 0.6419 70,00 0.3061 1'42*7094 0*6412 80*00 0*3217 144*5199 0*6452 80,00 0*3132 144,4570 0.6445 90400 0,3288 146&2752 0.6484 90.00 0.3202 146*2150 0,6477 100.00 0O3360 148*0530 0,6516 100*00 0,3273 147.9943 0,6509 110.00 0,3431 149.8411 0,6548 11 000 0,3342 149,7844 0.6541 120*00 0.3502 151.6438 0,6579 120*00 0,3412 151,5890 0O6572 130*00 0,3573 153,4611 0,6610 _ 130,00 0.3481 153*4080 0,6604 140.00 0*3643 155.2931 0,6641 140.00 0,3549 155 2417 0,6634 150.00 0.3713 157,1397 0,6671 150*00 0*3617 157,0899 0*6665 160,00 0,3782 159o0010 0o6702 160*00 0,3686 158,9526 - 0,6695 170*00 0*3852 160&8769 0&6732 170*00 03753 160.8300 0*6725 180,00 0.3921 162.7674 0,6761 180.00 0,3821 162.7219 0,6755 190a00 _ 0.3990 164.6725 0.6791 1900 _ _ 03888 1646283 06785 200.20 0,4058 166.5920 0*6820- 200,00 0.3955 166,5491 06814

-96 - PRESSURE= 210a GAGE= 195.304 SAT TEMP = -103.20 TABLE VI (CONT'D) PRESSURE= 220 C GAGE= 205*304 SAT TEMP = -100 87 T F~ V H S T F V H -100000 0.1591 114.1141 0.5752 -100.00 0.1488 113.7329 0.5734 -90,00 0,1687 115.8231 0.5799 -90.00 0.1584 115.4919 0.5782 -80.00 0.1779 117.5019 0.5844 -80&00 0,1674 117.2011 0,5827 -70,00 0,1866 119 1577 0,5887 -70.00 0,1759 118.8801 0,5871 -60.00 0.1950 120.7997 0.5928 -60.00 0.1842 120.5481 0.5913 -50,00 0 2031 122.4354 0,5969 -50.00 0.1922 122.2042 0,5954 -40.00 0 2111 124.0768 0.6008 -40.00 0.1998 123.8533 0O5994 -30.00 0 2189 125.7129 0,6047 -30.00 0,2074 125.5084 0,6033 -20.00 0.2265 127.3594 0&6085 -20000 002148 127.1611 0e6071 -10.00 0.2340 129.0091 0.6122 -10,00 0,2220 128.8211 0.6108 0. 0.2414 130.6665 0.6158 0. 0.2292 130.4877 0.6145 10000 0.2487 132.3350 0.6194 10.00 0.2362 132.1655 0.6181 20.00 0.2559 134.0120 0,6230 20.00 0.2432 133.8499 0,6217 30.00 0,2630 135.7017 0.6264 30,00 0.2500 135.5466 0.6252 40.00 0.2700 137.4015 0,6299 40.00 0,2568 137.2536 0,6286 50O00 0,2770 139.1140 0.6333 50.00 0.2635 138.9716 0,6320 60,00 0,2839 140.8398 0,6366 60.00 0,2702 140,7033 0.6354 70&00 0.2907 142.5753 0e6399 70.00 0.2767 142.4449 0.6387 80.00 0,2976 144.3308 0,6432 80,00 0,2832 144.2001 0,6420 90,00 0,3043 146.0942 0.6465 90.00 0&2898 145.9730 0,6452 100.00 0.3109 147.8725 0.6497 100.00 0,2962 147.7557 0,6485 110.00 0.3177 149.6708 0.6528 110.00 0.3027 149.5570 0.6516 120.00 0.3243 151.4791 0,6560 120.00 0,3090 151.3691 0.6548 130.00 0.3308 153.2976 0,6591 130.00 0.3153 153.1918 0.6579 140.00 0,3375 155.1387 0,-6622 140,00 0.3217 155.0356 0.6610 150.00 0,3441 156.9901 0.6653 150.00 0.3280 156.8902 0.6641 160,00 0.3506 158.8559 0,6683 160.00 0,3342 158.7591 0.6671 170,00 0,3571 16067362 0.6713 170.00 0,3404 160.6423 0.6701 180,00 0.3635 162.6309 0,6743 180,00 0,3466 162,5398 0,6731 190,00 0.3700 164.5400 0.6773 190,00 0.3528 164,4516 0,6761 200,00 0*3764 166.4633 0,6802 200,00 0.3590 166.3776 0.6790 PRESSURE= 230 __ PRESSURE= 240, GAGE= 215,304 GAGE= 225.304 SAT TEMP = -98,61 SAT TEMP = -96.42 T F V H S T F~ V H S -90,00 0,1489 115.1456 0,5765 -90,00 0,1400 114.7818 0,5748 -80.00 0,1578 116.8899 0,5811 -80.00 0,1489 116,5702 0,5795 -70,00 0.1662 118.6007 0,5856 -70.00 0.1572 118&3066 0,5841 -60.00 0,1743 120.2867 0,5898 -60,00 0.1652 120.0232 0,5884 -50.00 0,1821 121,9634 0.5940 -50.00 0,1728 121.7171 0,5926 -40.00 0.1896 123&6297 0,5980 -40.00 0,1801 123.4030 0,5967 -30.00 0,1969 125.2975 0&6019 -30.00 0,1873 125.0830 0,6006 -20,00 0,2041 126,9630 0,6058 _-20&00 0.1943 126.7630 0,6045 -10.00 0,2111 128.6349 0,6095 -10.00 0,2011 128.4408 0,6083 0. 0,2181 130,3146 0,6132 0. 0,2078 130.1313 0,6120 10,00 0.2249 131.9952 0,6168 10,00 0.2144 131.8245 20.00 0,2316 133,6885 0.6204 20,00 0,2209 133.5255 30,00 0,2382 135.3895 0&6239 30,00 0,2273 135,2344..40.00 _ 0,2447 137.1048 0,6274 40&00 0,2337 136.9555 50.00 0,2512 138,8294 0,6308 50.00 0,2399 138.6864 0.6156 0.6192 0.6227 0.6262 0,6296 60.00 0,2576 140,5649 0,6342 60.00 0,2461 140C4280 0,6330 70,00 0,2640 142.3151 0,6375 70,00 0,2523 142.1831 0&6364 80,00 0,2703 144.0760 0,6408 80,00 0,2584 143*9493 0,6397 90,00 0,2765 145.8519 0,6441 90,00 0,2644 145.7287 0.6429 __ 100.00 0,2828 147.6408 0,6473_ 100,00 0,2704 147,5223 0*6462 110.00 0,2889 149.4429 0&6505 110.00 0,2764 149*3313 0e6494 120,00 0,2951 151*2584 0,6536 120*00 0,2823 151,1482 0,6525 130,00 0,3012 153.0879 0,6568 130,00 0,2881 152.9808 0,6557 140,00 0,3072 154.9322 0,6599 _ 14000 02940 154.8287 0,6588 150.00 0,3133 156.7903 0O6629 150O00 0,2998 156.6902 0.6618 160.00 0,3193 158,6622 0,6660 __ _ 16000 0,3056 158.5654 0,6649 170*00 0,3253 160,5481 0e6690 170,00 03114 160,4543 0,6679 180,00 0,3312 162,4486 0,6720 180,00 0,3171 162.3574 0,6709 190,00 0,3372 164.3632 0,6750 190.00 0,3228 164.2747 0.6739 200,00 0,3431 166*2917 0,6779 200,00 0*3285 166.2021 0,6768 210,00 0,3490 168.2342 0,6808 210,00 0.3342- 168*1510 0,6798

-97 - TABLE VI (CONT'D)._ ___ _ PRESSURE- 250. _ _._____ __ PRESSURE= 260. _ ___ GAGE= 235e304 GAGE= 245.304 SAT TEMP = -94.30 SAT TEMP = -92&24 T F V H S T F V H S -90.00 0,1318 114.4066 0.5731 - -90.00 0.1241 114.0075 0.5714 -80.00 0.1406 116*2358 0,5780 -80.00 0_1330 115*8941 0.5764 -70.00 0.1489 118.0123 0,5826 -70.00 0.1412 117*7064 0.5811 -60.00 0,1567 119.7516 0,5870 -60O00 0.1489 119.4713 0,5856 -50.00 0.1642 121.4643 0.5912 -50.00 061563 121.2137 0.5899 -40.00 0.1714 123.1713 0o5953 -40.00 0,1633 122.9342 0,5940 -30.00 0.1784 124.8644 0,5993 -30.00 0,1701 124.6416 005980 -20.00 0,1852 126.5596 0,6032 -20o00 0.1769 126.3528 0.6020 -10.00 001919 128.2527 0,6070 -10.00 0,1833 128.0574 0,6058 O. 0,1984 129.9484 0,6108 0O 0,1897 129.7631 006096 10.00 0,2048 131,6518 0o6144 10,00 0.1959 131.4773 0,6133 20,00__ 0,2111 133.3609 0,6180 20.00 0,2021 133.1946 0,6169 30&00 0,2173 135.0781 0,6216 30.00 0,2081 134,9204 0,6204 40O00 0,2235 136^8052 006251 40.00 0,2141 136.6537 0.6239 50.00 0,2296 138*5424 0*6285 50,00 0,2200 138 3975 006274 60,00 0,2356 140,2904 0,6319 60,00 0.2258 140,1519 0,6308 70,00 0,2416 142.0533 0.6353 70000 0.2316 141,9171 0,6342 80,00 0,2474 143.8220 0.6386 80,00 0,2373 143.6941 0,6375 90*00 0.2532 145*6051 0,6418 90,00 0,2429 145.4809 0,6408 100.00 _ _0,2590 __1474033 _ 0,6451 100.00 0,2485 147.2840 0o6440 110.00 0,2648 149.2141 0,6483 110,00 0,2541 149.0992 0,6472 120,00 0,2705 151,0378 0,6515 120000 0,2596 150,9267 0,6504 130.00 0,2762 152,8734 0,6546 130000 0,2651 152.7658 0.6536 140,00 0,2818 154.7250 0,6577 140.00 0.2706 154.6211 0.6567 150,00 0,2874 156.5899 0.6608 150,00 0,2760 156.4895 0.6598 160,00 0,2930 158,4684 0.6638 160.00 0,2814 158.3713 0,6628 170,00 0,2986 160.3604 006669 170.00 0.2868 160.2664 0.6659 180.00 0.3041 162.2661 006699 180,00 0,2921 162,1747 0.6689 190,00 0,3096 164.1863 0,6729 190,00 0.2975 164.0977 0,6719 200,00 0,3151 166.1201 0,6758 200,00 0.3028 166,0343 0,6748 210,00 0,3206 168.0677 0,6787 210.00 0*3081 167.9845 0.6778 PRESSURE __270.__ ___ _ ___ESURE - __ 280_ __ GAGE- 255,304 GAGE= 265&304 SAT TEMP = -90.24 SAT TEMP = -88,29 T F~ V H S T V H __ __ -90.00 0,1167 113.5810 0,5696 -80.00 0.1190 115.1588 0.5732 -80.00 0,1258 115.5355 0.5748 -70,00 0,1272_ 117.0633 __ 0,5782 _ -70.00 0,1340 117,3879 0.5796 -60.00 0,1348 118.8945 0.5828 -60.00 0.1416 119,1895 0,5842 -50.00 0,1420 120.6881 0,5872 -50,00 0.1489 120,9536 0,5886 -40,00 0,1488 122.4464 0.5915 -40.00 0,1558 122,6916 05927 -30,00 0,1555 124&1976 __0,5956 -30,00 -0-,1626 124.4240 0.5968 -20.00 0,1618 1259303 0,5996 -20.00 0,1691 126,1424 0,6008 -10,00 _01681 127.6633 0,6035 -10.00 0,1754 127*8591 0,6046 O0 0*1742 129.3942 0a6073 O. 0.1816 129,5754 0,6084 10.00 0,1801 131.1236 0,6110 1000 0,1877 131,3007 0,6121 20.00 001859 132,8600 0,6147 20,00 0,1937 133.0267 0,6158_ __ 30.00 0.1916 134,5987 _ 0,6183 30.00 0,1996 13467613 0,6193 40,00 0.1973 136.3491 0,6218 40.00 0,2054 136*5010 0*6229 50.00 0,2029 138.1064 0,6253 50.00 0,2111 138,2517 0.6263 60.00 0,2083 139.8712 0.6287 60,00 0,2168 140,0126 0.6297 70,00 0,2138 141.6487 0*6321 70,00 0,2223 141.7831 0.6331 80.00 0,2191 143.4344 0,6354 80,00 0,2279 143,5658 0,6365 90,00 0,2245 145.2355 0,6388 90,00 0,2333 145,3563 0,6397 100.00 0.2298 147.0462 0.6420 100,00 0.2388 147,1642 0,6430 110.00 0,2350 148.8685 0,6452 110000 0,2442 148,9840 0,6462 120,00 0,2402 150.7028 0,6484 120,00 0,2496 150,8160 0,6494 130.00 0,2454 152.5529 0,6516 130.00 0,2548 152,6580 0O6526 140.00 0,2505 154&4146 0,6547 140,00 0,2602 154,5170 0*6557 150*00 0,2556 156.2890 06578___ 150.00 0,2654 156.3890 0.6588 160O00 0,2607 158.1764 0,6609 160.00 0,2707 158,2741 0,6619 170*00 0,2657 160.0769 06639_ 170.00 0,2758 160.1707- 0.6649 -- 18000 02707 161.9928 -0,&67 180000 0,2810 162,0833 0*6679 190.00 0,2757 163.9211 0,6700 190.00 0,2862 164.0092 0.6709 200,00 0.2807 165.8627 0,6729 200.00 0,2913 165.9485 0.6739 210,00 __ 0.2856 1678176 0*6759 210.00 0,2964 167.8984 0*6768 220.00 0,2906 169,7858 0.6788

-98 - TABLE VI (CONT'D) PRESSUR=E 290. GAGE= 275304 SAT TEMP = -86*40 PRESSURE= 300. ___ GAGE= 285.304 SAT TEMP = -84.55 T F V_ __v H S T F~ _ V H_ _ S__ -80.00 0.1125 114.7607 0*5716 -80.00 0.1065 114.3529 0s5700 -70.00 0,1209 116.7247 A05767 -70.00 0.1149 _ 116.3685 0.5752 -60.00 0.1285 118.5965 0.5815 -60.00 0.1225 118.2872 0.5801 -50.00 0.1356 120.4158 0*5860 -50.00 0.1295 120*1351 0.5347 -40.00 0,1424 122.2011 0.5903 -40.00 0.1363 121.9494 0.5890 -3000 _ 0.1489 123.9673 0.5944 _ -30.00 0.1427 123.7321 0,5932 -20.00 0.1551 125.7183 0.5985 -20.00 0,1488 125.5025 0,5973 -10,00 0.1612 127.4636 0.6024 _ -10.00 0.1548 127,2608 0_6013 0. 0.1672 129.2047 066062 06 0.1606 129.0130 0,6051 10.00 0,1730 130.9461 0.6100 10.00 0,1663 130.7667 0,6089 20.00 0,1787 132.6911 0.6136 20.00 0.1719 132.5205 0.6126 30.00 0.1842 134.4390 0.6172 __ 30.00 0.1773.134.2779 _0,6162 40.00 0.1898 13661961 0.6208 40.00 0,1828 136*0464 0,5198 50.00 0.1952 137.9599 0&6243 50.00 0.1880 137.8125 0.6233 60.00 0.2005 139.7315 06277 60.00 0.1932 139.5911 0.6268 70,00 0.2058 141.5144 0,6311 70.00 0.1984 141.3795 0.6302 80,00 0.2110 143.3059 0,6345 80.00 0.2035 143.1768 0.6335 90.00 0,2162 145.1109 0,6378 90.00 0.2085 144.9859 0.6368 100,00 0.2214 146.9266 0,6411 100.00 0.2135 146.8066 0,6401 110,00 0,2265 148.7534 0.6443 110.00 0.2185 148.6381 0,6434 12000 0,2315 150.5920 0,6475 120*00 0.2234 150.4809 0,6466 130,00 0,2365 152.4452 0,6507 130.00 0,2283 152.3372 0,6498 140,00 0.2415 1543106 0.6538 140,00 0,2331 154,2U06 0,6529 150.00 0,2465 156,1886 _ _0,6569 _ _ 150,00 0,2379 156.0856 0,6560 160,00 0,2514 1580794 0.00 0 160,00 0,2427 157,9822 0,6591 17000 _ 0,2563 159.9830_ _0,6630 _ 170,00 0.2475 159.8891 0.6621 180,00 0.2611 161.9014 0.6661 180,00 0,2522 161.8100 0.6652 190,00 0,2660 163,8326 0,6690 190.00 0,2569 163.7441 0,6682 200,00 0.2708 165,7769 0,6720 200,00 0,2616 165.6912 0,6711 210,00 0,2756 167.7344 0,6750 210,00 0.2662 167.6513 0,6741 220,00 0.2804 169.7052 0,6779 220.00 0,2709 169.6245 0.6770 _ PRESSURE-= _ 320_ _ PRESSURE 340, GAGE= 305,304 GAGE= 325,304 SAT TEMP = -80,99 SAT TEMP = -77,60 T F~ V H S T F V H S -80,00 0,0952 113,4494 0,5666 - 7000 0,0938 114,8015 0,5692 -70,00 0.1038 115.6246 0,5723 -60,00 0C1016_ 116.9418 0,5747 -60,00 0,1114 117,6302 0,5774 -50.00 0,1087 118.9526 0,5796 -50.00 0,1186 119.5626 0,5822 -40,00 0.1152 120.8826 0,5843 -40*00 0.1251 121.4259 0.5866 -30.00 0,1214 122*7613 0.5387 -30,00 0,1314 123,2561 0,5 910 -20,00 Q,1272 124.5978 0,5929 -20,00 0,1374 125.0586 0,5951 -10.00 0.1329 126.4256 0,5971 -10.00 0.1432 126.8454 0,5991 0.___ 0.1383 128.2328 0.6010 O0 0,1487 128,6215 0,6030 10,00 0,1436 130.0292 0,6049 10.00 0,1543 130.4013 0,6069 20.00 0.1487 131.8258 0,6087 20,00 0,1596 132*1739 0,6106 30,00 0,1537 133.6165 0,6124 30,00 0,1648 133.9514 0,6143 40.00 01587_ 135,4156 0,6160 40.00 0,1700 135.7300 0,6179 50.00 0,1636 137.2190 0.6196 50.00 0.1750 137.5146 0,6214 60.00_ 0.1683 139.0206 0,6231 60.00 0,1800 139,3077 0&6249 70,00 0,1730 140.8342 0,6265 70.00 0,1849 141.1076 0,6283 80,00 0,1777 142.6539 0,6299 80,00 0.1898 142,9170 0,6317 90.00 0,1822 144.4827 0,6333 90,00 0,1945 144,7343 0&6350 100.00 0.1868 146.3235 0,6366 100,00 0,1993 146.5653 0,6383 110,00 0.1913 148.1735 0,6399 110,00 0,2041 148,4082 0,6416 120,00 0,1957 150.0335 0,6431 120,00 0,2087 1502581 0*6448 130,00 0,2001 151.9029 0.6463 130100 0,2133 152,120'5 0,6480 140.00 0.2045 153,7881 0,6495 140,00 0,2179 153,9977 0,6512 150.00 0,2088 155.6846 0,6526 150.00 0,2225 155&8866 0,6543 160.00 0.2131_ 157.5926 0,6557 160,00 0,2270 157,7876 0,6574 170,00 0,2174 159.5125 0.6588 170,00 0,2315 159,7009 0,6604 180,00 __0,2216 161.4449 _0,6619 180,00 0,2359 161,6270 0O6635 190.00 0,2259 163.3903 0,6649 190,00 0,2404 163.5670 0,6665 200.00 0,2301 165.3480 0*6679 200,00 0,2448 165,5196 0,6695 210.00 0,2342 167,3183 0,6708 210,00 0,2492 167.4850 0,6724 220,00 0,2384 169.3011 0,6738 220,00 0,2536 169.4632 0,6754 230.00 0.2425 171.2982 - 0.6767

-99 - TABLE VI (COSNTD) -... PESSU R_ _. 0 GAGE= 345.304 SAT TEMP = -74.36 PRESSURE 3800 GAGE= 365304 SAT TEMP = -71.26 T F~ V H S TF F V H _ -70.00 0,0844 113.8758 0.5660 -70.00 0,0755 112.8002 0,5625 -6000 00927 116.1955 0.5719 -60 000 0.0843 11563629 0.5690 -50.00 0.0998 118.3124 0.5771 -50.00 0,0918 117.6264 0.5746 -40000 0.1064 120.3150 0,5820 -40,00 090983 11977102 055796 -30.00 0.1124 122.2465 0.5865 -30.00 0.1043 121.7047 0.5843 -20.00 0.1182 124,1348 0,5909 -20000 0.a1101 123.6522 0.5888 -10.00 0.1237 125.9920 0,5950 -10.00 0.1154 125.5429 005931 0. __ 0.1290 127.8280 0,5991 0. 0 O1205 127.7_4108_ 0,5972 10.00 0.1341 129.6541 0.6030 10.00 0.1256 129.2694 0,6012 20000 001391 131e4709 0.6068 20,00 0,1304 131,1081 006050 30,00 0,1439 133,2837 0,6106 30,00 0,1351 132.9439 0.6038 40.00 0,1487 135,0980 0,61462 2 40,00_ 0.1397 134.7752 0,6122 5 50.00 0, 1534 1369128 0,6178 50 0. 0,1442 13666054 0,6162 60,00 0,1579 138.7331 0,6214 60.00 0,1487 138.4422 0,6197 7000 0.1625 140,5583 0 6249 70 00 0.1530 140.2795 0,6232 80,00 0,1669 142.3909 0.6283 80,00 0.1573 142,1255 0,6267 90,00 0.1713 144.2279 0.6317 90.00 100.00__ 0,1756 146,0797 0,6350 _ 100.0 110t00 001799 147,9398 0,6383 110.00 120.00 0,1842 149.8090 0,6415 120*00 130.00 0,1883 151,6845 0,6447.. 130,00 140,00 0,1925 153.5779 0,6479 140.00 0,1614 143,9711 0.6301 0.1656 145.8343.. 0,6334 0,1698 147.7047 0,6367 0.1739 149.5898 0,6400 0,1778 151.4652 0,6432 0.1818 153.3670 0,6464 150,00 0,1967 155.4820 0,6511 150*00 0,1858 155 2789 0,6496 160,00 0 2008 157.3972 056542 160,00 0,1898 157.2014 0,6527 17000 0,2049 159.3238 0,6573 - 170,00 01937 159.1348- 06558 180,00 0,2089 161.2618 0,6603 180000 001975 161.0786 0,6589 190.00 0.2129 163.2132 006634 190.00 0,2014 163&0361 0,6619 200.00 0,2170 165.1766 0,6664 200*00 0,2052 165.0053 006649 210000 0,2209 167 1523 06693 210,00 0.2090 16649863 0,6679 220,00 0,2249 169.1402 0,6723 220,00 0.2128 168.9794 0.6708 230.00 0 2288 171.1416 0-6752 230.00 02165- 170.9851 0,6738 __ PRESSURE= __ 400, _ __ __ PRESSURE= 420, GAGE= 385304 GAGE= 405.304 SAT TEMP = -68.29 SAT TEMP = -65&44 T F~ V H S T F V H S -60&00 0,0765 114.4538 0*5660 -60.00 0.0691 113.4019 0,5627 -50.00 0,0842 116,8814 0,5720_ -50&00 0.0774 116,0873 0,5693 -4000 0,0910 119,0878 0&5773 -40,00 0,0842 118.4216 0,5749 -30*00 0,0970 121*1600 0,5822 -30,00 0,0903 120.5720 0,5800 -20*00 0,1027 123*1493 0.5868 -20&00 0,0960 122.6365 0,5848 -10,00 0,1080 125,0929 0,5911 -10,00 0,1012 124,6229 0,5892 0. 0,1131 126&9967 0,5953 0* 0,1062 126.5616 0.5935 1000 0___ 1179 128,8777 0,5994 10.00 0,1110 128,4802 0,5976 20&00 0,1226 130.7444 0,6033 20.00 0.1156 130.3708 0,6016 30.00 0,1272 132,5980 0,6071 30,00 0,1200 132.2510 0.6055 40&00 001317 134.4506 0,6109 40,00 0,1243 134.1217 0,6093 50&00 0.1359 136,2925 0,6145 50,00 0,1286 135.9876 0,6130 60*00 0.1403 138.1473 0,6181 60.00 0,1327 137.8531 0,6166 70,00 001445 140.0047 0.6217 70.00 0,1368 139.7195 0,6201 80e00 0,1486 141,8574 0,6251 80.00 0,1408 1-41.5897 0-6236 90000 0,1527 143.7203 0,6286 90,00 0,1447 143.4617 0,6271 100.00 0,1567 145.5917 0,6319 100400 0,1486 145.3451 0,6305 110*00 0,1606 147.4696 0,6353 110.00 0*1524 147.2338 0,6338 120,00 0*1645 149.3551 0,6385 120,00 0*1561 149.1292 0O6371 130,00 0,1684 151,2511 0,6418 130,00 0,1598 151,0311 0,6404 140,00 0,1723 153*1597 0*6450 140,00 0*1636 152.9485 - 0.-6436 150*00 0*1761 155.0779 0O6482 150,00 0,1672 154.8747 0,6468 160,00 0,1798 157,0062 0,6513 160,00 0,1709 156*8142 0,6499 170,00 0,1836 158,9450 0&6544 170*00 0,1745 158.7563 0,6530 180,00 0,1873 160,8952 0e6575 180000 0*1780 160.7116 0O6561 190,00 0,1910 162,8588 0*6605 190*00 0.1816 162&6815 0,6592 200,00 0,1947 164,8338 0,6635 200*00 0,1851 164,6624 0 6622 210,00 001983 166,8204 0.6665 210,00 0,1886 166,6539 0,6652 220,00 0,2019 168,8187 0,6695 220*00 0,.1921 168.6581 0,6682 230,00 0,2055 170,8288 0.6724 230*00 0,1955 170.6726 0,6711 240,00 0,2091 172*8524 0,6753 240,00 0,1990 172.7010 0,674C

-100 - TABLE VI (CONT'D) _ PRESSURE= 440, _ _ PRESSURE= 460 _ GAGE= 425,304 GAGE= 445*304 SAT TEMP = -62*71 SAT TEMP = -60*08 T F V H S T F V H S -60.00 0,0617 112 1445 0o5589 -60.00 0*0537 110 4581 05542 -50*00 0*0708 115 2035 0&5665 -50*00 060645 114.2094 0*5635 -40,00 0.0779 117,6998 0-5725 -40,00 0*0721 116~9466 0 — 5701 -30.00 0*0842 119.9744 0*5779 -30*00 0*0784 119.3292 0*5757 -20*00 0.0898 122.0983 0.5828 -20*00 0,0841 121.5424 0,5808 -10,00 000950 124.1341 0,5873 -10000 00894 123.6557 0,5855 0O 0.0999 126.1272 0.5917 0O 0.0942 125 6715 0,5899 10. 00 0.1046 128.0719 0.5959 10.00 0,0988 127.6593 0,5942 _ 20.00 0.1091 129.9886 0,5999 20.00 0,1032 129*6093 0,5983 30.00 0,1135 131.8973 0.6039 30.00 0.1075 131.5378 0a6C23 40*00 0.1177 133.7874 0,6077 40,00 0,1116 133.4523 0,6062 _ 50*00 0,1218 135 6712 0,6114 50&00 0,1156 13503560 006100 60.00 0*1258 137.5554 0,6151 60.00 0,1195 137.2538 0.6136 70*00 0.1298 139.4346 0,6187 70,00 _01234 139,1511 0.6173 80*00 0,1336 141 3197 06222 80*00 0,1271 141 0466 0*6208 90.00 0,1374 143.2012 0*6257 90,00 0,1308 142.9445 0,6243 100400 0,1412 145,0969 0,6291 100400 0,1344 144.8501 0*6277 __ 110*00 0.1449 14+6.9968 _0,6324 110600 0,1380 14Z6.7588 0,6311 120.00 0.1485 1'48.9023 0&6358 120.00 0.1415 148.6722 0,6344 130.00 01'521 150,8104 0,6390 130,00 0,1450 150,5948 0,6377 140 00 0,- 1557 152.7366 0,6423 140,00 0,1485 152.5279 0o6410 150.00 0,1592 154 6710 0*6455 150*00 0.1519 154.4708 0&6442 160*00 0*1627 156.6144 0*6486 160600 0.1553 156*4179 0,6474 170i00 0,1662 158 5673 __ 06517 170,00 0.1586 158.3762 0,6505 18000 01i-696 16505279 0.6548- 180.00 0,1619 160.3463 0,6536 190,00 _ 0,1730 162.5042 0*6579 _____ 19000 0*.1652 _162.3282 0.6567 _ 200*00 0.1764 164.4910 06609 200,00 0*1685 164,3204 0*6597 210,00 0*1798 166,4888 0,6639 _210.00 0.1717 166.3231 0*6627 22000 0,1831 16864976 086669 220,00 0i1750 168.3365 0,6657 230000 0,1864 170 5166 _ 0,6699 __ __ 230*00 __ 0*1781_ 170.3607 06687 240*00 0*1897 172.5498 0*6728 240*00 0.1813 172.3988 0&6716 _____ PRESSURE=-_ 480 GAGE= 465*304 SAT TEMP = -57.55 PRESSURE= __ 50C __ GAGE= 4850304 SAT TFMD = -55. 1 __ T F~ _______ ^ ___ H s T FT V _ _ _H S -50.00 0,0584 113,0569 0,5601 -50.00 0.0522 111.6765 05562 -40.00 0o0666 116,1097 0,5675 -40*00 00613 _115,2005 0__05647 -30a00 0,0732 118,6606 0*5735 -30,00 0,0682 117&9411 0.5712 -20*00 0*0789 120,9652 005788 -20,00 0&0740 120.3511 0,5767 -10*00 0.0841 123,1299 0,5836 -10.00 0,0792 122*6038 0,5818 O0 0.0888 125*2003 0*5882 _ O__ __0.0840 124*7359 _ 5865 _ _ 10*00 0*0935 127.2361 0,5926 10.00 0,0886 126,8043 0,5909 20*00 0,0978 129.2149 0s5967 _2000 0&0928 128,8228 0.5952 30,00 0,1020 131,1746 0e6008 30O00 0*0969 130.8018 0O5993 40*00 0*1060 1331115 0,6047 40,00 0,1009 132,7662 0O6032 50,00 0,1099 135*0338 0,6085 50.00 0,1047 134,7120 0,6071 60*00 0.1138 136.9518 046122 600.00 0*1084 136.6419 0o6108_ 70,00 0,1175 138.8630 0*6159 70,00 0,1121 138.5743 0.6145 80,00 0,1212 140.7743_ 06194 80 00 0,1156 140,4962 0,6181 90.00 0,1247 142.6816 0.6229 90,00 0,1191 142,4223 0.6217 100o00 0,1283 144,6001 0,6264 100.00 0*1226 144.3510 0,6251 110o00 0,1317 146*5143 0.6298 110 00 0.1260 146.2804 0.6286 120.00 0,1352 148.4445 0,6332 120,00 0,1293 148.2124 0,6319 130,00 0,1385 150.3735 0. ---6365 13000 00,1325- 150.1514 0.6352 14000_ 0,1419 152,3158 0,6397 140.00 0,1358 152,1031 0,6385 150.00 0o1452 154.2650 046429 150.00 0,1390' 154.0609.6 016417 160.00 0.1485 156.2220 0,6461 160.00 0,1422 156*0258 0O6449 170.00 0,1517 158.1875 0.6493 170,00 0,1453 157*9986 0,6481 180,00 0,1549 160.1627 0,6524 180*00 0.1484 159*9810 0,6512 190o00 0.1581 162.1511 0.6555 190,00 0o1515 161 9751 0,6543 200.00 0_1612 164.1493 0s6585 200,00 __01546 163.9786 0,6574 210,00 0.1644 166.1577 0,6615 210.00 0.1576 165.9919 0.6604 220000 0,1675 168,1765 0,6645 220.00 0,1606 168,0154 0.6634 230*00 0.1705 170.2050 0&6675 230.00 0*1636 17060514 0,6664 240*00 0,1736 172.2480 _0,6704 240.00 0,1665 172,0987 0 6693 250*00 0*1767 174*3021 0,6734 250,00 0,1695 174.1568 -0 06722

-101 - TABLE VI (CONT'D) DR'CFSSUJRF= 52?0 GAGE= 505.304 SAT TFMP = -52.78 PRESSURE= 540. GAGE= 5250304 SAT TEMP = -50054 T F ~ V H s T F~ V H S -50.00 000452 109.7559 0.5511 -50.00 0.0353 106.0716 0.5417 -40.00 0.0562 114.1849 0.5618 -40.00 0O0512 113.0174.05585 -30.00 0.0634 117.1617 0.5688 -30.00 0,0590 116.3547 0.5664 -20O00 0.0694 119.7272 0.5747 -20.00 0,0652 119.0632 0e5726 -10.00 0.0747 122.0520 0,5799 -10.00 0.0704 12164733 0,5780 0, 0,0794 124.2403 005847 O. 0.0753 123 7533 0,5831 10.00 0.0840 126.3648 0.5893 10.00 0.0798 125o9120 0.5877 20,00 0.0882 128.4170 0.5936 20O00 0.0839 12830010 0a5921 30.00 0.0923 130.4316 0,5978 30.00 0.0879 130.0462 0.5963 40.00 0.0961 132.4048 0.6018 40.00 0.0918 132 0656 06004 50.00 0.0999 134.3850 0.6057 50000 0.0955 134.0533 0,6043 60,00 0,1036 136.3367 0.6095 60.00 0.0990 136.0278 0,6082 70.00 031071 138.2831 0.6132 70.00 0,1025 137.9888 0.6119 80.00 0,1106 140,2217 0,6168 80a00 0.1059 139.9448 0,6156 90.00 01140 142.1570 0.6204 90.00 0.1092 141.8898 -06192 100.00 0.1173 144.0994 0,6239 100.00 0.1125 143.8463 0.6227 1i1iUO U.iZU6 14i6UaiU U,627 I 11UeUO U.1L:7 0 I 0 1aUJ UiOLO 120.00__ 01239 147.9840__ 0.6307 120.00 0. 1188 147*7546 0_6295 _ 130.00 01270 149.9286 0.6340 -130.00 0.1219 149.7050..06329 140.00 __0.1302 151a8898 0.6373 14000 __0.1250 151.6760 0.6362 ___ 150.00 0.1333 153,8564 0.6406.. 150.00 0.1280 153.6514 0.6395 160.00 0.1364 155,8293 0.6438 160.00 0.1310 155.6325 0o6427 170.00 0.1394 157,8095 0.6470 170.00 0.1340 157,6203 0.6459 180.00 01_424 159,7975 0.6501___ _ 180.00 0.1369 159.6139 0.6490 190.00 0.1454 161,7982 0.6532 190,00 0.1398 161.6213 0.6521 200,00 0.1484 163,8078 0*6563 200.00 0.1427 163.6372 0,6552 210,00 0.1513 165.8270 006593 210.00 0.1455 165.6621 0.6582 220,00 001542 167,8559 0,6623 220.00 0,1484 167.6965 0,6613 230 00 0,1571 169 8962 U.6653 230.00 0.1512 169,7413 0,6642 240.00 '0.1600 171.9485 0,6683 _ _240.00 0,1540 171.7985 0 6672 -— 250.00 -- 0.1629.174.O 11-3I 0,6712 - 250.00 0 1567 -i738660 0.6701 PRESSURE= __ 600, _ GAGE= 585.304 oRFSSUJP= 70 0 GAGE= 685304 T F o 7 H T F V H S -20,00 0,0537 116.8364 0,5661 -2000 0.0379 112,0968 0,5534 0e53 0.00 0,0643 122,1666 0,5779 0,00 0.0497 119.1918 0,5692 20,00 0,0728 126J296_ 0.5876 _ _ 20,00 0e0583 124.4522 0.5804 40.00 0,0803 130.9730 0,5963 40,00 0,0656 129.0953 0,5899 60,00 0 0,0873 135.082'2 006044 60.00 0.0720 133.4480 0.5984 060694 80.00 0.0937 139,1020 0,6120 80.00 0,0781 137.6694 0,6064 100.000 000999 143.0859 0,6192 100 00 0,0837 141.8015.0,6139 ___ 120,00 0,1058 147,0594 0,6262 120.00 0,0891 145,8948 0,6211 140,00 0.1115 15150388 0.6329 140,00 0,0942 149,9745 0,6280 160.0 0 0,1171 155.0349 0,6395 160,00 0,0992 154,0570 0,6347 180,000 0,1224 159.0550 0,6459 180,00 0.1041 158,1535 0,6412 200,00 0,1279 163.1264 220,00 0,1331 167.2196 240,00 0,1382 171,3511 _260,00 01433 175.5229 280,00 0,1483 179,7360 300.00 0,1532 183,9913 0,6522 0.6583 0,6643 0,6701 0,6759 0,6816 200,00 0.1088 162,2716 0,6475 220.00 0.1134 166,4167 0'6537 240.00 0.1180 170.6103 0,6598 260.00 0,1225 174,8277 0,6658 280.00 0,1269 179,0826 0,6716 300.00 0,1313 183,3762 0,6773 320.00 0,1356 187.7094 0,6830 340,00 0,1398 192,0824 0,6885 360,00 0,1440 196,4955 0,6939 380,00 0,1482 200,9483 0,6993 400.00 0.1523 205,4404 0,7046 420.00 0.1564 209.9711 0,7098 320,00 _ 340.00 360.00 _ 380.00 400,00?42 * ~ ' ).1581 188.2890 ),1630 192,6290 ).1677 197.0111 )01725 201,4348 ),1772 205,8992 ).1R19 210.4036 0.6872 0,6927 0,6981 0.7034 0,7087 0.7138 440.00 0,1865 214.9468 0.7189 440.00 0,1605 214,5396 0,7149 460,00 0,1913 219.5419 0,7240 460,00 0,1645 219,1450 0,7200 480,00 0,1959 224.1635 0,7290 480,00 0,1686 223,7860 0,7250 __ 50000 0,2005 228,8210 0,7339 500,00 0.1725 228,4616 _ 07299 520,00 0,2050 233,5132 0,7387 520.00 0,1765 2331704 07348 540.00 0,2096 238.2385 0,7435 540e00 0.1804 237,9110 0*7396 560,00 0,2141 242,9956 0,7482 560,00 0,1845 242&6974 0,7443 580b00 0,2186 247,7827 0,7528 580.00 0,1884 _247,5010 0,7490 600.00 0,2231 252,5984 0,7574 600.00 0,1923 252.3324 0,7536 620,00 0,2276 257,4409 0,7620 620.00 0.1962 257,1900 0,7581 640,00 -0,2320 262,3085 0,7664 640.00 o0,2001 2620721 0,7626 660,00 0,2365 267,1994 0,7708 660,00 0.2039 266.9769 0,7670 680,00 0.2409 272,1118 0,7752 680.00 0,2078 271,9028 07714 70000 0.2453 277,0439 0,7795 700.00 0,2116 276,8478 0,7757 -- - - — ~-~- -- -- -- -- ---------

-102 - TABLE VI (CONT'D) _ PRESSURE= 800 ___ __ ____ PRESSURE= 900 _ __ ___ GAGE= 785304 GAGE= 885*304 T F V H -S T F V H S -20,00 _00271 106.7678 0.5399 _ -20.0 0 _0.0225 1.03 4629 0.5314 0.00 0.0387 115.7763 0,5600 0,00 0.0308 112.3122 0,5510 20.00 0&0475 121.9844 005732 20.00 0.0391 119.3540 0.5661 40&00 0*0546 127.1147 0.5837 40.00 0.0461 125,0577 0.5777 60&00 000607 131.7776 0*5928 60.00 0.0520 130.0615 0,5875 80,00 0.0664 136.1973 0.6012 80,00 0.0573 134.7184 0,5963 100.00 _ 00716 140*4797 0.6090 __100.00 0,0622 139&1799 0.6045 120.00 0.0766 144.7212 0.6164 120.00 0*0668 143.5267 0.6121 140.00 0,0813 148.9056 0,6235 140.00 0.0713 147*8369 0.6194 160.00 0,0859 153*0763 0.6304 160.00 0.0755 152.0982 0.6264 180.00 0.0903 157.2490 0.6370 180.00 0.0796 156.3481 0.6331 200,00 0.0946 161*4343 0*6434 200.00 0.0835 160.6004 0.6397 220.00 0.0988 16566396 0.6497 220.00 0.0874 164.8650 0,6460 240*00 0.1029 169.8704 0,6559 240.00 0.0911 16961491 0.6523 26000 0.1069 174.1304 0*6619 260*00 0.0948 173.4576 0.6583 280,00 0.1108 178.4221 0O6677 280.00 0.0984 177.7940 0.6643 3000O 0,1148 182.7689 0,6735 300.00 01020 182*1611 0.6701 320,00 0,1187 187.1372 0.6792 320.00 0.1055 1.86.5604 0,6758 340*00 0*1225 191.5428 0.6848 340.00 0.1089 190.9929 0,6814 360&00 0.1262 195.9861 0&6903 360*00 0.1124 195 4843 0.6870 380O00 0,1300 200.4672 0O6957 380.00 0,1158 199.9932 0.6924 400.00 0.1336 204.9858 0.7010 40000 0.1191 204,5379 0.6978 420.00 0.1373 209.5416 0.7062 420.00 0 1224 209.1181 0,7030 440,00 0.1409 214*1338 0*7114 440.00 0.1257 213.7333 0,7082 460_00 0,1445 218.7618 047165 460.00 0.1290 218.3831 0A7133 480.00 0.1481 22344245 0,7215 480*-00 0*1322 223.0665 0.7184 500.00 0.1517 228.1208 0&7264 __500.00 0.1354 227.7825 _ 0.7233 520000 0.1552 232.8497 0,7313 520.00 0.1386 232,5302 0*7282 540*00 0.1587 237.6097 0.7361 540.00 0.1418 237.3083 0.7331 560,00 0,1622 242.3995 0,7409 560.00 0,1449 242.1155 0.7378 580,00 0.1657 247.2176 0.7456 _ 58000 0.1481 246.9504 0.7425 600,00 0.1691 252*0626 0*7502 600.00 0.1512 251.8116 0.7471 620.00 0 1726 256.9327 0.7547 620*00 0.1543 256*6976 0*7517 640*00 0.1760 261.8263 0*7592 640e00 0.1574 261 6067 0*7562 660.00 0.1795 266.7583 0.7637 660.00 0*1604 266.5371 0*7607 680.00 0.1829 271.6973 0.7680 680,00 0,1635 271.4873 0.7650 700.00 0.1863 27646549 0.7723 700*00 0,1665 276 4554 0.7694 PRESSURE= 1000* GAGE= 985*304 PRESSURE __ 1200, O GAGE= 11851304 I F v M D -20,00 0*0204 101.6236 0.5263 0,00 0*0258 109.4247 0,5436 2__ 2Q0 __ 0.0329 116.8093 0.5594 40.00 0,0393 122.9348 0.5719 60000 0,0451 128.3244 0,5825 80,00 0,0502 133,2256 0,5917 100,00_ 00548 137.8695 0*6002 120*00 0*0592 142.3601 0,6081 140&00 0.0633 146.7578 0*6155 160.00 0.0672 151.1003 0.6226 180,00 0.0711 155.4538 0*6296 200,00 0*0747 159.7735 0.6362 220*00 0*0783 164.0972 0.6427 240,00 0*0818 168.4337 0.6490 260 00 0,0852 172.7895 0,6551 280*00 0.0885 177.1690 0*6611 300.00 0.0918 181.5758 0.6670 320.00 0.0950 186.0120 0&6727 340_00 0,0982 190.4794 0.6784 360,00 0.1013 194.9788 0*6840 380,00 0.1044 199.5109 0,6894 400*00 0.1074 204.0758 0,6948 420*00 0.1105 208.7012 0,7001 440.00 0.1135 213.3391 0,7053 460.00 0.1165 218,0102 0*7105 480,00 0*1195 222.7137 0,7155 500,00 0.1224 227.4489 0,7205 520*00 0*1253 232.2148 0.7254 540*00 0.1282 237.0103 0.7303 560.00 0.1311 241.8341 0.7350 580.00 0.1340 246.6850 0*7398 600.00 0.1368 251.5616 0O7444 620.00 0,1396 256.4623 0O7490 640.00 0,1424 261.3857 0O7535 660.00 0.1452 266.3301 0,7580 680*00 0,1480 271*2938 0,7623 700,00 0*1508 276.2751 0,7667 ' r V H S -20,00 0.0185 99.5523 0*5199 0,00 0,0215 106.2923 0e5349 20j00 0.0254 112*7109 005486 40.00 0.0303 119.0936 0.5617 60*00 0,0351 124.9120 0,5731 80.00 0,0397 130*2759 0,5832 100.00 0,0439 135.2700 0,5923 120,00 0.0478 140,0404 0,6007 140*00 0.0515 144.6674 0*6085 160,00 0.0550 149.2032 0*6160 180.00 000583 153.6826 0*6231 200,00 0O0615 158.1293 0*6299 22000 0*0646 162 5597 0 6365 240.00 0.0678 167.0287 0 6430 260,00 0,0707 171.4770 0*6493 280,00 0.0736 175.9403 —,6554 300.00 0*0765 180.4233 0,6614 320.00 0*0793 184.9297 0,6672 340,00 0,0820 189.4621 0*6730 360,00 0,0847 194.0224 0,6786 380,00 0*0874 198.6118 0,6841 400,00 0*0901 203.2310 0.6896 420*00 00927 207,8804 0*6949 440-00 0,0952 212.5601 0,7002 460*00 0,0978 217*2696 0*7054 480,00 0*1003 222.0085 0*7105 500.00 0.1028 226.7762 0*7155 520,00 0,1053 231 5717 0&7204 540*00 0*1079 236*4275 0&7253 560*00 O61103 241.2834 0.7301 580.00 0.1128 246.1649 0&7349 600.00 0.1152 251.0707 0,7396 620*00 0*1176 255*9996 0,7442 640*00 0,1200 260.9501 017487 660.00 0*1224 265*9205 0*7532 680*00 0*1248 270*9094 0e7576 700.00 0.1271 275.9150 0,7620

-103 - TABLE VI (CONT'D) PRESSURE= GAGE= 1400.. ___.PRESSURE= _ 1600t_ - -- _... 1385.304 GAGE= 15850304 T F -VH s T F V H S -20.00 0.0176 98.5090 0.5160 ____ -20.00 0.0170_ 97.7267 0,5128 0.00 0.0197 104&7536 0,5299 0.00 0.0186 103.7755 0.5263 20.00 0.0221 110.4267 0.5420 20,00 0.0204 109.2087 0.5379 40.00 0.0252 116.2045 0.5538 40.00 0.0226 114.5220 0.5487 60.00 0,0289 122.0018 0.5652 60.00 0.0251 119.8273 0*5591 80.00 0,0326 127.5273 0.5756 80.00 0.0280 125.2613 0.5694 100.00 0.0363 132.7559 _ 0.5852 ___ 100.00 0.0311 130.5606 0,5790 120.00 0,0398 137.7999 0O5940 120.00 0.0341 135.6938 0,5880 140.00 0,0432 142.6337 0.6022 140,00 0.0370 140.6613 0,5965 160.00 0.0463 147.3472 0,6100 160.00 0.0399 145*5701 0,6045 180,00 0.0493 151. 9807 0,6173 180.00 0,0427 150.3392 0,6121 200.00 0.0522 156.5627 0.6244 200.00 0.0453 155.0430 0,6193 220,00 0.0550 161.1140 0,6312 220,00 0,0479 159.7038 0,6263 240,00 0.0578 165.6497 0,6377 240,00 0,0503 164.3386 0,6330 260,00 0.0604 170.1805 0.6441 260000 0,0527 168.9600 0,6395 280,00 0.0630 174.7148 0.6503 280.00 0.0551 173.5779 0,6459 300,00 0.0656 17903027 0&6565 300,00 0.0574 178.1995 0,6520 320,00 0,0681 183.8763 0,6624 320,00 0,0596 182.8304 0.6580 340,00 0.0705 188.4706 0,6682 340,00 _ 0,0618 187,4747 0.6639 360.00 0.0729 193,0881 0.6739 360*00 0.0640 192.1807 0.6697 380,00 0,0753 197.7309 0,6795 380,00 0.0662 196.8745 0,6754 400.00 0,0776 202.4002 0.6850 400,00 0.0683 201.5914 0,6809 420.00 0.0799 207,0968 0.6904 420.00 0.0703 206.3326 0*6864 440,00 0,0822 211.8210 06957 440.00 0,0724 211.0988 0,6918 460.00 0,0845 216.5731 0,7009 460.00 0.0744 215.8906 0.6970 480.00 0,0867 221.3528 0&7061 480.00 0.0764 220.7080 0,7022 500,00 0.0889 226.1596 0.7112 500,00 0.0784 225.5507 0,7073 520.00 0.0911 230,9929 0,7161 520,00 6.0804 230.4184 0.7123 540,00 0,0932 235,8520 0.7210 540 00 0.0823 235.3104 0&7173 560.00 0.0954 240,7357 0,7259 560,00 0.0842 240.2259 0.7221 580,00 0,0975 245*6431 0.7306 580.00 0,0862 245.1640 0,7269 600.00 0,0996 250.5729 0,7353 600,00 0,0881 250.1236 0*7317 620.00 0.1017 255,5238 0,7400 620.00 0.0899 25561035 0,7363 640.00 0,1039 260*5262 0.7446 640,00 0,0918 260.1024 0,7409 660.00 0,1060 265.5215 0*7491 660.00 0.0937 265.1188 0,7454 680.00 0,1081 270.5342 0,7535 680.00 0,0955 270.1512 0,7499 700*00 0,1102 275.5628 0,7579 700,00 0,0973 275.1981 087543 PRESSURE= _ 1800, _ __PRESSURE= 2000, GAGE= 1785,304 GAGE= 1985,304 T F~ v H SF s H -20.00 0,0166 97.0360 005098 -20.00 0.0163 96.5847 0,5074 0,00 0,0180 103.1778 0,5235 0,00 0,0175 102,7516 0,5211 20O00 0,0194 108.3962 0,5346 20.00 0.0187 107.9442 0.5322 40,00 0.0210 113,4977 0,5450 40.00 0,0200 11268590 0,5423 60,00 0,0228 118.4959 0,5549 60.00 0.0214 117.6249 0,5516 80,00 0,0250 123.5506 0,5644 80,00 0,0231 122.4691 0,5608 100,00 0.0274 128,7488 0,5739 100.00 0,0249 127,3608 0,5697 120,00 0,0300 133.8827 0,5829 120,00 0.0270 132,4020 0,5785 140.00 _ 0,0325 138.9308 0,5914 140*00 0.0292 137,4176 0,5870 160.00 0,0351 14308762 0,5995 160.00 0.0314 142,3978 0,5952 180,00 0.0375 148.7276 0,6073 180,00 0,0336 147.3201 0,6030 200,00 0.0400 153.5902 0,6147 200.00 0,0358 152.1823 0,6105 220*00 0,0423 158.3470 0,6218 220&00 0,0379 156,9920 0,6177 240,00 0.0446 163.0703 0,6287 240.00 0.0400 161*8564 0,6247 26000__ 0.0468 167.7735 0,6353 260.00 0,0421 166.6313 0,6315 280,00 0,0490 172,4669 0,6418 280,00 0,0441 171.3922 0.6380 300,00 0,0511 177,1587 0,6480 _ 300,00 0,0460 176.1474 0,6443 320,00 000531 181,8552 0,6541 320.00 0,0479 180,9035 0*6505 340,00 0,0551 186.5614 0,6601 340,00 0,0498 185,6657 0,6565 360,00 0*0571 191.2809 0,6659 360*00 0,0516 190.4382 0,6624 380*00 0,0590 196*0164 0,6716 380,00 0,0534 195.2241 0.6682 400,00 0,0609 200.7699 0,6772 400.00 0,0551 200.0258 0.6738 420,00 0,0629 205.5894 0,6828 420.00 0.0569 204.8450 0,6794 440,00 0,0648 210,3959 0,6882 440,00 0,0586 2 ---09.-6-30 0,6848 460.00 0,0666 215,2256 0,6935 460,00 0,0603 214.5404 0O6902 480.00 0*0684 220,0788 0,6987 480*00 0,0619 219.4176 0.6954 500,00 0,0702 224.9555 007038 500*00 0.0637 224.3749 0&7006 520,00 0,0720 229.8556 0 — 7089 520.00 0,0653 229&3059 0,7057 540.00 0,0738 234.7785 0,7138 540.00 0,0669 234.2584 0,7107 A.m A an 7;r IIQ A77 n. 1...... V f o 7:) o uW V e V ( last Z.5 -3 7. ~. 0 580,00 0.0773 244.6902 600*00 0*0790 249*6771 - 620,00 0,0807 254,6835 640.00 0,0824 259.7079 660,00 0.0841 264.7492 0,7236 0,7283 0,7330 0,7376 0.7422 tuovu u.uoo68 Z_ 9*2/318,1 57 580,00 0.0701 244,2253 0,7205 600,00 0,0717 249*2382 0*7253 620*00 0,0733 254.2695 0,7300 640,00 0,0748 259.3180 0.7346 660 00 0,0764 264,3824 0,7392 680 0 00779 — 2694616 -- 0.7437 700 00 0,0795 274.5539 0,7481 680 00 000858 269.8059 0,7466 700,00 0,0874 274,8765 0,7510

TABLE VI (CONT'D) _PRESSURE=_ 2_ 200.a _ ___ __ _ _ _PRESSURE= 2400i GAGE= 2185.30402 GAGE= 2385,30402 I __ v H F v H _ 0600 0.0171 102.4114 0.5190 0.00 0.0168 102.0770 0.5169 20.00 _ 0.0182 107.6643 0.5302 20.00 0.0177 107*2451 0*5279 40.00 0.0193 112.4678 0-5400 40.00 0.0187 112.1407 0.5380 60.00 0.0204 117.0539 0*5490 60.00 0.0198 116.7579 0.5470 80.00 0.0217 121.7104 0,5578 80.00 0.0208 121.2953 0.5556 100.00 0.0232 126.4664 _ 0.5665 100.00 0.0220 125.7913 0,5638 120.00 0,-0248 131.2506 0,5749 120 00 0,0234 130.5015 0.5720 140.00 0.0267 136.1864 _05832 140000 0.0248 135.2156 0.5800 160.00 0.0286 141.1189 0..5913 160.00 0,0264 140.0813 0,5880 180.00 0.0305 146.0482 0*5992 180.00 0.0281 144.9569 0,5958 200.00 0.0325 150.9516 0.6067 200,00 0,0298 149.8504 0.6033 220.00 000344 155.8212 _ 06140 _ 22000 00316 154.7407__ 06106 240.00 0.0363 160.6580 06210 240.00 0.0333 159.6173 06177 2600 00 0.0382 165.5424 0.6279 260.00 0.0350 164*4774 0.6245 280.00 00401 170.3613 0.6345 280.00 000367 169.3225 056312 300.00 0,0419 175.1724 06409 _ 3000.00 0.0385 174.2397 056377 320*00 0,0436 179&9819 0,6471 320000 0.0401 179.0955 0,6440 340.00 0,0454 184.7949 0.6532 340*00 0.0417 183.9536 0.6502 360.00 0*.0471 189.6156 06592 360*00 0.0433 188.8178 0O6562 380.00 000487 194.4474 0.6650 380.00 0.0449 193*6913 0.6621 400.00 0.0504 199.2929 0,6707 400.00 0.0464 198.5767 0.6678 420.000 000520 204.1540 0.6763 420.00 000479 203.4762 0.6734 440.00 0.0536 209.0322 0.6818 440.00 0,0494 208.3913 0,6790 460.00 __00552 213.9285 0,06872 460.00 0.0509 213.3231__ 0.6844 480.00 0,0567 218.8434 0.6925 480.00 0,0523 218.2723 0i6897 5000582 223.7772 6977 500.00 05, 237 00538 223.2392 0&6949 520.00 0,0597 228.7297 07028 520&00 0,0552 228.2241.7-001 540.00 0.0612 233.7008 07078 540.00 0.0566 233.2266 0a7051 560,00 0.0628 238&7506 0,7128 560*00 000579 238.2464 07101 580.00 0&0643 243.7701 007177 580.00 0,0593 2;432829 0.7150 600.00 0.0657 248*8079 0.7225 600.00 0.0607 248.3352 - 0.7198 620.00 0.0672 253.8630 0,7272 __620.00 0.0621 253.4642 0.7246 640.00 0.0686 258.9345 0-7319 640.00 0.0634 258.5578 0,7293 660,00 0.0701 264.0211 0.7364 660.00 0,0648 263.6657 0.7339 680.00 0.0715 269.1216 0.7410 680.00 0.0661 268.7868 0.7384 700.00 00729 274,2346 0*7454 700.00 0*0674 273.9196 0,7429 PRESSURE=2600. __________________ PRESSURE= 2800, GAGE= 2585,30402 GAGE= 278530402 I F~ v H T F V _H S 0.00 0.0166 102.0139 - 0.5154 0,00 0.0163 101,8640 0.5138 20.00 0.0174 107.2168 0,5265 __20.00 0.0172 107.1639 0.5251 40*00 0.0183 112.0358 0,5364 40.00 0.0179 111.8678 0.5347 60.00 0.0192 116.5627 0,5453 60.00 0.0187 116.3873 0.5436 80.00 0O0201 121.0103 0.5537 80,00 0,0196 120.7944 0,5519 100.00 0,0211 125*4599 0.5617 _ 100.00 000204 125.1696 0.5599 120.00 0.0222 129,8897 0O5695 120.00 0,0214 129,6301 0.5677 140.00 0O0235 134.5825 0,5775 _ _140*00 0,0223 134.0190 0,5751 160,00 0.0248 139.2524 0,5851 160.00 0.0235 138.7142 0.5828 180,00 0.0261 143.9711 0.5926 180,00 0*0247 143.3587 0,5902 200.00 0.0277 148.9115 0.6003 200,00 0.0260 148.0562 0,5974 220,00 0.0293 153,7819 0,6075 220,00_ 0.0274 152.9688 0,6048 240*00 0.0309 158.6653 0o6146 240.00 0.0289 157.8263 0,6118 26000 000324 163.5503 0.6215 260.00 0,0303 162.7085 0,6187 280.00 0.0340 168.4318 0.6282 - 280.00 0.0317 167.6039 0O6254 300.00 0.0355 173.3086 0,6347 300.00 0.0331 172.5062 0*6320 320.00 0.0370 178.1819 0,6410 320.00 0.0346 177.4124 0.6383 340.00 0,0386 18331461 0,6473 340.00__ 0.0360 182.3218 0,6446 360.00 0,0401 188.0483 0,6534 360.00 0.0373 187.2352 0.6506 380,00 0,0416 192.9591 0,6593 380.00 __ 0,0388 192.2542 0,6567 400*00 0,0430 197.8808 0.6651 400.00 0,0402 197.2079 0.6625 420,00 0,0445 202,8153 0.6708 420,00 0,0415 202.1739 0,6682 440.00 0.0459 207.7642 0,6763 440,00 0,0428 207,1536 0,6738 460,00 0,0472 212,7286 0,6818 460,00 0.0441 212.1480 0,6793 480,00 0,0486 217.7094 006871 48-000 0- 0,0454 217.1577 0.6847 500.00 0O0500 222,7068 0,6924 500.00 0.0467 222.1834 0 6900 520e00 0,0513 227.7213 0 — 6976 520.00 0,0479 227e2252 0.6952 540.00 0,0526 232*7526 0,7026 540.00 0,0492 232.2831 0.7003 560*00 0,0539 237*8004 0,7076 560,00 0,0504 237,3568 0,7053 580,00 0,0552 242.8643 0,7126 580,00 0*0516 242.4459 0,7103 600,00 0,0565 247.9435 0*7174 600 O0 0,0528 247.5498 0 7151 620.00 0,0577 253.0372 0,7222 620,00 0,0540 252.6676 0,7199 -640,00 0,0590 258.1-443 0,7269. 640.00 0,0-5-52 257.7984 0,7246 660,00 0.0602 263.2637 0.7315 660.00 0.0564 262,9412 0,7293 680,00 0.0615 268.4571 0,7361 680.00 0,0575 268*0947 0,7338 700,00 0,0628 273,6091 0,7405 700&00 0,0587 273.2577 0,7383

-105 - P PRESSUR3-_ 3000. GAGE= 2985.30402 160 00 0O022 1 53o. 3'i2 180.00 0*0236 142 o. 9 3 200.00 i0.0 'O. - ~ i 220.00 0 0 i:..- 0 240*00._ 00272 lills 2 0.00 0.02: l _.30000 0 0311 17.o 6 320.00 0.0324 176.*6so 340*00 006 [ i!o -a' 360*00 0.OOj i 0 O. J * 3o0*00 0*0. 62* * 400.00 0.0. e _ -o.,-; 420G00 0.0Cu- ' 0 3 440*00 0 0 402 206 61 6 1 460.00 0.0414 21 1.oL2 4o0.00 0.0) zo ":lo.o..b, "0OO00 0" 043"..'o 1 L:20.00 0.04DO 0 2 26 540.00 0.O04tf 360.00 0.0474- 236.1 6 80.00 0.0 --. 0: _600.00 0.0C / _, 620.00 0.0:,o- O - - 640 Q.00 0.~0 1 -: * -- 0 660.00 _ O. O JO oo. 1 0 680.00 0.04 700.00 '.o,. 022. TABLE VI (CONT'D) PRE 0ue,0. 160*00 0.3o61 1 0.00 0.:-:_ 200.00 0o 6 0, ' '. 20.00 0._ 0 260.00 0. c? 2 0 00 8 c '. 3O0.00 0.0:-,- 300.00 0. 65o 320.00 0... 340.00 O..... 360.00 0 o.,o 3b0*00 0.cu 400*00 U0 -- 420.00 0u. _ D I 440*00 8.,,,'v 460.00 0*. -:: 5 20.00 v0., - o _ 5 02 *00,031 54000 ~,w i 0- 0 580.00 u *,... _...600.00 O.. /.. 620*00 0 _ 640*00 O / _ _____ 660.*00 06., 0000 0._o,- 700.00 SSURE= 3500. GAGE= 3485.30402 V H S 0 *OO- _, 0 * ' i 0 0.0217 142.2703 0.5838 0. 12.i o 1. 5:0 O0 0 0 0 O' s l L f 0 * _ i. 0 *_. 0.0241 15i.1i-c. 0.s10,0. ' -. so 0.0; / 0.02OO 1 0 0 0 0, o pa 0*0 C2 0 1 - 0 O.s 0.0:..,: c: OOJ...s 0.0,G:'. l-00.0L 00 0.6603 0*0.81.; 1O.lO1 0 o1 _. 0.0 10. 01 0 003601 220.451 8. 6O.-2 0.0392 225.5-725 0.878 0.0402 230.7063 0.6930 0.0412 235.8565 0 o69861 0.0422 241.0226 08.7031 0,0433 246.200G 0*7080 0.044"3 251.38989 07129 0.0453 2 0 6. ) 5 11 i 0.0462 261.8o 30 0.7223 0004-i2 267.0244 0O72Z70 0.0482 272.2540 O. s1i PRESSUE_= 4000. PRFSSURE= 5000 GAGE= 3985.30402 GAGF= 4985.30402 T F..... V H S i-.. V _ H S. 160.00 0.0200 138.1795 0,5743 _ 160*00 0.0186 __138.6783 0.56o- 1 180.00 0.0204 142.2026 0.5807 180.00 0 0190 142*9882 0.5762 200,00 0 0211 146.6017 0._o7 200.00 0*0194 147.0958 0.5826 220.00 0. 0217 150.9627 0.5940.220*00 0 0199 151.4979 _ 0*5891 240.00 0 0223 155.3511 _ 08.6 04 _ 4_ 240* O * 0. 0 203 1 5 155 *7 75 2 0..... 5953 260.00 0 0231 160.0393 0.6070 260*00 0.0208 360.1842 0.6016 280.00 0239 164.6o2> 0.oij _ 280&00 0 0213 164.5998 0.6076 300.00 0.0246 169.3515 0.6196 300.00 0 0217 169.0577 0,6136 320.00,0255 174.0987 0.6257 320.0 0 0.0222 173.5512 0.6194 340.00 0,0264 179.0303 u.6320__ 340.00 0.0228 178. 3211 0.6254 360 00 0 0273 183.9377 0. 63 _. 360.00 0._0234.1^. _10 0... - 380.00 0.0282 188.8939 0.6440 380.00 0.0240 187.7853 0.6 '0 400.00 0.029-j1 1i 0 *o 01o-r, OC 400*00 0.0246 192*6069 00.6.7 420 00 0.0300 198.9235 0.6557 - 420.00 0.0252 197.4611 - 0.64d3 4400 00310 0.0310 203.9851 06614 _ 440.00 0.0259 2024-022 — 0.638 460400 0.0319 209.07-17 0.6670 460.00 0.0266 207.539t1 0.6594 480.00 0.0329 214.18014...6. ___- 480.00 0.0273 212.6027 0O6649 50000.0'0338 219.3077 __0.6779 ___ _ 500.00_ 0.0280 2 17 7084 0.6703' 520.00 0.0347 224.4 -- 0.6832 52 0.0682 S200 0J0287 222.8511 - 06756 54000 00356 - 229.6117 0.6884 54000 0 0295 228.0260 06808 560.00 0.0365 234.7849 0.6935 560.00 0,0302 233.2290 0,686u 580.00 0.0374 239.9704 0.6985 580.00 0,0309 238.4562. _.-6910__ 600.00 0.0384 245.2909 0,7036 600.00 0.0316 243.7042 0.6960 620 00 0.0393 250.5214 0.7085 _ 620*00 0.0324 248.9700 0710 640.00 0.0402 255.7633 0.7133 3640.00 0.0331 254.26508 070P8 _66000_ 00411 261.0i '4- O 10 0 __660.00 0.0338 259.5442 0.7106 680.00 0.0420 266.2765 0.7227 680.00 0.0345 264.8479 0.7153 700.00 0.0429 271.5453 0.7273 _ 70000 0.0352 270.1598 0.7199

APPENDIX B VAPOR PRESSURE -106 -

-107 - TABLE VII COMPARISON OF VAPOR PRESSURE DATA WITH THE VAPOR PRESSURE EQUATION FOR CARBON TETRAFLUORIDE Critical Temperature (obs.) Critical Pressure (calcd ) = 409.50 ~R = 543.16 PSIA Equation: logloP = 20.71545389 - 2467.505285 - 4.69017025 loglT T + 6.4798076 x 10'4T + 0'770707795(424-T)log (424-T) where P is in psia and T in ~R. P P Percent Deviation Temperature (observed) (calculated) Pobs Pcalc Source oR psia psia -- o x 100 Pobs 166.59 169.94 1735.66 179.14 181.55 1835.62 184.14 188.17 188.84 189.79 191.63 1935.45 196.74 197.530 197.55 197.84 199.64 202.18 220.84 2350.02 239.11 0. 0290 0.0425 0.0599 0. 1006 0. 1258 0.1523 0. 1586 0.2243 0.2359 0.2572 0.2952 0.3403 0.4351 0.4544 0. 4622 0.4738 0. 5427 0. 6512 2.1316 35.517 5.569 0.0290 0.0413 0.0602 0. 1014 0. 1262 0.1515 0. 1585 0.2228 0.2354 0.2543 0.2947 0.3399 0, 4366 0.4553 0. 46358 0. 4738 0. 5404 0. 6477 2.1254 35. 5237 5. 5690 0.000 +2.823 -0.501 -0.795 -0.5317 +0.525 +0.063 +0.669 +0.212 +1.127 +0.169 +0. 118 -0.5345 -0.198 -0.346 0.000 +0.424 +0.537 +0.291 -0.191 0.000 30 30 30 30 3o 3o * * 30 30 30 30 * 30 30 30 30 30 30

-108 -TABLE VII (CON ' D) COMPARISON OF VAPOR PRESSURE DATA WITH THE VAPOR PRESSURE EQUATION FOR CARBON TETRAFLUORIDE P P Percent Deviation Temperature (observed) (calculated) Pobs calc Source ~R psia psia obsP x 100 obs 241.07 242.12 245.29 248.62 252.02 255.29 256.03 258.26 258.532 260.24 260.84 261.40 261.77 261.79 262.64 282.22 285.14 287.19 289.33 291.96 302.5533 309.47 316.5533 322.85 327.33 333555.04 339.10 3435.04 344.54 344.57 348.59 348.77 351.86 355.66 358.49 565.65 6.118 6.414 7.421 8.618 10.003 11.492 11.844 13.229 15.002 14.056 14.404 14.723 14.936 14.949 15.448 31.34 34.71 36.91 40.37 42.61 57.66 70.16 835.86 94.05 111.26 127.34 149.24 161.34 165.64 166.44 180.04 179.29 193.22 208.02 217.50 242.22 6.1154 6.4253 7.4380 8.6422 10.010 11.490 11.848 12.979 13.010 14.053 14.5392 14.713 14.929 14.941 15.446 31.227 34.362 36.702 39.271 42.61 57.89 70.549 84.533 99.600 111.03 126.95 145.58 158.70 1635.92 164.02 178.62 179.29 191.17 206.54 218.56 241.78 +0o. 042 -0.176 -0.229 -0.281 -0.070 +0.017 -0.0534 +1.889 -0. 062 +0.021 +0.0 o83 30 30 30 30 30 30 30 30 30 30 +0. o68 +o. o47 +0o.054 +0.013 +0.361 +1. 002 +0. 563 +2.722 0.000 -0.399 -0.554 -0.802 -5.901 30 30 30 30 * * * * * * * 7 +0.207 +0.5306 +2.452 +1.636 +1.038 +1.454 +0.789 0.000 +1.061 +0.711 -0.487 +0o 182 *X * *X*X**X *X 7 * ^* 7 *

-109 - TABLE VII (CONTtD) COMPARISON OF VAPOR PRESSURE DATA WITH THE VAPOR PRESSURE EQUATION FOR CARBON TETRAFLUORIDE P P Percent Deviation Temperature (observed) (calculated) Pobs - Pcalc Source ~R psip psia Pobs x 100 Pobs 363.71 238.08 242.06 -1.672 37 365.69 248.36 251.44 -1.240 37 373.88 292.72 293.14 -0.143 * 373.97 292.45 293.63 -0.403 37 378.83 317.43 320.75 -1.046 37 380.99 330.66 333.40 -0.829 37 383.72 353.22 349.95 +0.926* 387.83 373.28 376.07 -0.747 37 391.61 402.67 401.46 +0.300 37 394.49 418.84 421.74 -0.692 37 398.63 449.70 452.44 -0.609 37 400.63 468.22 467.97 +0.053 37 401.47 476.22 474.63 +0.333 * 403.13 487.22 488.0o6 -0.017* 403.99 494.72 495.16 -0.089* 404.03 490.85 495.49 -0.945 37 405.18 504.22 505.15 -0.184* 405.54 509.72 508.21 +0.296* 406.58 516.72 517.16 -0.085 407.39 524.22 524.22 0.000* 407.45 518.77 524.77 -1.156 37 408.17 531.22 531.15 +0.013 * 409.50 (critical tempera- *1 409.5~0 ture observed) 543.16 409.79 540.81 (critical temperature and pressure observed) * This investigation.

APPENDIX C SATURATED LIQUID DENSITY -110 -

-111 - TABLE VIII COMPARISON OF LIQUID DENSITY DATA WITH THE LIQUID DENSITY EQUATION Equation: d(1 in lb/cu.ft. dc = 39.06 lb/cu.ft. dI = dc + 69.56848907 + 36.17166615 (1 - Tc - 409 50 ~R (1 - T/Tc)1/3 + 4.58661139 (1 - T/TC)2/3 T/Tc) - 8.05898583 (1 - T/TC)4/3 EXPERIMENTAL CALCULATED TEMPERATURE ^^S1^~' MPERCENT DEVIATION TEMPERATUE DENSITY DENSITY Pexp'y-Pfc SOURCE (~R) (lb/cu. ft) (lb/cu. ft) expx 100 Pexp 165.59 118.31 118.38 - 0.057 167.69 122.36 118.02 + 3.547 37 171.29 122.56 117.46.+ 4.005 37 206.44 111.92 111.77 + 0.133 * 253.26 101.70 105.50 - 1.771 38 256.57 102.80 102.88 - 0.076* 258.12 101.07 102.58 - 1.499 38 287.69 96.67 96.70 - o.o054 * 314.14 90.89 90.87 + 0.027 * 358.19 78.99 79.05 - 0.073 * 375.64 73.02 72.94 + 0.124* 394.46 63.92 63.92 - 0.002* 405.35 54.65 54.68 - 0.052 407.74 50.57 50o.64 - 0.142 408.16 49.58 49.60 - o0o48 * 408.58 48.59 483355 + 0.126 * 408.96 46.84 46.79 + 0.106 * * This investigation.

APPENDIX D HEAT CAPACITY OF VAPOR AT ZERO PRESSURE -112 -

-113 - TABLE IX HEAT CAPACITIES AT ZERO PRESSURE (Cv) BY STATISTICAL METHODS FOR CF4 [IN BTU/ (LB) (~F)] Temperature ~R 180 360 540 720 900 1080 1170 Translational 0.033846 0.033846 0.033846 0.033846 0.033846 0.033846 0.033846 Rotational 0.033846 0.033846 0.033846 0. 033846 0.033846 0.033846 0.033846 Vibrational 0.004064 0.042322 0.076358 0.106492 0.129010 0.145442 0.11902 Anharmonic 0.000009 0.000278 0.000709 0.001120 0.001500 0.001862 0.002037 Total 0.071765 0.110292 0.144759 0.175304 0.198202 0.214996 0.221631 TABLE X COMPARISON OF HEAT CAPACITIES AT ZERO PRESSURE WITH THE HEAT CAPACITY EQUATION Equation: Cv = 3.00559282 x 10-2 + 2.37043352 x 10-4T - 2.8,660077 x 10-8T2 - 2.95338806 x 10-11T3 where Cv is in Btu/(lb)(~F) and T in ~R Percent T(~R) C* (Stat.) Cv (Equation) DeviationT 180 0.071765 0.071626 + 0.199 360 0.110292 0.110311 - 0.017 o40 0.144759 0.14p079 - 0.221 720 0.17,304 0.174895 + 0.233 900 0.198202 0.198726 - 0.264 1080 0.214996 0.21>539 - 0.252 1170 0.221631 0.220991 + 0.289 Dvitin C*(Stat.) - C*(Equation) Percent Deviation = -(a -Cv C*(Stat.) v x 100

APPENDIX E EVALUATION OF THERMODYNAMIC PROPERTIES AT THE REFERENCE CONDITIONS -114 -

-115 - 'ABLE XI ENTROPY DETERMINATION BY THERMAL METHODS AT THE REFERENCE TEMPERATURE Datum plane S = 0 at O~K Reference temperature = 100~K Temperature AS Method of Range cal/(g.mole)(~K) Evaluation 0 - 12~K 0.689 12 ~K f Cp 0~K p dT - evaluated from Debye and Planck-Einstein extrapolation. 12 - 76.2 ~K 15.261 I.2- ~K dT J Cp - evaluated graphically 12 ~K from the data of Eucken and Schroder. (13) Transition at 76.23 ~K 76.23 - 89A.17~K 4.640 2.590 Data of Eucken and Schroder. 89 47 dT Cp - Tev! lua.ted graphically 76.23 T from the data of Eucken and Schroder, Fusion at 89.47~K 89.47 - 100 ~K 1,8 o 2.218 Data of (E k'.ken and Scrroder. 100 ~K, r evaluated f-rom the liciuid hes"r capacity equation of Selby mand Aston, ( Entropy of saturated liquid at 100~K 27.268 [0.3o962 Btu,/() ( ~R ] --- -- -- --- ------- RP-4~ —~~- ---~YLiLPrm: -- VV*~LPIUU(~r-r.~~~U-~~n-OL

-116 - TABLE XII ENTHALPY DETERMINATION BY THERMAL METHODS AT THE REFERENCE TEMPERATURE -- c -- -- Datum plane H = 0 at 0~K Reference temperature~ 100 ~K Temperature AH Range cal/g.mole Method of evaluation 0 - 12~K 6.262 12 ~K J Cp dT evaluated from Debye and 0 ~K Planck-Einstein extrapolation. 12 - 76.23~K 667.10 76.23~K J Cp dT evaluated graphically 12 ~K from the data of Eucken and Schroder. (13) Transition at 76,230K 76.23 - 89,47~K 353.707 215.580 Data of Eucken and Schroder. 89.47 J C dT evaluated graphically 76.23 p from the data of Eucken and Schroder. Fusion at 89.47 ~K 89.47 - 100~K 167.309 193.323 Data of Eucken and Schroder. 100 K I f Cp dT evaluated from the 89.47~K liquid heat capacity equation of Selby and Aston. (40) Enthalpy of Saturated liquid at 100~K 1603.281 (32.76883 Btu/lb)

-117 - TABLE XIII ENTROPY OF IDEAL GAS AT 300 OK AND 1 ATM BY STATISTICAL METHODS Component S [cal/(mole) (~K) ] Tranalational 39.3846 Rotational 19.9584 Vibrational 3.1618 Anharmonic 0.0231 Total 62.5279 This value compares well with the value of 62.9321 obtained by thermal methods. (See page 171.) This presents a further check on the consistency of the heat capacity equation, obtained from the correlation of heat capacity values by statistical methods.

APPENDIX F CALIBRATION OF THE PLATINUM RESISTANCE THERMOMETERS -118 -

Calibration of the Pla.tinlnm Resistance Thermometers DTo platinu'm thermometers were used to measure the temperatures in this investigation. The older platinim thermometer No. 169~313, made by Leeds and Northrup Company -was used for the vapor pressure and critical temperature measurement-s. The thermometer was recalibrated at the melting point of ice and the boiling point of water by means of a standard platinum resistance thermometer in the Sohma Precision Laboratory. The modified Callendar formula, Rt - 2.4980 o t l ) + / t(C) ' 100t 2490 + 1.501 ( -( 0.9680 100 100 + 0.1089(1(1( was used to evaluate the temperatures above 0~C, corresponding to any resistance, measured cby means of Mueller Bridge No. 203295, also made by Leeds and N\ortnhrap Companyo The third term was zero for temperatures above 00~C All other temperat-ure measurements were obtained with the new platinum resistance thermometer, No. 1504255 using the new Mueller Bridge No. 1327006, both made by Leeds and Northrup Company. This rhermometer has been calibrated b- the National Bureau of Standards on January 21, 1959. The following values have been reported by them in the Callendar formula~ t(~c) R t ~ Ro t + t l)(t )3 (78) a Ro 100 100 100 100

-120 -where a 0.003926395 6 - 1.49159 = 0.11020 (t below 0 ~C) = 0 (t above 0~C) and R - 25.543 abs. ohms. They supplied a complete table of values in the temperature range of interest for quick interpolation.

APPENDIX GJ PROGRAMS FOR CALCULATING THE THERMODYNAMiC PROPERTIES ON IBM '704 -121 -

-122 -Nomenclature for the Variables on the Machine Machine Variable DC PC TC R XI X2 X3 x4 Yl Y2 Y3 Y4 Z1 Z2 z3 z4 A,B,C,D,E,F Equivalent de Pc Tc R a1 a2 aa4 Variables specified for individual programs 7 6 AB,C,D,E,F A2,B2,C2,A3,B3,C3 A4,A5,B5,C5 SB SK EPSI ZERO EXP A2,B2,C2,A3,B3,C3 A4,A5,B5, C5 b k C CONTROL WORD 2.302585093

-123 - PROGRAM 1 Determination of Constants of the Vapor Pressure Equation and C:orrelation of Vapor Pressure Data This program evaluates the constants A., B, D, E F of the vapor pressure equation (Eqtuation 21) by the method of five point fit and evaluates tne values of percent deviation for the given set of data pointso 'The values of five temperatures and pressures T1, P1, T2 P2 T, T4 P5, T^' P5, TF and EXP are fed into the macbine in FORMAT (2E 3608),, followed by the given set of T1, and P data, in FORMAT (2F 36.8). The machine prints out+ the cornstants and tabulates the values of temperature, experimental pressure, calculated pressure and percent deviation defined by exp

-124 - NALLAN C S CHARI C12-N 004 002 2 V P CONS *COMPILEFORTRAN EXECUTE DIMENSION X(50),B(lO),E(50) _____ __ 2 READINPUT TAPE 7,3T1,P1,T2,P2,T3,P3.T4.P4,T5,P5,F.EXP 3 FORMAT(2E36.8) ~XLI-________-LrLQX(2)=1.O X(3)=l.O X(4)=l.O X( 5 ).= 1.lO0 X(6)=1.0/T1 X(7)=lO _1. T2_ X(8)=1.0/T3 X(9)=1.0/T4 X(10)=1*0/T5 X(11)=LOGF(T1)/EXP X(12)=LOGF(T2)/EXP X(l13)LOGF(T3)/EXP X(14)=LOGF(T4)/EXP X(15)=LOGF(T5)/EXP X(16)=T1 X(17)=T2 X(18)=T3 X(19)=T4 X(20)=T5 X(21)=((F-T1)/T1)*(LOGF(F-T1)/EXP) X(22)=((F-T2)/T2)*(LOGF(F-T2)/EXP) X(23)=((F-T3)/T3)*(LOGF(F-T3)/EXP)___ X(24)=((F-T4)/T4)*(LOGF(F-T4)/EXP) X(25)=((F-T5)/T5)*(LOGF(F-T5)/EXP) B(1)=LOGF(P1)/EXP B(2)=LOGF(P2)/EXP B(3)=LOGF(P3)/EXP B(4)=LOGF(P4)/EXP B(5)=LOGF(P5)/EXP 5 D=1.0 6 M=XSIMEQF(5S,51,XB,DE) 7 GO TO (8,2,2),M 8 WRITE OUTPUT TAPE 6,9,X(1),X(2),X(3),X(4),X(5) 9 FORMAT(99H1 THE FOLLOWING ARE THE CONSTANTS FOR TH XE VAPOR PRESSURE EQUATION FOR FREONC318/14HO A=F14.8 X /14HO B=F14.8/14HO C=F14.8/14HO D=E X14.8)/14HO E=E14.8) AX( 1) B=X(2) C=X(3) D=X(4) E =X(5)11 WRITE OUTPUT TAPE 6,12 12 FORMAT(106H1COMPARISON OF THE CALCULATED VAPOR PRESSURES WITH EXPE XRIMENTAL DATA FROM DIFFERENT SOURCES FOR FREON C318/74HOTEMPERATUR XE EXP PRESSURE CALC PRESSURE PERCENT DEVIATION SOURCE) 24 READ INPUT TAPE 7,25,TPEXP 25 FORMAT(2F36.8) 26 OGPzA+(B/T)+(C*LOGF(T)/2e302585093)+(D*T)+(E*((F-T)/T)*(LOGF(F-T)/ x 2,3o2585093)) 27 P=EXPF(2.302585093*OGP) 28 DEV=100.*(PEXP-P)/PEXP___ 13 WRITE OUTPUT TAPE 6,14,T,PEXPtPDEV 14 FORMATfF9.2,F15.4.Fl5.4,F16.3) 29 GO TO 24 *DATA

-12 F - PROGRAM 2 Determination of Constants of the Liquid Density cEquation by the Method of Least Squares and Correlation of Liquid Density Data The program evaluates the constants a1, a2, a- and a4 of the liquid density equation (Ecquation 22) by the method of least squares. The data Tc and dc are fed into the machine in FORMLAT (2F 36.8) followed by two sets of the given T, d" data in the same format, both separated by a blank card. The first set of data, are used in computing the constants by the method of least squares and the second set for correlation of data. The machine prints out the constants and tabulates the values of T, dQ (experimental), d" (calculated) and percent deviation defined by e -— ^alca x 100 di. expo

-126 - NALLAN C S CHARI C12-N * COMPILE FORTRAN,EXECUTE.DIMENSION X(50),B(10),E(50)............ 2 READ INPUT TAPE 7,3,TCDC 3 FORMAT (2F36.8) 4 X(1)=O.0 X(2)=0.0 X(3)=0.0.____..X4L=0 O..._____________ X(5)=0.0 X(6)=0.0 X(7)=0.0 X(8)=0.0 X(9)=0.0 X (10 0QJ - X( 11)=0,0 -.X......X12)=0Q0 X(13)=0.0 X(14)=0.0 X(15)=0o0 009 008 2 LIQ DENS B(1)=0.0....... B(2)=0.0 B(3)=0.0 B(4)=0.0.. _ __ ___ 5 READ INPUT TAPE 793,T,DL IF (T-0.0)53_6 ______6 U3=1.0-(T/TC) U1=U3**(1.0/3.0) U2=U3**(2.0/3.0) U4=U3**(4.0/3.0) U5=U3**(5.0/3.0) U7=U3**(7.0/3.0) U8=U3**(8.0/3.0) BETA=(DL-DC) X(1)=X(1)+U2 X(2)=X(2)+U3 X ( 3 ) =X ( 3t U.).J4____ X(4)=X(4)+U5 X(5)=X(5)+U3 __ X(6)=X(6)+U4.X(7)=X(7)+U5 _ _ X(8)=X(8)+U6 __________ __ X(9)=XI9)-+U 4_______________________________ X(10)=X(10)+U5 X(11)=X(11)+U6 __ ______ X(12)=X(12)+U7... X(13)=X(13)+U5 X(14)=X(14)+U6 X ( 15Xt154 +U7 X(16)=X(16)+U8 --...... B(1)=B(1)+(BETA*U1) _______ B(2)=B(2)+(BETA*U2) _...... B(3)=B(3)+(BETA*U3) ___ ________ B(4)=B(4)+(BETA*U4).....___.O..... —.GOJO _ 5__-.____ ______________ 8 D=1.0 9 M=XSIMEQF(4,491,XBDE).._ ___. _..._ __ 10 GO TO (11,2,2),M ___. _ 11 WIT. OQUT.PUT _-TAPE~ 625.XitX2L,2) X(3). X(4) 25 FORMAT(99H1 THE FOLLOWING ARE THE CONSTANTS FOR TH....... - XE LIQUID DENSITY EQUATION FOR FRE0QN -_1i14H0_ A_A-_F 8 ___ X /14H0 B=F14.8/14HO C=F14.8/14HO D=F.....___ X14.8) 26 WRITE OUTPUT TAPE 6,27 2_7-_EORMAI1116HQ____ TEMPERATURE 5XPL D5N2ITY X CALC DENSITY PERCENT DEVIATION)..___._ 28 READ INPUT TAPE 7,3,T,DEXP _. IF(T-0.0 )282,29 29 U3=1.0-T/TC U1=U3**0. 33333333 U2__-U_3**_O0 666666 ___ U4=U3**1 3333333._......... _DLCALC=DC+X(1)*U1+X(2)*U2+X(3)*U3+X(4)*U4 DEV=((DEXP-DLCALC)/ DEXP)*100.G 30 WRITE_OUTPUT TAPE6,31,TDEXPDLCALCDEV 31 FORMAT(F25.5,F27.8,F27.8,F32.9) GO T028_ _

-127 - PROGRAM 5 Determination of Liquid Heat Capacity from the Heat Capgacity of Gas The program calculates the heat capacity of liquid from the given heat capacity equation at zero pressure (Cv) in the form of Equation (32) The machine solves the saturated gas volume for a given temperature by Newton's iteration method and solves Equations (50) through (58). The constants of the liquid heat capacity equation are fed in Yl, Y2, Y3. and Y4 locations. It gives out a table of values of dP, d2 P dYl dP dP temperature, pressure, "vg, v., (- sa) ) (-s) (at d' - s s' dT' dsat' dT dV T vCv 0V' {calc.,) C texp) and percent deviation defined by xp) 7 —c(~a~lc x 100 (exp

-128 - NALLAN C S CHARI C12-N 009 008 2 SP HEAT *COMPILEFORTRANEXECUTE.....-READI.NPUT TAPE7,3..DC"P-C-I -tRX, - X2,X3,X4,YY2 Y 3LYZZ1 ZZ-Z3,.... XA,B,C,D,E,F,A2,B2,C2,A3,B3,C3,A4,A5,B5,C5,SB,SKEPSI,ZERO 3 FORMAT(3E24.8).. 4 READ INPUT TAPE 7,5,TVAPP 5 FORMAT(2F36.8) 6 CVSTR=Z1+Z2*T+Z3*T*T+Z4*T*T*T 7____1 -1 -_ _ -_____ U1=U3**(1.0/3*0) _.___ U2=U3**(2.0/3,0) _ _ 8 U4=U3**(4.0/3,0) 9 VL=1.0/(DC+(X1*U1)+(X2*U2)+1X3*U3)+(X4*U4)1 11 OGP=A+(B/T)+(C*LOGF(T)/2.302585093)+(D*T)+(E*((F-T)/T)*(LOGF(F-T)/ X2.302585093)) P=EXPF(2.302585093*OGP) _ 12 VMB1=VAPP-SB_ _ 14 EXP=EXPF(-SK*T/TC) 13 VM=VMB=VMB**2.0 VMB3=VMB1**3.0 VMB4=VMB1**4,0 ____ _ _ _ VMB5=VMB1**5.0 VMB6=VMB1**60 15 FU1=R*T FU2=A2+B2*T+C2*EXP FU4=A4 FU5=A5+B5*T+C5*EXP FX=(FU1/VMB1)+(FU2/VMB2)+~(FU3/VMB3)+(FU4/_VMB4J-+(FU5/VMB5)-P FPRMX=-((FU1/VMB2)+(2.0*FU2/VMB3)+(3.0*FU3/VMB4)+(4.0*FJ4/VMB5)+ X(5.0.*FU5/VMB6)) ).....____. 16 Q=FX/FPRMX 17 IF (ABSF(Q)-EPSI) 20,20,18 18 VMB1=VMBl-Q 19 GO TO 14 ___ _____ _ _ 20 VG=VMB1+SB __._ 22 BNU=2.302585093*B _ _ _ DNU=2.302585093*D PAN1=-BNU/(TT*_) PAN2=(C/T)+DNU-(E/T)..___...._.... PAN3=-E*F*LOGF(F-T)/(T*T) _ ______.... DPDTS=P*(PAN1+PAN2+PAN3) 23 Ql=(SK*SK/(TC*TC))*EXP...._ 24 VMB1=VG-SB 25 VMB2=3VMB1*VMB1 26 VMB3=VMB2*VMB1.__._._ _ 27 VMB4=VMB3*VMB1 _....... 28 VMB5=VMB4*VMB1 ____ -_2__Z9_..VMB66=VMB5*VMB1 _ __ 31 SP1=C2*Q1/VMB1 SP2=C3*Q1/(2,n*VMR2) SP3=C5*Q1/(4.0O*VMB4) ____- ___v~CVSTR-(0.185053*.T*4SPl+SP2_+SP3._.. PART1=2.0*BNU/T ____ ____ PART2=E-C.. —_.._.........__.-......-.......... PART3=2.0*E*F*LOGF(F-T)/T _ P-ART4=-t*F/( F-T)___ PART5=P/(T*T) D2_______2PDTS=PART5*1PAR-lI+PARTi2+PARTI3PART4 +(DPDTS*DPDTS/P) _..._ _ DPDVT=-( It-U1/VMB2)+(2.0*FU2/VMB3)+(3.0*FU3/VMB4)+(4.0*FU4/VMB5)+ __ X(5.0*F1l5/VMR6) )_ __ CH=(-SK/TC)*EXP _____ _- F2PRM=B2+C2*CH _._. _ ___ _. _ _. __ _. __ _ _ _ F3PRM=B3+C3*CH _ _ ______. F5PRM=B5+C5*CH __.__ — _. --.. 40 DPDTV='R/VNBi)+(F2PRM/VMB2)+(F3PRM/VMB3)+(F5PRM/VMB5) 41 DVLDTS=(VL*VL)*(1.0/(3.0*TC))*((Xl/U2)+(2.0*X2/U1)+(3.o*X3)+(4.0*X X4*U1)) — SEC1=T*(LtG-VL1*D2PDSTS __-__....__ _.. SEC2=T*DPDTS*DVLDTS ______ _ _ __ _SEC3=T*(DPDTS-DPDTV) *DPDLS-ODPDTV)/DPDVI__ _ __ _ ______ 42 CLCALC=CV-(.185053*(SEC1-SEC2+SEC3)) 43 CLEXP=Y1+Y2*T+Y3*T*T+Y4*T*T*T 44 DEV=((CLEXP-CLCALC)/CLEXP)*100.0 _______ _45.RI.TE OUTPUT TAPE 6.,46 TIP,~VGVLDPDTS-D_2-PDLTSDYLDTS,_DPDTVDPDVT,._... XCVSTR,CV,CLCALC,CLEXP,DEV — __ ____ 46 FORMAT112H1 TEMP=E16.812ZHQ PRES=E~1.8/12H0 ____ VG=E1 X6.8/12HO VL=E16.8/12HO (DP/DT)S=E16.8/12HO(D2P/DT2)S=E16.8 X/12HO (DVL/DT)S=E16.8/12H0 (DP/DT)V=E16.8/12HO (DP/DV)T=E16.8/12 XHO CV*=E16.8/12HO CV=E16.8/12HO CL(CAL)=E16.8/12HO _ _ _ _ X CL(EXP)=E16.8/12HOPERCNT DEV=E16.8) __ 47 GO TO 4

-129 - PROGRAM 4 Determination of Href, Sref, X and Y The program calculates the values of Href, Sref, X and Y from Equations (43), (53), (69) and (76) and from the relation that the entropy of vaporization is equivalent to AHV/T. The following are the locations of the variables fed into the machine. Yl Tref Y2 Enthalpy of liquid at Tref Y3 Entropy of liquid at Tref

-130 - NALLAN C S CHAR I C12-N 004 004 2 THRMPROP *COMPILE FORTRAN EXECUTE * PUNCH ORJECT 2 READINPUT TAPE793,DCPCTCRXlt1X2,X39X4Y1Y2VY3,Y4.Zl1Z2,Z3.Z4. ____ _ XA BrCDEgFA2 *B2 C2,A3 B3~C3. A4~A5*B5;C5.*SB.SKEPSI ZERO 3 FORMAT(3E24.8) EXP=EXPF(-SK*T/TC) OGP=A+(B/T)+(C*LOGF(T)/2 302585093)+(D*T)+(E*((F-T)/T)* ( LOGF(F-T) / X2*302585093)) P______ PEXPF ( 2 302585093*0GP) VMB1=(R*T/P) __6 VMB=VMB1**2.0 VMB3=VMB1**3.0 VMB4=VMB1**4.0 VMB5=VMB1**5. VMB6=VMBR1**60 FX= ( FU1/VMB1)+(FU2/VMB2)+ (FU3/VMB3 ) +(FU4/VMB4)+(FU5/VMB5)-P FPRMX=-((FU/VMB2)+(2.0*FU2/VMB3)+(3OFU3/VMB4)+(4.OFU4/VMBS)+ __ X(5.0*FU5/VMB6)) Q=FX/FPRMX IF (ABSF(Q)-EPSI) 898,7 7 VMB1= VMB 1-Q ____ GO TO 6 ___V G:VM.-1+SB_____ DG1.0/VG VMB2=VMB1**2 *.0 VMB3=VMB1**3.0 VMB4=VMB 1*4. 0 VMB5=VMB1**50O U3=1.0-(T/TC) U1=U3**(1.0/3*0) U2=U3**( 20/3.0) U4=U3**(4.0/30 ) DL=DC+X 1*Ul+X2*U2+X3*U3+X4*U4 ____ VL=1.0/DL BNU=2 302585093*B DNU2. 302585093*D PAN 1=-BNU/( T*T ) PAN2=(C/T)+DNU-(E/T) PAN3=-E*F+LO GF(F-T) / ( T*T) DPDTS=P*(PAN1+PAN2+PAN3) Q1l1 0+(SK*T/TC) Q2=SK*EXP/TC FN1=A2+ (C2*EXP*Q1 ) FN2A3+( C3*EXP*Q1) FN3=A5+(C5*EXP*Q1 ) TP2=T*T TP3=TP2*T __ _ TP4=TP3*T PTNI=(71*T)+(O.5*72*TP2)+(Z3*TP3/3.0)+(0.25*7Z4*TP4) PIN2=(P*VG)+(FN1/VMB1)+(FN2/(2.0*VMB2))+(A4/(3.0*VMB3) +(FN3/(4.0* XVMB4)) ) __ QIN1=Zl*LOGF(T)+Z2*T+(Z3*TP2/2.0)+(Z4*TP3/3.0) OIN7=R*IOGF(VMBl)-(B2/VMB1)-(B3/(2,0*VM82))-(B5/(4.0*VMB4)) _ QIN3=(C2/VMB1)+(C3/(2.0*VMB2))+(C5/(4.0*VMB4)) HRFF=Y2+ T*( VG-VL * DPDTS*0 185053 ) SREF=Y3+((VG-VL)*DPDTS*0.185053) X =HR EF-P IN 1 —(l 8 505__P I N_ ) Y=SREF-QIN1-0. 185053* ( QIN2+Q2*QIN3) WRTTF QlijTPUT TAPF 63,,3T.HRFFaX WRITE OUTPUT TAPE 6,3,TSREF,Y

-131 - PROGRAM 5 Saturation Temperature Table The program calculates the values of vapor pressure, gage, specific volume of liquid, specific volume of gas, density of liquid, density of gas, enthalpy of liquid, latent heat of vaporization, enthalpy of gas, entropy of liquid and entropy of gas for a given temperature and tabulates them as shown in Table IV. The values of X and Y from Program 4 are fed into locations Yl and Y2. The temperatures and approximate values of volumes are fed in FORMAT (2F 36.8). The volumes of gas are computed by simultaneous solution of the vapor pressure equation (Equation 21) and P-V-T equation (Equation 35) by the Newton's iteration method with a tolerance of E.

-132 - NLtAN-A C &S~ C- 1 —2- -C12N — 0 ----004 ---2 — THRMPROP — *COMPILE FORTRANEXECUTE * PUNCH OR.JFCT 2 READINPUT TAPE7,3,DC,PC,TCRX1,X2,X3,X4,Y1,Y2,Y3,Y4,Zl,Z2,Z3,Z4, __XA,B,_ DEC. F A2 B2 C2 A3 B3,C3.A4^A5,B5,C5TSBSKEP$IZERO __ ___ 3 FORMAT(3E24.8) X=Y1 --- —-- Y=Y2 DELTA=Y3 WRITE OUTPUT TAPE 6,20 __ __ 20 FORMATf 1l9Hl TEMP P PR E S S U R_- LIQUID GAS LLQUID ____ X GAS LIQUID LATENT GAS LIQUID GAS / ___O_ -__ —XHODEG F PSIA G A G E SP VOL SP VOL DENSITY EDE__ XNSITY ENTHALPY HEAT ENTHALPY ENTROPY ENTROPY/4HO ) 4 READ INPUT TAPE7,5,T9VAPP 5 FORMAT(2F36.8)!___ 100 IElI- TC) 113 l011__! ( 103 ____ 101 P=PC _ YMB1I.OCzM.I-S.__O __ _______ __ VL= 1.0/DC GO TO 8 103 U3=1.0-(T/TC) ________ = Ul=3**{ 1.~0/3. 01 __ _ _ __.. _ _. U2=U3**( 2.0/3.0) ___ U4=U3**( 4_0/3.0) __ ____ _ _ __ DL=DC+X1*U1+X2*U2+X3*U3+X4*U4 VL=.0/DL 31 IF (T-210.69) 32.32933 ____ _ 3Z2 EPSI=0001 __ _ ___ __ _.__ 33 EXP=EXPF(-SK*T/TC) ___ _ O QGP=A+(B/T +LC*LPGF(T)/2.302585093)+(D*T) +(E*((F-T)/T)*(LOGF(F-T)/ X2.302585093)) P=EXPF (2.302585093*OGP) FU1=R*T __ ___ _ _FU2=A2+B2*T+C2*EXP _____ __ _ FU3=A3+B3*T+C3*EXP ________ _ _FU4=A4 __ _ _ _ __ ___ ___ FU5=A5+B5*T+C5*EXP VMB1=VAPP-SB 6 VMB2=VMB1**2.0 MVB3=VMB 1_ ~ 0__ __ VMB4=VMB1**4.0 _____ _ _ __ _ _ LVMB5-=VMB1*5,0 ___ __ _0 _ _ VMB6=VMB1**6.0 FX (FUl/VMB1 ) +(FU2/VMB2 ) + ( FU3/VMB3) + (FU4/VMB4)+ ( FU5/VMB5)-P FPRMX=-((FU1/VMB2)+(2.0*FU2/VMB3)+(3.0*FU3/VMB4)+(4.0*FU4/VMB5)+ __ _ ________ X(5.O*FU5/VMB6) )_ ___ Q=FX/FPRMX IF (ABSF(Q)-EPSI) 8,87__ 7 VMB1=VMBl-Q GO TO 6 8 VG=VMBl+SB DG-l^0/VG VMB2=VMB1**2.0 VMB3=VMB1**3.0 VMB4=VMB1**4.0 VMB5=VMB1**5 0 VMB6=VMBi**6 0 BNU=2. 302585093*B

-133 - DNU=2. 302585093*D PAN1=-BNU/(T*T) PAN2= (C/T)+DNU-(E/T).___ _.PA.N3= T —E*F *,.LGJFrJ ( F-I ___) ___( T * T ) _____ DPDTS=P* (PAN1+PAN2+PAN3) -__ _-_ -i.Qli-i.LQ.+ ______ ( _S __*_I_ T C )__ ____ _ Q2=SK*EXP/TC FN1=A2+(C2*EXP*Q1) FN2=A3+ (C3*EXP*Q1) __.__ _ N3-A5- C5 *EXP*Q 1 ) ___ ____ TP2=T*T _ _ __T TP3-PLP2*I _ __ __ __, TP4=TP3*T PIN1=(Zl*T)+(0.5*Z2*TP2 )+(Z3*TP3/3.0)+(0.25*Z4*TP4) PIN2=(P*VG)+(FN1/VMB1)+(FN2/(2.0*VMB2))+(A4/(3.0*VMB3))+(FN3/(4.0* ____ XVMB4_ QIN1=Zl*LOGF(T)+Z2*T+(Z3*TP2/2.0)+(Z4*TP3/3.0) __ __ _Q I N2R*LOGFVMB 1 )-(B2/VMB1) -B 3/ ( 2. O*VMB2 )1-(85/( 4O*VMB4 ) ) QIN3=(C2/VMB1)+(C3/(2.0*VMB2))+(C5/(4.0*VMB4)) 10 HG=X+PIN1+(PIN2*0.185053) SG=Y+QI N+0. 185053* ( QIN2+2*QIN3) HEAT=T*(VG-VL)*DPDTS*O. 185053 ____ HL=HG-HEAT SL=SG-(HEAT/T) TF=T-459.69 IF (P-115.O) 11,11,15 11 IF (P-14.7) 12,12,16 12 IF (P-10.0)13,13917 13 IF (P-10.)14,14,18 14 IF (P-0.20) 19,15,19_ _ 15 PG=P-14.696 WRITE OUTPUT TAPE 6,21,TF,PPGVLVGDLDGHLHEATHGSLSG 21 FORMAT(F6.O,F9.2.F10.2,F11.6,F1O.5,F11.3,F 9.49F12.4,F11.3,F12*4,F __ _X9.4,F10.4)_______ __ ___________________ GO TO 4 __ 16 PG P-14.696 __ __ WRITE OUTPUT TAPE 6922,TF,P,PG,VLVGDLDGHLHEATHGSLoSG 22 FORMAT(F6.0,F9.3~F10.3,F11.6,F1O.5,F11.3,F 9*.4F12.4,F11.3,F12.4,F X9.4,F10.4) __- — Gn TOL -4____ ____ _ 17 PG=29.92-(P*2.036) ____ __ WRITE OUTPUT TAPE 6,23,TFtP PGVL VGDL,DG,HL,HEATHGSLSG 23 FORMAT ( F6.OF9.3,FlO.3,F11.6,F10.5 F11. 3,F1O.5F11.4,F11.3,F12.4,F X9.4,F10.4) GO TO 4 _ 18 PG=29.92-(P*2.036) WRITE OUTPUT TAPE 6,24,TFP,PG,VLVGDL,DGHLHEAT,,HG,.LSG 24 FORMAT(F6.OF9.4,F0I.4,Fll6,F105tF11.3,F105,F11.4,F1I.3,F12.4,F X9.4,F10.4) GO TO 4 19 PG=29.92-(P*2.036) WRITE OUTPUT TAPE 6,25,TFP*PGVLVGDLDGtHLHEATHGSLSG 25 FORMAT(F6.o0F1lo.5Flo.5,FlO.6tFlo.5,F1ll.3F1l16tFlIo.4,Fll3Fl12.4, XF9.4,F1O04) GO TO 4

PROGRAM 6 Saturation Pressure Table The program calculates the values of gage pressure, saturation temperature, specific volume of liquid, specific volume of gas, density of liquid, density of gas, enthalpy of liquid, latent heat of vaporization, enthalpy of gas, entropy of liquid and entropy of gas for a given pressure as shown in Table V. The saturation temperature is obtained by the Newton's iteration method with a tolerance e. The specific volume of gas is obtained in a similar manner to that of the saturation temperature table. However, the scanning time on the machine is considerably reduced by feeding in the values of z as functions of Tr and Pr, The values of S1 to S21 represent the values of z fed in this manner. At the completion of each set of z values for the given set of pressures, a blank (control card) is introduced followed by the next set of z values. The machine thus interpolates the value of z and for the first assumption uses a value of V = zRT/P instead of RT/P, thereby reducing the machine scanning time by nearly half.

-135 - NALLAN C S CHARI C12-N 008 006 2_ SAT PRES *COMPILEFORTRANEXECUTEPUNCH OBJECT 2 READINPUT TAPE7.t3DOCPCTC.RX1lX2,X3.X4Y1lY2,Y3,Y4,Z1Z2.Z3,Z4~ XA,B,C,D,E,F,A2,B2,C2,A3,B3,C3,A4,A5,B5,C5,SB,SK,EPSI,ZERO F____ORMA T( 3E2418__ __.____ -___________________ X=Y1 DELTA=Y3 WRITE OUTPUT TAPE 6920 20 FORMAT(119H1 P R E S S U R E TEMP LIQUID GAS LIQUI _ XD _ GAS __ LIQUID__.LATENT GAS LGAS / X120HO PSIA G A G E DEG F SP VOL SP VOL DENSITY XDENSITY ENTHALPY HEAT ENTHALPY ENTROPY ENTROPY/4HO ) 4 READ INPUT TAPE 7,5,P,TAPPVFIN 5 FORMAT(3F24.8) 100 IF(P-PC)32,101,32 101 T=TC __ VMB1=( 1.0/DC)-SB VL.0/DC______ GO TO 40 32 IF(P-0.0)4933.34 33 READ INPUT TAPE 7,5S1 S2,S3,S4,S5,S6,57,S8tS9.S10S11512,S13,S14 XS15,5S16,S179S18,S19,S20,S21 _________ GO TO 4 34 T=TAPP _ 6 FOPzA+(B/T)+(C*LOGF(T)/2.302585093)+(D*T)+(E*((F-T)/T)*(LOGF(F-T)/ X2.302585093))-(LOGF(P)/2.302585093) BNU=2.302585093*B DNU=2.302585093*D ___ PAN1=-BNU/(T*T) PAN2=(C/T)+DNU-(E/T)_ PAN3=-E*F*LOGF(F-T)/(T*T) FPRMP=PAN1+PAN2+PAN3 G"FOP/FPRMP IF(ABSF(G)-EPSI )8,897 7 T=T-G GO TO 6 8 TF=T-459.69 U3= 1 3 0-( T/TC ) U1=U3**( 1.0/3.0) U)2=t13** f 2 0/3 0) U4=U3**(4.0/30 ) DL=DC+X l*U1+X2*U2+X3*U3+X4*U4 _VL=l.O/DL 30 TR=T/TC 41 IF(TR-2.08)42,42,71 42 IF(TR-2.00) 43943972 43 IF(TR-1.92)44,44,73 44 IF(TR-1l80)45^45974 45 IF(TR-1.68)46946,75 46 IF(TR-1.56) 47,47,76 47 IF(TR-1.44)48,48,77 48 IF (TR-1 3?)49.49,78 49 IF (TR-1.28)50,50979 50 IF(TR-l124)51,51,80 51 IF (TR-1.20)52,52,81..__ IF(TRD-l-6 _t_3*~_*R?,2 53 IF(TR-1l12)54,54,83 54 TffTR-1^n)55*i5 *.ftR4

-136 - 55 IF(TR-1.04)56,56,85 56 IF(TR-1.OOQ)57*5786 57 IF(TR-0.96)58958987 58 IF (TR-0.92)59,59,88 59 IF(TR-0.88)60960989 60 IF(TR-0.84)70.70,90 70 IF(TR-0O80)71,71991 71 7=S1 GO TO 93 72 Z=S2 2 GO TO 93 73 Z=S3 GO TO 93 74 Z=S4 GO TO 93 75 Z=S5 GO TO 93 76 Z=S6_ GO TO 93 77 Z=S7 GO TO 93 78 Z=S8___ GO TO 93 79 Z=S9 _ GO TO 93 80 Z=510 GO TO 93 81 Z=Sll GO TO 93 82 i8 2 =S 12 GO TO 93 83 Z=513 GO TO 93 84 Z=S14 GO TO 93 85 Z=S15 GO TO 93 86 Z=516 GO TO 93 87 Z=S17___ GO TO 93 88 Z=S18 GO TO 93 89 Z=S19 GO TO 93 90 Z=S20 GO TO 93 91 Z=S21 GO TO 93 93 EXP=EXPF(-SK*T/TC) FU1=R*T FU2=A2 +B2*T+C2*EXP FU3=A3+B3*T+C3*EXP FU4=A4 FU5=A5+B5*T+C5*EXP V=Z*R* T/P VMB1=V-SB IF(V-3000.)61,61,4

-137 - 61 IF(V-100.0 )62,6264 62 IF(V-40.0)63,63,65 63 IF(V-0.02)4,66.66 &4_EP SI -Q. i _ _=__ _, _ _____ _ _ GO TO 66 65 EPsQ.OQ l________________ — — __-__ ____ _____ 66 VMB2=VMB1**2.0 VMB3=VMBl**3.0 VMB4=VMB1**4.0.. _VMB5 =-VMB 1*_5,_ Q_ ___ __ VMB6=VMB1**6.0 _FXL=FU1/VMB1)+LF1U2/VMB2)+(FU3/VMB3)+(FU4/VMB4)+ —FU5/VMB5)-P — _ FPRMX=-((FU1/VMB2)+(2.0*FU2/VMB3)+(3.0*FU3/VMB4)+(4.0*FU4/VMB5)+ X(5*0*FU5/VMB6)) Q=FX/FPRMX 67 IF(ABSF(Q)-EPSI )40,40,68_ __ __ 68 VMB1=VMB1-Q 69 GO.. TO 66 _ _. ____. _ 40 VG=VMB1+SB TF=T-459*69 DG=1.0/VG ___VMB2=VMB V MB B1 _ __ __ _ ___-_ VMB3=VMB1**3.0 _VMB4=VMB1**4.0 __ _ __ _ __ VMB5=VMB1**5.0 VMB6=VMB1**6.0 BNU=2 302585093*B DNU=2.302585093* D____ ___ _ PAN1=-BNU/(T*T) PAN2= (C/T)+DNU-(E/T) ____ PAN3=-E*F*LOGF(F-T)/(T*T) DPDTS=P*(PAN1+PAN2+PAN3) Q1=1.0+(SK*T/TC) Q2=SK*EXP / T C FN1=A2+(C2*EXP*Q1) _FN2=A3+(C3*EXP*Q1)_ FN3=A5+(C5*EXP*Q1) TP2=T*T TP3=TP2*T.__T =TP-3* T_, PIN1= ( Z1*T)+(0.5*Z2*TP2)+(Z3*TP3/30 )+(0.25*Z4*TP4) PIN2-=(P*VG)+( FN1/VMB1)+(FN2/(2.0*VMB2 ) +( A4/ ( 3.0*VMB3) )+(FN3/(4.0* XVMB4)) QINl=Zl*LOGF(T)+Z2*T+(Z3*TP2/2.0 )+(Z4*TP3/3.0 ) QIN2=R*LOGF(VMB1)-(B2/VMB1)-(B3/(2.0*VMB2))-(B5/(4.0*VMB4)) QIN3=(C2/VMB1 )+ (C3/(2.0*VMB2 ) +(C5/(4.0*VMB4) ) HG=X+PINI+(PIN2*0. 185053) SG=Y+QIN+O. 185053* (QIN2+Q2*QI N3) HEATT* (VG-VL)*DPDTS*0. 185053 HL=HG-HEFAT SL=SG-(HEAT/T) IF (P-100;0) 11,15.15 11 IF(P-14.696) 12,27.16 12 IF (P-10.0)13,17,17 13 IF (P-1*0)14,14,18 A TF /Dt-n.70)I 1.190.19_ 15 PGP-14.696 WRITE nlITPUlT TAPE 6,21PPGTFVLVGDLDGHLHEATHGtSL.SG

-138 - 21 FORMAT(F6.1,F8.2,F12.2,F11.6,F1O.5,F9.3,F1O.4,F12.4,F 9.3,F12,4, 16 PG=_ P-_1l4. 6... _____...... GO TO 4 17 PG=29.92-(P*2.036) _ WRI OUTPUT IAPE 62_PyPGGTFVL,:G DL, DGH L/ HEAITHG,.SL.G 23 FORMAT(F6.1,F9.3,F11.2,FII.6,F9.4F1O.3,F11.5,F11.4,F9.3,F12.4, __XF~4:F10.4_ GO TO 4 18 PG=29.92-(P*2.036) WRITE OUTPUT TAPE 6,242,PPGTFVLVGDLDGHLHEATHGSLSG 24 FORMAT(F7.261tF9.4,.F10.2 F11.6,F910.45F3,F1,1.5,F1.4F9.3,Fl12., XF9.49F10.4) __ GO iQ4 __4_ _ _ 19 PG=29.92-(P*2.036) WRITE OUTPUT TAPE 6,25,PPGTFVL VGDL,DGHLHEATHGSLSG 25 FORMAT(F7.2,F19O3.5,F9.2,F11.6,F8.3,F1.3,F12.6,5F1O.4,F9.3,F12.4, XF9.4,F10.4) __ __ GO TO 4 27 PG=P-14.6962-( 0 WRITE OUTPUT TAPE 6,28,PPGTF,VLtVGDLDGHLgHEATHGSLSG 28 FORMAT(F8.37F7.3,F11.2,F11.6F,F10.5,F9.3,F1.45F12.4,F9.3,F12.4. XF9.4,F10.4) GO TO 4 G O _ T O,A, 4 _ _ __ _ _______ _ _ _ _

-139 - PROGRAM 7 Superheat Tables Up To Critical Pressure This program computes the saturation temperature for a given pressure and evaluates the values of specific volume, enthalpy and entropy for a series of temperatures. The evaluation of these properties starts from the nearest round figure of temperature higher than the saturation temperature. This program can be used to prepare the tables for a given degree of superheat or for a given range of temperatures. A value of 0.0 is fed for the control word ZERO in the former case. In the other case it has a value of 1.0. The locations of the variables are Yl = Y Y2 = Y Y3 = Increment of temperatures required Y4 = Degree of superheat The method of evaluating the properties is the same as described for Program 6.

-14o -NALLAN-C-S —$CH4-AR — C -!12-N 01- 0... ----200-2.-..... Hi SUP H *COMPILEFORTRAN,EXECUTE,PUNCH OBJECT 2 READINPUT TAPE7,3,DC,PCTC,RXlX2,X3,X4YYlY2,Y3,Y4,Zl1Z2,Z3,Z4, XA,B,CD,E,F,A2,B2,C2,A3,B3,C3,A4,A5,B5,C5,SB,SKEPSI,ZERO 3 FORMAT(3E24.8 )______ - 62 READ INPUT TAPE 7,639TINILTNU 63 FORMAT(2F36.8) ___ __ _ X=Y1 Y:Y2 DELTA=Y3 DEGR=Y4_ 4 READ INPUT TAPE 7,5,PTAPPVFIN 5 FORMAT(3F248 ___ _____ 22 IF(P-0.0)4,23,24 23 READ INPUT TAPE 7,5,S1,52,S3,S4,S55S6,S7,S8,S9,S10,S11,S12,S13,S14 XS15,S16,S17,S18,S19,S20,S21 G_ GO O T 4 __ _ _ 24 T=TAPP IF (P-14.696) 26,27,27__ _ 26 PG=29.92-(2.036*P) GO TO 6 27 PG=P-14.696 6 FOP=A+(B/T)+(C*LOGF(T)/2.302585093)+(D*T)+(E*((F-T)/T)*(LOGF(F-T)/ X2.302585093))-(LOGF(P)/2.302585093) BNU=2.302585093*B_ _ DNU=2.302585093*D PAN1=-BNU/(T*T) PAN2=(C/T)+DNU-(E/T ) _ PAN3=-E*F*LOGF F-T ) / (*T ) _ FPRMP=PAN1+PAN2+PAN3 G=FOP/FPRMP _ __ IF(ABSF(G)-EPSI)89897 7 T=T-G GO TO 6 8 TSAT=T-459.69___ WRITE OUTPUT TAPE 6,29,,PPGTSAT 29 FORMAT(16H1 PRESSURE=F14.5/16H GAGE:F14.5/16H S XAT TEMP =F11.2) WRITE OUTPUT TAPE 6,25 25 FORMAT(41HO T F V H S 28 IF(T-TINIL)10,10,9 9 TINIL=TINIL+1O.O GO TO 28 __ 10 T=TINIL 30 TR=T/TC 41 IF(TR-2.08)42,42,71 42 IF(TR-200) 4343,72___ 43 IF(TR-1.92)44,44,73 44 IF(TR-1.80)45,45,74 45 IF(TR-1.68)46946,75 46 IF(TR-1.56) 47,47,76 47 IF(TR-1.44)48,48,77 48 IF(TR-1.32)49,49,78 49 IF (TR-1.28)50,50,79 50 IF(TR-1.24)51,51,80 51 IF (TR-1.20)52952,81 52 IF(TR-1 16)53953,82 53 IF(TR-1.12)54,54,83 54 IF(TR-1.08)55,55,84

-141 - 55 IF(TR-1.04)56956,85 56 IF( TR-1.00)57 57,86 57 IF(TR-0.96)58,58 87 58 I F. (ITR-0_.92) 59,59 88 59 IF(TR-0.88)60,60,89 60 IF(TR-_Q-0 )661_619Q0_ 61 IF(TR-0.80)71,71,91 71 Z=S1 GO TO 93 _7 _Z-=S2 _ 2___ GO TO 93 _73 Z= _ ___ ____ GO TO 93 74 Z=S4 GO TO 93 75 ZS5 ____ GO TO 93 76 Z-=S_6 _ _ GO TO 93 77 Z=S7 GO TO 93 _78 Z S8 _ _8_ __ __ GO TO 93 79 Z=S9 GO TO 93 80 Z=S10 GO TO 93 81 _ZS1 __ _5 __ GO TO 93 82 Z=S12 __ __ GO TO 93 83 Z=SI3 GO TO 93 84 Z=S14 GO TO 93 85 Z:S l5_______ GO TO 93 86 Z=S16 GO TO 93 87 Z=S7______ GO TO 93 88 Z=S18 _GO TO 93 89 Z:S19 GO TO 93 90 Z=S20 GO TO 93 91 Z=521 _ -_ GO TO 93 93 EXP=EXPF(-SK*T/TC) FU1=R*T FU2=A2.Z+B2T+ C2 E X P FU3=A3+B3*T+C3*EXP FU4=A4_ FU5=A5+B5*T+C5*EXP V=Z*R* T/P VMB =V-SB IF(V-300.O ) 11*1194

11 IF(V-100.O) 12,12,14 12 IF (V-40.O)13*13,15 13 IF (V-0.020) 4,16,16 14 EPSI=.OO_____ GO TO 16 15 EPSI=00001____ 16 VMB2=VMB1**2*0 VMB3=VMB1**3.0 VMB4=VMB1**4 0 VMBSR5VMRl**5,O VMB6=VMB1**6.0 _ FX=(FU1/VMB1)+ (FU2/VMB2) +FU3/VMB3)+(FU4/VMB4)+ FU5/VMB5)-P FPRMX=-((FUl/VMB2)+(2.0*FU2/VMB3)+(3.0*FU3/VMB4)+(4.0*FU4/VMB5)+ X(5.0*FU5/VMB6)) Q=FX/FPRMX 17 IF (ABSF(_Q)-EPSI) 2 0,2018 18 VMB1=VMB1-Q 19 GO TO 16_& 20 VG=VMB1+SB TF=T-459.69 100 IF(ZERO-O.O) 102,101,102 101 TNU=TINIL+DEGR 102 IF(T-TNU)21,21,4 21 DG=1 0/VG VMB2=VMB1*VMB1 VMB3=VMB1**3.0 VMB4=VMB1**4.0 Q1=l 10+(SK*T/TC) __ Q2=SK*EXP/TC FN1=A2+(C2*EXP*01) FN2=A3+(C3*EXP*Q1) FN3=A5+(C5*EXP*Q1) TP2=T*T TP3=TP2*T TP4=TP3*T PIN1=(Z1*T)+(O.5*Z2*TP2)+(Z3*TP3/3.0)+(0.25*Z4*TP4) PIN2=(P*VG)+(FN1/VMB1)+(FN2/(2.0*VMB2))+(A4/(3.0*VMB3))+(FN3/(4O0* XVMB4)) QINL=Z1*LOGF(T)+Z2*T+(Z3*TP2/2.0)+(Z4*TP3/3.0) QIN2=R*LOGF(VMB1)-(B2/VMB1)-(B3/(2.0*VMB2))-(B5/(4.0*VMB4)) QIN3=(C2/VMB1)+(C3/(2.0*VMB2))+(C5/(4.0*VMB4)) HG=X+PIN1+(PIN2*0.185053) SG=Y+QIN1+0.185053*(QIN2+Q2*QIN3) WRITE OUTPUT TAPE6,31,TFVGHGSG 31 FORMAT(F8.2,F11.49Fll.4,Fll.4) T=T+DELTA GO TO 30

-143 - PROGRAM 8 Superheat Tables Above the Critical Pressure The program computes the values of specific volume, enthalpy and entropy of gas, for a series of temperatures with a given increment of temperature. The values of the initial and final temperatures and the increment of temperature required are fed into the machine. The input variables are: Yl = X Y2 = Y Y3 = Increment of Temperature chosen TINIL = Initial temperature TNU = Final temperature The method of calculation of Program 7. properties is the same as described for

-144 - — Nt.A — LC-Se-CAR I C12-N. —.-0.9 020 2 SUP HT2 *COMPILE FORTRANEXECUTEPUNCH OBJECT 2 READINPUT TAPE7,3,DCPCTC.R.X1 X2,X3,X4Y1,Y2,Y3.Y4,Z1 Z2,Z3,Z4t _ XABCDEF,A2,B2,C2,A3,B3,C3,A4,A5B,5,C5,SB,SK,EPSIZERO _ 3 EQRMAL13E24^8i ___ -_ _- -- _ 62 READ INPUT TAPE 7,63,TINILTNU X=Y1 Y=Y2 DELTA=Y3 _ 4 READ INPUT TAPE 5 P- _ ___-__ __ _ _ _ 5 FORMAT(F72.8) 24 PG=P-14*696 __ __ ____ _ _ WRITE OUTPUT TAPE 6,29,PPG 29 FORMAT(16H1 PRESSURE=F14.5/16H GAGE=F14.5) WRITE OUTPUT TAPE 6t25 25 FORMAT(41HO T F__ _ ___H _ _ ____ __ 10 T=TINIL 30 EXP=EXPFA-SKTTC) ___ ___ ___)_ FU1=R*T FU2=A2+B2*T+C2*EXP FU3=A3+B3*T+C3*EXP.... ~ FU4=A4............ FU5=A5+B5*T+C5*EXP V=O.02 VMB1=V-SB 15 EPSI=O.0001 16 VMB2=VMB1**2.O VMB3=VMB1**3.0 _ __ ____ __ VMB4=VMB1**4.0 VMB5=VMBl**__5_ VMB6=VMB1**6.0 FX=(FU1/VMB1 )+( FU2/VMB2)+(FU3/VMB3) +(FU4/VMB4)+(FU5/VME5)-P FPRMX=-((FU1/VMB2)+(2.0*FU2/VMB3)+(3.0*FU3/VMB4)+(4.0*FU4/VMB5)+ X(5.0*FU5/VMB6) )_ -_ ___ Q=FX/FPRMX 17 IF (ABSF(Q)-EPSI) 20,2018 ___ _____ 18 VMB1=VMB1-Q 19 GO TO 16 20 VG=VMB1+SB TF=T-459.69__ IF(T-TNU)21,21,4 21 DG=1.O/VG __ ______ _____ ___ _ _ _ _____ VMB2=VMB1*VMBl VMB3=VMB1**3.0 VMB4=VMB1**4.0 Q11.0O+(SK*T/TC) Q2=SK*EXP/TC FN1=A2+(C2*EXP*Q1)O )_____ FN2=A3+(C3*EXP*Q1) FN3=A5+(C5*EXP*Q1) TP2=T*T TP3=TP2*T _ TP4=TP3*T PINl=(Z1*T)+(0.5*Z2*TP2)+(Z3*TP3/3.0)+(0*25*Z4*TP4) PIN2:(P*VG)+(FN1/VMB1)+(FN2/(2.0*VMB2))+(A4/(3.0*VMB3))+(FN3/(400* XVMB4)) QIN1=Zl*LOGF(T)+Z2*T+(Z3*TP2/2.0)+(Z4*TP3/3.0) QIN2=R*LOGF(VMB1)-(B2/VMB1)-(B3/(2.0*VMB2))-(B5/(4.0*VMB4)) _) QIN3=(C2/VMB1)+(C3/(2.O*VMB2))+(C5/(4.0*VMB4) ) HG=X+PIN1+(PIN2*0.185053) SG=Y+QIN1+0.185053*(QIN2+Q2*QIN3) -__. WRITE OUTPUT TAPE6,31,TF,VGHGQSG 31 FORMAT(F8.2,F11.4,F11.4F11.4) 32 T=T+DFL-TA GO TO 30

-14 - PROGRAM 9 Constant Volume Tables This program evaluates the pressure, enthalpy and entropy of the gas at a given volume as functions of temperature. The volumes and the initial temperatures corresponding to each volume are fed into the machine in FORMAT (2F 36.8). The other variables fed into the machine are: Y1 = X Y2 = Y Y3 = Increment of temperatures chosen Y4 = Final temperature ZERO = Nearest round figure higher than the critical temperature The method of calculation is the same as described earlier.

-146 - - NALLAN _C S CHARI __ _ C 1 2-N 004 040 2 _ _ CON VOLU *COMPILE FORTRAN,EXECUTE * PUNCH OBJECT 2 READINPUT TAPE7,3,DC,PC,TCtR,X1 X2,X3,X4Y1,Y2,Y3,Y4,Z1,Z2,Z3,Z4, XA.B, C _, D.*E_ F, A2 B2 C_ C3_AA B5; C5 SB3 SK ~ E PZI4 B 3 FORMAT(3E24.8) 4 +_READ LNPUT TAPE 7,5,VGJIIN.- ____ X=Y1 DELTA=Y3._.5 FORMAT ( 2F36 *.8 )..........._______ ___ __ WRITE OUTPUT TAPE 6929,VG 29 FORMAT ( 19H1 _ _ VOLUMEF8 3 __________________ WRITE OUTPUT TAPE 6,21 21 FORMAT(40HO T(F) P H S /4H ) T=TIN+459.69 ___2QEXP =EXP - SK* LTC L ___ ________________________ __ __ _____ FU1=R*T _ _ FU2 A2+B 2 * T +C 2*EXP__.___ ___ _____ _ __ __ FU3=A3+B3*T+C3*EXP FU4=A4 FU5=A5+B5*T+C5*EXP ___..VMB1=VG-SB __ _________ _ _. _ VMB2=VMB1**2.0. _... _ VMB3=VMB1**3. ________________. _ _ _ _ VMB4=VMB1**4.0 VMB5=VMB1**5.0 P=(FU1/VMB1)+(FU2/VMB2)+(FU3/VMB3)+(FU4/VMB4)+(FU5/VMB5) -_ - Q1=1,0+(SK*T/TC) Q2=SK*EXP/TC __FN1=A2+(C2*EXP*Q1) __________________________________________ ___ FN2=A3+ (C3*EXP*Q1 ) FN3=A5+ (C5*EXP*Q1) TP2=T*T TP3=TP2*T TP4=TP3*T _ i__ PIN1-= Z1iT) +O,5*-Z2*TP2)+ Z3+TP3/3.0 )+-O.25*Z4*TP4)- ____ _ PIN2=(P*VG)+(FN1/VMB1)+(FN2/( 2.0*VMB2 ) )+(A4/(3.0*VMB3 )+(FN3/(4.0* XVMB4)) QIN1=Z1*LOGF(T)+Z2*T+(Z3*TP2/2.0)+(Z4*TP3/3.0) __ _ QIN2=R*LOGF(VMB1)-(B2/VMB1)4-LB3/2.0*VMB2) )-B5/(4 O*VMB4)) QIN3=(C2/VMB1)+(C3/(2.0*VMB2))+(C5/(4.0*VMB4)) 10 JHG=X+PIN1I(PIN2*0. 185053____ SG=Y+QIN1+0. 185053*(Q01N2+Q2*QIN3) TF=T-459.69 WRITE OUTPUT TAPE 6,31,TF,P,HG,SG 31 FRMAT(F7.2F11 F11 lF114)_________ IF(VG-(1.0/DC))32,35,32 35__EL-ML —TC ) 3 2 3 7L2 _ _______ 37 T=ZERO T=T=+DELTA IF(T-Y4)20920,4

-147 - PROGRAM 10 Constant Entropy Tables This program evaluates the pressure, specific volume of gas and enthalpy of gas for the given entropy as functions of temperature. The entropy and the initial and final temperatures corresponding to each entropy required for the computation are fed into the machine in FORMAT (3F 24.8). Other variables fed into the machine are: Yl = X Y2 = Y Y3 = Increment of temperature required The equation for entropy (Equation 75) is solved for the volume by the Newton's iteration procedure for a given temperature. Further computations are the same as described earlier.

_NALLAN C S CHARI C12-N 010 040 2 ENTROPY *COMPILE FORTRAN,EXECUTE,PUNCH OBJECT 2 READINPUT TAPE7,3,DCPCTCRXlX2,X3,X4,Y1,Y2,Y3,Y4,Z1,Z29Z3,Z4, XA,B,CD,E,F,A2,B2,C2,A3,B3,C3,A4,A5,B5,C5,SBSKEPSIZERO __3 FORMAT3E24S _____________________________________________ 4 READ INPUT TAPE 7,6~S,TINTFIN.__6 FQRMAT(3F24l __ __ ____ TIN=TIN+459.69._ _ TFIN=TFIN+459.69 WRITE OUTPUT TAPE 6,22,S __ 2Z.F ORMAT-L1L7H lS= F 10.4) ___ 24 WRITE OUTPUT TAPE 6,24 _ 4 FORMAT(37HO TEMP PRESSUREE VOLUME ENTHALPY /4H _ 1) ____ X=Y1 Y=Y2 DELTA=Y3 __ T=TIN_ 30 Ql=1.O+(SK*T/TC) EXP=EXPF(l-SKIZ TC) __ __ _____ Q2=SK*EXP/TC FN1=A2+(C2*EXP*Q1) FN2=A3+(C3*EXP*Q1) ____~FN 3IA5_+C5 * EX P*Q1L__ _ _.______ ___ TP2=T*T _ P-T lP2 T P2,I_..._.._ _....._ _ TP4=TP3*T PIN1=(Z1*T)+(0.5*Z2*TP2)+(Z3*TP3/3.0)+(O.25*Z4*TP4) QIN1=Z1*LOGF(T)+Z2*T+(Z3*TP2/2.0)+(Z4*TP3/3.0) G__ UF=-LS-QI N1-Y f(0.18 05*R) ____ _______ __ 8 R___ VMB1=EXPF(GUF) V____VMB1+SB_ __ __________________ __ IF(V-300.0)11,11,4 11 IF(V-100.0) 212,1214 12 IF(V-40.0)13,13,15 13 IF (V-0*02)15915,16 __ 14 EPSI=0O001 G____ GO I ____ _______ 15 EPSI=0000O01 GO TO 17 16 EPSI=O.0001 17 VMB2VMB1I*2._0 ____ _ VMB3=VMB1**3.0 VMB4=VMB1**4.0_____ VMB5=VMB1**5.0 QIN2=R*LOGF(VMB1)-(B2/VMB1)-(B3/(2.0*VMB2))-(B5/(4.0*VMB4)) QIN3=(C2/VMB1)+(C3/(2.0*VMB2))+(C5/(4.0*VMB4)) _ FS=Y-S+QIN1+0.185053*(QIN2+Q2*QIN3)_ QPR2 (R/VMB1)+(B2/VMB2)+(B3/VMB3)+(B5/VMB5) QPR3=-((C2/VMB2)+(C3/VMB3)+(C5/VMB5) ) _ _ SPRM=0.185053*(QPR2+Q2*QPR3) Q=FS/SPRM IF(ABSF(Q)-EPSI)20,20,18 _18 VMB1=VMB1-Q _ __ 19 GO TO 17 20 VG=VMB+SB _ _ __ FU1=R*T FU2=A2+82*T+C2*EXP FU3=A3+B3*T+C3*EXP FU4=-A4 FU5=A5+B5*T+C5*EXP P=(FU1/VMB1)+(FU2/VMB2)+(FU3/VMB3)+(FU4/VMB4)+(FU5/VMB5) PIN2=(P*VG)+(FN1/VMBl)+(FN2/(2.0*VMB2))+(A4/(3.0*VMB3))+(FN3/(4o0* _ XVMB4 ) _HG=X+PIN1+(PIN2*0.185053) TF=T-459,69 WRITE OUTPUT TAPE 6,21,TF,P,VG,HG 21 FORMAT(F7.1,F10.5,FF10.5,FlO4) T=T+DELTA IF(T-TFIN) 30,30,4 *DATA

APPE1ND X H SATUAT.ED VAPOR DENSITIES OBTAINED BY EXTRAPOLATION OF.''1vT DATA BY BHAA ( 6") TO T1E VAPOR PRESSURE CURVE -1)49q

-150 - TABLE XIII SAT RATED v7APOR DENSITIES OBTAINED BY EXTRAPOLATION OF tPaV DATA BY BHADA(6) TO THE VAPOR PRESSURE CURVE Saturation Dens ty Temperature _ib/c!-ofto) (~F) 3.2948 -133.6 3o 9018 -125o 5 5.0429 -114o1 6.6133 -101.3 9.2498 -87.1 12lo63 -74.9 16o205 -64.3 18.519 -60.5 19.849 -58.5 24,637 -53.4 32.669 -50.3

APPEND7IX I GENERAALZZED DATA ON TEE LIQUID DENSITIES OF SOME FUOROCHLORO DERiV'ATIVES OF METHANE

-152 - TABIE XIV GENETFALIZED DATA ON THE LIQUID DENSITIES OF SOME F~LUOROCHLORO DERIVATIV',ES OF METHANE -d --- ". O~R) d(-(lb/ -fT+o) (1-T/T,)2 (l-T/T )1/3 Source 1o CCI 2F2 VaZesE of;rit~io>al constants used Tc=693029OR; dc=34084 Ib/cu.ft. 83,o 7"2 50o8.6 o5742342o 9135746 18 669o71 56,809 lo0497501 lo9462076 18 655o57 6,o086 = 14332963 1 9898346 18 593,39 73~877 o27485294 2~1372143 18 576o11 76o537.30569784 2.1646141 18 555o05 79,421 o34130753 2,1902753 18 5:;'4,87 79~440 o34160373 201902587 18 537~77 81o662 o36918798 2.2118111 18 51 6o,53 84,409 o o208023 2o2437561 18 49 o69 87.062 o43891836 2 2624734 18 4745 9 88.985 o46339987 2 2829808 18 46lo63 90o452 o48153082 2.3002674 18 459.65 90o589,48427070 2.2994016 18 440o6y 0-7 91o700 o49932659 2o3095978 18 40o 57 92 531.51028930 2o318044o 18 4223 65 94o235 o53281887 2o3355111 18 35901 1l00o403.61488938 2.3998393 18 52712,:,5 108o263 o 71714277 2,4885774 18 2o CCIF3 ~aij.nes of critical constants used - T cz543.62~R; dc=36,07 lb/cu.ft. 57~ 77 50 o 90 o.0487424 1o 8622650 2 529o.1 56o5?5 o08766394 o9176675 2:5_1~l o 63o95 o15072275 1o 9909356 2 499 8'3 67~64 ol8651754 2.0266026 2 84, o87 71.55 o22688630 2,0650630 2 L46ao 42 75,62 o27219570 2l o 016467 2 W,433o55 8,7 lJ 1,o8L 34481199 2,1595279 2 2328, 5 90,11 o44756141 2.2394577 2 3,34 44 9630 C 52903350 2,2957528 2 n301 c 6 2.00 o 50-1 o 58295107 2 3398786 2 235o64 108.48,68467543 204261075 2

CC) 0n,-d LI> H H H F ~ — i i 0 E 01 0 10 H 00 n0 O o NO ^ |-'I #,-U W 1 ^-j CD C~) 0, ~ o 0j CO C) H 0 E-.'I 3 r-{ i-i |_ 0 H.,o H q.., OE H b-r' *0 Iv; 9 r -i t.-^ 4 o r i S; — E 'C' 41 -CH -p S'C 0 0 c0. 0 o-d 02 o Ca, \' A t 1) FO 6 -3 * C>n C * H Cj H- O\ CO OC C)) 0 -c CI F — F1 — ON H-' O -H t 'M~) LH A u\. Oj. At Lrm-N oo F0i C 0) 0 20 O CO ON C (C) Cy- C) 0 0G x\ uo HH) 0 0000 Cr- o ) CU oQ o o CYO ' O, AH r-H ', H 0',. OH -- 0 LI> CY-) Ct 0 LIS C) C CON -00- CO 0- O 0O0", to oo o H 0 0 - CU 0 0 C — 0C CUi CU HAO O cO 0 0(- CO) L COJ r-i - -At U>s LI'> L."'. At o o o o 0 0 0.),-0 H- CU C). CM L).'I xL) I> Cq \C'0 H~C LC COD CX- LCU'NH - H on Cn U 0 0C\ (tCO C>) C CO CO Lr At C7\ r-t ) COJ OONON r -1DooDOS CO CrO\ C ONC CN -oc CD H-H-K> L\- 0 HO C-U0 x H,_ -C OO\ H -' t r- I OJ 1-4 -0 0O O0 CO CO CO CO cOO 0>000!CUH r-1 r-i rCU 'C) cO o^b r! GI\ OJ bc. <0 LC\ CC)C \I) LU\HD r-Ui <0 0 C ^-CO 0,-4 0 _-.- r-i o, cr' 0000 0 0000 ~000 0O000 ONO, CC, rO t0 L H L-c C' >- -;Or 0> 0- ( K> '(C, LC ' CO O (Y A, C) ' H) - 0 LICM 0 f OC e -4 0! r-1 00"x 0^ ~ — C- iOh — \ tr)-c o O CO 0! -0 c) 0 0 0 0 0 0 ' oo o; o. o -J -:.4' -4o At cC U > AT LK\ H-t C0 (I > H- ON (9 (9 — 0 0 -p 0 G 0 4( o oH C'> F) 00' C 0 %d aI'> At 0 tL\ 4 H C) At F-L o t IFa) C.') 00 + _ I ) r.e Li 4'I i -1 >1 LP\ LI> LC\ LI\ LC\ LI\ LU\ >O IH- C-O 0 H- 0 0 Lr\CD Co - 'LC\ -- o Lr\ Lr\ ~ CC) 0 \0 0t OHJ 0 0 H L -t 0 H-C oO - h\ 0 0 r-A O! 0C O 0 0 C CU ~ o o o i o rH CU CU C CU CU 0I4 CUq \ 0 O CLI C -.t0A cO 1C> 0 H-. CU Cot I A -O - _- CC0 C \ (\ C O 0 -- O 0 0I C'. 0 iC 0,-i 4Co 0F I-..- C0. y' O - ' -- O A-t" (Y; r-! COi CO IC' W LC \,( U " L u \X. L\ U-L,\ CO CD C, CU1 CD H 0 0-1 CO CU H-0 k0 Lr\ OJ 0 00 OJ t- O sCO H0 N — CO 0 HL — o o o C0 Cq (N C'i " C CU 00 0ON C0 0 0 <0' 0' *0 H-O 0 o [H —t \0 00 't: —I Lr\! C —>- oo jI H- AO CC) CU 0>0 0 0 0000 C C '-. C 0C 0 Oi Oti C~r o~se (7 L o- t o H-C'> O'i '4 C C' i ( F[

-154 TABILE X-'.: (CON T) GENERALIZED DATA ON TBHE LIQU:ID DENTSITIES OF di SOM' FHJ0R07EL0RO DER1VATIVES OF METHANE T —'" d.lb,,/c.. -ft;, ) I/T/ 3 (i-T/T3 ( )1!3 Source 5o Cl HF3 au ea.,s of crf4oial cornErtas used % -38033&R; d.^3278 lb/cu.oft.o 370T79 86o587 Oo 45924732 2.42268002 20 45 4oi.4 73o037 O 029027388 2.27997151 20 -46o70 70.o37 o26063392 2.24356866 20 A4C:, 7 73 67o195 0 o22538030 2~21202222 20 5lKo77 S 57o-429 0,1311.2181 2,07722014 20 529o 76 49 322 0.063283271 2o00678444 20 536 ~9 41 827 0 02101505 1.90496787 20 537ofo 39o763 0.01225139 92600347 20 *Lce L

APPENDIX J REDUCED 'APOR PRESSURE DATA FOR SOME CHLOLROFLUORO DERIVATIVES OF MEITHANE -155 -

11 Ltf\ r'1! -4 U P) 0 F^j?i2.E4 en k~ Cf.) L4 P I F - 0 W, r) n CU 'rH Cd o KO U' - 0 0 \0 ut% r..l, a o 0%. r-~) t- Lr,\ II U F-qOU (D) C) 0 CO 0 FQbP? 0 r-I' ci CD CU' F-)0 I' 0000* * 0000* 00000* * * 00000000* 0000000* * * c( C') c C) C() CY)C) C C) CC C) C') (Y n CY) C C) C C) (C ) CC) C Cy (C)C) CY) C ) CC) c C CC), (Y') C C) C) C C- Y ) C C') CC) CC) -4 oC H c4 c 00 CO ) 1>- ( O\.0 Cxl o ) H L- -4 CO CC) C\ 0 Lrx4 COJ CO L L\ O LC\ 0 oN COJ - [ — LC o Cy ON Co < C) CC) 0 0 Lr\ L\ LTN H OJ r-I \0 r- J K CO 0 cJ CC 0 H -4- C\j OCJ D r- C, — 4- LfOCO -4' -4 - O O-: 0 0O 4 CC o CO LrCCO 0UO L L- I4- UC\ CC-4- -4 OK -4- -4 O D o \ 0% rC K0 C O\ CO H -:-4 O 4-4 r- C Qn o >-'K CJ 0 00 'CO -4 t — H — 0 Lr\ 0 Cr) L\ CC) CO \, CU OJ \0 0o. N — CO Lr'N 0 C, CO CO -4 OJ,0", on CC) H-o H- cO CO \-'O \0 C), —.t ' 4 O'\ 'c - H 0\ O -0 r LCrX _c-) (~C( C U 000 H OE O O 0 - -I 0 \ CO \-O-..-0 IC,O Lr\ L\ LCr\ Lr\' LrN Lrm O -4 0 0 0 0. 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 a 4 -4- (Y- (CC) f ) C1 CC) C0 cn ) 0) 0C) CCy CC) CCC)C") C C)) C- C O O O r-l r-I r-C r-C Cr r-H H H r- r-H H -- rH rH H riA on ~-\D C:\ (C_ co Lr', LPf O o 0 L, CY-) ' O,. 0 Lr' 0\ C\ CO ^Q 0 CO, —1 L'\, 0 '\ -C1 O 04: -Cq- Lr'x 0q.O\, \:;[ ~ 0 -4' 0,-i D0 0.Gk L\ -— C C j Lrxo 0GO: -t L::u CO CO r — -J a kO k.C oq — ~ OC — t'k0 C1i u'~ Oh LO. CYt 0 H —t O'x C C ) ~ ~ ' - K O C U C O L C N L C N C U 0 L o x ) ' C ) C C ) C U O N L C \ O N C U C O O C O ' - - I ) N H - x & C U - 4 4 W o —x KC0)\ C C'\ CCCi O J - - I 0H - -A4 0 C ) CO C OCO LLCX N k O -. ) LC N \ c \D U O- Lx-0\ a! CU CO r — r ON H]' ---t 4 % ON LO'X\ LrX ~) On \.C' -t -f ON H —! KC Lr%, _CNQ _ \ CO N CJ CU, LH ( rCC C - H — (( _CU ' o - 0 N O — \ C4 0i-\ C O r-CO H-C0 L,C) < Lr, LoX CG) CUr 4 4 ('C ) CU Cl CUt CU H \. i0 0 0 0 0 0 CO H- H -C O<L ( Ld - ' N ( \ LO.1 '(Y - o, c\! J OJi O rir-rj O O O O I t-0 D 0*D \,f Lr(\ LI\ Lf\ Lf\ r Lf.f L\r"- 4: o0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 la 0 a0 0 0 0 0 0 0 0 0 0 0 CUj C '\ CU C aCU Ci CU CU OJ OJ CU CU OJ aC CUJ C0 CU CU H H -( H H -- i - I - r —! r- r — -i r- r -H- r —4,-i - - - Q LrC' O "N, GO ICCC, C C: C% O C CUi Cy, r 4 —, 0 CO, H- CU \), OC ON, \,D uN GN CO - - 0 G\ -- L Q r\CN.A- o.! "' O.i H H —I c" -- CO "C;.j, C) 'X co~ 0C 4 OCVi ' > -- Co \ 0(\-' CN L N ' ) xC)\ Cy- ( C4Lr C y-) CO > 1 O N 4\. L' Q '., 4 C)~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~. —.ff0 0%\ cdi ~-4 u-\ 0 (1! ux u'x c~ o,-. ) u- C%\-4 er, Lr~O.r>-t-4 Lr', cm r-1 <o,-4,-4 o4,-4 00o (',.! 0v o:. O4 o.oj:o — t —' -f -~ r-i 0 CL) a " r- r-i "U C O 4 4 44. o, L C-\ (0 — CU 0 0 4 C C 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 00 o% L\0.D - j 0 r ' -0 04- 0, 0 0: r- H H r -4 H r r H- C r-i 0 C 0 ) 0o>-t -4 - L'-4 o -'C r. —.!' O', ( U -' C)". —4'CC.d (.\ I 1-. 0Cx O or)O. 4 ' -4 o -' (~H, —CC o7't - " x. L~-\(7.,D u-,kL.C.) r I r-i '.) b-.o -t. — 0 L'-. Co C), — ooC o - o? m~ e oo CD -- - b-.D 0q r c r-, 0 0 0 a 0 a 0 0 0 a a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o~~~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~.oC~...... IcO 000>0' - CC'-: uc'\ C tO C O LrC C C U'C.;OOrV, 7,V.O U_: fO, Co!:- H- xX)~- Cx. <C X; N.) xoNox,0. oC C' Oh 4'4 aC. o ",,C O. OL oK O (V, on 'C-)(... 4, V I O <. o Q C' ' r- H r- H H i r —, -: r!: -:;,-' r —i H r —,4 r —i ( O C % CM OCi. O C 0.C\ O ( x OJ OC C C O. (; O i I(. 0

-157 - TABLE XV ()CONT) 7:.- 'D VAPOR PRESS TE DATA FOR CF4 P 409~ 50 ~R 543 16 psia.jI,.~ eL C. r -P(p-Cs -i-a) — r TJ lT __ _ -l-ogT-10(P/P ) ) Source =K. 5_ ~~~~~~~~~~~~~~~~~i,. - ogi C 289 3 30Q 947 3 o 31o 33 42733 339 o0o 343o4 348 o 57 341o 77 35,.86 '55 66 3 Q o Q65 69 373.97 30 o7 99 3,~ o83 39o 79 405.34 40 7 35 4 o,. (- r:.t..l+ al) 57066 70 o1.6 94.05..n, 26 127.3,4 149.24 610 34 1L65.64 166.4L 180.04 -79.29 193 22 208.02 21-7.50 242.22 238.08 2-48.36 292.72 29 2.45 317.43 3 30,66 353.22 373028 '4. o67 4,8.84 4)49. 70 468,22 48,7 22 494 72 490.85 504 22 5'P6 77 531.22 543.6 (9al ''iat ed. ) 1o41.534 1.40259 1. 35448 1.32323 1.29453 1.26839 1.25 03 1,22958 1.20761 1,19374 1.18854 1.18844 1.17473 1.17413 1.16382 1.15138 o.14229 1.126o8 1.12590 1.1 1980 1.09527 1.09501 1,08096 1.07483 1.06718 1.05587 1.o4568 oO3805 o02727 1.02214 1-.02000 1.oO1580 1.01364 1001354.o010o66 1.00976 1,00718 0oo 518 1.00503 1.00326 1 0000 1.12889 l1. 0544 0097405 o088884 0.81137 0.76156 0.68859 0.62996 0.56104 0.52719 0.51577 0.51368 0.47956 0.48137.o 44888 0.41683 0.39747 0.35072 0.35821 0.33985 0.26848 0.26888 0.23328 0.21556 0.18687 0O16289 0.13001 0.11291 0.08201 0 o.o6450 0.05715 0,04722 o0 o4o61 0o04401. 0.03230 0.02761 0.02169 0.0154o 0.01995 o.00967 0.00000 * * 7 * * * *7 % 7 * 7 37 37 37 37 37 37 37 37 * 37 37 37 37 37 *x " r- T C n e 1i; -..-L+.

LD r CO, CX] r- 0 C) 0 F-i H), F-3 CH W. ct C I o eq o' (0 C.) i ( CJ 0 aD 0 C) 0 CO C) 0 Pq & }0 O ri v-I 'C) '-I CC K -.L — GD GD Al- 0\G C C) CC] o e C —.y l- LC\ eq ff- D GD 0O 0 0 CX] Lr>LC \GD 0cX -4d CC (X'G H o04 e.nq-r-A H i> -kL\GO C>- iC - 0o 0 LOC I- 1 LC CO CDJ -> - 0 0 0 GD 0 GDC CO rD \ \D GD C\ C-) \D:;) >- CY') o GD,- 0 0 — )' eq C Ho C\ -- ( 9 D CQ r - -4- e ( C\ i r —i o CJ C('\,D \D L C-IT - 't;e Ci CI CC] Q C0 r-C rC — r — rH r- r H C-d r — rv -I r - I H -H r- -H A r I - r-H - H - CC 0> >I LnC. CI -4 C -- 0 CY-4 CO\ 0 o l AD Dco -4- 00 o0 D 0 C\ eq 0 mt- b- eM -t 0. t -C- LCi CC] C N 0 0 0 O0e 00000000 r-{ -i rH i-l i-5 H r-i4 r- — I H HLr CU 0 CT C LH C\JC\ JCU l,\H C C -J C\JO C\J CU C t'C rHC C\0 1CL lJO JCO -J-C 0 C CLiG0 CC] C0 ' 0\ CCO, ). L\ H v H 0> CJ -4- eo C- I H LAr\H 0 C-0 - C D C- 0 -- > LC\ 0 eq GCO! d 4 C H CC] C1 - O Ch- 0 0 H _ eq C] CO I 0 H eq C\ \ rH j c- O^r\ \ O1 CC] ) 0 0 D LrD\ C" G oG) c0O — tC Lrx C- q HY) Ck l, -d-t CY' - r-i -\ H 0 0\ H0 C0o o C\J - H 0co 0 \ G D \ H 0 C-i CCC 0 >DG oC C O"\ L-\ 0C -q- r -- i \-t qCC \OO r- 00 0 0 q CC] H H i- r -- 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 GD0, CC] CCvt9 a", -t C) 0> CY) 0 >t CC 0 e I>' rAt C. LA C0 t G #) ' o.C O C O o CC - a)o-4 0 0 C~- -4CL 0 0 H 0 0H 0 O O o O O O. O 9 O. 0 O O a O 0 0 - L9 L9 a 0 a 0 0 G O a 0 O O C 4-1 CvO 0: 04 r- -t a L t\ GX C C-0.- r- -4 ' C -4 00 eq Q H' D CCIS - - 0- ' t o — o '\DD,-4 r q -I'; -- 0" 0 o C ( oY -t- L-\ -- 0~ r-. o, 1L- 'S o o.o - Ci OC 03,. rc -',. cc", 0\ vrA r-0 C - C-C r- C —. C (\;0 Ce C- C O -4-d- -4- Lw r L rG Lr0 CC] -4 CO \ C; 0I\ G Ci 0> CX] G t 0D;t 0> L \ C> 0 -4- G 0 4 C — oq, —C > r- C\C GD 0 CC? 0C> eq CC — 0\ -)CD C]) d>GxD L- CCi L cvi, L C —0 t a- -- 00 -4- 0 C ) \ C i I- I-4 -4 ' 0 (S rL rA LCY LfH (T' 4 ox, i,J:4. if o ~l Lr\ 0 x\ o a U c 0 L 3 7~' tt WC 'Lr (i \ 0 X O WO~-i o 'o 0 C) oi o> cv oo eq C- oJ e (r A' o o o o o o o oG oG o> o o o o A\ -4 Co C C - -CC, o o0 -\ eq= >, C x l f eq 4. r L-4 -\ CX CCA,C r\> CC CC> CC iL C GD GD GD 'GD 0 GD GD GD GD G GD GD GCD

TABLE rI REDUCED VAPOR PRESSURE DATA FOR CC!F3.D, T ~~~3 P.7.. 543 062~R 561o3 psia, RP(psia) T TS og /(P/P/) Source 261. o 50 O0.4797 2,07885 3.06823 2 31.C0.44.~674 17.h74887 2.079502 L344 2 4.623 i 57608 1 58416 2 387.50 44.38 1.40289 1.10201 2 44L447 137.44 1.22308 0.61109 2 o491.692rC)085. 9 1 o0562 0292982 540.06 537.9 1o00659 0.01849 2 L2 S __ ~~~~~~~~~~~~~~~~~.....

APPENDIX K DETAILS OF CAL^ULATION FOR THE ENTHALPY AND ENTROPFY AT T-"!HE REFERENCE TEMPERATURE

i6l DETAILS OP CALCULATION FOR THE ENTHALPY AND ENTROPY AT TIE REFERENCE CONDITIONS The daum plane for computing the enthalpy and entropy was taken t{o be solid state at absolute zero, Thus at 0~R. H = 0 and S = 0 for solid C 4. Euclken and Schroder ( 13) measured the heat capacity of solid CF4 in the t.emperature range of from 12~K upto the melting point of 89.47~K, Their values are presented in Table XIX. TABLE XIX HEAT CAPACITY (Cp ) OF SOLID CF4 Cp 7(~K) cal/(g. mole)(~K) 12 1.82 15 2.98 20 4o85 25 6o50 30 7o95 35 91o.6 4o 10o23 45 rl o21 50 12o07 55 12.95 6o 13o88 65 15.02 70 16,57 75 20o79 7620 3 Transition point 80 16.10 85 1.6,52 87 16.48 89 16.o03 Q890 47 Melting point For heat capacities below 12~K. E-uken and Schroeder developed +;the ol owing euation for carbon tetrafluoride:

-p D G(70/T. + p ( 93</1 + 0.030 1 Cp (77) where e is tin ca l (g mole) ~K) and T in ~K. cp and cp! are respectively..... p a./(Deres pevl y the Debye fur-ction and the Planck-Einsntein function. Table XX presents a su-nmary of the C values in the range of p 0 12~K obtained by solving Equation (77) at each of the temperatures. The values of the Debye functions and the Plan-k-Einstein functions have been (45) obtrai-ned from the tables presented by Mac Dougall. TABLE XX HiEAT CAPACITY (C) OF SOLID CF7 BELOW 12~K p ~ Cp T(~K) cal/(g. mole)(~K) 0 0.000 2 0.01.7 4 o0.0o87 6 o.288 8 0.682 10 1.185 1.2 1.819 C.t.er dat.a available from Eucken and Sch~roder are the (CzH)Transition at 76.23~K f 353. 707 4-/-ol aad the enrthal py change of fusion at 8947~K of 167.309 cal/g7mole Figures 12 and 13 present the graphical methods used In obtaining some of the values given in Table XII. The entropy values have been sim-l ar1y obtained by plot-b ing C /T versus T evaluated from Tables XIX and lX and determining the area under the curve between the given temperature lims 0 From th.e 1 u id state at 89,47~K to tahe saturated liquid condition

-163 -2.0......... -------- 1.8 1.6 1.4 1.2 0 o 1.0 E 0. / o 120K / CpdT =6.262 0.6 0~ K Cal/g.mol0.4 0.2 0 2 4 6 8 10 12 T K Figure 12. Graphical Integration of Cpdt for Solid CF4 Between 0OK and 12oK.

-164 - 2 0 o _5 E 0 0 U0 a Io 0 10 20 30 40 50 60 70 80 T ~K Figure 13. Graphical Integration of Cpdt for Solid CF4 Between 12 K and 76.23'K.

-165 - (4o) at 100~K,-the liquid heat capacity equation by Selby and Aston has been used in evaluating the enthalpy and entropy changes as follows: 100~K 100~K SeH = n c dT = C (24.54 - o.114o+ 5.160 x 10 T) dT liq - P 89.47 89.47~K = 193.323 cal/g. mole 100 ~K 100 ~K \Sli = C T / (2454 - 0.1140 + 5.160 x 10-4T) dT liq C P T T 89.47`- 89.47~K = 2.218 cal/'(g. mole)(~K) The remaining steps shown in Tables XI and XII are self- explanatory. The values of entropy changes of transition and fusion have been obtained by dividing the enthalpy changes by the respective temperatures of transition and fusion. The value of Href has been obtained by adding the enthalpy change of vaporization obtained by the Clausius-Clapeyron equation to the enthalpy of liquid at the reference temperature. The entropy at the reference condition Sref was similarly obtained by adding the entropy change of vaporization, which is equivalent to ZvHV/T, to the entropy of liquid at 180~R. Program 4 in Appendix G has been used for the computation of these values. Following are the results from this program:

-166 - Tref = 180~R and saturated vapor (P - 0.1097263 psia) Href = 99~347077 Btu/lb Sref = 0.67950135 Btu/(lb)(~R) The values of X and Y obtained from Equations (69) and (76) calculated by means of program 4 are: X- = 86.102162 Y = 0.36172528

APPENDIX L DEYAXLS OF OAL LATIONIS FOR THE DETERMINATION OF ENTROPY BY STATISTICAL MEIV.E- ODS AND TIHE.RMAL METHODS FOR THE IDEAL CASE

DETE::NATI._ ON OlF ENTROEY BY STATISTICAL METHODS h.e met ods of cal clation, used in obtairning the values of entropies pzresentedd -in Table X III are summarized below I.o Tansla +tonal Component The trans.ational co..ribution t.o entropy has been derived by staistis+ical rnhods and has been expressed by the following Sacku.r Tetrode Equ,;ation (2~: S* (trans.o) R In M + 5 R in T - 2.298 (78) 2 2 2o External rotational component~ ITh.e energy possessed by a molecule as a result of its rotation is a function of its moment of inertia and its speed of rotation. The symmetry number ao, which is the number of different positions in which the molecule can be rotated with identical appearance from every point of view, has been determined to be 12 for CF4. Gelles and Pitzer (15) computed the produc-t of the principal moments of inertia for CF4 and reported t -he value tJo be 3.24 x 10-114 The following equation (21) has been presented by Hougen and Watson for the rotational con'tribution for the entropy: S (rot) - R ln T + 1 R ln (ITyIZ) 2 2 y - R In T + 267.54 (79) where the product IxIyIzrepresent's the product of the principal moments of inertia, -168 -

-169 - 3. Vibrational energy component: The vibrational contribution for entropy has been obtained as summation of the contributions of all individual degrees of freedom, each corresponding to the particular value of the fundamental frequency v, as follows: S B R eXi - ln (1-exi) (80) i-where[( where xi = 1.4388 vi/T (l1) and T is in degrees Kelvin. Details of the fundamental frequencies used and the statistical weights of the energy levels are the same as described for the heat capacity at zero pressure in the section entitled "Correlation of Data," 4. Anharmonic contribution: The anharmonic contribution for entropy was computed by an extension of the methods described in detail for the heat capacity at zero pressure in the section entitled "Correlation of Data." The final form for the entropy contribution is given below: S* (anh) = (01573) a b (82) U where the values of a, b, and U are obtained from Equations (27) through (30).

DETERMINATION OF ENTROPY BY THERMAL METHODS FOR THE IDEAL CASE The value of entropy of gaseous CF4 for the ideal case at 1 atrmiosphere pressure and any temperature T has been obtained from the following steps: Step 1: S (sa at Data have been used it. liquid) -- S (sat. liquid) 1800R at -198.32~F (261.37~R) (normal boiling point) by Selby and Aston(40) on the saturated liquid heat capacities for the computation of entropy change as follows: 261,37~R dT LS = C - _ -P T 180~R 261.37~R (24.54 _ 0.1140 + 5.160 x 10-4T) dT (83) T 180oR (where T is in ~K) Step 2: S (sat. liquid) --- S (sat. vapor) at 261.37~R at 261.37~R and 14.696 psia and 14.696 psia From Equations (43) and (53), S = _ = JPM (V-V1) C + D E D (1+ F F-T)) - T T T T T (84) where T = 261.37~R, P = 14.696 psia, B' = 2.302585093 B, and D = 2.302585093 D' The value of V = RT/P has been used for the ideal case. -170 -

-171 - Step 3: S (sat, vapor) at 261,37~R and 14.696 psia 540OR LS = S C dT - P T 261.37~R S (gas) at 540~R and 14.696 psia 540~R r * = I c = C p 261.37~R dT T (for ideal gas) + 2.37043352 x 10 54o /I (3.00559282 x lO2 T 261,37~R - 2.85660077 x 10-8T - 2.95338806 x l1011T2) dT (85) The summary of these calculations is given as follows: S of liquid at 180~: ~-Step 1 ~s -Step 2 -Step 3 R = 27.2680 cal (mole) ( K) 6,8594 20.4692 7.3355 S of ideal gas (at 540 R and 1 atm. pressure) 61.9321

APPENDIX M TABLE OF CONSTANTS AND CONVERSION FACTORS -172 -

-173 - TABLE OF CONSTANTS AND CONVERSION FACTORS Constants of the vapor pressure equation: A 20.71545389 B -2467.505285 C -4,69017025 D 6.4798076 x 10-4 E 0.770707795 F 424 Constants of the liquid density equation: al 69.56848907 a2 4.58661139 a3 36.17166615 a4 -8.05898583 Constants of the Martin-Hou equation of state: A2 -3.1553788 B2 3.2480704 x 10-3 C2 -2.1911976 A3 0.056830627 B -5.6586787 x 10-5 C3 0.052630252 A4 -3.1575738 x 10-4 A5 -15210836 x 10-6 B5 6.6533754 x 10-9 C -3.5786565 x 10-6 b 5.7104970 x 10-3 k 5.0 R 0.12193362 (cu.ft )(psia)/(lb)(~R) Constants of the heat capacity equation: c0 3.00559282 p 2.37043352 y -2.85660077 & -2.95338806 x 10-2 x 10-4 x 10-8 - 1011 x 10 Critical properties: Tc 409.50 ~R Pc 543.16 psia Vc 0.025601639 cu.ft./lb dc 39.06 lb/cu.ft. Zc= P -c = 0.27849549 R Tc

-174 - TABLE OF CONSTANTS AND CONVERSION FACTORS (CON'T) Other constants and conversion factors: R 10.7315 (cu.ft.)(psia)/(lb mole)(~R) 1.98589 Btu/(lbmole)(~R) 1.98719 thermochemical cal/(g. mole)(~R) M 88.011 hc/K 1.4388 J 0.185053 Btu/(psia)(cu.ft.) ~R ~F + 459.69 Reference conditions for the tables: H = 0 and S=O for solid CF4 at 0~R At the reference temperature, Tref = 180~R Href = 99.347077 Btu/lb Sref = 0.67950135 Btu/(lb)(~R) -ref

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