Design of molecular architectures for polymeric mesophase formation
dc.contributor.author | Pugh, Coleen | en_US |
dc.contributor.author | Liu, Hui | en_US |
dc.contributor.author | Arehart, Stephen V. | en_US |
dc.contributor.author | Narayanan, Ramasubramanian | en_US |
dc.date.accessioned | 2014-05-23T15:59:14Z | |
dc.date.available | 2014-05-23T15:59:14Z | |
dc.date.issued | 1995-07 | en_US |
dc.identifier.citation | Pugh, Coleen; Liu, Hui; Arehart, Stephen V.; Narayanan, Ramasubramanian (1995). "Design of molecular architectures for polymeric mesophase formation." Macromolecular Symposia 98(1): 293-310. <http://hdl.handle.net/2027.42/106862> | en_US |
dc.identifier.issn | 1022-1360 | en_US |
dc.identifier.issn | 1521-3900 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/106862 | |
dc.description.abstract | Based on the tendency of low molar mass liquid crystals composed of extended mesogens symmetrically disubstituted with long n ‐alkoxy substituents to exhibit smectic C mesophases, we have proposed that SCLCPs with laterally attached (vs. terminally attached) mesogens offer an ideal architecture for obtaining s C* mesophases. In particular, mesogens that typically form the desirable s C* ‐n phase sequence can be laterally attached to the polymer backbone through a chiral spacer, which should result in high values of spontaneous polarization. Not only are we using mesogens which exhibit s C* ‐n phase sequences, we are also attempting to induce smectic layering into systems which typically form nematic mesophases by using immiscible hydrocarbon/fluorocarbon components and electron‐donor‐acceptor interactions. Thus far, the thermotropic behavior of poly{5‐[[[2', 5'‐bis[(3″‐fluoro‐4″‐dimethoxyphenyl)ethynyl]benzyl]oxy]carbonyl[2.2.1]hept‐2‐ene]s and poly(5‐[[[2',5'‐bis[(3″‐fIuoro‐4″‐methoxybenzoyl)oxy]benzyl]oxy]carbonyl]‐bicyclo[2.2.1]hept‐2‐ene)s correspond to that of their low molar mass analogs. Preliminary results demonstrate that smectic layering is successfully induced in 2,5‐bis[(4'‐ n ‐alkoxybenzoyl)oxy]toluenes and polynorbornenes with laterally attached 2,5‐bis[(4'‐ n ‐alkoxybenzoyl)oxy]benzyl mesogens by terminating the n ‐alkoxy substituents with perfluorinated segments. | en_US |
dc.publisher | Wiley Periodicals, Inc. | en_US |
dc.publisher | Hüthig & Wepf Verlag | en_US |
dc.title | Design of molecular architectures for polymeric mesophase formation | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, MI 48109‐1055, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/106862/1/19950980126_ftp.pdf | |
dc.identifier.doi | 10.1002/masy.19950980126 | en_US |
dc.identifier.source | Macromolecular Symposia | en_US |
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dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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