Porous Solids Arising from Synergistic and Competing Modes of Assembly: Combining Coordination Chemistry and Covalent Bond Formation
dc.contributor.author | Dutta, Ananya | en_US |
dc.contributor.author | Koh, Kyoungmoo | en_US |
dc.contributor.author | Wong‐foy, Antek G. | en_US |
dc.contributor.author | Matzger, Adam J. | en_US |
dc.date.accessioned | 2015-04-02T15:12:22Z | |
dc.date.available | 2016-05-10T20:26:28Z | en |
dc.date.issued | 2015-03-23 | en_US |
dc.identifier.citation | Dutta, Ananya; Koh, Kyoungmoo; Wong‐foy, Antek G. ; Matzger, Adam J. (2015). "Porous Solids Arising from Synergistic and Competing Modes of Assembly: Combining Coordination Chemistry and Covalent Bond Formation." Angewandte Chemie 127(13): 4055-4059. | en_US |
dc.identifier.issn | 0044-8249 | en_US |
dc.identifier.issn | 1521-3757 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/110844 | |
dc.description.abstract | Design and synthesis of porous solids employing both reversible coordination chemistry and reversible covalent bond formation is described. The combination of two different linkage modes in a single material presents a link between two distinct classes of porous materials as exemplified by metal–organic frameworks (MOFs) and covalent organic frameworks (COFs). This strategy, in addition to being a compelling material‐discovery method, also offers a platform for developing a fundamental understanding of the factors influencing the competing modes of assembly. We also demonstrate that even temporary formation of reversible connections between components may be leveraged to make new phases thus offering design routes to polymorphic frameworks. Moreover, this approach has the striking potential of providing a rich landscape of structurally complex materials from commercially available or readily accessible feedstocks.Auf gute Zusammenarbeit: Koordinationschemie und die Bildung kovalenter Bindungen können im selben Material zur gleichen Zeit auftreten. Ein Gleichgewicht zwischen Inkubationszeit der organischen Verbindungen und Solvenszerfall/Basenbildung steuert die Konkurrenz zwischen den beiden Prozessen und bestimmt die gebildete Phase. Selbst die temporäre Bildung reversibler Verknüpfungen zwischen Komponenten lässt sich zur Herstellung neuer Phasen nutzen. | en_US |
dc.publisher | WILEY‐VCH Verlag | en_US |
dc.subject.other | Koordinationsmodi | en_US |
dc.subject.other | Kovalente organische Gerüste | en_US |
dc.subject.other | Kristall‐Engineering | en_US |
dc.subject.other | Metall‐organische Gerüste | en_US |
dc.subject.other | Mikroporöse Materialien | en_US |
dc.title | Porous Solids Arising from Synergistic and Competing Modes of Assembly: Combining Coordination Chemistry and Covalent Bond Formation | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, MI 48109 (USA) | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI 48109 (USA) | en_US |
dc.contributor.affiliationother | Current address: The Dow Chemical Company, Core R&D, Midland, MI 48674 (USA) | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/110844/1/ange_201411735_sm_miscellaneous_information.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/110844/2/4055_ftp.pdf | |
dc.identifier.doi | 10.1002/ange.201411735 | en_US |
dc.identifier.source | Angewandte Chemie | en_US |
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dc.identifier.citedreference | In this context it should be noted that in situ ligand formation from irreversible covalent coupling in tandem with coordination chemistry has been demonstrated. See for example: D. Zhao, D. Yuan, A. Yakovenko, H.‐C. Zhou, Chem. Commun. 2010, 46, 4196 – 4199. | en_US |
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dc.identifier.citedreference | As we have noted elsewhere, and in contrast to its misuse in the field, such framework materials must not be termed “polymorphs”. Polymorphs have a strict isomeric relationship that is not easily satisfied in porous material containing varying degrees of solvation. This fact motivates the use of the present term “polymorphic frameworks”. The distinction is critical because, for example, stability ordering of polymorphic framework materials is expected to be solvent dependent whereas this is forbidden for true polymorphs. In fact, the closest molecular analogy is in solvate stability where solvate inclusion engenders relative stability relationships that can depend strongly on solvent and temperature. In molecular compounds such relationships are sometimes termed “pseudopolymorphic”. Thus by this logic the different topologies of coordination polymers could be considered to be pseudopolymorphs. However, such a term is esoteric and subject to debate even within the small‐molecule community and so “polymorphic framework” is preferred. | en_US |
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dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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