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An Efficient Halogen‐Free Electrolyte for Use in Rechargeable Magnesium Batteries
dc.contributor.authorTutusaus, Oscaren_US
dc.contributor.authorMohtadi, Ranaen_US
dc.contributor.authorArthur, Timothy S.en_US
dc.contributor.authorMizuno, Fuminorien_US
dc.contributor.authorNelson, Emily G.en_US
dc.contributor.authorSevryugina, Yulia V.en_US
dc.date.accessioned2015-07-01T20:56:21Z
dc.date.available2016-07-05T17:27:58Zen
dc.date.issued2015-06-26en_US
dc.identifier.citationTutusaus, Oscar; Mohtadi, Rana; Arthur, Timothy S.; Mizuno, Fuminori; Nelson, Emily G.; Sevryugina, Yulia V. (2015). "An Efficient Halogen‐Free Electrolyte for Use in Rechargeable Magnesium Batteries." Angewandte Chemie 127(27): 8011-8015.en_US
dc.identifier.issn0044-8249en_US
dc.identifier.issn1521-3757en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/111952
dc.description.abstractUnlocking the full potential of rechargeable magnesium batteries has been partially hindered by the reliance on chloride‐based complex systems. Despite the high anodic stability of these electrolytes, they are corrosive toward metallic battery components, which reduce their practical electrochemical window. Following on our new design concept involving boron cluster anions, monocarborane CB11H12− produced the first halogen‐free, simple‐type Mg salt that is compatible with Mg metal and displays an oxidative stability surpassing that of ether solvents. Owing to its inertness and non‐corrosive nature, the Mg(CB11H12)2/tetraglyme (MMC/G4) electrolyte system permits standardized methods of high‐voltage cathode testing that uses a typical coin cell. This achievement is a turning point in the research and development of Mg electrolytes that has deep implications on realizing practical rechargeable Mg batteries.Ein einfacher und doch vielfältiger Magnesiummonocarboran(MMC)‐basierter Elektrolyt als bemerkenswertes halogenfreies und umweltschonendes System ist mit Mg‐Metall kompatibel und weist die bislang höchste anodische Stabilität auf. Wegen seiner nichtkorrodierenden Art ermöglicht der MMC‐Elektrolyt die Untersuchung von Hochspannungskathoden in einer Knopfzelle – ein wichtiger Schritt hin zu praktisch einsetzbaren wiederaufladbaren Mg‐Batterien.en_US
dc.publisherWILEY‐VCH Verlagen_US
dc.subject.otherWiederaufladbare Batterienen_US
dc.subject.otherNichtkorrodierende Elektrolyteen_US
dc.subject.otherMagnesiumen_US
dc.subject.otherElektrochemieen_US
dc.subject.otherCarboraneen_US
dc.titleAn Efficient Halogen‐Free Electrolyte for Use in Rechargeable Magnesium Batteriesen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan (USA)en_US
dc.contributor.affiliationotherDepartment of Chemistry, Texas Christian University (USA)en_US
dc.contributor.affiliationotherMaterials Research Department, Toyota Research Institute of North America, Ann Arbor, MI 48105 (USA)en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/111952/1/8011_ftp.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/111952/2/ange_201412202_sm_miscellaneous_information.pdf
dc.identifier.doi10.1002/ange.201412202en_US
dc.identifier.sourceAngewandte Chemieen_US
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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