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MOFâ 5â Polystyrene: Direct Production from Monomer, Improved Hydrolytic Stability, and Unique Guest Adsorption
dc.contributor.authorGamage, Nipuni‐dhanesha H.
dc.contributor.authorMcDonald, Kyle A.
dc.contributor.authorMatzger, Adam J.
dc.date.accessioned2016-10-17T21:18:17Z
dc.date.available2017-11-01T15:31:29Zen
dc.date.issued2016-09-19
dc.identifier.citationGamage, Nipuni‐dhanesha H. ; McDonald, Kyle A.; Matzger, Adam J. (2016). "MOFâ 5â Polystyrene: Direct Production from Monomer, Improved Hydrolytic Stability, and Unique Guest Adsorption." Angewandte Chemie 128(39): 12278-12282.
dc.identifier.issn0044-8249
dc.identifier.issn1521-3757
dc.identifier.urihttps://hdl.handle.net/2027.42/134159
dc.description.abstractAn unprecedented mode of reactivity of Zn4Oâ based metalâ organic frameworks (MOFs) offers a straightforward and powerful approach to polymerâ hybridized porous solids. The concept is illustrated with the production of MOFâ 5â polystyrene wherein polystyrene is grafted and uniformly distributed throughout MOFâ 5 crystals after heating in pure styrene for 4â 24â h. The surface area and polystyrene content of the material can be fineâ tuned by controlling the duration of heating styrene in the presence of MOFâ 5. Polystyrene grafting significantly alters the physical and chemical properties of pristine MOFâ 5, which is evident from the unique guest adsorption properties (solvatochromic dye uptake and improved CO2 capacity) as well as the dramatically improved hydrolytic stability of composite. Based on the fact that MOFâ 5 is the best studied member of the structure class, and has been produced at scale by industry, these findings can be directly leveraged for a range of current applications.Mit Polystyrol gepackte MOFs: Eine bisher unbekannte Reaktivität eines der am besten untersuchten Metallâ organischen Gerüstmaterialien, MOFâ 5, bietet Zugang zu polymerhybridisierten porösen Festkörpern. Ein MOFâ 5â Polystyrol(MOFâ 5â PS)â Komposit wurde direkt aus dem Monomer Styrol hergestellt. Das Polystyrol ist im MOFâ 5â PSâ Gerüst einheitlich verteilt und bewirkt eine erhöhte Hydrolysestabilität.
dc.publisherWiley Periodicals, Inc.
dc.subject.otherMOF-Polymer-Komposite
dc.subject.otherPolymere
dc.subject.otherHydrolysestabilität
dc.subject.otherMetall-organische Gerüstverbindungen
dc.subject.otherAdsorption
dc.titleMOFâ 5â Polystyrene: Direct Production from Monomer, Improved Hydrolytic Stability, and Unique Guest Adsorption
dc.typeArticleen_US
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbsecondlevelMaterials Science and Engineering
dc.subject.hlbsecondlevelChemical Engineering
dc.subject.hlbtoplevelEngineering
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/134159/1/ange201606926.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/134159/2/ange201606926-sup-0001-misc_information.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/134159/3/ange201606926_am.pdf
dc.identifier.doi10.1002/ange.201606926
dc.identifier.sourceAngewandte Chemie
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