Concerted Rattling in CsAg5Te3 Leading to Ultralow Thermal Conductivity and High Thermoelectric Performance

Abstract

Thermoelectric (TE) materials convert heat energy directly into electricity, and introducing new materials with high conversion efficiency is a great challenge because of the rare combination of interdependent electrical and thermal transport properties required to be present in a single material. The TE efficiency is defined by the figure of merit ZT=(S2Ï ) T/κ, where S is the Seebeck coefficient, Ï is the electrical conductivity, κ is the total thermal conductivity, and T is the absolute temperature. A new pâ type thermoelectric material, CsAg5Te3, is presented that exhibits ultralow lattice thermal conductivity (ca. 0.18â Wmâ 1â Kâ 1) and a high figure of merit of about 1.5 at 727â K. The lattice thermal conductivity is the lowest among stateâ ofâ theâ art thermoelectrics; it is attributed to a previously unrecognized phonon scattering mechanism that involves the concerted rattling of a group of Ag ions that strongly raises the Grüneisen parameters of the material.A pâ type thermoelectric material, CsAg5Te3, is presented. It exhibits ultralow thermal conductivity (Ï°tolâ 0.18â Wmâ 1â Kâ 1) and a high figure of merit (ZTâ 1.5 at 727â K). The low thermal conductivity is attributed to a previously unrecognized phonon scattering mechanism that involves the rattling of Ag ions, strongly raising the Grüneisen parameters of the material.