Atomistic Conversion Reaction Mechanism of WO3 in Secondary Ion Batteries of Li, Na, and Ca
dc.contributor.author | He, Yang | |
dc.contributor.author | Gu, Meng | |
dc.contributor.author | Xiao, Haiyan | |
dc.contributor.author | Luo, Langli | |
dc.contributor.author | Shao, Yuyan | |
dc.contributor.author | Gao, Fei | |
dc.contributor.author | Du, Yingge | |
dc.contributor.author | Mao, Scott X. | |
dc.contributor.author | Wang, Chongmin | |
dc.date.accessioned | 2017-01-06T20:46:34Z | |
dc.date.available | 2017-07-10T14:31:42Z | en |
dc.date.issued | 2016-05-17 | |
dc.identifier.citation | He, Yang; Gu, Meng; Xiao, Haiyan; Luo, Langli; Shao, Yuyan; Gao, Fei; Du, Yingge; Mao, Scott X.; Wang, Chongmin (2016). "Atomistic Conversion Reaction Mechanism of WO3 in Secondary Ion Batteries of Li, Na, and Ca." Angewandte Chemie 128(21): 6352-6355. | |
dc.identifier.issn | 0044-8249 | |
dc.identifier.issn | 1521-3757 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/134843 | |
dc.description.abstract | Intercalation and conversion are two fundamental chemical processes for battery materials in response to ion insertion. The interplay between these two chemical processes has never been directly seen and understood at atomic scale. Here, using in situ HRTEM, we captured the atomistic conversion reaction processes during Li, Na, Ca insertion into a WO3 single crystal model electrode. An intercalation step prior to conversion is explicitly revealed at atomic scale for the first time for Li, Na, Ca. Nanoscale diffraction and ab initio molecular dynamic simulations revealed that after intercalation, the inserted ion–oxygen bond formation destabilizes the transition‐metal framework which gradually shrinks, distorts and finally collapses to an amorphous W and MxO (M=Li, Na, Ca) composite structure. This study provides a full atomistic picture of the transition from intercalation to conversion, which is of essential importance for both secondary ion batteries and electrochromic devices.Das Wechselspiel zwischen Ioneninterkalation und Umwandlung des WO3‐Elektrodenmaterials wurde durch In‐situ‐TEM auf atomarer Ebene untersucht. Die Bildung von Ion‐Sauerstoff‐Bindungen destabilisiert das WO3‐Gerüst: Es schrumpft, wird verzerrt und fällt schließlich zu einer amorphen W‐ und MxO‐Verbundstruktur (M=Li, Na, Ca) zusammen. | |
dc.publisher | Wiley Periodicals, Inc. | |
dc.subject.other | WO3 | |
dc.subject.other | Interkalation | |
dc.subject.other | Ionenbatterien | |
dc.subject.other | Elektroden | |
dc.subject.other | In-situ-TEM | |
dc.title | Atomistic Conversion Reaction Mechanism of WO3 in Secondary Ion Batteries of Li, Na, and Ca | |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Materials Science and Engineering | |
dc.subject.hlbsecondlevel | Chemical Engineering | |
dc.subject.hlbsecondlevel | Chemistry | |
dc.subject.hlbtoplevel | Science | |
dc.subject.hlbtoplevel | Engineering | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/134843/1/ange201601542_am.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/134843/2/ange201601542.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/134843/3/ange201601542-sup-0001-misc_information.pdf | |
dc.identifier.doi | 10.1002/ange.201601542 | |
dc.identifier.source | Angewandte Chemie | |
dc.identifier.citedreference | W. J. Li, Z. W. Fu, Appl. Surf. Sci. 2010, 256, 2447 – 2452. | |
dc.identifier.citedreference | P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J.-M. Tarascon, Nature 2000, 407, 496 – 499. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | S.-W. Kim, N. Pereira, N. A. Chernova, F. Omenya, P. Gao, M. S. Whittingham, G. G. Amatucci, D. Su, F. Wang, ACS Nano 2015, 9, 10076 – 10084; | |
dc.identifier.citedreference | M. Langell, S. Bernasek, Phys. Rev. B 1981, 23, 1584 – 1593; | |
dc.identifier.citedreference | K. He, F. Lin, Y. Zhu, X. Yu, J. Li, R. Lin, D. Nordlund, T.-C. Weng, R. M. Richards, X.-Q. Yang, M. M. Doeff, E. A. Stach, Y. Mo, H. L. Xin, D. Su, Nano Lett. 2015, 15, 5755 – 5763; | |
dc.identifier.citedreference | F. Wang, H. C. Yu, M. H. Chen, L. Wu, N. Pereira, K. Thornton, A. Van der Ven, Y. Zhu, G. G. Amatucci, J. Graetz, Nat. Commun. 2012, 3, 1201; | |
dc.identifier.citedreference | K. He, Y. Zhou, P. Gao, L. Wang, N. Pereira, G. G. Amatucci, K.-W. Nam, X.-Q. Yang, Y. Zhu, F. Wang, D. Su, ACS Nano 2014, 8, 7251 – 7259. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | A. Nie, L. Y. Gan, Y. Cheng, H. Asayesh-Ardakani, Q. Q. Li, C. Z. Dong, R. Z. Tao, F. Mashayek, H. T. Wang, U. S. Schlogl, R. F. Kile, R. S. Yassar, ACS Nano 2013, 7, 6203 – 6211; | |
dc.identifier.citedreference | L. Zhong, X. H. Liu, G. F. Wang, S. X. Mao, J. Y. Huang, Phys. Rev. Lett. 2011, 106, 248302. | |
dc.identifier.citedreference | L. Luo, J. Wu, J. Xu, V. P. Dravid, ACS Nano 2014, 8, 11560 – 11566. | |
dc.identifier.citedreference | Q. Su, D. Xie, J. Zhang, G. Du, B. Xu, ACS Nano 2013, 7, 9115 – 9121. | |
dc.identifier.citedreference | K. E. Gregorczyk, Y. Liu, J. P. Sullivan, G. W. Rubloff, ACS Nano 2013, 7, 6354 – 6360. | |
dc.identifier.citedreference | L. Q. Mai, B. Hu, W. Chen, Y. Y. Qi, C. S. Lao, R. S. Yang, Y. Dai, Z. L. Wang, Adv. Mater. 2007, 19, 3712 – 3716. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | Q. Zhong, J. Dahn, K. Colbow, Phys. Rev. B 1992, 46, 2554 – 2560; | |
dc.identifier.citedreference | S. H. Lee, M. J. Seong, H. M. Cheong, E. Ozkan, E. C. Tracy, S. K. Deb, Solid State Ionics 2003, 156, 447 – 452; | |
dc.identifier.citedreference | K. Qi, J. Wei, M. Sun, Q. Huang, X. Li, Z. Xu, W. Wang, X. Bai, Angew. Chem. Int. Ed. 2015, 54, 15222 – 15225; Angew. Chem. 2015, 127, 15437 – 15440. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | S. H. Lee, Y. H. Kim, R. Deshpande, P. A. Parilla, E. Whitney, D. T. Gillaspie, K. M. Jones, A. H. Mahan, S. Zhang, A. C. Dillon, Adv. Mater. 2008, 20, 3627 – 3632; | |
dc.identifier.citedreference | H. Yuan, L. Jiao, J. Cao, X. Liu, M. Zhao, Y. Wang, J. Mater. Sci. Technol. 2004, 20, 41 – 45. | |
dc.identifier.citedreference | Y. Du, M. Gu, T. Varga, C. Wang, M. E. Bowden, S. A. Chambers, ACS Appl. Mater. Interfaces 2014, 6, 14253 – 14258. | |
dc.identifier.citedreference | J. Y. Huang, L. Zhong, C. M. Wang, J. P. Sullivan, W. Xu, L. Q. Zhang, S. X. Mao, N. S. Hudak, X. H. Liu, A. Subramanian, H. Fan, L. Qi, A. Kushima, J. Li, Science 2010, 330, 1515 – 1520. | |
dc.identifier.citedreference | Y. He, D. M. Piper, M. Gu, J. J. Travis, S. M. George, S. H. Lee, A. Genc, L. Pullan, J. Liu, S. X. Mao, J. G. Zhang, C. Ban, C. Wang, ACS Nano 2014, 8, 11816 – 11823. | |
dc.identifier.citedreference | W. Qiang, W. Zhenhai, J. Yeonseok, C. Jiyoung, L. Kwangyeol, L. Jinghong, Nanotechnology 2006, 17, 3116. | |
dc.identifier.citedreference | A. Devaraj, M. Gu, R. Colby, P. Yan, C. M. Wang, J. M. Zheng, J. Xiao, A. Genc, J. G. Zhang, I. Belharouak, D. Wang, K. Amine, S. Thevuthasan, Nat. Commun. 2015, 6, 8014. | |
dc.identifier.citedreference | A. Ponrouch, C. Frontera, F. Barde, M. R. Palacin, Nat. Mater. 2015, 15, 169 – 172. | |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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