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A Typical Metal‐Ion‐Responsive Color‐Tunable Emitting Insulated π‐Conjugated Polymer Film

dc.contributor.authorHosomi, Takuro
dc.contributor.authorMasai, Hiroshi
dc.contributor.authorFujihara, Tetsuaki
dc.contributor.authorTsuji, Yasushi
dc.contributor.authorTerao, Jun
dc.date.accessioned2017-06-16T20:12:24Z
dc.date.available2017-12-01T21:54:13Zen
dc.date.issued2016-10-17
dc.identifier.citationHosomi, Takuro; Masai, Hiroshi; Fujihara, Tetsuaki; Tsuji, Yasushi; Terao, Jun (2016). "A Typical Metal‐Ion‐Responsive Color‐Tunable Emitting Insulated π‐Conjugated Polymer Film." Angewandte Chemie International Edition 55(43): 13427-13431.
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.urihttps://hdl.handle.net/2027.42/137405
dc.description.abstractWe report the synthesis of an insulated π‐conjugated polymer containing 2,2′‐bipyridine moieties as metal coordination sites. Metal coordination to the polymer enabled easy and reversible tuning of the luminescent color without changes to the main chain skeleton. The permethylated α‐cyclodextrin (PM α‐CD)‐based insulation structure allowed the metalated polymers to demonstrate efficient emission even in the solid state, with identical spectral shapes to the dilute solutions. In addition, the coordination ability of the metal‐free polymer was maintained in the solid state, resulting in reversible changes in the luminescent color in response to the metal ions. The synthesized polymer is expected to be suitable for application in recyclable luminescent sensors to distinguish different metal ions.Metal‐ion sensor: An insulated π‐conjugated polymer containing metal‐binding sites was synthesized. The coordination of metal ions to these sites alters the electronic properties of the polymer considerably. As a consequence the emission wavelength of the polymer varies and the polymer acts as a sensor for metal ions.
dc.publisherWiley Periodicals, Inc.
dc.subject.otherpolymers
dc.subject.otherluminescence
dc.subject.othersupramolecular chemistry
dc.subject.otherfluorescence
dc.subject.othercyclodextrins
dc.titleA Typical Metal‐Ion‐Responsive Color‐Tunable Emitting Insulated π‐Conjugated Polymer Film
dc.typeArticleen_US
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/137405/1/anie201603160.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/137405/2/anie201603160-sup-0001-misc_information.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/137405/3/anie201603160_am.pdf
dc.identifier.doi10.1002/anie.201603160
dc.identifier.sourceAngewandte Chemie International Edition
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