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Design of 2D Porous Coordination Polymers Based on Metallacrown Units

dc.contributor.authorAtzeri, Corrado
dc.contributor.authorMarchiò, Luciano
dc.contributor.authorChow, Chun Y.
dc.contributor.authorKampf, Jeff W.
dc.contributor.authorPecoraro, Vincent L.
dc.contributor.authorTegoni, Matteo
dc.date.accessioned2017-06-16T20:16:24Z
dc.date.available2017-06-16T20:16:24Z
dc.date.issued2016-05-04
dc.identifier.citationAtzeri, Corrado; Marchiò, Luciano ; Chow, Chun Y.; Kampf, Jeff W.; Pecoraro, Vincent L.; Tegoni, Matteo (2016). "Design of 2D Porous Coordination Polymers Based on Metallacrown Units." Chemistry – A European Journal 22(19): 6482-6486.
dc.identifier.issn0947-6539
dc.identifier.issn1521-3765
dc.identifier.urihttps://hdl.handle.net/2027.42/137586
dc.description.abstractA 12‐metallacrown‐4 (MC) complex was designed and employed as the building block in the synthesis of coordination polymers, one of which is the first permanently porous MC architecture. The connection of the four‐fold symmetric MC subunits by CuII nodes led to the formation of 2D layers of metallacrowns. Channels are present in the crystalline architecture, which exhibits permanent porosity manifested in N2 and CO2 uptake capacity.Permanently porous metallacrowns: Metallacrowns have been exploited for the first time as tailored building blocks for the construction of new (porous) coordination polymers. Metallacrowns are metal‐rich complexes that have exhibited excellent properties in magnetism and luminescence. Benefiting from high‐interest metallacrown building blocks in the synthesis of MOFs can unfold a whole new class of functional materials (see figure).
dc.publisherWiley Periodicals, Inc.
dc.subject.othercoordination polymers
dc.subject.otherhydroxamic acids
dc.subject.othergas adsorption
dc.subject.otherporosity
dc.subject.othermetallacrowns
dc.titleDesign of 2D Porous Coordination Polymers Based on Metallacrown Units
dc.typeArticleen_US
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/137586/1/chem201600562-sup-0001-misc_information.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/137586/2/chem201600562.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/137586/3/chem201600562_am.pdf
dc.identifier.doi10.1002/chem.201600562
dc.identifier.sourceChemistry – A European Journal
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