Aramid Nanofiber Composites for Energy Storage Applications
dc.contributor.author | Tung, Siu On | |
dc.date.accessioned | 2017-10-05T20:27:14Z | |
dc.date.available | NO_RESTRICTION | |
dc.date.available | 2017-10-05T20:27:14Z | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/138543 | |
dc.description.abstract | Lithium ion batteries and non-aqueous redox flow batteries represent two of the most important energy storage technologies to efficient electric vehicles and power grid, which are essential to decreasing U.S. dependence on fossil fuels and sustainable economic growth. Many of the developmental roadblocks for these batteries are related to the separator, an electrically insulating layer between the cathode and anode. Lithium dendrite growth has limited the performance and threatened the safety of lithium ion batteries by piercing the separator and causing internal shorts. In non-aqueous redox flow batteries, active material crossover through microporous separators and the general lack of a suitable ion conducting membrane has led to low operating efficiencies and rapid capacity fade. Developing new separators for these batteries involve the combination of different and sometimes seemingly contradictory properties, such as high ionic conductivity, mechanical stability, thermal stability, chemical stability, and selective permeability. In this dissertation, I present work on composites made from Kevlar-drived aramid nanofibers (ANF) through rational design and fabrication techniques. For lithium ion batteries, a dendrite suppressing layer-by-layer composite of ANF and polyethylene oxide is present with goals of high ionic conductivity, improved safety and thermal stability. For non-aqueous redox flow batteries, a nanoporous ANF separator with surface polyelectrolyte modification is used to achieve high coulombic efficiencies and cycle life in practical flow cells. Finally, manufacturability of ANF based separators is addressed through a prototype machine for continuous ANF separator production and a novel separator coated on anode assembly. In combination, these studies serve as a foundation for addressing the challenges in separator engineering for lithium ion batteries and redox flow batteries. | |
dc.language.iso | en_US | |
dc.subject | Energy Storage | |
dc.subject | Redox Flow Batteries | |
dc.subject | Lithium Ion Batteries | |
dc.subject | Aramid Nanofibers | |
dc.subject | Composites | |
dc.subject | Nanotechnology | |
dc.title | Aramid Nanofiber Composites for Energy Storage Applications | |
dc.type | Thesis | en_US |
dc.description.thesisdegreename | PhD | en_US |
dc.description.thesisdegreediscipline | Macromolecular Science & Engineering | |
dc.description.thesisdegreegrantor | University of Michigan, Horace H. Rackham School of Graduate Studies | |
dc.contributor.committeemember | Kotov, Nicholas | |
dc.contributor.committeemember | Thompson, Levi Theodore | |
dc.contributor.committeemember | Barteau, Mark A | |
dc.contributor.committeemember | Laine, Richard M | |
dc.subject.hlbsecondlevel | Materials Science and Engineering | |
dc.subject.hlbtoplevel | Engineering | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/138543/1/situng_1.pdf | |
dc.identifier.orcid | 0000-0003-3998-4185 | |
dc.identifier.name-orcid | Tung, Siu on; 0000-0003-3998-4185 | en_US |
dc.owningcollname | Dissertations and Theses (Ph.D. and Master's) |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.