Now showing items 41-50 of 99
Making or Breaking Metal- Dependent Catalytic Activity: The Role of Stammers in Designed Three- Stranded Coiled Coils
(Wiley Periodicals, Inc.ACS Publications, 2020-11-09)
While many life- critical reactions would be infeasibly slow without metal cofactors, a detailed understanding of how protein structure can influence catalytic activity remains elusive. Using de novo designed three- ...
Hydrazone and Oxime Olefination via Ruthenium Alkylidenes
(Wiley, 2022-05-23)
We describe the development of an efficient method for the olefination of hydrazones and oximes. The key design approach that enables this transformation is tuning of the energy/polarity of C=N π-bonds by employing heteroatom ...
Synergetic effect of aramid nanofiber‐graphene oxide hybrid filler on the properties of rubber compounds for tire tread application
(John Wiley & Sons, Inc., 2022-04-05)
The properties of rubber compounds used in tire tread largely contribute to the overall performance of tires in vehicles. Among the various ingredients used, reinforcing fillers are known for having the most significant ...
Layered Biomimetic Composites from MXenes with Sequential Bridging
(Wiley Periodicals, Inc., 2022-03-21)
Layer‐by‐layer (LbL) assembly is a widely used technique for the self‐assembly of layered nanocomposites from clay sheets, carbon nanotubes, graphene oxide, nanoparticles, and other materials. Other approaches for fabricating ...
FRACPRED- 2D- PRM: A Fraction Prediction Algorithm- Assisted 2D Liquid Chromatography- Based Parallel Reaction Monitoring- Mass Spectrometry Approach for Measuring Low- Abundance Proteins in Human Plasma
(Wiley Periodicals, Inc., 2020-12)
Multidimensional fractionation- based enrichment methods improve the sensitivity of proteomic analysis for low- abundance proteins. However, a major limitation of conventional multidimensional proteomics is the extensive ...
Control of Stereoselectivity in Diverse Hapalindole Metabolites is Mediated by Cofactor‐Induced Combinatorial Pairing of Stig Cyclases
(Wiley Periodicals, Inc.Academic Press, 2020-05-18)
Stereospecific polycyclic core formation of hapalindoles and fischerindoles is controlled by Stig cyclases through a three‐step cascade involving Cope rearrangement, 6‐exo‐trig cyclization, and a final electrophilic aromatic ...
Semiclassical transition state theory/master equation kinetics of HO + CO: Performance evaluation
(World ScientificWiley Periodicals, Inc., 2020-12)
Previously, master equation (ME) simulations using semiclassical transition state theory (SCTST) and high‐accuracy extrapolated ab initio thermochemistry (HEAT) predicted rate constants in excellent agreement with published ...
Recent Progress in Steroid Synthesis Triggered by the Emergence of New Catalytic Methods
(Wiley‐VCH, 2020-02-21)
β‐Mannosylation through O‐Alkylation of Anomeric Cesium Alkoxides: Mechanistic Studies and Synthesis of the Hexasaccharide Core of Complex Fucosylated N‐Linked Glycans
(Wiley Periodicals, Inc.CRC Press, 2020-04-23)
Mass Activated Droplet Sorting (MADS) Enables Highâ Throughput Screening of Enzymatic Reactions at Nanoliter Scale
(Wiley Periodicals, Inc., 2020-03-09)
Microfluidic droplet sorting enables the highâ throughput screening and selection of waterâ inâ oil microreactors at speeds and volumes unparalleled by traditional wellâ plate approaches. Most such systems sort using ...