Now showing items 401-410 of 466
Carbon-13 and silicon-29 NMR spectra of some [tris(trimethylsilyl)methyl]-substituted silanes and related compounds
(Elsevier, 1982-08-24)
Fourier Transform 13C and 29Si NMR spectra are reported for series of [tris-(trimethylsilyl)methyl] dimethylsilanes, [tris(trimethylsilyl)methyl] diphenylsilanes, and for related compounds. Analysis of chemical shift values ...
A colorimetric assay for chemical heparin in plasma
(Elsevier, 1982-07-15)
A simple, rapid colorimetric assay for plasma heparin is presented. The assay employs the metachromasia of azure A when heparin is added. It is useful for 0 to 10 units/ml and does not depend on heparin's anticoagulant ...
Stereoselective acyclic synthesis via allylmetals: Threo vicinal diols from both - and -[gamma]-alkoxyallyltins and aldehydes
(Elsevier, 1987)
Both - and -[gamma]-alkoxyallyltins stereoselectively add to aldehydes in the presence of BF3[middle dot]OEt2 at -78[deg]C in CH2Cl2 to produce the threo (or syn) vicinal diol monoalkyl ether unit.
Rapid and efficient preparation of free amino acids from strong acid salts on columns of crosslinked poly-4-vinylpyridine
(Elsevier, 1982-05-15)
Acidic and neutral amino acids were recovered from their strong acid salts or from large excesses of strong acids by passage through columns of crosslinked poly-4-vinylpyridine. Basic amino acids eluted as the monoacid ...
Assignment of the chemical shift values of N-trityl -homoserine lactone
(Elsevier, 1988)
This paper reports the correct assignment of all chemical shift values of N-trityl -homoserine lactone based on the 1H-nmr spectra of N-trityl-2S, 3R-[3-2H]- and 2S, 3S-[2,3-2H2]homoserine lactone.
Transmetallation of n-(trialkylstannyl)methylimines. A new method for the generation and cycloaddition of 2-azaallyl anions.
(Elsevier, 1988)
Transmetallation of imines 1 at -78[deg] with RLi provided 2-azaallyl anions 2, which readily undergo cycloaddition with olefinic anionophiles, providing pyrrolidines. Of particular note is the generation of unstabilized ...
Postnatal development of ACTH and [alpha]-MSH in the medulla oblongata of rat: [alpha]-MSH is the predominant peptide
(Elsevier, 1985)
ACTH and [alpha]-MSH levels were measured by radioimmunoassays in extracts of the caudal medulla oblongata of developing rats on postnatal (P) days 1-42 at 7 day intervals, and in adult rats. From P1 to adulthood, ACTH ...