Now showing items 3441-3450 of 3524
Effects of stereoisomeric structure and bond location on the ignition and reaction pathways of hexenes
(Wiley Periodicals, Inc., 2021-02)
The current work presents new experimental autoignition and speciation data on the two cis- hexene isomers: cis- 2- hexene and cis- 3- hexene. The new data provide insights on the effects of carbon- carbon double ...
Frontispiz: Diverse Nanoassemblies of Graphene Quantum Dots and Their Mineralogical Counterparts
(Wiley Periodicals, Inc., 2020-05-25)
A novel method of high‐purity extracellular vesicle enrichment from microliter‐scale human serum for proteomic analysis
(Endotext, MDText.com, Inc.Wiley Periodicals, Inc., 2021-02)
We have developed a rapid, low‐cost, and simple separation strategy to separate extracellular vesicles (EVs) from a small amount of serum (i.e.,<100 μL) with minimal contamination by serum proteins and lipoprotein particles ...
Achieving Balanced Energetics through Cocrystallization
(, 2nd ed.Wiley Periodicals, Inc., 2019-11-25)
Achieving energetic materials with a balanced ratio of oxidant to fuel is a challenge that has been difficult to meet through molecular synthesis. The alternative approach, composite formulation, fails to achieve intimate ...
The pH- Induced Selectivity Between Cysteine or Histidine Coordinated Heme in an Artificial α- Helical Metalloprotein
(SpringerWiley Periodicals, Inc., 2021-02-19)
De Novo metalloprotein design assesses the relationship between metal active site architecture and catalytic reactivity. Herein, we use an α- helical scaffold to control the iron coordination geometry when a heme cofactor ...
Making or Breaking Metal- Dependent Catalytic Activity: The Role of Stammers in Designed Three- Stranded Coiled Coils
(Wiley Periodicals, Inc.ACS Publications, 2020-11-09)
While many life- critical reactions would be infeasibly slow without metal cofactors, a detailed understanding of how protein structure can influence catalytic activity remains elusive. Using de novo designed three- ...
Hydrazone and Oxime Olefination via Ruthenium Alkylidenes
(Wiley, 2022-05-23)
We describe the development of an efficient method for the olefination of hydrazones and oximes. The key design approach that enables this transformation is tuning of the energy/polarity of C=N π-bonds by employing heteroatom ...
Synergetic effect of aramid nanofiber‐graphene oxide hybrid filler on the properties of rubber compounds for tire tread application
(John Wiley & Sons, Inc., 2022-04-05)
The properties of rubber compounds used in tire tread largely contribute to the overall performance of tires in vehicles. Among the various ingredients used, reinforcing fillers are known for having the most significant ...
Layered Biomimetic Composites from MXenes with Sequential Bridging
(Wiley Periodicals, Inc., 2022-03-21)
Layer‐by‐layer (LbL) assembly is a widely used technique for the self‐assembly of layered nanocomposites from clay sheets, carbon nanotubes, graphene oxide, nanoparticles, and other materials. Other approaches for fabricating ...
CE‐MS with electrokinetic supercharging and application to determination of neurotransmitters
(Wiley Periodicals, Inc., 2019-11)
Electrokinetic supercharging (EKS) is known as one of the most effective online electrophoretic preconcentration techniques, though pairing with it with mass spectrometry has presented challenges. Here, EKS is successfully ...