Now showing items 731-740 of 804
On the Interpretation and Correlation of High‐Temperature Ignition Delays in Reactors with Varying Thermodynamic Conditions
(Marcel DekkerWiley Periodicals, Inc., 2018-06)
Ignition delay time (IDT) is a useful global metric for fuel performance screening and a major target for kinetic modeling. Measurements of IDT are conceptually straightforward; however, interpretation could be complicated, ...
Preparation of polyfunctional diorganomercurials and their transmetallation to diorganozincs. Applications to the preparation of optically active secon
(Elsevier, 1992-10-13)
Two new methods of preparation of functionalized diorganomercurials have been developed. The first method involves a substitution reaction of (ICH2 Their transmetallation with zinc dust (toluene, 80[deg]C, 3-5 h) affords ...
Defect interactions on solid surfaces
(Elsevier, 1993-03-10)
A unified approach to the calculation of the elastic interaction between defects on a surface that describe, for example, steps, islands, and stress domains is presented. This is accomplished by determining the spatial ...
Hydrodesulfurization over model sulfide cluster-derived catalysts
(Elsevier, 1991)
There is growing interest in the use of organometallic clusters as precursors to model heterogeneous catalysts. This interest is partially derived from the expectation that "solid-state metal complex catalysts" will be ...
A complete general valence force field for secondary chlorides
(Elsevier, 1973-12)
A general valence force field for secondary chlorides has been refined which includes torsional force constants based on assignments of low frequency modes in model compounds. This force field also incorporates force ...
Vibrational analysis of crystalline diketopiperazine--I. Raman and i.r. spectra
(Elsevier, 1984)
Raman and i.r. spectra have been obtained of diketopiperazine and five of its isotopic derivatives: (CONDCH2)2, (CONHCD2)2, (CONDCD2)2, (13CONHCH2)2 and (13CONDCH2)2. In addition to solution spectra and powder spectra at ...
Synthesis of some functional germanium heterocycles: Germirenes and derivatives of germacyclopentene
(Elsevier, 1972-07-16)
The germirene, 1,1,4,4-tetraiodo-2,3,5,6-tetramethyl-1,4-digerma-2,5-cyclohexadiene, (VI), was prepared from germanium diiodide and 2-butyne. Reduction with lithium aluminum hydride replaces the iodine with hydrogen. The ...
Assignment of torsion and low frequency bending vibrations of secondary chlorides
(Elsevier, 1973-10)
Far infrared and Raman spectra of 2-chloropropane, 2-chlorobutane and dl- and meso-2,4-dichloropentane have been analyzed in order to assign the torsional force constants in the valence force field for secondary chlorides. ...
Recent advances in enhancing the sensitivity of electrophoresis and electrochromatography in capillaries and microchips (2014–2016)
(Wiley Periodicals, Inc., 2017-01)