Now showing items 51-60 of 204
Preparation of highly functionalized 3,4-disubstituted cyclobutene-1,2-diones using functionalized zinc-copper organometallics
(Elsevier, 1992)
The selective substitution reactions of the zinc-copper reagents with 3,4-dichlorocyclobutene-1,2-dione 2 allows to prepare a variety of new functionalized symmetrical and mixed 2,4-disubstituted cyclobutene-1,2-diones of ...
Monte Carlo simulation of the adsorption of co on pt(111): thermodynamic considerations for the surface configuration of adsorbed species
(Elsevier, 1991-02-02)
We have developed a "two-site" lattice gas model which provides a theoretical framework for understanding adsorption equilibrium in systems for which the potential energy surface is inherently heterogeneous in terms of ...
Synthesis and characterization of cage and bicyclic silsesquioxanes via dehydration of silanols
(John Wiley & Sons, Ltd., 1999-04)
Synthesis of cage and ladder silsesquioxanes by the dehydration of silanols using dicyclohexylcarbodiimide (DCC) is described. The reaction of 1,3-dicyclohexyldisiloxane-1,1,3,3-tetraol with DCC gave octa(cyclohexylsilsesquioxane) ...
cis-2-Tri-n-butylstannylvinyl cuprates: a new synthon for the cis-1,2-ethene dianion
(Elsevier, 1992-01-01)
Conjugate additions of lower order and higher order cyano cuprates containing the cis-2-tri-n-butylstannylvinyl group to cycloalkenones have been studied. The higher order cuprates were more reactive towards hindered enones ...
The reaction of sulfur with dilithio compounds. The syntheses and structures of phenanthro [1, 10-cd]-1,2-dithiole and phenanthro[4,5-cde] [1,2]dithiin
(VCH Publishers, Inc.Wiley Periodiocals, Inc., 1994-04)
The sequential reaction of selected polycyclic aromatic hydrocarbons with butyllithium/TMEDA/hexane and sulfur allows preparation of ring-fused dithiins, dithioles, and thiophenes. In this manner, phenanthrene has been ...
Vacancy Generation During Grain Boundary Migration
(Kluwer Academic Publishers; Springer Science+Business Media, 1998-12)
We present a molecular dynamics simulation study of vacancy generation and emission from grain boundaries during curvature-driven grain boundary migration. The U-shaped half-loop bicrystal geometry is employed in order to ...
A new preparation of highly functionaized aromatic and heteroaromatic zinc and copper organometallics
(Elsevier, 1990)
Functionalized aromatic iodides possessing an ester, cyano, chloride or keto group can be converted to arylzinc iodides by reaction with zinc in DMF or DMAC. After transmetallation to the corresponding arylcopper, they ...
Thermodynamics of ammonium halopallidates I. Heat capacity and thermodynamic properties of (NH4)2PdCl6 at temperatures from 6 K to 350 K
(Elsevier, 1992-09)
The heat capacity of ammonium hexachloropallidate (NH4)2PdCl6 was measured at temperatures from 6 K to 350 K by adiabatic calorimetry. The heat-capacity curve is smooth and without anomalies. It rises rapidly from T0 to T ...
Incubation in cyclohexene decomposition at high temperatures
(John Wiley & Sons, Inc., 1990-02)
A detailed master equation simulation has been carried out for the thermal unimolecular decomposition of C 6 H 10 in a shock tube. At the highest temperatures studied experimentally [J. H. Kiefer and J. N. Shah, J. Phys. ...
SN2' Substitutions of 1,3-Dichloropropenes with the Functionalized Copper-Zinc Reagents RCu(CN)ZnX
(Elsevier, 1990)
The addition of benzenesulfenyl (or benzeneselenyl) chlorides to propargylic chlorides affords regio- and stereospecifically (E)-1,3-dichloro-2-phenylsulfenyl (or phenylselenyl) propenes (2a-c). These new reagents were ...