Now showing items 741-750 of 758
Effects of stereoisomeric structure and bond location on the ignition and reaction pathways of hexenes
(Wiley Periodicals, Inc., 2021-02)
The current work presents new experimental autoignition and speciation data on the two cis- hexene isomers: cis- 2- hexene and cis- 3- hexene. The new data provide insights on the effects of carbon- carbon double ...
FRACPRED- 2D- PRM: A Fraction Prediction Algorithm- Assisted 2D Liquid Chromatography- Based Parallel Reaction Monitoring- Mass Spectrometry Approach for Measuring Low- Abundance Proteins in Human Plasma
(Wiley Periodicals, Inc., 2020-12)
Multidimensional fractionation- based enrichment methods improve the sensitivity of proteomic analysis for low- abundance proteins. However, a major limitation of conventional multidimensional proteomics is the extensive ...
Semiclassical transition state theory/master equation kinetics of HO + CO: Performance evaluation
(World ScientificWiley Periodicals, Inc., 2020-12)
Previously, master equation (ME) simulations using semiclassical transition state theory (SCTST) and high‐accuracy extrapolated ab initio thermochemistry (HEAT) predicted rate constants in excellent agreement with published ...
Recent Progress in Steroid Synthesis Triggered by the Emergence of New Catalytic Methods
(Wiley‐VCH, 2020-02-21)
β‐Mannosylation through O‐Alkylation of Anomeric Cesium Alkoxides: Mechanistic Studies and Synthesis of the Hexasaccharide Core of Complex Fucosylated N‐Linked Glycans
(Wiley Periodicals, Inc.CRC Press, 2020-04-23)
Glassy Carbon low-temperature thermodynamic properties
(Elsevier, 1970-11)
The heat capacity of Glassy Carbon was measured by adiabatic calorimetry from 5 to 350 K and has no transitions or thermal anomalies. It parallels that of pyrolytic graphite annealed at 2600 [deg]C in showing an approximate ...
Fluoride catalyzed rearrangements of polysilsesquioxanes, mixed Me, vinyl T 8 , Me, vinyl T 10 and T 12 cages
(John Wiley & Sons, Ltd., 2010-08)
Insoluble mixtures of polyvinylsilsesquioxane, -(vinylSiO 1.5 ) n - PVS, and polymethylsilsesquioxanes, -(MeSiO 1.5 ) n - PMS, in THF at ambient when treated with catalytic amounts (1–5 mol%) of fluoride ion introduced ...
Rate constant of the reaction of chlorine atoms with methanol over the temperature range 291–475 K
(Wiley Subscription Services, Inc., A Wiley Company, 2010-02)
The rate constant of the reaction Cl + CH 3 OH ( k 1 ) has been measured in 500–950 Torr of N 2 over the temperature range 291–475 K. The rate constant determination was carried out using the relative rate technique with ...
Atmospheric chemistry of cyclohexanone: UV spectrum and kinetics of reaction with chlorine atoms
(Wiley Subscription Services, Inc., A Wiley Company, 2008-05)
Absolute and relative rate techniques were used to study the reactivity of Cl atoms with cyclohexanone in 6 Torr of argon or 800–950 Torr of N 2 at 295 ± 2 K. The absolute rate experiments gave k (Cl + cyclohexanone) = ...
Kinetics of the gas-phase reactions of chlorine atoms with CH 2 F 2 , CH 3 CCl 3 , and CF 3 CFH 2 over the temperature range 253–553 K
(Wiley Subscription Services, Inc., A Wiley Company, 2009-06)
Relative rate techniques were used to study the title reactions in 930–1200 mbar of N 2 diluent. The reaction rate coefficients measured in the present work are summarized by the expressions k (Cl + CH 2 F 2 ) = 1.19 × ...