Now showing items 1-10 of 13
Vibrational analysis of crystalline diketopiperazine--II. Normal mode calculations
(Elsevier, 1984)
Based on our Raman and i.r. [1] data and assignments for DKP and five of its isotopic derivatives, we have refined an intramolecular force field in a non-redundant basis. This analysis shows that the cis peptide group may ...
Thermophysics of metal alkanoates IV. Heat capacities and thermodynamic properties of potassium 2-methylpropanoate
(Elsevier, 1984-02)
The molar heat capacity of potassium 2-methylpropanoate, (CH3)2CHCO2K, has been measured between 8 and 350 K by adiabatic calorimetry, and found to be normal. The corresponding thermodynamic functions have been calculated. ...
Thermophysics of metal alkanoates III. Heat capacities and thermodynamic properties of lithium and potassium propanoates
(Elsevier, 1984-01)
At 298.15 K, the values of Cp, m/R, Smo/R, {Hmo - Hmo(0)}/R, and {Gmo - Hmo(0)}/RT ar 15.58, 17.13, 2588.6 K, and -8.445 for CH3CH2CO2Li(cr), and 17.30, 21.16, 3134.0 K, and -10.647 for CH3CH2CO2K(cr). The energetics and ...
Preparation of 1-deuterioaldehydes via tub use of diisobutylaluminum deuteride (DIBAL-D)
(Elsevier, 1984)
Deuterioaldehydes, essential precursors In the preparation of chiral primary deuterioalcohols, have been prepared in yields ranging from 55-75% via reduction of methyl and ethyl esters at -78[deg]C with diisobutylaluminun ...
Hydroformylation as a simple and efficient one carbon homologation of homoallylic alcohols. Synthesis of prelog-djerassi lactone.
(Elsevier, 1984)
A hydroformylation oxidation sequence is described for the efficient conversion of homoallylic alcohols to [delta]-lactones. The methodology is applied to the synthesis of Prelog-Djerassi lactone.
Synthesis of N-acetyllactosamine containing a -[6-3H]galactopyranosyl group
(Elsevier, 1984-07-01)
A simple and convenient method for the introduction of radiolabel onto C-6' of N-acetyllactosamine is described. 1-N-Benzyl-3-O-[beta]--galactopyranosyl--arabinosylamine (1) was synthesized from 3-O-[beta]--galactopyrano ...
Stereospecific synthesis of - and -1 alkoxy-1,3-butadienes
(Elsevier, 1984)
A stereospecific, highly efficient, generally applicable synthesis of - and -1-alkoxy-1,3-butadienes involving dehydrative decarboxylations of 4,5-unsaturated-2-alkoxy-3-hydroxy-carboxylic acids is described.
The reaction of pyrite with diphenyl ether
(Elsevier, 1984)
Diphenyl ether is converted into diphenyl sulfide (largely), dibenzofuran, phenoxybiphenyls, diphenoxybiphenyls, and several other sulfur- containing compounds by reaction with pyrite at 350-360[deg].
Gold-titania interactions: Temperature dependence of surface area and crystallinity of TiO2 and gold dispersion
(Elsevier, 1984-05)
The influence of temperature on the BET surface area, crystallinity, and anatase/rutile phase transformation of blank TiO2 and Au/TiO2 catalysts is studied. Presence of gold delays the recrystallization of anatase and the ...
Comment on enhanced Raman scattering from adsorbates on semiconductor surfaces
(Elsevier, 1984-11-02)
A recently published model of surface enhanced Raman scattering from adsorbed molecules on semiconductor surfaces is compared to our experimental results for amorphous carbon on PbTe. The model fails to account for the ...