Now showing items 1-10 of 22
Interaction of five -mannose-specific lectins with a series of synthetic branched trisaccharides
(Elsevier, 1991-06-25)
The interaction of a series of synthetic, branched trisaccharides with five -mannose-specific lectins was studied by precipitation-inhibition assay. The branched methyl [alpha]--mannotrioside, [alpha]--Manp-(1-->3)-[[ ...
Thermodynamics of iron sulfides I. Heat capacity and thermodynamic properties of Fe9S10 at temperatures from 5 K to 740 K
(Elsevier, 1991-03)
Measurements of the heat capacity of Fe9S10 over the temperature range 5 K to 740 K reveal a first-order structural transition at 495 K and two higher-order transitions with maxima at 534 K and 591 K. The last two are of ...
Heating characteristics and atomic emission waveforms for glow discharge ion bombardment furnaces
(Elsevier, 1991)
Ion bombardment of a graphite cathode in a glow discharge plasma is used to heat the cathode to temperatures suitable for the vaporization of solution residues from the cathode surface. Two low-mass cathode configurations ...
Selective multiple methylene insertion reactions mediated by iodomethylzine iodide: Mechanistic considerations and synthetic applications
(Elsevier, 1991-04-15)
The reaction of alkynylcoppers 1 with an excess of iodomethylzinc iodide selectively furnishes the quadruple methylene insertion copper organometallics 2 in fair to good yields. The mechanism of the reaction has been ...
Non-biomimetic route to deoxyadenosine adducts of carcinogenic polycyclic aromatic hydrocarbons
(Elsevier, 1991-10-21)
Aminotriols are prepared by direct aminolysis of the diol epoxides of polycyclic aromatic hydrocarbons, providing a substantial improvement over literature methods. The condensation of aminotriols with 6-halopurine ...
Excitatory amino acidergic pathways and receptors in the basal ganglia
(Springer-Verlag, 1991-10)
The striatum receives the majority of excitatory amino acidergic input to the basal ganglia from neocortical and allocortical sources. The subthalamic nucleus and the substantia nigra also receive excitatory amino acidergic ...
Highly stereoselective preparation of nitro olefins and nitro dienes by the addition-elimination of copper-zinc organometallics to [beta]-alkylthio and [beta]-phenylsulfonyl nitro olefins
(Elsevier, 1991-01-21)
The addition-elimination of copper-zinc organometallics RCu(CN)ZnX to (E)-1-nitro-2-phenylsulfonyl ethylene 2a gave highly functionalized pure (E) nitro olefins and stereoselectively (1E, 3E) and (1E, 3Z)-1-nitrodienes in ...
The selectivity of hydrazine oxidation on a polycrystalline rhodium surface
(Elsevier, 1991-11-02)
The surface reactions of coadsorbed hydrazine and atomic oxygen have been examined by means of temperature-programmed reaction spectroscopy (TPRS) on a clean polycrystalline rhodium surface over the 90 to 1450 K temperature ...
Monte Carlo simulation of the adsorption of co on pt(111): thermodynamic considerations for the surface configuration of adsorbed species
(Elsevier, 1991-02-02)
We have developed a "two-site" lattice gas model which provides a theoretical framework for understanding adsorption equilibrium in systems for which the potential energy surface is inherently heterogeneous in terms of ...
Structural and kinetic studies in propene oxidation over Sb oxide dispersed on TiO2
(Elsevier, 1991-02)
Antimony oxide dispersed on TiO2 was characterized using FTIR, Raman, and Auger spectroscopies as well as XRD. They indicate that the electronic environment about Sb is perturbed at low concentration suggesting that the ...