Now showing items 1-10 of 31
Studies on morpholinosphingolipids: Potent inhibitors of glucosylceramide synthase
(Elsevier, 1994-04-25)
Synthetic 1-morpholino-1-deoxyceramides were designed to inhibit glucosylceramide synthase. The most potent inhibitor 2a possesses the unnatural R,R-configuration of D-threo-sphingosine.
Iodine-promoted decomposition of 1-aryl-3,3-dialkyltriazenes: A mild method for the synthesis of aryl iodides
(Elsevier, 1994-08-01)
Iodine promoted decomposition of 1-aryl-3,3-dialkyltriazenes in organic solvents is shown to give high yields of the corresponding aryl iodides under extremely mild conditions. The presence of iodine greatly accelerates ...
Synthesis and assignments of regioisomeric cyanoimidazole esters
(Elsevier, 1994-02-28)
Regioassignments of ethyl cyanoimidazolecarboxylates have been performed by the nuclear Overhauser effect(NOE) studies on the regioisomeric monocyanoimidazoles obtained by the hydrolysis of the esters followed by ...
Synthesis of (+/-)tylophorine by the intramolecular cycloaddition of an azide with an [omega]-chloroalkene
(Elsevier, 1994)
Cyclization of (Z)-1-(2-chloromethyl)phenyl-5-azidopent-1-ene 10 in benzene at 120[deg]C followed by treatment with sodium borohydride produced 1,2,3,5,10,10a-hexahydropyrrolo[1,2-b]isoquinoline 11 in 71% yield. A similar ...
Thermodynamics of alkali alkanoates X. Heat capacities and thermodynamic properties of lithium methanoate and lithium ethanoate at temperatures from [approximate] 5 K to 580 K
(Elsevier, 1994-12)
Heat capacities of lithium methanoate and ethanoate (CA Registry numbers [556-63-8] and [546-89-4]) have been measured by adiabatic intermittent-heating equilibrium calorimetry from temperatures T near 5 K to 350 K and by ...
Hydrazine adsorption and decomposition on the GaAs(100)-c(8 x 2) surface
(Elsevier, 1994-12-20)
Temperature programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), and high resolution electron energy loss spectroscopy (HREELS) have been used to study the decomposition mechanism of hydrazine (N2H4) on the ...
An evaluation of the rotational barrier about the B---N bond of 1-aminoborepins
(Elsevier, 1994-04-05)
13C NMR spectroscopy has been used to determined the barriers to rotation about the B---N bonds of 1-(N-benzyl-N-methylamino)borepin and 1-(N-benzyl-N-methylamino)-4,5-dihydroborepin as 18 and 19.8 kcal mol-1, respectively. ...
Living ring opening metathesis polymerization of mesogenic norbornene derivatives
(Wiley Periodicals, Inc.Hüthig & Wepf Verlag, 1994-01)
A new class of SCLCPs was prepared by polymerizing mesogenic norbornene derivatives using Mo(CHCMe 2 R)(N‐2,6‐C 6 H 3 ‐ i ‐Pr 2 )(O‐ t ‐Bu) 2 (R = CH 3 or Ph). Monomers based on norbornene ring systems were chosen because ...
The reaction of sulfur with dilithio compounds. The syntheses and structures of phenanthro [1, 10-cd]-1,2-dithiole and phenanthro[4,5-cde] [1,2]dithiin
(VCH Publishers, Inc.Wiley Periodiocals, Inc., 1994-04)
The sequential reaction of selected polycyclic aromatic hydrocarbons with butyllithium/TMEDA/hexane and sulfur allows preparation of ring-fused dithiins, dithioles, and thiophenes. In this manner, phenanthrene has been ...
The structure and function of supported molybdenum nitride hydrodenitrogenation catalysts
(Elsevier, 1994-03)
A series of [gamma]-Al2O3 supported Mo nitrides were prepared by the temperature programmed reaction of supported molybdates with NH3. Several loadings, heating rates, and space velocities were employed in an attempt to ...