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Rapid Guest Exchange and Ultraâ Low Surface Tension Solvents Optimize Metalâ Organic Framework Activation
dc.contributor.authorMa, Jialiu
dc.contributor.authorKalenak, Andre P.
dc.contributor.authorWong‐foy, Antek G.
dc.contributor.authorMatzger, Adam J.
dc.date.accessioned2017-12-15T16:47:09Z
dc.date.available2019-01-07T18:34:36Zen
dc.date.issued2017-11-13
dc.identifier.citationMa, Jialiu; Kalenak, Andre P.; Wong‐foy, Antek G. ; Matzger, Adam J. (2017). "Rapid Guest Exchange and Ultraâ Low Surface Tension Solvents Optimize Metalâ Organic Framework Activation." Angewandte Chemie 129(46): 14810-14813.
dc.identifier.issn0044-8249
dc.identifier.issn1521-3757
dc.identifier.urihttps://hdl.handle.net/2027.42/139930
dc.description.abstractExploratory research into the critical steps in metalâ organic framework (MOF) activation involving solvent exchange and solvent evacuation are reported. It is discovered that solvent exchange kinetics are extremely fast, and minutes rather days are appropriate for solvent exchange in many MOFs. It is also demonstrated that choice of a very low surface tension solvent is critical in successfully activating challenging MOFs. MOFs that have failed to be activated previously can achieve predicted surface areas provided that lower surface tension solvents, such as nâ hexane and perfluoropentane, are applied. The insights herein aid in the efficient activation of MOFs in both laboratory and industrial settings and provide best practices for avoiding structural collapse.Ein Wechsel des Lösungsmittels mit anschlieà ender Evakuierung aktiviert Metallâ organische Gerüste (MOFs), maximiert ihre Oberflächen und verbessert ihre Eigenschaften bei der Gasspeicherung. Wenn der Austausch schnell erfolgt und Lösungsmittel mit sehr niedriger Oberflächenspannung verwendet werden, bleibt die Porosität erhalten, und die MOFâ Struktur fällt nicht in sich zusammen.
dc.publisherWiley Periodicals, Inc.
dc.subject.otherOberflächenspannung
dc.subject.otherLösungsmittel
dc.subject.otherMikroporöse Materialien
dc.subject.otherMetall-organische Gerüststrukturen
dc.subject.otherAktivierung
dc.titleRapid Guest Exchange and Ultraâ Low Surface Tension Solvents Optimize Metalâ Organic Framework Activation
dc.typeArticleen_US
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemical Engineering
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbsecondlevelMaterials Science and Engineering
dc.subject.hlbtoplevelEngineering
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/139930/1/ange201709187.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/139930/2/ange201709187_am.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/139930/3/ange201709187-sup-0001-misc_information.pdf
dc.identifier.doi10.1002/ange.201709187
dc.identifier.sourceAngewandte Chemie
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