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Enzymatic glyceride synthesis in a foam reactor
dc.contributor.authorYeh, Yu‐chih
dc.contributor.authorGulari, Erdogan
dc.date.accessioned2018-02-05T16:33:39Z
dc.date.available2018-02-05T16:33:39Z
dc.date.issued1998-05
dc.identifier.citationYeh, Yu‐chih ; Gulari, Erdogan (1998). "Enzymatic glyceride synthesis in a foam reactor." Journal of the American Oil Chemists’ Society 75(5): 643-650.
dc.identifier.issn0003-021X
dc.identifier.issn1558-9331
dc.identifier.urihttps://hdl.handle.net/2027.42/141443
dc.description.abstractWe report the results of our study on Rhizomucor miehei lipaseâ catalyzed lauric acidâ glycerol esterification in a foam reactor. A satisfactory yield of glyceride synthesis can be achieved with an unusually high initial water content (50% w/w). We found that product formation could be regulated by controlling foaming. Foaming was a function of the air flow rate, reaction temperature, pH value, ionic strength, and substrate molar ratio. Monolaurin and dilaurin, which constituted nearly 80% of the total yield, were the two dominant products in this reaction; trilaurin was also formed at the initial stages of the reaction. A study of pH and ionic strength effects on an independent basis revealed that they affect the interfacial mechanism in different manners. On varying the ratio of lauric acid and glycerol, only a slight change in the degree of conversion was detected and the consumption rate of fatty acid was approximately the same.
dc.publisherSpringer-Verlag
dc.publisherWiley Periodicals, Inc.
dc.subject.othersubstrate inhibition
dc.subject.otherEsterification
dc.subject.otherfoams
dc.subject.otherglyceride synthesis
dc.subject.otherHPLC
dc.subject.otherlipase
dc.subject.otherRhizomucor miehei
dc.titleEnzymatic glyceride synthesis in a foam reactor
dc.typeArticleen_US
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/141443/1/aocs0643.pdf
dc.identifier.doi10.1007/s11746-998-0078-8
dc.identifier.sourceJournal of the American Oil Chemists’ Society
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dc.identifier.citedreferenceBerger, M., K. Laumen, and M.P. Schneider, Enzymatic Esterification of Glycerol I. Lipaseâ Catalyzed Synthesis of Regioisomerically Pure 1,3â snâ Diacylglycerols, Ibid. 68: 955 â 960 ( 1992 ).
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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