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The Influence of Chemical Modification on Linker Rotational Dynamics in Metal–Organic Frameworks
dc.contributor.authorDamron, Joshua T.
dc.contributor.authorMa, Jialiu
dc.contributor.authorKurz, Ricardo
dc.contributor.authorSaalwächter, Kay
dc.contributor.authorMatzger, Adam J.
dc.contributor.authorRamamoorthy, Ayyalusamy
dc.date.accessioned2018-07-13T15:46:57Z
dc.date.available2019-09-04T20:15:39Zen
dc.date.issued2018-07-09
dc.identifier.citationDamron, Joshua T.; Ma, Jialiu; Kurz, Ricardo; Saalwächter, Kay ; Matzger, Adam J.; Ramamoorthy, Ayyalusamy (2018). "The Influence of Chemical Modification on Linker Rotational Dynamics in Metal–Organic Frameworks." Angewandte Chemie International Edition 57(28): 8678-8681.
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.urihttps://hdl.handle.net/2027.42/144616
dc.description.abstractThe robust synthetic flexibility of metal–organic frameworks (MOFs) offers a promising class of tailorable materials, for which the ability to tune specific physicochemical properties is highly desired. This is achievable only through a thorough description of the consequences for chemical manipulations both in structure and dynamics. Magic angle spinning solid‐state NMR spectroscopy offers many modalities in this pursuit, particularly for dynamic studies. Herein, we employ a separated‐local‐field NMR approach to show how specific intraframework chemical modifications to MOF UiO‐66 heavily modulate the dynamic evolution of the organic ring moiety over several orders of magnitude.Intraframework ring rotations in metal–organic frameworks have been sensitively detected by dipolar dephasing over the rotor period in magic angle spinning solid‐state NMR experiments. Information on the dynamics within MOFs is important, because the rate of rotational motions of linkers affects sorption and separation properties of MOFs.
dc.publisherBlackwell Science Ltd
dc.publisherWiley Periodicals, Inc.
dc.subject.otherdynamics
dc.subject.otherNMR spectroscopy
dc.subject.othermetal–organic frameworks
dc.subject.othermicroporous materials
dc.subject.otherdensity functional theory
dc.titleThe Influence of Chemical Modification on Linker Rotational Dynamics in Metal–Organic Frameworks
dc.typeArticleen_US
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/144616/1/anie201805004.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/144616/2/anie201805004-sup-0001-misc_information.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/144616/3/anie201805004_am.pdf
dc.identifier.doi10.1002/anie.201805004
dc.identifier.sourceAngewandte Chemie International Edition
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