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The Influence of Chemical Modification on Linker Rotational Dynamics in Metal–Organic Frameworks
dc.contributor.authorDamron, Joshua T.
dc.contributor.authorMa, Jialiu
dc.contributor.authorKurz, Ricardo
dc.contributor.authorSaalwächter, Kay
dc.contributor.authorMatzger, Adam J.
dc.contributor.authorRamamoorthy, Ayyalusamy
dc.date.accessioned2018-07-13T15:47:54Z
dc.date.available2019-09-04T20:15:39Zen
dc.date.issued2018-07-09
dc.identifier.citationDamron, Joshua T.; Ma, Jialiu; Kurz, Ricardo; Saalwächter, Kay ; Matzger, Adam J.; Ramamoorthy, Ayyalusamy (2018). "The Influence of Chemical Modification on Linker Rotational Dynamics in Metal–Organic Frameworks." Angewandte Chemie 130(28): 8814-8817.
dc.identifier.issn0044-8249
dc.identifier.issn1521-3757
dc.identifier.urihttps://hdl.handle.net/2027.42/144665
dc.description.abstractThe robust synthetic flexibility of metal–organic frameworks (MOFs) offers a promising class of tailorable materials, for which the ability to tune specific physicochemical properties is highly desired. This is achievable only through a thorough description of the consequences for chemical manipulations both in structure and dynamics. Magic angle spinning solid‐state NMR spectroscopy offers many modalities in this pursuit, particularly for dynamic studies. Herein, we employ a separated‐local‐field NMR approach to show how specific intraframework chemical modifications to MOF UiO‐66 heavily modulate the dynamic evolution of the organic ring moiety over several orders of magnitude.Ringrotationen in MOFs wurden in Festkörper‐NMR‐Experimenten unter Probenrotation um den magischen Winkel durch dipolare Dephasierung über die Rotorperiode detektiert. Informationen zur Dynamik in Metall‐organischen Gerüsten sind wichtig, weil die Geschwindigkeit der Rotationsbewegung des Linkers die Sorptions‐ und Trenneigenschaften von MOFs beeinflusst.
dc.publisherBlackwell Science Ltd
dc.publisherWiley Periodicals, Inc.
dc.subject.otherDFT-Rechnungen
dc.subject.otherMetall-organische Gerüste
dc.subject.otherMikroporöse Materialien
dc.subject.otherNMR-Spektroskopie
dc.subject.otherDynamik
dc.titleThe Influence of Chemical Modification on Linker Rotational Dynamics in Metal–Organic Frameworks
dc.typeArticleen_US
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemical Engineering
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbsecondlevelMaterials Science and Engineering
dc.subject.hlbtoplevelScience
dc.subject.hlbtoplevelEngineering
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/144665/1/ange201805004_am.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/144665/2/ange201805004-sup-0001-misc_information.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/144665/3/ange201805004.pdf
dc.identifier.doi10.1002/ange.201805004
dc.identifier.sourceAngewandte Chemie
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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