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Room‐Temperature Ferroelectricity in an Organic Cocrystal

dc.contributor.authorWiscons, Ren A.
dc.contributor.authorGoud, N. Rajesh
dc.contributor.authorDamron, Joshua T.
dc.contributor.authorMatzger, Adam J.
dc.date.accessioned2018-08-13T18:48:55Z
dc.date.available2019-09-04T20:15:38Zen
dc.date.issued2018-07-16
dc.identifier.citationWiscons, Ren A.; Goud, N. Rajesh; Damron, Joshua T.; Matzger, Adam J. (2018). "Room‐Temperature Ferroelectricity in an Organic Cocrystal." Angewandte Chemie 130(29): 9182-9185.
dc.identifier.issn0044-8249
dc.identifier.issn1521-3757
dc.identifier.urihttps://hdl.handle.net/2027.42/145232
dc.description.abstractFerroelectric materials exhibit switchable remanent polarization due to reversible symmetry breaking under an applied electric field. Previous research has leveraged temperature‐induced neutral‐ionic transitions in charge‐transfer (CT) cocrystals to access ferroelectrics that operate through displacement of molecules under an applied field. However, displacive ferroelectric behavior is rare in organic CT cocrystals and achieving a Curie temperature (TC) above ambient has been elusive. Here a cocrystal between acenaphthene and 2,3,5,6‐tetrafluoro‐7,7,8,8‐tetracyanoquinodimethane is presented that shows switchable remanent polarization at room temperature (TC=68 °C). Raman spectroscopy, X‐ray diffraction, and solid‐state NMR spectroscopy indicate the ferroelectric behavior is facilitated by acenaphthene (AN) rotation, deviating from conventional design strategies for CT ferroelectrics. These findings highlight the relevance of non‐CT interactions in the design of displacive ferroelectric cocrystals.Schaltbare Restpolarisierung bei Raumtemperatur wird für den organischen Ladungstransferkokristall AN‐F4TCNQ beobachtet. Die Curie‐Temperatur für den ferroelektrischen Übergang wurde mit dynamischer Differenzkalorimetrie zu 68 °C bestimmt. Die anschließende elektronische und strukturelle Charakterisierung von AN‐F4TCNQ ergab, dass dynamische Bewegungen von Acenaphthen (AN) zu der hohen Wechseltemperatur der Polarisierung beitragen.
dc.publisherWiley Periodicals, Inc.
dc.subject.otherPolarisierung
dc.subject.otherOrganische Elektronik
dc.subject.otherLadungstransfer
dc.subject.otherKristall-Engineering
dc.subject.otherFerroelektrika
dc.titleRoom‐Temperature Ferroelectricity in an Organic Cocrystal
dc.typeArticleen_US
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemical Engineering
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbsecondlevelMaterials Science and Engineering
dc.subject.hlbtoplevelEngineering
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/145232/1/ange201805071.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/145232/2/ange201805071-sup-0001-misc_information.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/145232/3/ange201805071_am.pdf
dc.identifier.doi10.1002/ange.201805071
dc.identifier.sourceAngewandte Chemie
dc.identifier.citedreferenceS. Horiuchi, R. Kumai, Y. Okimoto, Y. Tokura, Synth. Met. 2003, 133–134, 615 – 618.
dc.identifier.citedreferenceA. S. Tayi, A. K. Shveyd, A. C.-H. Sue, J. M. Szarko, B. S. Rolczynski, D. Cao, T. J. Kennedy, A. A. Sarjeant, C. L. Stern, W. F. Paxton, W. Wu, S. K. Dey, A. C. Fahrenbach, J. R. Guest, H. Mohseni, L. X. Chen, K. L. Wang, J. F. Stoddart, S. I. Stupp, Nature 2012, 488, 485 – 489.
dc.identifier.citedreference 
dc.identifier.citedreferenceH. M. McConnell, B. M. Hoffman, R. M. Metzger, Proc. Natl. Acad. Sci. USA 1965, 53, 46 – 50;
dc.identifier.citedreferenceC. K. Prout, J. D. Wright, Angew. Chem. Int. Ed. Engl. 1968, 7, 659 – 667; Angew. Chem. 1968, 80, 688 – 697.
dc.identifier.citedreference 
dc.identifier.citedreferenceS. Horiuchi, K. Kobayashi, R. Kuami, N. Minami, F. Kagawa, Y. Tokura, Nat. Commun. 2015, 6, 1 – 7;
dc.identifier.citedreferenceJ. Hubbard, J. B. Torrance, Phys. Rev. Lett. 1981, 47, 1750 – 1754;
dc.identifier.citedreferenceF. Kagawa, S. Horiuchi, M. Tokunaga, J. Fujioka, Y. Tokura, Nat. Phys. 2010, 6, 169 – 172.
dc.identifier.citedreferenceR. Taylor, O. Kennard, J. Am. Chem. Soc. 1982, 104, 5063 – 5070.
dc.identifier.citedreference 
dc.identifier.citedreferenceA. Salmerón-Valverde, J. G. Robles-Martínez, J. García-Serrano, R. Gómez, R. M. Ridaura, M. Quintana, A. Zehe, Mol. Eng. 1999, 8, 419 – 426;
dc.identifier.citedreferenceN. Castagnetti, G. Kociok-Köhn, E. Da Como, A. Girlando, Phys. Rev. B 2017, 95, 1 – 7;
dc.identifier.citedreferenceM. Masino, A. Girlando, A. Brillante, Phys. Rev. B 2007, 76, 1 – 7;
dc.identifier.citedreferenceA. Dengl, R. Beyer, T. Peterseim, T. Ivek, G. Untereiner, M. Dressel, J. Chem. Phys. 2014, 240, 1 – 6.
dc.identifier.citedreferenceN. Hill, J. Phys. Chem. B 2000, 104, 6694 – 6709.
dc.identifier.citedreferenceP. Batail, S. J. LaPlaca, J. J. Mayerle, J. B. Torrance, J. Am. Chem. Soc. 1981, 103, 951 – 953.
dc.identifier.citedreference 
dc.identifier.citedreferenceT. Akutagawa, H. Koshinaka, D. Sato, S. Takeda, S.-I. Noro, H. Takakashi, R. Kumai, Y. Tokura, T. Nakamura, Nat. Mater. 2009, 8, 342 – 347;
dc.identifier.citedreferenceJ. Harada, T. Shimojo, H. Oyamaguchi, H. Hasegawa, Y. Takahashi, K. Satomi, Y. Sazuki, J. Kawamata, T. Inabe, Nat. Chem. 2016, 8, 946 – 952;
dc.identifier.citedreferenceJ.-I. Ichikawa, N. Hoshino, T. Takeda, T. Akutagawa, J. Am. Chem. Soc. 2015, 137, 13155 – 13160.
dc.identifier.citedreference 
dc.identifier.citedreferenceJ.-Y. Le Questel, M. Berthelot, C. Laurence, J. Phys. Org. Chem. 2000, 13, 347 – 358;
dc.identifier.citedreferenceM. Domagała, S. J. Grabowski, J. Phys. Chem. A 2005, 109, 5683 – 5688.
dc.identifier.citedreferenceCCDC  1840748–1840751 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre.
dc.identifier.citedreference 
dc.identifier.citedreferenceZ. G. Soos, Annu. Rev. Phys. Chem. 1974, 25, 121 – 153;
dc.identifier.citedreferenceJ. B. Torrance, J. E. Vazquez, J. J. Mayerle, V. Y. Lee, Phys. Rev. Lett. 1981, 46, 253 – 257;
dc.identifier.citedreferenceJ. B. Torrance, A. Girlando, J. J. Mayerle, J. I. Crowley, V. Y. Lee, P. Batail, Phys. Rev. Lett. 1981, 47, 1747 – 1750;
dc.identifier.citedreferenceS. Horiuchi, Y. Okimoto, R. Kuami, Y. Tokura, J. Am. Chem. Soc. 2001, 123, 665 – 670;
dc.identifier.citedreferenceS. Horiuchi, R. Kumai, Y. Okimoto, Y. Tokura, Chem. Phys. 2006, 325, 78 – 91;
dc.identifier.citedreferenceI. Shokaryev, A. J. C. Buurma, O. D. Jurchescu, M. A. Uijttewaal, G. A. de Wijs, T. T. M. Palstra, R. A. de Groot, J. Phys. Chem. A 2008, 112, 2497 – 2502;
dc.identifier.citedreferenceK. P. Goetz, D. Vermeulen, M. E. Payne, C. Kloc, L. E. McNeil, O. D. Jurchescu, J. Mater. Chem. C 2014, 2, 3065 – 3076;
dc.identifier.citedreferenceN. R. Goud, A. J. Matzger, Cryst. Growth Des. 2017, 17, 328 – 336;
dc.identifier.citedreferenceS. Horiuchi, Y. Okimoto, R. Kumai, Y. Tokura, Science 2003, 299, 229 – 232.
dc.identifier.citedreference 
dc.identifier.citedreferenceA. S. Tayi, A. Kaeser, M. Matsumo, T. Aida, S. I. Stupp, Nat. Chem. 2015, 7, 281 – 292;
dc.identifier.citedreferenceS. Horiuchi, F. Ishii, R. Kumai, Y. Okimoto, H. Tachibana, N. Nagaosa, Y. Tokura, Nat. Mater. 2005, 4, 163 – 166;
dc.identifier.citedreferenceS. Chen, C. Z. Xiao, J. Am. Chem. Soc. 2014, 136, 6428 – 6436.
dc.identifier.citedreferenceS. Horiuchi, Y. Tokura, Nature 2008, 7, 357 – 366.
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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