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Weight‐of‐Evidence Approach for Assessing Removal of Metals from the Water Column for Chronic Environmental Hazard Classification
dc.contributor.authorBurton, G. Allen
dc.contributor.authorHudson, Michelle L.
dc.contributor.authorHuntsman, Philippa
dc.contributor.authorCarbonaro, Richard F.
dc.contributor.authorRader, Kevin J.
dc.contributor.authorWaeterschoot, Hugo
dc.contributor.authorBaken, Stijn
dc.contributor.authorGarman, Emily
dc.date.accessioned2019-09-30T15:32:04Z
dc.date.availableWITHHELD_13_MONTHS
dc.date.available2019-09-30T15:32:04Z
dc.date.issued2019-09
dc.identifier.citationBurton, G. Allen; Hudson, Michelle L.; Huntsman, Philippa; Carbonaro, Richard F.; Rader, Kevin J.; Waeterschoot, Hugo; Baken, Stijn; Garman, Emily (2019). "Weight‐of‐Evidence Approach for Assessing Removal of Metals from the Water Column for Chronic Environmental Hazard Classification." Environmental Toxicology and Chemistry 38(9): 1839-1849.
dc.identifier.issn0730-7268
dc.identifier.issn1552-8618
dc.identifier.urihttps://hdl.handle.net/2027.42/151334
dc.description.abstractThe United Nations and the European Union have developed guidelines for the assessment of long‐term (chronic) chemical environmental hazards. This approach recognizes that these hazards are often related to spillage of chemicals into freshwater environments. The goal of the present study was to examine the concept of metal ion removal from the water column in the context of hazard assessment and classification. We propose a weight‐of‐evidence approach that assesses several aspects of metals including the intrinsic properties of metals, the rate at which metals bind to particles in the water column and settle, the transformation of metals to nonavailable and nontoxic forms, and the potential for remobilization of metals from sediment. We developed a test method to quantify metal removal in aqueous systems: the extended transformation/dissolution protocol (T/DP‐E). The method is based on that of the Organisation for Economic Co‐operation and Development (OECD). The key element of the protocol extension is the addition of substrate particles (as found in nature), allowing the removal processes to occur. The present study focused on extending this test to support the assessment of metal removal from aqueous systems, equivalent to the concept of “degradability” for organic chemicals. Although the technical aspects of our proposed method are different from the OECD method for organics, its use for hazard classification is equivalent. Models were developed providing mechanistic insight into processes occurring during the T/DP‐E method. Some metals, such as copper, rapidly decreased (within 96 h) under the 70% threshold criterion, whereas others, such as strontium, did not. A variety of method variables were evaluated and optimized to allow for a reproducible, realistic hazard classification method that mimics reasonable worst‐case scenarios. We propose that this method be standardized for OECD hazard classification via round robin (ring) testing to ascertain its intra‐ and interlaboratory variability. Environ Toxicol Chem 2019;38:1839–1849. © 2019 SETAC.
dc.publisherWiley Periodicals, Inc.
dc.publisherAmerican Chemical Society
dc.subject.otherAquatic metals
dc.subject.otherOrganisation for Economic Co‐operation and Development environmental protocols
dc.subject.otherMetal classification
dc.subject.otherMetal hazards in aquatic systems
dc.titleWeight‐of‐Evidence Approach for Assessing Removal of Metals from the Water Column for Chronic Environmental Hazard Classification
dc.typeArticle
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelBiological Chemistry
dc.subject.hlbsecondlevelNatural Resources and Environment
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/151334/1/etc4470_am.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/151334/2/etc4470.pdf
dc.identifier.doi10.1002/etc.4470
dc.identifier.sourceEnvironmental Toxicology and Chemistry
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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