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Achieving Balanced Energetics through Cocrystallization
dc.contributor.authorBellas, Michael K.
dc.contributor.authorMatzger, Adam J.
dc.date.accessioned2020-01-13T15:08:12Z
dc.date.availableWITHHELD_11_MONTHS
dc.date.available2020-01-13T15:08:12Z
dc.date.issued2019-11-25
dc.identifier.citationBellas, Michael K.; Matzger, Adam J. (2019). "Achieving Balanced Energetics through Cocrystallization." Angewandte Chemie 131(48): 17345-17348.
dc.identifier.issn0044-8249
dc.identifier.issn1521-3757
dc.identifier.urihttps://hdl.handle.net/2027.42/152711
dc.description.abstractAchieving energetic materials with a balanced ratio of oxidant to fuel is a challenge that has been difficult to meet through molecular synthesis. The alternative approach, composite formulation, fails to achieve intimate association of the components to the detriment of performance. Herein, the energetic oxidizer ammonium dinitramide (ADN) is combined with fuel‐rich pyrazine‐1,4‐dioxide via cocrystallization. The result is a material with a balanced oxidant/fuel ratio in which the components maintain intimate association. The material exhibits desirable physical and energetic properties which are much improved over ADN and comparable to contemporary energetics.Balanceakt: Eine neu entwickelte Methode ermöglicht die Herstellung von sauerstoffbalancierten energetischen Materialien durch Kokristallisation. Sie vermeidet die Risiken der molekularen Synthese und erreicht eine innige Verbindung von oxidierenden und Brennstoffgruppen. Angewendet auf Ammoniumdinitramid macht die Methode ein energetisches Material mit verbesserten physikalischen und energetischen Eigenschaften zugänglich.
dc.publisher, 2nd ed.
dc.publisherWiley Periodicals, Inc.
dc.subject.otherKristall-Engineering
dc.subject.otherEnergetik
dc.subject.otherKokristalle
dc.subject.otherNichtkovalente Wechselwirkungen
dc.subject.otherAmmoniumdinitramid
dc.titleAchieving Balanced Energetics through Cocrystallization
dc.typeArticle
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemical Engineering
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbsecondlevelMaterials Science and Engineering
dc.subject.hlbtoplevelScience
dc.subject.hlbtoplevelEngineering
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/152711/1/ange201908709-sup-0001-misc_information.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/152711/2/ange201908709.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/152711/3/ange201908709_am.pdf
dc.identifier.doi10.1002/ange.201908709
dc.identifier.sourceAngewandte Chemie
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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