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Interrupted Carbonyl‐Alkyne Metathesis
dc.contributor.authorMcFarlin, Austin T.
dc.contributor.authorWatson, Rebecca B.
dc.contributor.authorZehnder, Troy E.
dc.contributor.authorSchindler, Corinna S.
dc.date.accessioned2020-02-05T15:07:11Z
dc.date.availableWITHHELD_12_MONTHS
dc.date.available2020-02-05T15:07:11Z
dc.date.issued2020-01-23
dc.identifier.citationMcFarlin, Austin T.; Watson, Rebecca B.; Zehnder, Troy E.; Schindler, Corinna S. (2020). "Interrupted Carbonyl‐Alkyne Metathesis." Advanced Synthesis & Catalysis 362(2): 365-369.
dc.identifier.issn1615-4150
dc.identifier.issn1615-4169
dc.identifier.urihttps://hdl.handle.net/2027.42/153682
dc.description.abstractCarbonyl‐olefin metathesis and carbonyl‐alkyne metathesis represent established reactivity modes between carbonyls, alkenes, and alkynes under Lewis and Brønsted acid catalysis. Recently, an interrupted carbonyl‐olefin metathesis reaction has been reported that results in tetrahydrofluorenes via a distinct fragmentation of the reactive intermediate. We herein report the development of an analogous transformation interrupting the carbonyl‐alkyne metathesis reaction path resulting in dihydrofluorene products relying on Lewis acidic superelectrophiles as active catalytic species.
dc.publisherWiley-VCH
dc.subject.otherNazarov cyclization
dc.subject.othercarbonyl-alkyne metathesis
dc.subject.otherinterrupted carbonyl-alkyne metathesis
dc.subject.othersuperelectrophile
dc.subject.otherLewis acid catalysis
dc.titleInterrupted Carbonyl‐Alkyne Metathesis
dc.typeArticle
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/153682/1/adsc201901358.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/153682/2/adsc201901358_am.pdf
dc.description.bitstreamurlhttps://deepblue.lib.umich.edu/bitstream/2027.42/153682/3/adsc201901358-sup-0001-misc_information.pdf
dc.identifier.doi10.1002/adsc.201901358
dc.identifier.sourceAdvanced Synthesis & Catalysis
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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