Boosting Oxygen and Peroxide Reduction Reactions on PdCu Intermetallic Cubes
dc.contributor.author | Zhang, Qingfeng | |
dc.contributor.author | Li, Fan | |
dc.contributor.author | Lin, Lina | |
dc.contributor.author | Peng, Jiaheng | |
dc.contributor.author | Zhang, Wencong | |
dc.contributor.author | Chen, Wenlong | |
dc.contributor.author | Xiang, Qian | |
dc.contributor.author | Shi, Fenglei | |
dc.contributor.author | Shang, Wen | |
dc.contributor.author | Tao, Peng | |
dc.contributor.author | Song, Chengyi | |
dc.contributor.author | Huang, Rong | |
dc.contributor.author | Zhu, Hong | |
dc.contributor.author | Deng, Tao | |
dc.contributor.author | Wu, Jianbo | |
dc.date.accessioned | 2020-07-02T20:32:49Z | |
dc.date.available | WITHHELD_12_MONTHS | |
dc.date.available | 2020-07-02T20:32:49Z | |
dc.date.issued | 2020-06-17 | |
dc.identifier.citation | Zhang, Qingfeng; Li, Fan; Lin, Lina; Peng, Jiaheng; Zhang, Wencong; Chen, Wenlong; Xiang, Qian; Shi, Fenglei; Shang, Wen; Tao, Peng; Song, Chengyi; Huang, Rong; Zhu, Hong; Deng, Tao; Wu, Jianbo (2020). "Boosting Oxygen and Peroxide Reduction Reactions on PdCu Intermetallic Cubes." ChemElectroChem 7(12): 2614-2620. | |
dc.identifier.issn | 2196-0216 | |
dc.identifier.issn | 2196-0216 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/155903 | |
dc.description.abstract | Palladium‐based nanocatalysts have the potential to replace platinum‐based catalysts for fuel‐cell reactions in alkaline electrolytes, especially PdCu intermetallic nanoparticles with high electrochemical activity and stability. However, unlike the synthetic methods for obtaining the nanoparticles, the effect of PdCu shape on the performance is relatively less well studied. Here, we demonstrate the facet dependence of PdCu intermetallics on the oxygen reduction reaction (ORR) and peroxide reduction, and reveal that the {100} dominant PdCu cubes have a much higher ORR mass activity and specific activity than spheres at 0.9 V vs. RHE, which is four and five times that of commercial Pd/C and Pt/C catalysts, respectively, and show only a 31.7 % decay after 30 000 cycles in the stability test. Moreover, cubic PdCu nanoparticles show higher peroxide electroreduction activity than Pd cubes and PdCu spheres. Density functional theory (DFT) calculation reveals that the huge difference originates from the reduction in oxygen adsorption energy and energy barrier of peroxide decomposition on the ordered {100} PdCu surface. Given the relationship between the shape and electrochemical performance, this study will contribute to further research on electrocatalytic improvements of catalysts in alkaline environments.Shape the future: PdCu intermetallic cubes and spheres are synthesized to investigate the facet dependence on the oxygen reduction reaction and peroxide reduction. The cubes show large improvements in mass activity towards both reactions, compared with the spheres. DFT calculation uncovers that the dominant {100} faces of the cubes offer more appropriate oxygen adsorption and are thermodynamically favorable for peroxide reduction compared to the surface of spheres. | |
dc.publisher | Wiley Periodicals, Inc. | |
dc.subject.other | oxygen reduction reaction | |
dc.subject.other | nanoparticles | |
dc.subject.other | intermetallic phases | |
dc.subject.other | electrocatalysts | |
dc.subject.other | peroxide reduction | |
dc.title | Boosting Oxygen and Peroxide Reduction Reactions on PdCu Intermetallic Cubes | |
dc.type | Article | |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Chemistry | |
dc.subject.hlbtoplevel | Science | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/155903/1/celc202000381.pdf | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/155903/2/celc202000381_am.pdf | |
dc.description.bitstreamurl | https://deepblue.lib.umich.edu/bitstream/2027.42/155903/3/celc202000381-sup-0001-misc_information.pdf | |
dc.identifier.doi | 10.1002/celc.202000381 | |
dc.identifier.source | ChemElectroChem | |
dc.identifier.citedreference | Y. Qiu, L. Xin, Y. Li, I. T. McCrum, F. Guo, T. Ma, Y. Ren, Q. Liu, L. Zhou, S. Gu, et al., J. Am. Chem. Soc. 2018, 1 – 20. | |
dc.identifier.citedreference | L. Arroyo-Ramírez, R. Montano-Serrano, T. Luna-Pineda, F. R. Román, R. G. Raptis, C. R. Cabrera, ACS Appl. Mater. Interfaces 2013, 5, 11603 – 11612. | |
dc.identifier.citedreference | M. Neergat, V. Gunasekar, R. Rahul, J. Electroanal. Chem. 2011, 658, 25 – 32. | |
dc.identifier.citedreference | M. H. Shao, K. Sasaki, R. R. Adzic, J. Am. Chem. Soc. 2006, 128, 3526 – 3527. | |
dc.identifier.citedreference | Y. Dai, P. Yu, Q. Huang, K. Sun, Fuel Cells 2016, 16, 165 – 169. | |
dc.identifier.citedreference | J. Wu, S. Shan, J. Luo, P. Joseph, V. Petkov, C. J. Zhong, ACS Appl. Mater. Interfaces 2015, 7, 25906 – 25913. | |
dc.identifier.citedreference | J. Mao, Y. Liu, Z. Chen, D. Wang, Y. Li, Chem. Commun. 2014, 50, 4588 – 4591. | |
dc.identifier.citedreference | W. P. Wu, A. P. Periasamy, G. L. Lin, Z. Y. Shih, H. T. Chang, J. Mater. Chem. A 2015, 3, 9675 – 9681. | |
dc.identifier.citedreference | Y. Yang, C. Dai, D. Wu, Z. Liu, D. Cheng, ChemElectroChem 2018, 5, 2571 – 2576. | |
dc.identifier.citedreference | Z. Yin, W. Zhou, Y. Gao, D. Ma, C. J. Kiely, X. Bao, Chem. Eur. J. 2012, 18, 4887 – 4893. | |
dc.identifier.citedreference | L. Zhang, S. Il Choi, J. Tao, H. C. Peng, S. Xie, Y. Zhu, Z. Xie, Y. Xia, Adv. Funct. Mater. 2014, 24, 7520 – 7529. | |
dc.identifier.citedreference | X. Wu, Q. Xu, Y. Yan, J. Huang, X. Li, Y. Jiang, H. Zhang, D. Yang, RSC Adv. 2018, 8, 34853 – 34859. | |
dc.identifier.citedreference | A. Dasgupta, R. M. Rioux, Catal. Today 2019, 330, 2 – 15. | |
dc.identifier.citedreference | Y. Yan, J. S. Du, K. D. Gilroy, D. Yang, Y. Xia, H. Zhang, Adv. Mater. 2017, 29, 1605997. | |
dc.identifier.citedreference | C. Wang, D. P. Chen, X. Sang, R. R. Unocic, S. E. Skrabalak, ACS Nano 2016, 10, 6345 – 6353. | |
dc.identifier.citedreference | K. Jiang, P. Wang, S. Guo, X. Zhang, X. Shen, G. Lu, D. Su, X. Huang, Angew. Chem. Int. Ed. 2016, 55, 9030 – 9035; Angew. Chem. 2016, 128, 9176 – 9181. | |
dc.identifier.citedreference | C. Wang, X. Sang, J. T. L. Gamler, D. P. Chen, R. R. Unocic, S. E. Skrabalak, Nano Lett. 2017, 17, 5526 – 5532. | |
dc.identifier.citedreference | L. Zhang, F. Hou, Y. Tan, Chem. Commun. 2012, 48, 7152 – 7154. | |
dc.identifier.citedreference | J. T. L. Gamler, A. Leonardi, H. M. Ashberry, N. N. Daanen, Y. Losovyj, R. R. Unocic, M. Engel, S. E. Skrabalak, ACS Nano 2019, 13, 4008 – 4017. | |
dc.identifier.citedreference | D. Wu, C. Dai, S. Li, D. Cheng, Chem. Lett. 2015, 44, 1101 – 1103. | |
dc.identifier.citedreference | Q. Gao, Y. Ju, D. An, M. Gao, C. Cui, J. Liu, H.-P. Cong, S.-H. Yu, ChemSusChem 2013, 6, 1878 – 1882. | |
dc.identifier.citedreference | M. Jin, H. Liu, H. Zhang, Z. Xie, J. Liu, Y. Xia, Nano Res. 2011, 4, 83 – 91. | |
dc.identifier.citedreference | M. Shao, J. H. Odell, S. Il Choi, Y. Xia, Electrochem. Commun. 2013, 31, 46 – 48. | |
dc.identifier.citedreference | S. Rudi, C. Cui, L. Gan, P. Strasser, Electrocatalysis 2014, 5, 408 – 418. | |
dc.identifier.citedreference | J. Greeley, I. E. L. Stephens, A. S. Bondarenko, T. P. Johansson, H. A. Hansen, T. F. Jaramillo, J. Rossmeisl, I. Chorkendorff, J. K. Nørskov, Nat. Chem. 2009, 1, 552 – 556. | |
dc.identifier.citedreference | X. Li, L. An, X. Wang, F. Li, R. Zou, D. Xia, J. Mater. Chem. 2012, 22, 6047 – 6052. | |
dc.identifier.citedreference | Y. Xiong, H. Shan, Z. Zhou, Y. Yan, W. Chen, Y. Yang, Y. Liu, H. Tian, J. Wu, H. Zhang, et al., Small 2017, 13, 1603423. | |
dc.identifier.citedreference | J. Wu, P. Li, Y. T. Pan, S. Warren, X. Yin, H. Yang, Chem. Soc. Rev. 2012, 41, 8066 – 8074. | |
dc.identifier.citedreference | F. Xiao, Y. Li, X. Zan, K. Liao, R. Xu, H. Duan, Adv. Funct. Mater. 2012, 22, 2487 – 2494. | |
dc.identifier.citedreference | M. Luo, Y. Sun, Y. Qin, S. Chen, Y. Li, C. Li, Y. Yang, D. Wu, N. Xu, Y. Xing, et al., Chem. Mater. 2018, 30, 6660 – 6667. | |
dc.identifier.citedreference | H. S. Wroblowa, Y.-C. Pan, G. Razumney, J. Electroanal. Chem. Interfacial Electrochem. 1976, 69, 195 – 201. | |
dc.identifier.citedreference | N. M. Marković, T. J. Schmidt, V. Stamenković, P. N. Ross, Fuel Cells 2001, 1, 105 – 116. | |
dc.identifier.citedreference | J. K. Nørskov, J. Rossmeisl, A. Logadottir, L. Lindqvist, J. R. Kitchin, T. Bligaard, H. Jónsson, J. Phys. Chem. B 2004, 108, 17886 – 17892. | |
dc.identifier.citedreference | Y. Sha, T. H. Yu, B. V. Merinov, W. A. Goddard, ACS Catal. 2014, 4, 1189 – 1197. | |
dc.identifier.citedreference | W. Zhang, G. Fan, H. Yi, G. Jia, Z. Li, C. Yuan, Y. Bai, D. Fu, Small 2018, 14, 1703713. | |
dc.identifier.citedreference | J. Wu, H. Yang, Acc. Chem. Res. 2013, 46, 1848 – 1857. | |
dc.identifier.citedreference | Z. Peng, H. Yang, Nano Today 2009, 4, 143 – 164. | |
dc.identifier.citedreference | M. Shao, Q. Chang, J. P. Dodelet, R. Chenitz, Chem. Rev. 2016, 116, 3594 – 3657. | |
dc.identifier.citedreference | J. Wu, J. Zhang, Z. Peng, S. Yang, F. T. Wagner, H. Yang, J. Am. Chem. Soc. 2010, 132, 4984 – 4985. | |
dc.identifier.citedreference | J. Wu, L. Qi, H. You, A. Gross, J. Li, H. Yang, J. Am. Chem. Soc. 2012, 134, 11880 – 11883. | |
dc.identifier.citedreference | X. Tian, X. Zhao, Y. Su, L. Wang, H. Wang, D. Dang, B. Chi, H. Liu, E. J. M. Hensen, X. W. Lou, B. Y. Xia, Science 2019, 856, 850 – 856. | |
dc.identifier.citedreference | A. Chalgin, F. Shi, F. Li, Q. Xiang, W. Chen, C. Song, P. Tao, W. Shang, T. Deng, J. Wu, CrystEngComm 2017, 19, 6964 – 6971. | |
dc.identifier.citedreference | Y. Ma, W. Gao, H. Shan, W. Chen, W. Shang, P. Tao, C. Song, C. Addiego, T. Deng, X. Pan, et al., Adv. Mater. 2017, 29, 1 – 8. | |
dc.identifier.citedreference | J. Wu, A. Gross, H. Yang, Nano Lett. 2011, 11, 798 – 802. | |
dc.identifier.citedreference | J. Wu, H. Yang, Nano Res. 2011, 4, 72 – 82. | |
dc.identifier.citedreference | F. Li, Y. Qin, A. Chalgin, X. Gu, W. Chen, Y. Ma, Q. Xiang, Y. Wu, F. Shi, Y. Zong, et al., ChemistrySelect 2019, 4, 5264 – 5268. | |
dc.identifier.citedreference | M. Luo, Z. Zhao, Y. Zhang, Y. Sun, Y. Xing, F. Lv, Y. Yang, X. Zhang, S. Hwang, Y. Qin, et al., Nature 2019, 574, 81 – 85. | |
dc.identifier.citedreference | D. Wang, H. L. Xin, Y. Yu, H. Wang, E. Rus, D. A. Muller, H. D. Abruña, J. Am. Chem. Soc. 2010, 132, 17664 – 17666. | |
dc.identifier.citedreference | F. Liao, T. W. B. Lo, S. C. E. Tsang, ChemCatChem 2015, 7, 1998 – 2014. | |
dc.identifier.citedreference | M. Shao, T. Yu, J. H. Odell, M. Jin, Y. Xia, Chem. Commun. 2011, 47, 6566. | |
dc.identifier.citedreference | T. C. Nagaiah, D. Schäfer, W. Schuhmann, N. Dimcheva, Anal. Chem. 2013, 85, 7897 – 7903. | |
dc.identifier.citedreference | G. J. DeYulia, J. M. Cárcamo, O. Bórquez-Ojeda, C. C. Shelton, D. W. Golde, Proc. Natl. Acad. Sci. USA 2005, 102, 5044 – 5049. | |
dc.identifier.citedreference | Y. Zhang, M. Janyasupab, C.-W. Liu, P.-Y. Lin, K.-W. Wang, J. Xu, C.-C. Liu, Int. J. Electrochem. 2012, 2012, 1 – 8. | |
dc.identifier.citedreference | B. D. Adams, C. K. Ostrom, A. Chen, J. Electrochem. Soc. 2011, 158, 434 – 439. | |
dc.identifier.citedreference | X. Sun, S. Guo, Y. Liu, S. Sun, Nano Lett. 2012, 12, 4859 – 4863. | |
dc.identifier.citedreference | B. Li, J. Prakash, Electrochem. Commun. 2009, 11, 1162 – 1165. | |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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